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Optimization of mixing speed and time to disperse the composite conductive agent composed of carbon black and graphene in lithium-ion battery slurry

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Particuology 2024年第9期92卷 1-12页

作者： Zhilong wang Jialong Tu Xinhao Yu Feixiang Li Zhenzhen Zhao Yahui Cui Tong Zhao Faculty of Mechanical and Precision Instrument Engineering Xi'an University of TechnologyXi'an710048China

This paper proposed an optimal approach to disperse the composite conductive agent which is composed of carbon black(CB)and graphene(Gr)within lithium-ion battery(LIB)slurry with different mixing speeds and mixing *** internal structures of LIB slurry are characterized by Electrochemical Impedance Spectroscopy,Scanning Electron Microscopy,and Raman ***,a composite conductive solution is prepared by mixing the composite conductive agent with NMP solvent under the conditions of five different mixing speeds n_(1)(n_(1)=1000,1100,1200,1300,1400 rpm)in the case of mixing time t_(1)=10 ***,LIB slurry is prepared by blending the composite conductive solution,LiCoO_(2)and PVDF-NMP solution under the conditions of five different mixing speeds n_(2)(n_(2)=1000±280,1100±280,1200±280,1300±280,1400±280 rpm)in the case of mixing time t_(2)=6 *** analyzing the internal structure of different LIB slurries,it shows that in the case of n_(1)=n_(2)=1200 rpm,a conductive network structure is well formed within LIB ***,in order to determine the optimal time to prepare the composite conductive solution for LIB slurry,nine different t_(1)(t_(1)=0,10,20,30,40,50,60,70,80 min)are *** analyzing the internal structure of different LIB slurries,a well-formed conductive network structure and a uniformly distributed composite conductive agent are deduced in LIB slurry when t_(1)=50 ***,it can be concluded that the composite conductive agent composed of CB and Gr is able to be uniformly dispersed in LIB slurry by establishing a well-formed conductive network structure under the optimal mixing speed n_(1)=n_(2)=1200 rpm and the optimal mixing time t_(1)=50 min,t_(2)=6 *** kind of the internal structure has the potential to be used to further analyze the dispersion characterizations of LIB slurry under different composite conductive agent and CB/Gr ratios with the aim of improving the final performance of LIB.

关键词： Lithium-ion battery slurry Composite conductive agent Carbon black Graphene

Hydrogen evolution reaction activity enhancement from active site turnover mechanism

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Journal of Energy Chemistry 2024年第5期92卷 629-638页

作者： Jiacheng wang Tongqing Yang Xiyue Li Haiqin Zhang Yixue Zhang Yan He Hongyao Xue College of Electromechanical Engineering Qingdao University of Science and TechnologyQingdao 266061ShandongChina

Although heteroatom doping is an effective way to improve the catalytic activity of transition metal phosphides(TMPs),the mechanism of activity enhancement needs to be further *** this end,we synthesized a Co-doped Ni_(2)P catalyst as a research model and found that the introduction of heterogeneous Co reconstructed the charge distribution around the P site,which effectively enhanced the hydrogen evolution reaction(HER)activity of the pure Ni_(2)*** on in-situ Raman real-time monitoring technology,we monitored for the first time that Co doping triggered a switch of the active site(from the original Co-active site to the P-active site),which promoted the adsorption of H_(2)O to enhance the HER *** density functional theory(DFT)calculations indicated that the P site of Co-Ni_(2)P expressed the highest activity and the Ni site of pure Ni_(2)P expressed the highest activity,which further confirms the in-situ Raman monitoring *** active site turnover mechanism discovered in this study will undoubtedly provide more rational and targeted ideas for future catalyst design.

关键词： In-situ Raman observation Heteroatom doping Activesites turnover Hydrogen production

Nonlinear Impact Damage Evolution of Charpy Type and Analysis of Its Key Influencing Factors

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Chinese Journal of Mechanical Engineering 2024年第1期37卷 254-264页

作者： Jianfeng Mao Qian Xu Jiadong Yang Chi Cao Dasheng wang Fengping Zhong Mingya Chen Institute of Process Equipment and Control Engineering Zhejiang University of TechnologyHangzhou 310032China Taizhou Key Laboratory of Advanced Manufacturing Technology Taizhou InstituteZhejiang University of TechnologyTaizhou 318014China State Key Laboratory of Nuclear Power Safety Monitoring Technology and Equipment Shenzhen 518172China Zhejiang Academy of Special Equipment Science Hangzhou 310020China Suzhou Nuclear Power Research Institute Suzhou 215004China

