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Dynamic recrystallization behavior and strengthening mechanism of a novel Mo-Ti_(3)AlC_(2) alloy at ultrahigh temperature

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Rare Metals 2024年第8期43卷 3946-3960页

作者： Lu Yang Xin-Yuan zheng Yang zhao Xi-Ran wang Fang-Nao Xiao Shi-Zhong wei School of Materials Science and Engineering Henan University of Science and TechnologyLuoyang 471023China National Joint Engineering Research Center for Abrasion Control and Molding of Metal Materials Henan University of Science and TechnologyLuoyang 471003China Department of Applied Mechanics Univ.Bourgogne FrancheComteFEMTO-ST InstituteCNRS/UF/ENSMM/UTBM25000BesangonFrance

Increasing the recrystallization temperature to achieve better high-temperature performance is critical in the development of molybdenum alloys for ultrahightemperature applications,such as the newest generation of multitype high-temperature nuclear *** this study,an innovative strategy was proposed to improve the performance of molybdenum alloys at high temperature by using the two-dimensional MAX(where M is an early transition metal,A is an A-group element and X is C or N)ceramic material Ti_(3)AlC_(2).The relationships between flow stress,strain rate and temperature were *** microstructure,distribution of misorientation and evolution of dislocations in the Mo-Ti_(3)AlC_(2) alloy were *** microscopic mechanism of the Ti_(3)AlC_(2) phase in the molybdenum alloy at high temperatures was *** experimental results showed that the peak flow stress of Mo-Ti_(3)AlC_(2) at 1600℃ reached 155 MPa,which was161.8% greater than that of pure *** activation energy of thermal deformation of Mo-Ti_(3)AlC_(2) was as large as537 kJ·mol~(-1),which was 17.6% more than that of pure *** recrystallization temperature reached 1600℃ or even *** topological reaction of the Ti_(3)AlC_(2) phase consumed a large amount of energy at high temperatures,resulting in increases in the deformation activation *** structures of AlTi_3 and Ti-O Magneli-phase oxides(Ti_nO_(2n-1)) were formed in-situ,which relied on kink bands and interlayer slip,resulting in many dislocations during ***,the special two-dimensional of the structure Ti_(3)AlC_(2) ceramic inhibited the recrystallization behavior of the Mo *** results of this study can provide theoretical guidance for the development of a new generation of molybdenum alloys for use in ultrahigh-temperature environments.

关键词： Mo alloy Two-dimensional reinforcement Dynamic recrystallization behavior Hot deformation Mechanical properties

Scale effects of leaf area index inversion based on environmental and disaster monitoring satellite data

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Science china Earth sciences 2010年第S1期53卷 92-98页

作者： ZHANG Hao1,LI XiaoWen1,2,CAO ChunXiang1,YANG Hua2,GAO MengXu1,3,zheng Sheng1,3,XU Min1,3,XIE DongHui2,JIA HuiCong1,JI wei1,zhao Jian1,3,CHEN wei1,3 & NI XiLiang1,3 1 State Key Laboratory of Remote Sensing Science,Jointly Sponsored by institute of Remote Sensing Applications,chinese academy of sciences and beijing Normal University,beijing 100101,china 2 State Key Laboratory of Remote Sensing Science,Jointly Sponsored by beijing Normal University and institute of Remote Sensing Applications of chinese academy of sciences,beijing 100875,china 3 Graduate University of chinese academy of sciences,beijing 10004.,china 1. State Key Laboratory of Remote Sensing Science Jointly Sponsored by Institute of Remote Sensing Applications Chinese Academy of Sciences and Beijing Normal University Beijing 100101 China2. State Key Laboratory of Remote Sensing Science Jointly Sponsored by Beijing Normal University and Institute of Remote Sensing Applications of Chinese Academy of Sciences Beijing 100875 China3. Graduate University of Chinese Academy of Sciences Beijing 100049 China

The spatial distribution of sub-pixel components has an impact on retrieval accuracy,and should be accounted for when inverting a three-dimensional adiative transfer model to retrieve leaf area index(LAI).To investigate this effect,we constructed three realistic scenarios with the same LAI values and other properties,except that the simulated plants had different *** implemented the radiosity method to subsequently produce synthetic bidirectional reflectance factor(BRF) datasets based upon these simulated *** inversion was conducted using these data,which showed that spatial distribution affects retrieval *** inversion was also conducted for LAI based on charge-coupled device(CCD) data from the Environment and Disaster Monitor Satellite(HJ-1),which depicted both forest and drought-resistant crop land *** showed that heterogeneity in coarse-resolution remote sensing data is the main error source in LAI *** spatial distribution of global fractal dimension index,which can be used to describe the area of sub-pixel components and their spatial distribution modes,shows good consistency with the coarse resolution LAI inversion error.

