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Science china chemistry 2008年第2期51卷 120-127页

作者： wei ruiping1,2. gu yanbo1 & wang jun1 1 state key laboratory of materials-oriented chemical engineering,{2., nanjing uni- versity of technology, nanjing 2.0009, china 2.2., Southeast university, nanjing 2.1189, china state key {2. of materials-oriented chemical engineering College of Chemistry and Chemical Engineering Nanjing University of Technology Nanjing China college of chemistry and {2. engineering Southeast University Nanjing China

The bimetal-bearing (CePt or LaPt) 12.tungstophosphoric acid (H3PW12.40 (PW)) catalysts supported on dealuminated USY zeolite (DUSY) were prepared by impregnation and characterized by XRD, BET, IR, and H2.chemisorption. Their catalytic activities were tested in the hydroisomerization of n-heptane with a continuous atmospheric fixed-bed reactor. After the steam treatment combined with the acid leaching, as well as the supporting with PW and the bimetals, the DUSY support retains the Y zeolite porosity and the PW well keeps its Keggin structure in catalysts. The doping of Ce into the catalysts enhances the dispersion of Pt on the catalyst surface. The Pt-bearing PW catalysts doped with Ce or La, especially Ce, exhibit much higher catalytic activity and selectivity than the catalysts without dopants at lowered reaction temperatures. At the optimal reaction conditions, i.e., the reaction temperature of 2.0℃ and WHSV of 1.4 h1, the catalyst with a Pt loading of 0.4%, PW loading of 10% and a molar ratio of Ce to Pt of 15:1 shows a conversion of n-heptane of 70.3% with a high selectivity for isomerization products of 94.1%.

关键词： hydroisomerization of n-heptane bimetal catalyst heteropoly acid USY platinum

Preparation, Characterization and Catalytic Behavior of 12.Molybdophosphoric Acid Encapsulated in the Supercage of Cs^＋-exchanged Y Zeolite

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Chinese Journal of chemical engineering 2009年第1期17卷 58-63页

作者：魏瑞平郭麦平王军 state key {2. of materials-oriented chemical engineering College of Chemistry and Chemical Engineer ing Nanjing University of Technology Nanjing 210009 China School of chemistry and chemical {2. Southeast University Nanjing 211189 China

In order to solve the serious leaching problem of supported heteropoly acid catalysts in polar reaction media, 12.molybdophosphoric acid encapsulated in the supercage of Cs^＋-exchanged Y zeolite was prepared by the ＂ship in the bottle＂ synthesis. The influence of ion-exchange conditions and the synthesis parameters on the encaosulation of PMo12.were investigated. The obtained solid sample was characterized by X-ray diffraction （XRD）, 31p magic angle spin nuclear magnetic resonance （MAS NMR） and Fourier Transform Infrared Spectroscopy （FT-IR）, and its catalytic activity in the esterification of acetic acid and n-butanol was tested. The ion-exchange time, concentration of aqueous Cs^＋ solution, pH value, and amount of Mo added in the synthesis mixture were revealed to influence the encapsulation very remarkably. Under the optimal conditions, 12.molybdophosphoric acid could be successfully encapsulated in the supercage of CsY zeolite, and the samples showed considerable catalytic activity and excellent reusability in the esterification reaction.

关键词： Y zeolite 12.molybdophosphoric acid ship in the bottle esterification

Biomedical polymers: synthesis, properties, and applications

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Science china chemistry 2022年第6期65卷 1010-1075页

作者： wei-Hai Chen Qi-Wen Chen Qian Chen Chunyan Cui Shun Duan Yongyuan Kang Yang Liu Yun Liu Wali Muhammad Shiqun Shao Chengqiang Tang Jinqiang wang Lei wang Meng-Hua Xiong Lichen Yin Kuo Zhang Zhanzhan Zhang Xu Zhen jun Feng Changyou Gao Zhen gu Chaoliang He Jian Ji Xiqun Jiang Wenguang Liu Zhuang Liu Huisheng Peng Youqing Shen Linqi Shi Xuemei Sun Hao wang jun wang Haihua Xiao Fu-Jian Xu Zhiyuan Zhong Xian-Zheng Zhang Xuesi Chen key laboratory of Biomedical Polymers of Ministry of Education&Department of {2. Wuhan UniversityWuhan430072China Institute of Functional Nano&Soft materials(FUNSOM) Jiangsu Key Laboratory for Carbon-Based Functional Materials&DevicesSoochow UniversitySuzhou215123China School of materials Science and engineering Tianjin Key Laboratory of Composite and Functional MaterialsTianjin UniversityTianjin300350China key laboratory of Biomedical {2. of Natural Macromolecules(Beijing university of chemical technology) Ministry of EducationBeijing Laboratory of Biomedical MaterialsCollege of Materials Science and EngineeringBeijing University of Chemical TechnologyBeijing100029China MOE key laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and EngineeringZhejiang UniversityHangzhou310027China state key {2. of Medicinal chemical Biology Key Laboratory of Functional Polymer Materials of Ministry of EducationCollege of ChemistryNankai UniversityTianjin300071China key laboratory of Advanced Drug Delivery Systems of Zhejiang Province College of Pharmaceutical SciencesZhejiang UniversityHangzhou310058China Jinhua Institute of Zhejiang university Jinhua321299China Zhejiang key laboratory of Smart Bio{2. and Center for Bionanoengineering College of Chemical and Biological EngineeringZhejiang UniversityHangzhou310027China ZJU-Hangzhou Global Scientific and Technological Innovation Center Hangzhou311215China state key {2. of Molecular engineering of Polymers Department of Macromolecular Science and Laboratory of Advanced MaterialsFudan UniversityShanghai200438China CAS key laboratory for Biomedical Effects of Nano{2. and Nanosafety CAS Center for Excellence in Nano-scienceNational Center for Nanoscience and Technology(NCNST)Beijing100190China School of Biomedical Sciences and engineering Guangzhou International CampusSouth China University of TechnologyGuangzhou510006China Institute of Functional Nano and So

