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Unlocking the stable interface in aqueous zinc-ion battery with multifunctional xylose-based electrolyte additives

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Journal of Energy Chemistry 2025年第1期100卷 770-778页

作者： Xiaoqin Li Jian xiang Lu Qiu Xiaohan Chen Yinkun Zhao Yujue wang Qu Yue Taotao Gao Wenlong Liu Dan Xiao Zhaoyu Jin Panpan Li Institute for Advanced Study Chengdu University School of Mechanical Engineering Chengdu University College of Food and Biological Engineering Chengdu University Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of China College of Materials Science and Engineering Sichuan University

The growth of dendrites and the side reactions occurring at the Zn anode pose significant challenges to the commercialization of aqueous Zn-ion batteries（AZIBs）. These challenges arise from the inherent conflict between mass transfer and electrochemical kinetics. In this study, we propose the use of a multifunctional electrolyte additive based on the xylose（Xylo） molecule to address these issues by modulating the solvation structure and electrode/electrolyte interface, thereby stabilizing the Zn anode. The introduction of the additive alters the solvation structure, creating steric hindrance that impedes charge transfer and then reduces electrochemical kinetics. Furthermore, in-situ analyses demonstrate that the reconstructed electrode/electrolyte interface facilitates stable and rapid Zn2+ion migration and suppresses corrosion and hydrogen evolution reactions. As a result, symmetric cells incorporating the Xylo additive exhibit significantly enhanced reversibility during the Zn plating/stripping process, with an impressively long lifespan of up to 1986 h, compared to cells using pure ZnSO4electrolyte. When combined with a polyaniline cathode, the full cells demonstrate improved capacity and long-term cyclic stability. This work offers an effective direction for improving the stability of Zn anode via electrolyte design, as well as highperformance AZIBs.

关键词： Solvation

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油茶对低磷胁迫的生理生化效应研究

林业科学研究 2010年第5期23卷 782-786页

作者：陈隆升陈永忠彭邵锋马力王瑞王湘南湖南省林业科学院湖南长沙410004

The physiological and biochemical responses of Camellia oleifera to low phosphorus stress were investigated in this study,and the different phosphorus concentrations of the treatments were conducted by using a single factor experiment with water culture in the *** showed that the activity of APA in leaves tissues and those secreted by the roots all increased under P deficiency,which respectively increased by 16.49%～86.47% and 28.7%～58.7% compared with those of the *** increase of APA may be an active adaptive response of Camellia oleifera to low phosphorus *** the situation of low phosphorus stress,the concentrations of soluble sugar and free proline increased whereas the soluble protein decreased,those showed that normal protein synthesis and carbohydrate metabolism were blocked under the situation of low phosphorus stress;Moreover,the homeostasis established by the increase of MDA concent and protective enzyme(SOD) activity in leaves was the mechanism of the adaptive response for Camellia oleifera to low phosphorus stress.

关键词：油茶低磷胁迫生理生化响应

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我国海上试验场建设总体设想

海洋技术 2010年第4期29卷 1-3页

作者：罗续业王项南周毅吴迪王春谊李彦国家海洋技术中心天津300112

海上试验场的建成可为海洋科学研究、海上技术装备的研发、测试、评价等提供科学有效的试验环境,并可获取长期连续、要素完备的数据资料。可为海洋调查观测技术装备的现场试验和定标检验、海洋观测监测方法研究、海洋学数学模型检验、... 详细信息

海上试验场的建成可为海洋科学研究、海上技术装备的研发、测试、评价等提供科学有效的试验环境,并可获取长期连续、要素完备的数据资料。可为海洋调查观测技术装备的现场试验和定标检验、海洋观测监测方法研究、海洋学数学模型检验、水下通讯和组网试验、水下传感器网络试验、卫星遥感器在轨现场定标和检验以及军事海洋学研究等科学活动提供技术服务平台。对于快速提升我国海洋技术装备和海洋科学研究水平,实现科技兴海战略具有重要意义。

关键词：海上试验场观测技术军事海洋科技兴海

Lung-targeted polyzwitterionic lipid nanoparticles for effective treatment of lung inflammation

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Science China Chemistry 2025年

作者： Wen Zhang Jiaxin Li nan wang Muzi Li Chen Peng Xinyue Zhang Guanghui Ouyang Yan Li Beijing Key Laboratory for Bioengineering and Sensing Technology School of Chemistry and Biological Engineering University of Science and Technology Beijing CAS Key Laboratory of Colloid Interface and Chemical Thermodynamics Institute of Chemistry Chinese Academy of Sciences