关键词： HJ-1 leaf area index scale effect spatial distribution

Investigation on cavitating turbulent flow for the twisted NACA66 hydrofoil using a PANS model with helicity modification

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Journal of Hydrodynamics 2024年第2期36卷 219-231页

作者： Chen Geng zhao-hui Qian Ke-xin zheng wei-xiang Ye Xian-wu Luo State Key Laboratory of Hydroscience cand Engineering Deparment of Energy and Power EngineeringTsinghua UniversityBeijing 100084China institute of Nuclear and New energy Technology Tsinghua UniversityBeijing 100084China

In the present paper,the unsteady cavitating turbulent flow over the twisted NACA66 hydrofoil is investigated based on an modified shear stress transfer k-ωpartially averaged Navier-Stokes(MSST PANS)model,i.e.,new MSST PANS(NMSST PANS)model,where the production term of kinetic energy in the turbulence model is modified with *** with the experimental data,cavitation evolution and its characteristic frequency are satisfactorily predicted by the proposed NMSST PANS *** is revealed that the interaction among the main flow,the reentrant jets,and sheet cavitation causes the formation of the primary shedding cavity near the mid-span and the secondary shedding cavity at each side of the twisted hydrofoil,and further induces the remarkable pressure gradient around shedding *** with the development of the primary and the secondary shedding cavities,the great pressure gradient associated with large cavity volume variation promotes the vortical flow generation and the spatial deformation of vortex structure during cavitation evolution,and results in the primary and the secondary U-type ***,dynamic mode decomposition(DMD)analysis is utilized to confirm the interaction among the main flow,the main reentrant jet and two side reentrant jets,and *** results indicate that the proposed NMSST PANS model is suitable to simulate the complicated cavitating turbulent flow for various engineering applications.

关键词： Cavitating turbulent flow partially averaged Navier-Stokes(PANS)model hydrofoil numerical simulation

Molecular-scale co-assembly membranes derived from keplerate cluster:carbonic anhydrase-mimicking nanocapsules for enhanced CO_(2)/N_(2)separation

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Science china Chemistry 2024年第10期67卷 3271-3282页

作者： Wan-Lei zhao Hongqiang Li Ruoxuan zheng Yixin Yang wei Chen Yu-Fei Song State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical TechnologyBeijing 100029China Quzhou institute for Innovation in Resource Chemical Engineering Quzhou 324000China

The development of CO_(2)separation membranes with high permeability and high selectivity,as well as ultra-thin selective layers,has always been ***,a molecular-scaled co-assembly strategy is employed to fabricate the Pebax-Mo_(132)(Pebax=polyether-block-amide copolymer;Mo_(132)=(NH_(4))_(42)[Mo_(72)^(Ⅵ)Mo_(60)^(Ⅴ)O_(372)(CH_(3)COO)_(30)(H_(2)O)_(72)])*** optimal selfstanding membrane,Pebax-Mo_(132)-5%,shows a CO_(2)permeability of~384 Barrer and an ultra-high ideal CO_(2)/N_(2)selectivity of~244,outperforming most membranes reported in the *** CO_(2)permeability and ideal CO_(2)/N_(2)selectivity are increased by 70%and 367%,respectively,compared with the pristine Pebax membrane.A thin-film composite membrane prepared by spin-coating technique on a support membrane with gutter layers also exhibits a CO_(2)permeance of 838 GPU and a CO_(2)/N_(2)selectivity of *** excellent performance can be attributed to the following reasons:(1)strong hydrogen bonding interactions between{Mo_(132)}clusters and Pebax confer excellent interfacial compatibility to the mixed matrix membranes;(2)incorporation of hollow{Mo_(132)}clusters into the Pebax molecular chain decreases the crystallinity of Pebax,and thereby accelerates the chain dynamics and increases the free volume of the membrane;(3)in situ diffuse reflectance infrared Fouriertransform spectroscopy demonstrates that the{Mo_(132)}clusters can effectively catalyze the hydration reaction of CO_(2)and promote the transport of CO_(2);(4)furthermore,the 0.35 nm pores of the crown ether-type{Mo_(9)O_(9)}allow the accurate size sieving of CO_(2)(0.33 nm)and N_(2)(0.36 nm)molecules.

