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Anthropogenic mineral generation and its potential resource supply:The case of niobium

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Science China Earth Sciences 2024年第8期67卷 2583-2591页

作者： Xianlai ZENg Moisés gómez Mahmoud BAKRY yong gENg Jinhui LI School of Environment Tsinghua UniversityBeijing 100084China School of Environmental Science and Engineering Shanghai Jiao Tong UniversityShanghai 200240China School of International and Public Affairs Shanghai Jiao Tong UniversityShanghai 200030China

The strategy of carbon neutrality is reshaping the global landscape of resource flow and *** the final sink of geological minerals,the proliferated anthropogenic minerals,also called secondary resources,play an increasingly important role in resource supply *** is a critical metal that lacks full concern for its *** fundamental principle of niobium circularity is to recycle and maintain the material as close to the manufacturing process as *** we estimate the niobium-containing applications lost at their end-of-life,underscoring the imperative to minimize such ***,we elucidate the extraction processes for scrap and alloy quantities throughout the industry's *** from anticipated waste generated by the majority of niobium applications,a forecast indicates a potential loss of approximately 168 kt by 2090 in the absence of ***,with a recycling efficiency of 90%for niobium,the projected loss diminishes to approximately 16 *** delve into the significance of niobium's circular economy and explore various aspects that demand further investigation for a seamless transition from linear to circular practices.

关键词： Niobium Anthropogenic mineral Circular economy Recycling Sustainability

Planar matrices and arrays of Feynman diagrams:poles for higher k

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Communications in Theoretical Physics 2024年第4期76卷 1-13页

作者： Alfredo guevara yong Zhang Perimeter Institute for Theoretical Physics WaterlooON N2L 2Y5Canada Department of Physics&Astronomy University of WaterlooWaterlooON N2L 3G1Canada Society of Fellows Harvard UniversityCambridgeMA 02138United States of America CAS Key Laboratory of Theoretical Physics Institute of Theoretical PhysicsChinese Academy of SciencesBeijing 100190China School of Physical Sciences University of Chinese Academy of SciencesNo.19A Yuquan RoadBejing 100049China

Planar arrays of tree diagrams were introduced as a generalization of Feynman diagrams that enable the computation of biadjoint amplitudes m_(n)(^(k))for k>*** this follow-up work,we investigate the poles of m_(n)(^(k))from the perspective of such *** general k,we characterize the underlying polytope as a Flag Complex and propose a computation of the amplitude-based solely on the knowledge of the poles,whose number is drastically less than the number of the full *** an example,we first provide all the poles for the cases(k,n)=(3,7),(3,8),(3,9),(3,10),(4,8)and(4,9)in terms of their planar arrays of degenerate Feynman *** then implement simple compatibility criteria together with an addition operation between arrays and recover the full collections/arrays for such *** the way,we implement hard and soft kinematical limits,which provide a map between the poles in kinematic space and their combinatoric *** use the operation to give a proof of a previously conjectured combinatorial duality for arrays in(k,n)and(n-k,n).We also outline the relation to boundary maps of the hypersimplex Δ_(k,n) and rays in the tropical grassmannian Tr(k,n).

关键词： Feynman diagrams biadjoint amplitudes poles

The Essential 2-rank for Classical groups

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Acta Mathematica Sinica,English Series 2024年第9期40卷 2169-2186页

作者： Jian Bei AN yong XU Department of Mathematics University of AucklandAucklandNew Zealand School of Mathematics and Statistics He’nan University of Science and TechnologyLuoyang 471023P.R.China

Let g be a symplectic or orthogonal group defined over a finite field with odd characteristic and let D≤g be a Sylow *** this paper,we classify the essential 2-subgroups and determine the essential 2-rank of the Frobenius category FD(g).Together with the results of An–Dietrich and Cao–An–Zeng,this completes the work of essential subgroups and essential ranks of classical groups.

关键词： Frobenius category conjugation families essential 2-rank symplectic groups orthogonal groups

p-d Orbital Hybridization Engineered Single-Atom Catalyst for Electrocatalytic Ammonia Synthesis

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Energy & Environmental Materials 2024年第2期7卷 119-125页

作者： Jingkun Yu Xue yong Siyu Lu green Catalysis Center and College of ChemistryZhengzhou UniversityZhengzhou 450001China Department of Chemistry University of SheffieldSheffieldS37HFUK

The rational design of metal single-atom catalysts(SACs)for electrochemical nitrogen reduction reaction(NRR)is ***-dimensional metal-organic frameworks(2DMOFs)is a unique class of promising *** to now,the roles of individual metals,coordination atoms,and their synergy effect on the electroanalytic performance remain ***,in this work,a series of 2DMOFs with different metals and coordinating atoms are systematically investigated as electrocatalysts for ammonia synthesis using density functional theory *** a specific metal,a proper metal-intermediate atoms p-d orbital hybridization interaction strength is found to be a key indicator for their NRR catalytic *** hybridization interaction strength can be quantitatively described with the p-/d-band center energy difference(Δd-p),which is found to be a sufficient descriptor for both the p-d hybridization strength and the NRR *** maximum free energy change(Δg_(max))andΔd-p have a volcanic relationship with OsC_(4)(Se)_(4)located at the apex of the volcanic curve,showing the best NRR *** asymmetrical coordination environment could regulate the band structure subtly in terms of band overlap and *** work may shed new light on the application of orbital engineering in electrocatalytic NRR activity and especially promotes the rational design for SACs.

