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Chinese Science Bulletin 2000年第S1期45卷 26-34页

作者： wang yunpengguangzhou institute of geochemistry, Chinese Academy of Sciences, guangzhou 510640,{2. guangzhou institute of {2. Chinese Academy of Sciences Guangzhou China

This paper presents the contents of 17 kinds of trace elements in plant leaf samples collected from 4 sections in the North Jiangsu oil field, and the dada on their visible-near infrared spectra. By comparing the results of the inner and outer oil-gas remote-sensing anomaly areas, the plant trace element composition, and the enrichment characteristics and their influence on the plant spectral properties are described. The results indicated that the plant leaves had very strong enrichment ability toward some elements such as Mg, Ca, K, Na, Fe, Al, Mn, V, Zn and Cr. The plant leaves from the oil-gas abnormal areas were enriched in trace elements of the Fe-series, but depleted in alkali and alkali-earth metal elements. The plant trace elements had a strong influence on the 'blue-shift' strength and the reflectance of visible bands. And the ratios between Fe, Co and K, Na, Cd, Cu, Ba are the effective remote-sensing oil-indicating factors of plant trace elements. plant trace element, geochemistry, remote

关键词： plant trace element geochemistry remote sensing spectra North Jiangsu oil fleld.

Nitric Oxide Emission Following Wetting of Dry Soils in Subtropical Humid Forests

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Pedosphere 2009年第6期19卷 692-699页

作者： LI De-Jun and wang Xin-Ming 2.State Key Laboratory of Organic geochemistry, {2. institute of geochemistry, Chinese Academy of Sciences, guangzhou 510640 (china) State Key Laboratory of Organic geochemistry Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou 510640 (China)

Information about soil nitric oxide （NO） emissions from subtropical forests is quite limited, and even less is known about the pulse emission of NO when wetting soils after a long period of dryness. In this study, we measured NO fluxes following wetting of dry soft in a broadleaf forest and a pine forest in subtropical china. Large pulses of NO fluxes were observed after soil wetting in both forests. NO fluxes increased significantly within 0.5 h following wetting in both forests and reached peak 1 and 4 h after soil wetting in the pine forest and the broadleaf forest, respectively. In the broadleaf forest, averaged peak flux of NO pulses was 157 ng N m^-2.s^-1, which was 8 times the flux value before wetting, and in the pine forest, the averaged peak flux was 135 ng N m-2.s 1, which was 15.5 times the flux value before wetting. The total pulses-induced NO emissions during the dry season were roughly estimated to be 2..4 mg N m^-2.in the broadleaf forest and 2..2.mg N m^-2.in the pine forest or made up a proportion of 4.6% of the annual NO emission in the broadleaf forest and 5.3% in the pine forest.

关键词： dry season flux. NO. pulse subtropical china

Evaluation criteria for gas source rocks of marine carbonate in china

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Progress in Natural Science:Materials International 2005年第9期15卷 810-817页

作者： wang Zhaoyun1**, ZHAO Wenzhi1 and wang Yunpeng2.1. Research {2. of Petroleum Exploration & Development,Petrochina, Beijing 100083, china 2. guangzhou {2. of geochemistry, Chinese Academy of Sciences, guangzhou 510640, china) Research institute of Petroleum Exploration and Development PetroChina Beijing 100083 China guangzhou institute of {2. Chinese Academy of Sciences Guangzhou 510640 China

Hydrocarbon generating and expulsion simulation experiments are carried out using samples artifically matched between the acid-dissolved residue of relatively low-maturity limestone and the original sample. This work makes up for the insufficiency of source rock samples with high abundance of organic matters and low maturity in china. The organic carbon content of the 10 prepared samples varies between 0.15% and 0.74%. Pyrolysis data and simulation experiment results of hydrocarbon generating and expulsion, which were obtained by a high-temperature and high-pressure open system, indicate that the lower limit of organic carbon content for marine carbonate rock to generate and expel hydrocarbons is 0.2.%—0.31%. In combination with the numerical analysis of organic carbon in marine carbonate rocks from Tarim Basin, Sichuan Basin, Ordos Basin and North china, as well as the contribution of these gas source rocks to the discovered gas pools, we think that the organic carbon criterion for carbonate gas source rocks should be 0.3%.

关键词： carbonate gas source rock gas-generating efficiency evaluation criteria simulation experiment.