The current research of Charpy impact mainly focuses on obtaining the ductile brittle transition temperature of materials by *** with experiments,numerical simulation can study many problems with harsh ***,there are still few studies on the influence of geometric factors such as side *** this paper,the geometry of standard Charpy impact test is *** with different widths and side grooves are *** finite element model of Charpy impact was established by ABAQUS *** test results and simulation results to verify each *** effects of sample width,side groove depth and side groove bottom fillet on the impact fracture resistance of the sample were *** results show that the specimen width is positively correlated with the impact toughness of the *** side groove greatly reduces the impact toughness of the material;the toughness of side groove decreases with the increase of depth;the fracture toughness of side groove decreases with the increase of fillet at the bottom of side *** proportion of toughness energy to impact energy of samples was *** results show that the toughness energy accounts for about 70%of the impact energy of the sample,which has little to do with the geometric characteristics of the *** study presents a reliable method for studying Charpy impact *** influence of geometric parameters is obtained,which provides a reference method for the study of impact toughness of high toughness materials.

关键词： Johnson-Cook model Impact toughness Charpy impact

Precisely Control Relationship between Sulfur Vacancy and H Absorption for Boosting Hydrogen Evolution Reaction

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Nano-Micro Letters 2024年第4期16卷 14-24页

作者： Jing Jin Xinyao wang Yang Hu Zhuang Zhang Hongbo Liu Jie Yin Pinxian Xi College of Chemistry and Chemical Engineering Frontiers Science Center for Rare IsotopesState Key Laboratory of Applied Organic ChemistryLanzhou UniversityLanzhou 730000People’s Republic of China

Ef fective and robust catalyst is the core of water splitting to produce ***, we report an anionic etching method to tailor the sulfur vacancy(VS) of NiS_(2) to further enhance the electrocatalytic performance for hydrogen evolution reaction(HER). With the VS concentration change from 2.4% to 8.5%, the H* adsorption strength on S sites changed and NiS_(2)-VS 5.9% shows the most optimized H* adsorption for HER with an ultralow onset potential(68 m V) and has long-term stability for 100 h in 1 M KOH media. In situ attenuated-total-reflection Fourier transform infrared spectroscopy(ATR-FTIRS) measurements are usually used to monitor the adsorption of intermediates. The S-H* peak of the Ni S_(2)-VS 5.9% appears at a very low voltage, which is favorable for the HER in alkaline media. Density functional theory calculations also demonstrate the Ni S_(2)-VS 5.9% has the optimal |ΔG^(H*)| of 0.17 e V. This work offers a simple and promising pathway to enhance catalytic activity via precise vacancies strategy.

关键词： Hydrogen evolution reaction S vacancies Nanosheet H Adsorption

Patent-based technological developments and surfactants application of lithium-ion batteries fire-extinguishing agent

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Journal of Energy Chemistry 2024年第1期88卷 39-63,I0002页

作者： Jianqi Zhang Tao Fan Shuai Yuan Chongye Chang Kuo wang Ziwei Song Xinming Qian State Key Laboratory of Explosion Science and Technology Beijing Institute of TechnologyBeijing 100084China Industrial Safety Research Institute China Academy of Safety Science and TechnologyBeijing 100012China Fire Engineering Department China People’s Police UniversityLangfang 065000HebeiChina

While newer,more efficient Lithium-ion batteries(LIBs)and extinguishing agents have been developed to reduce the occurrence of thermal runaway accidents,there is still a scarcity of research focused on the application of surfactants in different LIBs extinguishing agents,particularly in terms of patented *** aim of this review paper is to provide an overview of the technological progress of LIBs and LIBs extinguishing agents in terms of patents in Korea,Japan,Europe,the United States,China,*** initial part of this review paper is sort out LIBs technology development in different *** addition,to compare LIBs extinguishing agent progress and challenges of liquid,solid,combination of multiple,and *** subsequent section of this review focuses on an in-depth analysis dedicated to the efficiency and challenges faced by the surfactants corresponding design principles of LIBs extinguishing agents,such as nonionic and anionic surfactants.A total of 451,760 LIBs-related patent and 20 LIBs-fire-extinguishing agent-related patent were included in the *** extinguishing effect,cooling performance,and anti-recombustion on different agents have been *** a comprehensive comparison of these agents,this review suggests that temperature-sensitive hydrogel extinguishing agent is ideal for the effective control of LIBs *** progress and challenges of surfactants have been extensively examined,focusing on key factors such as surface activity,thermal stability,foaming properties,environmental friendliness,and electrical ***,it is crucial to emphasize that the selection of a suitable surfactant must align with the extinguishing strategy of the extinguishing agent for optimal firefighting effectiveness.