关键词： polyoxometalates molecular-scale assembly CO_(2)capture mixed matrix membranes

Theoretical Exploration of Alloying Effects on Stabilities and Mechanical Properties ofγʹPhase in Novel Co–Al–Nb-Base Superalloys

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Acta Metallurgica Sinica(English Letters) 2024年第7期37卷 1238-1248页

作者： Guan-Cheng Gu zhao-Jing Han Ze-Yu Chen zhao-Xuan Li Sheng-Bao Xia zheng-Ning Li Hua Jin wei-wei Xu Xing-Jun Liu Shenzhen Research institute of Xiamen University School of Aerospace EngineeringXiamen UniversityXiamen361005China institute of Materials Genome and Big Data Harbin Institute of TechnologyShenzhen518055China

The new developedγ/γʹCo–Al–Nb-base alloys show great potentials as high-temperature ***,finding appropriate compositions to improve performance of alloys still poses a great challenge to the development of Co–Al–Nb-base *** by the lack of alloying effects on fundamental properties of criticalγʹphase,we systematically performed a theoretical investigation on the effect of alloying elements TM(TM:Ti,V,Cr,Zr,Mo,Ta,W,Re,and Ru)on phase stabilities and mechanical properties of L1_(2)-typeγʹ(Co,Ni)_(3)(Al,Nb).By analyzing the stability ofγʹphase with respect to its competitive B2 and D0_(19) phases,the results shown that Ti,V,and Cr enhance the L1_(2) stability and widen the L1_(2)–D0_(19) energy barrier,in which V yields the maximum *** analysis of electronic structure indicated that the alternation of valence electrons at fermi level would be the atomic origin for doping TM inγʹ*** calculated results of mechanical properties shown that V and Cr are expected to be optimal dopant for enhancing the strength and the ductility ofγʹ*** addition of Ta is also beneficial for enhancing the strength at the slight expense of ductility ofγʹ*** drawing the mechanical maps,the preferred composition range for the phases with desired properties is roughly demarcated in theory for the multi-addition of V/Cr and V/Ta inγʹ*** findings would be useful for optimizing the performance of novelγ/γʹCo–Al–Nb-base superalloys.

关键词： Co-Al-Nb-base superalloys γ/γʹdual-phase Phase stability Mechanical properties First-principle methods

Superconducting,Topological,and Transport Properties of Kagome Metals CsTi_(3)Bi_(5)and RbTi_(3)Bi_(5)

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Research 2024年第2期2023卷 753-762页

作者： Xin-wei Yi zheng-wei Liao Jing-Yang You Bo Gu Gang Su School of Physical sciences University of Chinese Academy of SciencesBeijing 100049China Department of physics Faculty of ScienceNational University of Singapore117551Singapore Kavli institute for Theoretical sciences and CAS Center for Excellence in Topological Quantum ComputationUniversity of Chinese Academy of SciencesBeijing 100190China

The recently discovered ATi_(3)Bi_(5)(A=Cs,Rb)exhibit intriguing quantum phenomena including superconductivity,electronic nematicity,and abundant topological ***_(3)Bi_(5)present promising platforms for studying kagome superconductivity,band topology,and charge orders in parallel with *** this work,we comprehensively analyze various properties of ATi_(3)Bi_(5)covering superconductivity under pressure and doping,band topology under pressure,thermal conductivity,heat capacity,electrical resistance,and spin Hall conductivity(SHC)using first-principles *** superconducting transition temperature(Tc)of CsTi_(3)Bi_(5)and RbTi_(3)Bi_(5)at ambient pressure are about 1.85 and 1.92 *** subject to pressure,Tc of CsTi_(3)Bi_(5)exhibits a special valley and dome shape,which arises from quasi-two-dimensional compression to three-dimensional isotropic compression within the context of an overall decreasing ***,Tc of RbTi_(3)Bi_(5)can be effectively enhanced up to 3.09 K by tuning the kagome van Hove singularities(VHSs)and flat band through *** can also induce abundant topological surface states at the Fermi energy(EF)and tune VHSs across ***,our transport calculations are in excellent agreement with recent experiments,confirming the absence of charge density ***,SHC of CsTi_(3)Bi_(5)can reach up to 226h·(e·Ω·cm)^(-1)at *** work provides a timely and detailed analysis of the rich physical properties for ATi_(3)Bi_(5),offering valuable insights for further experimental verifications and investigations in this field.

关键词： doping superconductivity conductivity

Tuning the product selectivity of dimethyl oxalate hydrogenation over WO_(x) modified Cu/SiO_(2) catalysts

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Journal of energy Chemistry 2024年第10期97卷 128-138,I0004页

作者： zheng Li Zhuo Ma Yihui Li Ziang zhao Yuan Tan Ziyin Liu Xingkun Chen Nian Lei Huigang wang wei Lu Hejun Zhu Yunjie Ding Hangzhou institute of Advanced Studies Zhejiang Normal UniversityHangzhou 311231ZhejiangChina Dalian National Laboratory for Clean energy Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023LiaoningChina University of chinese academy of sciences Beijing 100049China Shaanxi Key Laboratory of Clean energy Technology Utilization Yulin BranchDalian National Laboratory For Clean EnergyCASYulin 719199ShaanxiChina State Key Laboratory of Catalysis Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023LiaoningChina