NaAlSi_3O_8-hollandite and other high-pressure minerals in the shock melt veins of the Suizhou meteorite

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Chinese Science Bulletin 2001年第13期46卷 1121-1126页

作者： XIE Xiande, CHEN Ming, wang Deqiang & El Goresy A.1.guangzhou {2. of geochemistry, Chinese Academy of Sciences, guangzhou 510640, china 2. Max-Planck-{2. fur Chemie, 5512. Mainz, Germany guangzhou institute of {2. Chinese Academy of Sciences Guangzhou 510640 China Max-Planck-institute für Chemie 55128 Mainz Germany

The Suizhou L6 chondrite contains a few very thin shock melt veins of 0.02.0.09 mm in width. In spite of small width of the veins, shock-induced high-pressure phases, such as coarse-grained NaAlSi3O8-hollandite, ringwoodite, majorite and fine-grained matrix majorite-pyropess have been discovered in these veins. NaAlSi3O8-hollandite, the high-pressure phase of plagioclase, in Suizhou shock veins occurs as a single phase mineral, no silicate glassy phase, such as albitic glass, was incorporated with it. The presence of above-mentioned high-pressure phases constrains the high pressure (up to 2.-2. GPa) and high temperature (up to 1900-2.00℃) regime in Suizhou shock veins, and indicates that the duration of high-pressure regime in the veins should be long enough (a few seconds) for phase transformation and crystallization of minerals under pressure. The discovery of the first natural single-phase crystalline NaAlSi3O8- holland-ite in Suizhou meteorite is of important significance in understanding the Earth’

关键词： high NaAlSi3O8-hollandite and other high-pressure minerals in the shock melt veins of the Suizhou meteorite

The Juancheng chondrite──A new meteorite falling recently in china

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Chinese Science Bulletin 1998年第21期43卷 1834-1837页

作者： CHEN Yongheng 1,2. wang Daode+2.and wang Ruitian+31. Department of Chemistry, {2. Normal University, {2. 510400, china 2. {2. institute of geochemistry, Chinese Academy of Sciences, guangzhou 510640, china 3. Heze Bureau of Seismolo Department of Chemistry Guangzhou Normal University Guangzhou China guangzhou institute of {2. Chinese Academy of Sciences Guangzhou China Heze Bureau of Seismology Shandong Province Heze China

The Juancheng chondrite, a new meteorite falling recently in Juancheng County, Shandong Province, china, is classified as an H5 (S2. chondrite based on the compositions of olivine (Fa= 19.2. σ Fa=0.46) and low-Ca pyroxene (Fs=16.9, σ Fa=0.4). The plagioclase in the Juancheng chondrite is rich in CaO, indicating a relatively high metamorphic temperature the parent body underwent.

关键词： Juancheng ordinary chondrite new meteorite.

The biomarkers of 2.6,10,15, 19-pentamethylicosenes and their carbon isotopic composition in the sediments from the Gulf of Mexico

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Chinese Science Bulletin 2006年第14期51卷 1736-1740页

作者： SONG Zhiguang1,2.& wang Cuiping1,31. State Key Laboratory of Organic geochemistry, {2. institute of geochemistry, Chinese Academy of Sciences, guangzhou 510640, china 2. {2. Research Center of Gas Hydrate, Chinese Academy of Sciences, guangzhou 510640, china 3. Graduate School of Chinese Academy of Sciences, Beijing 100039, china State Key Laboratory of Organic geochemistry Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou China guangzhou Research Center of Gas Hydrate Chinese Academy of Sciences Guangzhou China Graduate School of Chinese Academy of Sciences Beijing China

A group of 2.6,10,15,19-pentamethyli- cosenes (PMIΔ) containing 1―5 unsaturated double bonds has been identified in the sea floor sediments from the Gulf of Mexico at the Green Canyon 2.8 *** PMIΔ compounds are distributed between nC2. and nC2. on the mass chromatogram of aliphatic fraction. Their δ 13C values are very much depleted in 13C and in the range of ?86.7‰ to ?115.5‰, whereas the δ 13C values of companion n-alkanes range from ?2..4‰ to ?34.6‰. These unsaturated PMIΔ com-pounds are typical biomarkers derived from the an-aerobic oxidation of methane mediated by meth-ane-oxidizing archaeal bacteria and indicative of the gas seeps or even the occurrence of gas hydrates in the deep sea sediments.