Biomedical polymers have been extensively developed for promising applications in a lot of biomedical fields, such as therapeutic medicine delivery, disease detection and diagnosis, biosensing, regenerative medicine, and disease treatment. In this review, we summarize the most recent advances in the synthesis and application of biomedical polymers, and discuss the comprehensive understanding of their property-function relationship for corresponding biomedical applications. In particular, a few burgeoning bioactive polymers, such as peptide/biomembrane/microorganism/cell-based biomedical polymers, are also introduced and highlighted as the emerging biomaterials for cancer precision therapy. Furthermore, the foreseeable challenges and outlook of the development of more efficient, healthier and safer biomedical polymers are discussed. We wish this systemic and comprehensive review on highlighting frontier progress of biomedical polymers could inspire and promote new breakthrough in fundamental research and clinical translation.

关键词： biomedical polymer nanomedicine cancer therapy drug delivery bioimaging and biosensing tissue engineering regenerative medicine cytotoxicity biocompatibility

Repair, protection and regeneration of peripheral nerve injury

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Neural Regeneration Research 2015年第11期10卷 1777-1798页

作者： Shan-lin Chen Zeng-gan Chen Hong-lian Dai Jian-xun Ding Jia-song guo Na Han Bao-guo Jiang Hua-jun Jiang Juan Li Shi-pu Li Wen-jun Li Jing Liu Yang Liu jun-xiong Ma Jiang Peng Yun-dong Shen guang-wei Sun Pei-fu Tang gu-heng wang Xiang-hai wang Liang-bi Xiang Ren-guo Xie Jian-guang Xu Bin Yu Li-cheng Zhang Pei-xun Zhang Song-lin Zhou Department of Hand Surgery Beijing Jishuitan Hospital Department of Orthopedic Surgery Zhongshan Hospital Fudan University state key {2. of Advanced technology for materials Synthesis and Processing Wuhan University of Technology Biomedical materials and engineering Research Center of Hubei Province key laboratory of Polymer Eco{2. Changchun Institute of Applied Chemistry Chinese Academy of Sciences Department of Histology and Embryology Southern Medical University key laboratory of Tissue Construction and Detection of guangdong Province Institute of Bone Biology Academy of Orthopedics Peking university People's Hospital Department of Orthopedics First Affiliated Hospital of Dalian Medical University The First Affiliated Hospital of Dalian Medical university laboratory of Biotechnology Dalian Institute of Chemical PhysicsChinese Academy of Sciences Department of Orthopedics General Hospital of Shenyang Military Area Command of Chinese PLA Rescue Center of Severe Wound and Trauma of Chinese PLA Institute of Orthopedics Chinese PLA General Hospital The Neural Regeneration Co-innovation Center of Jiangsu Province Department of Hand Surgery Huashan Hospital Fudan University Department of Hand and Upper Extremity Surgery Jing’an District Centre Hospital Department of Orthopedics General Hospital of People's Liberation Army Department of Hand Surgery Affiliated Hospital of Nantong University Trauma Center Department of Orthopedic Surgery Shanghai First People’s Hospital Shanghai Jiao Tong University School of Medicine Jiangsu key laboratory of Neuroregeneration Co-innovation Center of Neuroregeneration Nantong University

Reading guide 1778Repair of long-segment peripheral nerve defects1779Bionic reconstruction of hand function after adult brachial plexus root avulsion1780Optimized design of regeneration material for the treatment of peripheral nerve injury1781Synergism of electroactive polymeric materials and electrical stimulation promotes peripheral nerve repair1783Schwann cell effect on peripheral nerve repair and regeneration .