关键词： first-principle calculations Nitrogen reduction p-d orbital hybridization single-atom catalysts

Homological Transfer between Additive Categories and Higher Differential Additive Categories

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Acta Mathematica Sinica,English Series 2024年第5期40卷 1325-1344页

作者： Xi TANg Zhao yong HUANg School of Science Guilin University of Aerospace TechnologyGuilin 541004P.R.China Department of Mathematics Nanjing UniversityNanjing 210093P.R.China

given an additive category C and an integer n≥*** higher differential additive category consists of objects X in C equipped with an endomorphism ϵ_(X)satisfying ϵ_(X)^(n).Let R be a,finite-dimensional basic algebra over an algebraically closed field and T the augmenting functor from the category of finitely generated left R-modules to that of finitely generated left R/(t^(n))-*** is proved that a finitely generated left R-module M isτ-rigid(respectively,(support)τ-tilting,almost completeτ-tilting)if and only if so is T(M)as a left R[t]/(t^(n))-***,R isτm-selfinjective if and only if so is R[t]/(t^(n)).

关键词： Higher differential objects wakamatsu tilting subcategories g_(ω)-projective modules sup-portτ-tilting modules τ_(m)-selfinjective algebras precluster tilting subcategories

Investigation of acoustic attributes based on preference and perceptional acoustics of Korean traditional halls for optimal design solutions

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Building Simulation 2024年第5期17卷 723-738页

作者： Beta Bayu Santika Haram Lee Jin yong Jeon Department of Architectural Engineering Hanyang UniversitySeoul 04763R.O.Korea

Immersed in the rich tapestry of traditional culture,gugak,the traditional Korean music stands as a captivating embodiment of artistic *** study embarked on a comprehensive evaluation of a gugak hall,employing acoustic measurements,computer simulations,and subjective perception *** evaluation focused on the reverberance,clarity,spatial impression,and preference,unravelling the secrets that shape the immersive gugak *** intricate computer simulations and auralization,the experience of gugak performances was meticulously brought to life,allowing exploration under diverse conditions by adjusting stage volume ratios from -20% to+20% and modifying the interior materials,including the walls,ceiling,and lateral *** gugak halls exhibited relatively low values of reverberation time(RT),early decay time(EDT),and binaural quality index(BQI)the dominant factor influencing the acoustic environment was the effect of sound strength(g).Musical clarity(C80)value did not show an inverse proportionality to the reverberation ***,genre differences between traditional Korean and Western classical music did not significantly affect listeners’perception and satisfaction with regards to reverberance,clarity,and spatial *** a result,gugak halls can adhere to the same acoustic design criteria as Western orchestra halls,since this study found that people perceived them the same *** this study,sound strength was found to be strongly correlated with perception *** was possible to enhance listeners’perception and preference regarding the acoustic environment through material and structural changes to the sidewalls and *** changes improved the reinforcement of low frequencies and simultaneously enhanced the relative effect of side ***,enhancing the reflection and spatial characteristics of the materials effectively improved listener *** on these findings,an optimal des

关键词： Korean traditional hall acoustical parameters perceptual evaluation acoustic preference stage volume ratio

Complement factor Ⅰ knockdown inhibits colon cancer development by affecting Wnt/β-catenin/c-Myc signaling pathway and glycolysis

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World Journal of gastrointestinal Oncology 2024年第6期16卷 2646-2662页

作者： yong-Jun Du Yue Jiang Yan-Mei Hou yong-Bo Shi Department of Proctology Hospital of Chengdu University of Traditional Chinese MedicineChengdu 610072Sichuan ProvinceChina School of Clinical Medicine Chengdu University of Traditional Chinese MedicineChengdu 610075Sichuan ProvinceChina Department of Proctology Zigong Hospital of Traditional Chinese MedicineZigong 643000Sichuan ProvinceChina

