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A New One-dimensional Zigzag Chain [Zn(1,5-NDC)(2,2′-bipy)]_n Obtained from Hydrothermal Reaction

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Chinese Journal of Structural Chemistry 2006年第11期25卷 1293-1296页

作者： MENG Ze-Rong HE Xiang wu xiao-Yuan CHEN li-Juan YANG Wen-Bin LU Can-Zhong State Key Laboratory of Structural Chemistry Fujian Institute of Research on theStructure of Matter The Chinese Academy of Sciences Fuzhou Fujian 350002 China

The title compound, [Zn（NDC）（2,2＇-bipy）], （NDC = 1,5-naphthalenedicarboxylate, 2,2＇- bipy = 2,2＇-bipyridine）, has been synthesized by a hydrothermal reaction and characterized by single-crystal X-ray diffraction analysis. It crystallizes in monoclinic, space group C2/c with a = 19.967（4）, b = 17.158（3）, c = 14.276（3） A,β = 129.623（5）°, V = 3767.4（12） A^3, Z = 8, C22H14N2O4Zn, Mr = 435.72, Dc= 1.536 g/cm^3, F（000） = 1776, μ（MoKα） = 1.336 mm^-1, the final R = 0.0777 and wR = 0.2447 for 2032 observed reflections （I 〉 26（/））. The Zn（II） ion is six-coordinated by two nitrogen and four oxygen atoms in a distorted octahedral environment. NDC ligand has a bis（bridging bidentate） coordination mode in the compound, The zinc atoms are linked by carboxylate groups of NDC ligand in bridging mode into a one-dimensional zigzag chain.

关键词： 1,5-NDC zinc coordination polymer crystal structure

Experimental Study on Engineering Behavior of Solidified Soil for Scour Repair and Protection

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China Ocean Engineering 2024年第4期38卷 625-635页

作者： wu xiao-ni li Ru-yu SHU Jian TANG Chao CHEN Jin-jian WANG Hui-li JIANG Hai-li WANG xiao State Key Laboratory of Ocean Engineering Department of Civil EngineeringShanghai Jiao Tong UniversityShanghai 200240China Shanghai Road and Bridge Group Co. Ltd.Shanghai 200433China Shanghai Engineering Research Center of Urban Infrastructure Renewal Shanghai 200032China Jiangsu Kunze Technology Co. Ltd.Nanjing 210000China

A new scour countermeasure using solidified slurry for offshore foundation has been proposed *** solidified slurry is pumped to seabed area around foundation for scour protection or pumped into the developed scour holes for scour repair as the fluidized material solidifies *** the pumping operation and solidification,the engineering behaviors of solidified slurry require to be considered synthetically for the reliable application in scour repair and protection of ocean engineering such as the pumpability related flow value,flow diffusion behavior related rheological property,anti-scour performance related retention rate in solidification and bearing capacity related strength property after *** this study,a series of laboratory tests are conducted to investigate the effects of mix proportion(initial water content and binder content)on the flow value,rheological properties,density,retention rate of solidified slurry and unconfined compressive strength(UCS).The results reveal that the flow value increases with the water content and decreases with the binder *** the solidified slurry exhibits Bingham plastic behavior when the shear rate is larger than 5 s^(-1).The Bingham model has been employed to fit the rheology test results,and empirical formulas for obtaining the density,yield stress and viscosity are established,providing scientific support for the numerical assessment of flow and diffusion of solidified *** rate of solidified slurry decreases with the water flow velocity and flow value,which means the pumpability of solidified slurry is contrary to anti-scour *** unconfined compressive strength after solidification reduces as the water content increases and binder content decreases.A design and application procedure of solidified soil for scour repair and protection is also proposed for engineering reference.

关键词： scour repair and protection solidified soil pumpability strength flow properties anti-scour performance

Nonlocal coherence harvesting from quantum vacuum

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Communications in Theoretical Physics 2024年第7期76卷 44-51页

作者： Rui-Di Wang Shu-Min wu xiao-li Huang Department of Physics Liaoning Normal UniversityDalian 116029China

It is well known that nonlocal coherence reflects nonclassical correlations better than quantum entanglement. Here, we analyze nonlocal coherence harvesting from the quantum vacuum to particle detectors adiabatically interacting with a quantum scalar field in Minkowski *** find that the harvesting-achievable separation range of nonlocal coherence is larger than that of quantum entanglement. As the energy gap grows sufficiently large, the detectors harvest less quantum coherence, while the detectors could extract more quantum entanglement from the vacuum state. Compared with the linear configuration and the scalene configuration, we should choose the model of equilateral triangle configuration to harvest tripartite coherence from the vacuum. Finally, we find a monogamous relationship, which means that tripartite l_(1)-norm of coherence is essentially bipartite types.