关键词： cell protection and regeneration of peripheral nerve injury Repair

Tailoring lattice strain in ultra-fine high-entropy alloys for active and stable methanol oxidation

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Science china materials 2021年第10期64卷 2454-2466页

作者： Dongdong wang Zhiwen Chen Yu-Cheng Huang wei Li Juan wang Zhuole Lu Kaizhi gu Tehua wang Yujie Wu Chen Chen Yiqiong Zhang Xiaoqing Huang Li Tao Chung-Li Dong jun Chen Chandra Veer Singh Shuangyin wang state key {2. of Chemo/Bio-Sensing and Chemometrics College of Chemistry and Chemical EngineeringHunan UniversityChangsha 410082 Department of materials Science and engineering University of TorontoToronto ON M5S 3E4 college of materials Science and {2. Changsha University of Science&TechnologyChangsha 410114 ARC Centre of Excellence for Electromaterials Science Intelligent Polymer Research Institute(IPRI)Australian Institute of Innovative Materials(AIIM)University of WollongongWollongong NSW 2522 Research Center for X-Ray Science&Department of Physics Tamkang UniversityNew Taipei City 25137 college of chemistry Chemical Engineering and Materials ScienceSoochow UniversitySuzhou 215123

High-entropy alloys(HEAs)have been widely studied due to their unconventional compositions and unique physicochemical properties for various ***,for the first time,we propose a surface strain strategy to tune the electrocatalytic activity of HEAs for methanol oxidation reaction(MOR).High-resolution aberration-corrected scanning transmission electron microscopy(STEM)and elemental mapping demonstrate both uniform atomic dispersion and the formation of a face-centered cubic(FCC)crystalline structure in Pt Fe Co Ni Cu *** HEAs obtained by heat treatment at 700℃(HEA-700)exhibit 0.94%compressive strain compared with that obtained at 400℃(HEA-400).As expected,the specific activity and mass activity of HEA-700 is higher than that of HEA-400 and most of the state-of-the-art *** enhanced MOR activity can be attributed to a shorter Pt–Pt bond distance in HEA-700 resulting from compressive *** nonprecious metal atoms in the core could generate compressive strain and down shift d-band centers via electron transfer to surface Pt *** work presents a new perspective for the design of high-performance HEAs electrocatalysts.

关键词： high-entropy alloys lattice strain methanol oxidation platinum-based catalysts electrocatalysis

碳酸酯类电解液中纳米银电极界面过程的原位拉曼光谱研究

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电化学（中英文） 2023年第12期29卷 14-23页

作者：谷宇胡元飞王卫伟尤恩铭唐帅苏建加易骏颜佳伟田中群毛秉伟固体表面物理化学国家重点实验室福建能源材料科学与技术创新实验室厦门大学化学化工学院福建厦门361005 化学学院郑州大学河南郑州450001

锂电池体系中负极表面固态电解质界面相(SEI)对锂电池性能起到至关重要的作用。然而,SEI结构和化学组成复杂,其形成机理至今仍未完全阐明,阻碍了锂电池的发展和应用。本文从方法学角度出发,采用表面增强拉曼光谱(SERS)“借力”策略,通... 详细信息

锂电池体系中负极表面固态电解质界面相(SEI)对锂电池性能起到至关重要的作用。然而,SEI结构和化学组成复杂,其形成机理至今仍未完全阐明,阻碍了锂电池的发展和应用。本文从方法学角度出发,采用表面增强拉曼光谱(SERS)“借力”策略,通过优化银纳米粒子的结构并借助其外来表面局域等离激元共振作用,开展以EC-DMC为溶剂的碳酸酯类电解液体系中SEI成膜过程的原位研究。为了确保可靠的原位SERS测试,我们设计了一种三电极体系气密拉曼电池。我们利用原位SERS方法,在纳米银电极上获得了SEI成膜过程的组成和结构信息。研究表明,SEI随电位变化呈现出双层结构,其中内层由薄且致密的无机组分构成,外层由疏松的有机组分构成。同时,研究发现LEMC是EC还原的主要成分,而不是LEDC,且金属锂参与的化学反应在形成稳定SEI中的起到关键作用。此外,锂发生沉积后,由于锂与银的合金效应导致其介电常数发生变化,从而削无法进一步增强SEI的拉曼信号。本文为深入理解负极表面SEI的形成及演变过程提供依据,并为今后开展锂电池体系相关界面过程的原位研究提供借鉴。