BACKgROUND Colon cancer(CC)occurrence and progression are considerably influenced by the tumor ***,the exact underlying regulatory mechanisms remain *** To investigate immune infiltration-related differentially expressed genes(DEgs)in CC and specifically explored the role and potential molecular mechanisms of complement factor I(CFI).METHODS Immune infiltration-associated DEgs were screened for CC using *** reverse transcription polymerase chain reaction was used to examine hub DEgs expression in the CC cell *** CFI-knockdown HT29 and HCT116 cell lines were constructed,and the diverse roles of CFI in vitro were assessed using CCK-8,5-ethynyl-2’-deoxyuridine,wound healing,and transwell *** and eosin staining and immunohistochemistry staining were employed to evaluate the influence of CFI on the tumorigenesis of CC xenograft models constructed using BALB/c male nude *** proteins associated with glycolysis and the Wnt pathway were measured using western *** Six key immune infiltration-related DEgs were screened,among which the expression of CFI,complement factor B,lymphoid enhancer binding factor 1,and SRY-related high-mobility-group box 4 was upregulated,whereas that of fatty acid-binding protein 1,and bone morphogenic protein-2 was ***,CFI could be used as a diagnostic biomarker for ***,CFI silencing inhibited CC cell proliferation,migration,invasion,and tumor ***,CFI knockdown downregulated the expression of key glycolysis-related proteins(glucose transporter type 1,hexokinase 2,lactate dehydrogenase A,and pyruvate kinase M2)and the Wnt pathway-related proteins(β-catenin and c-Myc).Further investigation indicated that CFI knockdown inhibited glycolysis in CC by blocking the Wnt/β-catenin/c-Myc *** The findings of the present study demonstrate that CFI plays a crucial role in CC development by influencing g

关键词： Colon cancer Immune infiltration Complement factor I glycolysis Wnt/β-catenin/c-Myc pathway

Constructing Lithium-Free Anode/Separator Interface via 3D Carbon Fabric Scaffold for Ultrasafe Lithium Metal Batteries

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Research 2024年第3期2023卷 359-368页

作者： Dongdong Li Shengchen Yang Zijian Zheng Wen-yong Lai State Key Laboratory of Organic Electronics and Information Displays(SKLOEID) Institute of Advanced Materials(IAM)School of Chemistry and Life SciencesNanjing University of Posts and Telecommunications9 Wenyuan RoadNanjing 210023China Department of Materials Chemistry Huzhou University1 Xueshi RoadHuzhou 313000China Laboratory for Advanced Interfacial Materials and Devices School of Fashion and TextilesDepartment of Applied Biology and Chemical TechnologyResearch Institute for Intelligent Wearable Systems(RI-IWEAR)Research Institute for Smart Energy(RISE)The Hong Kong Polytechnic UniversityHong Kong SAR 999077China

Metallic lithium represents a promising anode candidate to be utilized in future high-energy lithium ***,the undesirable dendrite growth and fragile solid-electrolyte interphase(SEI)pose critical challenge for pursuing further practical *** contrast to traditional approaches of using inert/lithiophilicity coating,here,we demonstrate a reverse strategy of introducing a highly conductive and lithophobic carbon fabric(CF)scaffold on lithium foil to guide a favorable nucleation site of lithium far away from the anode/separator *** CF scaffold with high conductivity can couple with inner electric field for achieving a uniform distribution of the lithium-ion flux,while the lithophobic feature offers the condition to guide the preferred deposition of lithium onto the underlying lithium foil,which greatly reduces the risk of dendrite-induced short ***,the SEI immersed in the CF scaffold is well supported by CF fibers and therefore exhibits extremely high stability during charge–discharge *** a result,the lithium/CF anodes show>2,000-h stable cycling at 0.5 mA cm−*** metal batteries equipped with our lithium/CF anode deliver a high capacity retention of~99.99%per cycle,i.e.,retain~97.3%capacity after 200 *** unique interface-regulation strategy is versatile for various conductive scaffolds(e.g.,ultrathin and ultralight conductive fabrics),exhibiting high superiority for highly safe lithium metal batteries.

关键词： lithium equipped versatile

Performance Study of MIMO-OSTBC Parallel Relay FSO System Based on gFDM

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Chinese Journal of Electronics 2024年第2期33卷 564-572页

作者： Rui ZHOU yong wa.g Yi wa.g Key Laboratory of Electromagnetic wave Information Technology and Metrology of Zhejiang Province College of Information Engineering China Jiliang University State Key Laboratory of Hydrology-water Resources and Hydraulic Engineering Hohai University

This paper investigates the performance of a new generalized frequency division multiplexing(gFDM)parallel relay free space optical(FSO) communication system using multi-input multi-output(MIMO) orthogonal space-time block codes(OSTBC) scheme. Under the M distribution atmospheric turbulence, taking into account the triple effects of irradiance, pointing errors and path loss, the mathematical expression of system symbol error rate is derived with the help of Meijer g-function. The symbol error performance of gFDM is compared with on-off keying,gaussian minimum shift keying, polarization shift keying and orthogonal frequency division multiplexing(OFDM)modulation methods. The effects of the MIMO-OSTBC parallel relay scheme on the gFDM system including filter roll down coefficient, the number of transmitting and receiving antennas, the number of relays, normalized beamwidth and jitter variance are analyzed, and the numerical results are verified by Monte Carlo simulation. This work provides a good foundation for engineering applications.

关键词： Monte Carlo methods Transmitting antennas Symbols Receiving antennas Modulation Jitter Transceivers