关键词： nonlocal coherence quantum vacuum monogamous relationship

Three-stage niobium mineralization at Bayan Obo, China

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National Science Review 2024年第4期11卷 102-110页

作者： Yan Yu Yang li Yu liu xiao-xiao ling li-Guang wu li Yang Lan Yang Bo Yang Yong-Gang Zhao Xian-Hua li State Key Laboratory of lithospheric Evolution Institute of Geology and Geophysics Chinese Academy of Sciences College of Earth and Planetary Science University of Chinese Academy of Sciences Ministry of Education Key Laboratory of Orogenic Belts and Crustal Evolution School of Earth and Space SciencesPeking University Mining Research Institute Baotou Iron and Steel(Group) Co.LTD State Key Laboratory of Baiyunobo Rare Earth Resource Research and Comprehensive Utilization

The Chinese Bayan Obo deposit is a world-class rare earth element(REE) deposit with considerable niobium(Nb) and iron(Fe) resources. A complete genetic understanding on all metals is fundamental for establishing genetic models at Bayan Obo. With extensive research being focused on REE enrichment, the timing and controls of Nb enrichment remain unresolved at Bayan Obo, which is mainly due to the challenges in dating, i.e. multistage thermal events, fine-grained minerals with complex textures and the rare occurrence of uranium-enriched minerals with mature dating methods. Based on robust geological and petrographic frameworks, here we conducted ion probe uranium-lead(U-Pb) dating of ferrocolumbite to unravel the timing, hence the genesis of Nb mineralization. Three types of hydrothermal ferrocolumbites—key Nb-bearing minerals—are identified based on their textures and mineral assemblages. They yield U-Pb ages of 1312 ± 47 Ma(n = 99), 438 ± 7 Ma(n = 93), and 268 ± 5 Ma(n = 19), respectively. In line with deposit geology, we tentatively link the first, second and third stage Nb mineralization to Mesoproterozoic carbonatite magmatism, ubiquitous early Paleozoic hydrothermal activity, and Permian granitic magmatism, respectively. While quantifying the contribution of metal endowment from each stage requires further investigation, our new dates highlight that multi-stage mineralization is critical for Nb enrichment at Bayan Obo, which may also have implications for the enrichment mechanism of Nb in REE deposits in general.

关键词： niobium mineralization U-Pb dating ferrocolumbite Bayan Obo

Molecular Characterization and Antibacterial Activity of a G-Type Lysozyme in Yellow Drum(Nibea albiflora)

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Journal of Ocean University of China 2024年第2期23卷 477-486页

作者： xiao Yao li Jiacheng TIAN Qianqian wu Baolan HAN Fang State Key Laboratory of Mariculture Breeding Fisheries College of Jimei UniversityXiamen 361021China

Lysozyme(EC3.***.1.17)plays an important role in the immune response;as a nonspecific immune factor,it can resist causative *** can be divided into c-type and g-type in *** a previous study,through genome-wide association analysis,the g-type lysozyme gene,which is named NaLyg in yellow drum(Nibea albiflora),was found to be a key candidate gene for disease resistance in response to Vibrio harveyi *** cDNA of NaLyg was 1025 bp,including four exons and three introns,and its open reading frame(ORF)had a full-length of 582 bp,encoding 193 amino *** was found to be conserved during evolution through bioinformatic *** NaLyg protein possessed a sugar binding domain and three catalytic sites,including Glu71,Asp84 and *** qRT-PCR results confirmed that NaLyg gene mRNA was visibly increased after *** *** NaLyg protein purified by prokaryotic expression killed some gram-negative bacterial pathogens by inducing cell wall destruction,including ***,Aeromonas hydrophila and Edwardsiella ***,the NaLyg protein killed two gram-positive bacteria,Bacillus subtilis and Staphylococcus *** together,the experimental results suggested that the NaLyg protein of *** played an important role in fighting bacterial infections.

关键词： Nibea albiflora innate immunity Vibrio harveyi g-type lysozyme antibacterial activity

Color-polarization synergistic target detection method considering shadow interference

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Defence Technology（防务技术） 2024年第7期37卷 50-61页

作者： Bin Feng Jinpei xiao Junchao Zhang lin li Yunlong wu Qing Ye School of Automation Northwestern Polytechnical UniversityXi'an710072China School of Automation Central South UniversityChangsha410083China State Key Laboratory of Pulsed Power Laser Technology National University of Defense TechnologyHefei230037China

Aiming at the problem of shadow interference in UAV's ground reconnaissance,a color and polarization synergistic target detection method is proposed for anti-shadow interference,based on the influence of two physical characteristics(wavelength and polarization)under different illuminations.A valid fusion strategy is proposed via integrating two separate detection results on color and polarization ***,a local enhancement and recognition module(LER)is introduced to boost the *** on our built dataset,experimental results show that our method achieves mAPof 87.76%,and12.37%higher than that of color image and 14.68%higher than that of polarization image.