Lipid nanoparticles (LNPs) are non-viral nucleic acid delivery systems that show great potential in vaccine development and disease treatment. Although LNPs are particularly advantageous for in vivo delivery, the wide application of LNPs is impeded as their systemic delivery of nucleic acid drugs to extrahepatic tissues remains highly challenging. To address this issue, we developed lung-targeted polyzwitterionic LNPs with zwitterionic polymer poly(2-methyacryloyloxyethyl phosphorylcholine)(PMPC) modified 1,2-dimyristoyl-sn-glycerol lipid for the delivery of small interfering RNA (siRNA). Three libraries with 90PMPC-LNPs@siRNA were established. The polyzwitterionic PMPC-LNPs had high siRNA encapsulation efficiency of about90%. The findings revealed that polyzwitterionic PMPC-LNPs@siRNA absorbed protein corona with the main component of Vitronectin, mediating lung-targeted delivery of siRNA. With good cellular uptake and endo/lysosomal escape ability, in vitro and in vivo studies demonstrated that polyzwitterionic PMPC-LNPs with siRNA against tumor necrosis factor-α (TNF-α) could significantly down-regulate the TNF-α in mRNA and protein levels, and improved the pathological features of lung inflammation. Polyzwitterionic PMPC-LNPs@siRNA achieved safe and efficient treatment of lung inflammation. Therefore, this work offered a promising siRNA therapeutic approach for lung diseases.

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左束支起搏的现状分析

心血管康复医学杂志 2023年第1期32卷 61-63页

作者：王湘楠李述峰哈尔滨医科大学附属第二医院心血管内科黑龙江哈尔滨150081

起搏器植入术是治疗缓慢性心律失常的有效手术方式。传统的起搏方式为右心室心尖部起搏和右室间隔起搏,此类起搏方式会导致心肌电活动和机械活动收缩不同步,增加心衰和心律失常的风险。而希氏束起搏和左束支起搏(LBBP)则解决了左、右心... 详细信息

起搏器植入术是治疗缓慢性心律失常的有效手术方式。传统的起搏方式为右心室心尖部起搏和右室间隔起搏,此类起搏方式会导致心肌电活动和机械活动收缩不同步,增加心衰和心律失常的风险。而希氏束起搏和左束支起搏(LBBP)则解决了左、右心室电和机械活动不同步的问题。本文就LBBP的现状作一综述。

关键词：心动过缓希氏束起搏心脏起搏器人工

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海水中溶解二氧化碳监测技术跟踪

海洋技术 2009年第4期28卷 24-26页

作者：王项南王晶吴迪张绍武李超周毅国家海洋技术中心天津300112 天津市天特国家贸易有限公司天津300230

综述了研究监测海水中二氧化碳含量的目的及意义和二氧化碳在海水中的存在形式,以及测量海水中溶解二氧化碳浓度的监测方法,着重介绍了直接测量的几种原理和目前主要采用的基于红外分析原理的研制方法,并对该领域的现状和发展进行了分析。

关键词：海水二氧化碳监测方法含量

Formation and evolution of supercritical geofluid

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Science China Earth Sciences 2025年第1期68卷 39-51页

作者： Huaiwei NI Yilin XIAO Xiaolin XIONG Xiandong LIU Chunxiao GAO Yi-xiang CHEN Yunguo LI Wan-Cai LI Xuan GUO Yang-Yang wang Dong-Bo TAN Li ZHANG State Key Laboratory of Lithospheric and Environmental Coevolution University of Science and Technology of China Deep Space Exploration Laboratory/School of Earth and Space Sciences University of Science and Technology of China Guangzhou Institute of Geochemistry Chinese Academy of Sciences School of Earth Sciences and Engineering Nanjing University State Key Lab of Superhard Materials Jilin University