Product selectivity and reaction pathway are highly dependent on surface structure of heterogeneous *** vapor-phase hydrogenation of dimethyl oxalate(DMO),"EG route"(DMO→methyl glycolate(MG)ethylene glycol(EG)→ethanol(ET))and"MA route"(DMO→MG→methyl acetate(MA))were proposed over traditional Cu based catalysts and Mo-based or Fe-based catalysts,***,tunable yield of ET(93.7%)and MA(72.1%)were obtained through different reaction routes over WO_(x) modified Cu/SiO_(2) catalysts,and the corresponding reaction route was further proved by kinetic study and in-situ DRIFTS *** studies demonstrated that H_(2) activation ability,acid density and Cu-WO_(x) interaction on the catalysts were tuned by regulating the surface W density,which resulted in the different reaction pathway and product ***'s more,high yield of MA produced from DMO hydrogenation was firstly reported with the H_(2) pressure as low as 0.5 MPa.

关键词： Ethanol Dimethyl oxalate Selective hydrogenation Methyl acetate WCu/SiO_(2)catalyst

Single-atom-mediated electron islands boost photocatalytic CO_(2)chemical fixation

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Science china Chemistry 2024年第7期67卷 2292-2299页

作者： Shu Shang Lei Li Xin He Hui wang Lirong zheng wei Shao Xiaodong Zhang Yi Xie Hefei National Research Center for Physical sciences at the Microscale University of Science and Technology of ChinaHefei 230026China institute of energy Hefei Comprehensive National Science CenterHefei 230031China beijing Synchrotron Radiation Facility Institute of High Energy PhysicsChinese Academy of SciencesBeijing 100049China School of Chemistry and Chemical Engineering Hefei Normal UniversityHefei 230031China

Photocatalytic cycloadditions of CO_(2)with epoxides are emerging as a significant platform for the green synthesis of valuable carbonates,where efficient catalytic systems with spatially separated charge carriers are ***,a single p-block metal atom is proposed to be a candidate for photogenerated electron localization on a metal oxide *** taking the Bi single-atom supported on ZnO nanosheet(Bi1/ZnO)as an example,we show that the Bi atom plays the role of an electron island in the sea of delocalized holes within ***,the as-formed electron island could readily promote the rate-determining ring-opening process of cycloaddition *** from the unique spatially separated electrons and holes,the Bi1/ZnO achieves a high yield of cyclic carbonates with almost 100%*** study provides a pioneering strategy for enhancing the performances of photocatalytic CO_(2)chemical fixation.

关键词： electron islands CO_(2)photofixation photogenerated charge carriers

highly efficient three-dimensional solar evaporator for zero liquid discharge desalination of high-salinity brine

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Carbon energy 2024年第9期6卷 52-65页

作者： Meichun Ding Demin zhao Panpan Feng Baolei wang Zhenying Duan Rui wei Yuxi zhao Chen-Yang Liu Chenwei Li School of Chemistry and Pharmaceutical Engineering Shandong First Medical University&Shandong Academy of Medical SciencesJinanChina Medical Science and Technology Innovation Center Shandong First Medical University&Shandong Academy of Medical SciencesJinanChina Institut de Chimie Radicalaire Aix Marseille UniverisityMarseilleFrance CAS Key Laboratory of Engineering Plastics CAS Research/Education Center for Excellence in Molecular SciencesInstitute of Chemistrythe Chinese Academy of SciencesBeijingChina

Solar-driven interfacial evaporation is a promising technology for freshwater production from seawater,but salt accumulation on the evaporator surface hinders its performance and *** this study,we report a simple and green strategy to fabricate a three-dimensional porous graphene spiral roll(3GSR)that enables highly efficient solar evaporation,salt collection,and water production from near-saturated brine with zero liquid discharge(ZLD).The 3GSR design facilitates energy recovery,radial brine transport,and directional salt crystallization,thereby resulting in an ultrahigh evaporation rate of 9.05 kg m^(-2) h^(-1)6 in 25 wt%brine under 1-sun illumina-tion for 48 h ***,the directional salt crystallization on its outer surface not only enlarges the evaporation area but also achieves an ultrahigh salt collection rate of 2.92 kg m^(-2) h^(-1),thus enabling ZLD ***,3GSR exhibits a record-high water production rate of 3.14 kg m^(-2) h^(-1) in an outdoor *** innovative solution offers a highly efficient and continuous solar desalination method for water production and ZLD brine treatment,which has great implications for addressing global water scarcity and environmental issues arising from brine disposal.

关键词： graphene aerogels graphene composites solar desalination solar-driven interfacial evaporation