关键词： Electro-optical countermeasure Ground reconnaissance Color-polarization Shadow interference Target recognition

Injection of a Self-propelled Polymer into a Small Circular Cavity

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Chinese Journal of Polymer Science 2024年第6期42卷 886-894页

作者： Chao Wang Yan-li Zhou xiao Yang Fan wu Meng-Bo Luo Department of Physics Taizhou UniversityTaizhou318000China Department of Physics Zhejiang UniversityHangzhou310027China

The injection of a polymer chain into a small circular cavity under tangential self-propelled force is studied by using Langevin dynamics *** indicate that the injection dynamics of the active polymer shows strong correlation with the polymer conformation inside the cavity depending on the polymer rigidity(k_(b)).The injection timeτvaries nonmonotonously with increasing k_(b),and reaches its minimum at k_(b)^(*).When k_(b) is small(k_(b)≪k_(b)^(*)),the polymer is nearly random coil in the cavity,and spends a long time at the final stage of the injection process due to the large repulsion between monomers inside the *** k_(b) is moderate(k_(b)∼k_(b)^(*)),the part of polymer inside the cavity forms spiral configuration under the tangential active force,and the whole polymer moves synchronously with a constant velocity during the injection process,leading to a small injection *** k_(b) is large(k_(b)≫k_(b)^(*)),the polymer is nearly straight at the initial stage of the injection process,and takes a long time to bend itself,leading to a large injection time.

关键词： Active Polymer Injection Dynamics Simulation

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FKBP38蛋白在乳腺癌中的表达研究

现代生物医学进展 2024年第1期24卷 12-17页

作者：闫云静赖姨梅吴晓丽王帅赵子建李芳红广东工业大学生物医药学院广东广州510006 赣南医学院第一附属医院江西赣州341000

目的:探讨乳腺癌组织FK506结合蛋白38(FK506-binding protein 38,FKBP38)的表达水平及其与病理分级和临床分期的关系。方法:采用免疫组化检测100例正常乳腺组织、300例浸润性导管癌(Invasion ductal carcinoma,IDC)和59例浸润性小叶癌组... 详细信息

目的:探讨乳腺癌组织FK506结合蛋白38(FK506-binding protein 38,FKBP38)的表达水平及其与病理分级和临床分期的关系。方法:采用免疫组化检测100例正常乳腺组织、300例浸润性导管癌(Invasion ductal carcinoma,IDC)和59例浸润性小叶癌组织(Invasion lobular carcinoma,ILD)中FKBP38的表达水平,分析FKBP38蛋白表达水平与乳腺癌临床病理参数之间的关系。结果:免疫组化结果表明,与正常乳腺组织相比,FKBP38在浸润性导管癌及浸润性小叶癌组织中的表达水平均显著降低,具有统计学差异(P<0.0001)。通过进一步分析可知,在浸润性导管癌中,FKBP38蛋白表达水平随病理分级及临床分期的增加而降低,具有统计学差异,而FKBP38蛋白与孕激素受体(Progesterone receptor,PR)蛋白的表达呈负相关。此外,三阴性乳腺癌(Triple-negative breast cancer,TNBC)FKBP38的表达水平显著高于非三阴性乳腺癌,同样,FKBP38在TNBC的表达水平随原发性肿瘤分期的增加而降低。结论:FKBP38蛋白水平在乳腺癌患者中表达水平显著降低,并与乳腺癌的病理分级、临床分期相关。这提示FKBP38蛋白水平可作为乳腺癌诊断和治疗的潜在靶点,但其作用机制仍需进一步研究。

关键词： FKBP38蛋白乳腺癌病理分级临床分期

From seawater to hydrogen via direct photocatalytic vapor splitting: A review on device design and system integration

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Frontiers in Energy 2024年第3期18卷 291-307页

作者： Hongxia li Khaja WAHAB AHMED Mohamed A.ABDELSALAM Michael FOWLER xiao-Yu wu Technology Innovation Institute Masdar CityAbu Dhabi 9639United Arab Emirates Department of Chemical Engineering University of WaterlooWaterlooON N2L 3G1Canada Department of Mechanical and Nuclear Engineering Khalifa University of Science and TechnologyAbu Dhabi 127788United Arab Emirates Department of Mechanical and Mechatronics Engineering University of WaterlooWaterlooON N2L 3G1Canada

Solar-driven hydrogen production from seawater attracts great interest for its emerging role in decarbonizing global energy consumption. Given the complexity of natural seawater content, photocatalytic vapor splitting offers a low-cost and safe solution, but with a very low solar-to-hydrogen conversion efficiency. With a focus on cutting-edge photothermal–photocatalytic device design and system integration, the recent research advances on vapor splitting from seawater, as well as industrial implementations in the past decades were reviewed. In addition, the design strategies of the key processes were reviewed, including vapor temperature and pressure control during solar thermal vapor generation from seawater, capillary-fed vaporization with salt repellent, and direct photocatalytic vapor splitting for hydrogen production. Moreover, the existing laboratory-scale and industrial-scale systems, and the integration principles and remaining challenges in the future seawater-to-hydrogen technology were discussed.

关键词： seawater hydrogen photocatalytic vapor splitting solar-driven