关键词：固态电解质界面相原位SERS 负极界面锂电池

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二次电池研究进展

物理化学学报 2022年第12期38卷 22-167页

作者：黄俊达朱宇辉冯煜韩叶虎谷振一刘日鑫杨冬月陈凯张相禹孙威辛森余彦尉海军张旭于乐王华刘新华付永柱李国杰吴兴隆马灿良王飞陈龙周光敏吴思思卢周广李秀婷刘继磊高鹏梁宵常智叶华林李彦光周亮尤雅王鹏飞杨超刘金平孙美玲毛明磊陈浩张山青黄岗余丁山徐建铁熊胜林张进涛王莹任玉荣杨春鹏徐韵涵陈亚楠许运华陈子峰杲祥文浦圣达郭少华李强曹晓雨明军皮欣朋梁超凡伽龙王俊雄焦淑红姚雨晏成林周栋李宝华彭新文陈冲唐永炳张桥保刘奇任金粲贺艳兵郝晓鸽郗凯陈立宝马建民电子科技大学材料与能源学院成都611731 中国科学院化学研究所北京100190 厦门大学材料学院福建厦门361005 中国科学技术大学材料科学与工程系合肥230026 东北师范大学物理学院长春130024 南京大学现代工程与应用科学学院南京210046 中国科学院长春应用化学研究所长春130022 北京化工大学有机无机复合材料国家重点实验室北京100029 北京工业大学材料与制造学部北京100124 北京航空航天大学化学学院北京100191 北京航空航天大学交通科学与工程学院北京100191 郑州大学化学学院郑州450001 郑州大学橡塑模具国家工程研究中心郑州450002 东北师范大学化学学院长春130024 山西大学分子科学研究所太原030006 复旦大学材料科学系上海200433 华东理工大学化工学院上海200237 清华大学深圳国际研究生院广东深圳518055 南方科技大学材料科学与工程系广东深圳518055 深圳大学高等研究院广东深圳518060 湖南大学材料科学与工程学院长沙410082 湖南大学化学化工学院长沙410082 中南大学材料科学与工程学院长沙410083 苏州大学功能纳米与软物质研究院江苏苏州215123 武汉理工大学材料复合新技术国家重点实验室武汉430070 西安交通大学电气工程学院西安710049 武汉理工大学化学化工与生命科学学院武汉430070 华中科技大学光学与电子信息学院武汉430074 Centre for Catalysis and Clean Energy School of Environment and ScienceGriffith UniversityGold CoastQLD4214Australia 中山大学化学学院广州510275 华南理工大学环境与能源学院广州510006 山东大学化学与化工学院济南250100 香港中文大学化学系中国香港999077 常州大学材料科学与工程学院江苏常州213164 天津大学化工学院天津300350 天津大学材料科学与工程学院天津300350 Department of materials University of OxfordOxfordOX13PH 青岛大学新能源科学与工程系山东青岛266071 河南工业大学化学化工学院郑州450001 华中科技大学材料科学与工程学院武汉430074 苏州大学能源学院江苏苏州215006 华南理工大学轻工科学与工程学院广州510641 中国科学院深圳先进技术研究院广东深圳518055 湖南大学物理与微电子科学学院长沙410082 香港城市大学物理系中国香港999077 Department of Mechanical and materials engineering University of Western OntarioLondonOntario N6A 5B9Canada 西安交通大学化学学院西安710049 中南大学粉末冶金国家重点实验室长沙410083

能源的存储和利用是当今科学和技术发展中的重大课题之一,尤其是作为高效的电能/化学能转化装置的二次电池相关技术一直是科学家研究的热点领域。在此背景下,本文较为系统地介绍目前二次电池的重要研究进展,将从二次电池的发展历史引入... 详细信息

能源的存储和利用是当今科学和技术发展中的重大课题之一,尤其是作为高效的电能/化学能转化装置的二次电池相关技术一直是科学家研究的热点领域。在此背景下,本文较为系统地介绍目前二次电池的重要研究进展,将从二次电池的发展历史引入,再到其相关的基础理论知识的介绍。随后较为详细地讨论当前不同体系的二次电池及相关应的关键材料的研究进展,涉及到锂离子电池、钠离子电池、钾离子电池、镁离子电池、锌离子电池、钙离子电池、铝离子电池、氟离子电池、氯离子电池、双离子电池、锂-硫(硒)电池、钠-硫(硒)电池、钾-硫(硒)电池、多价金属-硫基电池、锂-氧电池、钠-氧电池、钾-氧电池、多价金属-氧气电池、锂-溴(碘)电池、水系金属离子电池、光辅助电池、柔性电池、有机电池、金属-二氧化碳电池等。此外,也介绍了电池研究中常见的电极反应过程表征技术,包括冷冻电镜、透射电镜、同步辐射、原位谱学表征、磁性表征等。本文将有助于研究人员对二次电池进行全面系统的了解与把握,并为之后二次电池的研究提供很好的指导作用。

关键词：二次电池电池体系电池材料电化学知识表征技术

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