关键词： LIBs Fire-extinguishing agent Surfactants Patent

An aircraft brake control algorithm with torque compensation based on RBF neural network

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Chinese Journal of Aeronautics 2024年第1期37卷 438-450页

作者： Ning BAI Xiaochao LIU Juefei LI Zhuangzhuang wang Pengyuan QI Yaoxing SHANG Zongxia JIAO School of Automation Science and Electrical Engineering Beihang UniversityBeijing 100191China Science and Technology on Aircraft Control Laboratory Beihang UniversityBeijing 100191China Key Laboratory of Advanced Aircraft Systems(Beihang University) Ministry of Industry and Information TechnologyBeijing 100091China Research Institute for Frontier Science Beihang UniversityBeijing 100191China Ningbo Institute of Technology of Beihang University Ningbo 315800China Tianmushan Laboratory Xixi Octagon CityYuhang DistrictHangzhou 310023China

The wheel brake system of an aircraft is the key to ensure its safe landing and rejected takeoff.A wheel’s slip state is determined by the brake torque and ground adhesion torque,both of which have a large degree of *** is this nature that brings upon the challenge of obtaining high deceleration rate for aircraft brake *** overcome the disturbances caused by the above uncertainties,a braking control law is designed,which consists of two parts:runway surface recognition and wheel’s slip state *** runway surface recognition,the identification rules balancing safety and braking efficiency are defined,and the actual identification process is realized through recursive least square method with forgetting *** slip state tracking,the LuGre model with parameter adaptation and a brake torque compensation method based on RBF neural network are proposed,and their convergence are *** effectiveness of our control law is verified through simulation and ground *** in the experiments on the ground inertial test bench,compared to the improved pressure-biased-modulation(PBM)anti-skid algorithm,fewer wheel slips occur,and the average deceleration rate is increased by 5.78%,which makes it a control strategy with potential for engineering applications.

关键词： Aircraft landing Brakes Disturbance observer Neural networks Runway identification

Constructing extrinsic oxygen vacancy on the surface of photocatalyst as CO_(2)and electrons reservoirs to improve photocatalytic CO_(2)reduction activity

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Journal of Environmental Sciences 2024年第6期140卷 37-45页

作者： Zaiyong Jiang Hao Li Zhimin Yuan Zheng wang Maohong Fan Wenkang Miao Hong He State Key Joint Laboratory of Environment Simulation and Pollution Control Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China School of Chemistry&Chemical Engineering and Environmental Engineering Weifang UniversityWeifangShandong 261061China Departments of Chemical and Petroleum Engineering University of WyomingLaramieWY 82071USA Materials Genome Institute Shanghai UniversityShanghai 200444China

Constructing own oxygen vacancies in the photocatalysts is a very promising method to improve their photocatalytic CO_(2)reduction ***,some catalysts have excellent stabilities,making it difficult for them to construct their own oxygen *** simplify the above difficulty of stable photocatalysts,constructing extrinsic oxygen vacancies on their surface as a novel idea is ***,a stable TiO_(2)nanosheet is chosen as a research object,we uniformly deposited BiOCl quantum dots on their surface via a simple adsorption-deposition *** is found that BiOCl quantum dots are able to simultaneously self-transform into defective BiOCl with many oxygen vacancies when the photocatalyst is performed photocatalytic CO_(2)*** extrinsic oxygen vacancies can act as“CO_(2)and photo-generated electrons reservoirs”to improve CO_(2)capture and accelerate the separation of photogenerated electrons and *** the above reasons,the modified TiO_(2)showed obvious enhancement of photocatalytic CO_(2)reduction compared to pristine TiO_(2)and *** work may open a new avenue to broaden the use of oxygen vacancies in the process of photocatalytic CO_(2)reduction.