In this work, we provide a comprehensive review on the formation, evolution, properties, and effects of supercritical geofluid. In Earth's interior, enhanced miscibility between H2O and silicate by the addition of special components or by the increase of pressure and temperature gives rise to supercritical geofluid with a significant amount of both H2O and silicate *** formation of supercritical geofluid in magmatic-hydrothermal systems, typified by pegmatite system, is governed by meltfluid critical curve. The formation of supercritical geofluid in metamorphic systems, typified by subducted slab, is governed by the second critical end point. Experimental results suggest that the presence of boron and fluorine in pegmatite system makes it possible to form supercritical geofluid at crustal depths, but the release of supercritical geofluid from subducted slab is withheld until almost 100 km depth. A major presence of both H2O and depolymerized structural units（monomers, dimers, etc.） endows supercritical geofluid with unique physical properties including low density, low elastic moduli, low viscosity, high diffusivity,and high electrical conductivity. Supercritical geofluid can effectively mobilize a variety of elements even including high field strength elements and heavy rare earth elements. The chemical signatures of supercritical geofluid can be inherited by metasomatized mantle and mantle-derived melts, and this could give an explanation of the oxidation of arc magmas. Phase separation of supercritical geofluid through the mechanism of spinodal decomposition leads to formation of a melt network. Multiphase fluid inclusions recovered from subduction zone rocks and pegmatites are possible relics of supercritical geofluid. Supercritical geofluid can cause electrical anomaly and low seismic velocity near the top of subducted slab, and can be linked with intermediate-focus earthquakes. Supercritical geofluid may have played a crucial role in the formation of pe

关键词： Supercritical geofluid Miscibility Subduction zone Pegmatite

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Contribution of fungal biomass to persistent soil carbon across natural ecosystems

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Science China Earth Sciences 2025年

作者： xiang wang Guang-Hui YU Yakov KUZYAKOV Bo-Hao YIN Andreas KAPPLER Cong-Qiang LIU Bohai Coastal Critical Zone National Observation and Research Station Institute of Surface-Earth System Science School of Earth System Science Tianjin Key Laboratory of Earth Critical Zone Science and Sustainable Development in Bohai Rim Tianjin University Department of Soil Science of Temperate Ecosystems Department of Agricultural Soil Science University of G?ttingen Agro-Technological Institute Peoples Friendship University of Russia (RUDN University) Geomicrobiology Center for Applied Geosciences University of Tübingen Cluster of Excellence EXC 2124 Controlling Microbes to Fight Infection University of Tübingen

Fungi are known to be crucial in the formation and stabilization of soil organic matter through their exudates and dead residues (necromass). Yet, it remains unclear how fungi contribute to the persistence of carbon in soils over millennial scales across biomes. Here, this study fills the knowledge gap by linking fungal carbon stocks with minerals-associated carbon stocks across major biomes. A strong correlation between fungal biomass and reactive mineral-associated carbon stocks in soils across six biomes supports the substantial role of fungi in soil carbon persistence at the global level. High spatial resolution nanoscale secondary ion mass spectrometry revealed that fungi may stabilize carbon by forming organo-mineral associations through their close physical connection to reactive minerals and weathered nanoparticles. We propose a conceptual model that emphasizes the dualistic role of hypha-mineral interactions:(i) fungi accelerate organic matter decomposition by producing reactive oxygen species on the hypha-mineral interfaces, and (ii) fungi stabilize their residues on mineral surfaces, leading to millennial scale persistence of soil C. Concluding, fungi play a fundamental role in ecosystems that extends beyond the decomposition of persistent carbon. They are crucial in stabilizing carbon on mineral surfaces, thereby facilitating the long-term removal of carbon from rapid biotic cycling.

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Multivariate synergy for heightening ionic HOF robustness and proton conductivity

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Science China Chemistry 2025年

作者： xiang-Tian Bai Li-Hui Cao Xu-Yong Chen Jia-Yu wang Zi-Ye Zhou Shaanxi Key Laboratory of Chemical Additives for Industry College of Chemistry and Chemical EngineeringShaanxi University of Science and Technology

Multicomponent crystalline materials construct more complex and diversified structures with different combinations and modes,which expands the material structure space and application *** this work,we have successfully synthesized two twocomponent ionic hydrogen-bonded organic frameworks （iHOF-32 and iHOF-33） and a three-component iHOF （iHOF-34）.Guanidine hydrochloride which is rich in N and H and has a short chain length strengthens the hydrogen bonding network of iHOF,thereby aiding in the efficient migration of *** rigid architecture of 1,1'-diamino-4,4'-bipyridine diiodide furnishes additional scaffolding for the iHOFs and enhances its robustness under harsh ***-34 accomplishes the combination of the ultra-high proton conductivity of iHOF-32 and the robustness of iHOF-33 by the synergistic interaction among the three components of *** addition,iHOF-34 was fabricated as a composite membrane with a peak proton conductivity of 1.55×10-1S cm-1,which is 3.8 times higher than that of recast Nafion,and has extensive potential in fuel *** self-assembly strategy of multicomponent HOFs opens up new avenues for constructing diverse structures while promising new opportunities for applications in the fields of proton conduction and energy storage.

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