关键词： Oxygen vacancy BiOCl Photocatalyst CO_(2)reduction TiO_(2)

Overcoming the Limits of Cross-Sensitivity:Pattern Recognition Methods for Chemiresistive Gas Sensor Array

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Nano-Micro Letters 2024年第12期16卷 285-341页

作者： Haixia Mei Jingyi Peng Tao wang Tingting Zhou Hongran Zhao Tong Zhang Zhi Yang Key Lab Intelligent Rehabil&Barrier Free Disable(Ministry of Education) Changchun UniversityChangchun 130022People’s Republic of China Shanghai Key Laboratory of Intelligent Sensing and Detection Technology School of Mechanical and Power EngineeringEast China University of Science and TechnologyShanghai 200237People’s Republic of China National Key Laboratory of Advanced Micro and Nano Manufacture Technology Department of Micro/Nano ElectronicsSchool of Electronic Information and Electrical EngineeringShanghai Jiao Tong UniversityShanghai 200240People’s Republic of China State Key Laboratory of Integrated Optoelectronics College of Electronic Science and EngineeringJilin UniversityChangchun 130012People’s Republic of China

As information acquisition terminals for artificial olfaction,chemiresistive gas sensors are often troubled by their cross-sensitivity,and reducing their cross-response to ambient gases has always been a difficult and important point in the gas sensing *** recognition based on sensor array is the most conspicuous way to overcome the cross-sensitivity of gas *** is crucial to choose an appropriate pattern recognition method for enhancing data analysis,reducing errors and improving system reliability,obtaining better classification or gas concentration prediction *** this review,we analyze the sensing mechanism of crosssensitivity for chemiresistive gas *** further examine the types,working principles,characteristics,and applicable gas detection range of pattern recognition algorithms utilized in gas-sensing ***,we report,summarize,and evaluate the outstanding and novel advancements in pattern recognition methods for gas *** the same time,this work showcases the recent advancements in utilizing these methods for gas identification,particularly within three crucial domains:ensuring food safety,monitoring the environment,and aiding in medical *** conclusion,this study anticipates future research prospects by considering the existing landscape and *** is hoped that this work will make a positive contribution towards mitigating cross-sensitivity in gas-sensitive devices and offer valuable insights for algorithm selection in gas recognition applications.

关键词： Pattern recognition Sensor array Chemiresistive gas sensor Cross-sensitivity Artificial olfactory

Nano-silica modified lightweight and high-toughness carbon fiber/phenolic ablator with excellent thermal insulation and ablation performance

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Defence Technology（防务技术） 2024年第1期31卷 192-199页

作者： Wenjie Xu Wenda Song Xianfeng Jia Cheng Ma Jitong wang Wenming Qiao Licheng Ling State Key Laboratory of Chemical Engineering East China University of Science and TechnologyShanghai 200237China School of Chemical Engineering and Materials Changzhou Institute of TechnologyChangzhou 213032China Key Laboratory of Specially Functional Polymeric Materials and Related Technology(Ministry of Education) School of Materials Science and EngineeringEast China University of Science and TechnologyShanghai 200237China

Lightweight and high-toughness carbon fiber/phenolic ablator(CFPA)is required as the Thermal Protection System(TPS)material of aerospace vehicles for next-generation space *** improve the ablative properties,silica sol with good particle size distribution prepared using tetramethoxysilane(TMOS)was blended with natural rubber latex and deposited onto carbon fiber felt,which was then integrated with phenolic aerogel matrix,introducing nano-silica into the framework of *** modified CFPA with a low density of 0.28—0.31 g/cm3exhibits strain-in-fracture as high as 31.2%and thermal conductivity as low as 0.054 W/(m·K).Furthermore,a trace amount of nano-silica could effectively protect CFPA from erosion of oxidizing atmosphere in different high-temperature *** oxyacetylene ablation test of 3000°C for 20 s shows a mass ablation rate of 0.0225 g/s,a linear ablation rate of 0.209 mm/s for the modified CFPA,which are 9.64%and 24.82%lower than the unmodified ***,the long-time butane ablation test of 1200°C for 200 s shows an insignificant recession with mass and linear ablation rate of 0.079 g/s and 0.039 mm/s,16.84%and 13.33%lower than the unmodified ***,the fixed thermocouple in the test also demonstrates a good thermal insulation performance with a low peak back-face temperature of 207.7°C,12.25%lower than the unmodified ***,the nano-silica modified CFPA with excellent overall performance presents promising prospects in high-temperature aerospace applications.

关键词： Nano-silica Carbonfiber Phenolic aerogel Insulation Ablation