关键词：生物标志墨西哥湾沉积物 PMIA 天然气水化物

Noble gas and cosmic-ray exposure age of Juancheng chondrite

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Chinese Science Bulletin 1999年第12期44卷 1142-1143页

作者： wang Daode and wang Ruitian {2. institute of geochemistry, Chinese Academy of Sciences , guangzhou 510640, china Heze Bureau of Seismology, Shandong Province , Heze 2.402., china guangzhou institute of {2. Chinese Academy of Sciences Guangzhou China Heza Bureau of Seismology Shandong Province Heze China

The analytical results of noble gase in recently fallen Juancheng chondrite indicate that cosmic-ray ages of cosmogenic nuclei of 3He, 2.Ne and 38Ar are 5.1, 5.0 and 5.8 Ma, respectively, averaging 5.3 Ma. The gas retention ages radiogenic nuclei of 4He and 40Ar are 32.0 and 4 2.0 Ma, respectively. The average cosmic-ray age shows that it has occurred at breakup of the meteoroid from its parent body by impact before 5.3 Ma.

关键词： noble gas cosmic-ray exposure age chondrite Juancheng Shandong.

Total alkyl dibenzothiophenes content tracing the filling pathway of condensate reservoir in the Fushan Depression,South china Sea

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Science china Earth Sciences 2008年第S2期51卷 138-145页

作者： LI MeiJun1,wang TieGuan1,LIU Ju2.ZHANG MeiZhu2.LU Hong3,MA QinLin2.& GAO LiHui2.1 State Key Laboratory of Petroleum Resources and Prospecting,Earth Sciences and Geoinformatics School,china University of Petroleum,Beijing 102.49,china 2.Southern Oil Exploration and Development Company,Petrochina,guangzhou 510640,china 3 guangzhou institute of geochemistry,Chinese Academy of Sciences,guangzhou 5102.0,china State Key Laboratory of Petroleum Resources and Prospecting Earth Sciences and Geoinformatics School China University of Petroleum Beijing China Southern Oil Exploration and Development Company PetroChina Guangzhou China guangzhou institute of {2. Chinese Academy of Sciences Guangzhou China

The condensates are generally characterized by high maturity,low concentration of steranes and ter-panes biomarkers and low content of non-hydrocarbon fraction. In this case commonly used steranes,terpanes and carbazoles parameters cannot be effectively applied in the reservoir-filling tracing. The hydrogen bond formed by sulfur atom in the dibenzothiophenes (DBTs) results in molecule adsorption and fractionation during oil migration in reservoir. Like carbazoles,total DBTs content decreases with the increasing of oil migration distance. Therefore,a new parameter——total DBTs content is proposed to be used to trace the oil migration orientation and filling pathway. In present study,total DBTs con-tents of condensates and light oils are obtained by adding internal standard——eight deuterium atoms substituted DBT during Gas Chromatography-Mass Spectrometry analysis of aromatic fraction. Except for a few samples with much lower content of non-hydrocarbon fraction,the total DBTs content shows a fine positive correlation with that of carbazoles. Large errors can be caused in the process of pyrrolic nitrogen compounds separation. The application of this new parameter in the Fushan Depression of Beibu Gulf Basin,South china Sea indicates that this parameter is a reliable one to trace filling pathway in condensate reservoirs. Combined with other DBTs-related parameters,such as 4-/1-methydibenzo-thiophene and 2.4-/1,4-dimethyldibenzothiophene,oil migration orientation and filling pathway of the Fushan Depression was determined. The accumulations of Huachang oil field in the Fushan Depres-sion are mainly migrated and charged from northeast to southeast along the Huachang uplift. It can be predicated that the light oil and condensates in the Huachang oil field should be sourced from the source kitchen at the Bailian Sag. It shows that total DBTs content is an effective parameter to tracing oil migration orientation and filling pathway.

关键词： dibenzothiophene alkyl dibenzothiophene condensate reservoir filling pathway molecular markers the Fushan Depression

Identification of marine natural gases with different origin sources

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Science china Earth Sciences 2008年第S1期51卷 148-164页

作者： wang YunPeng 1 ,ZHAO ChangYi 2.,wang ZhaoYun 2.,wang HongJun 2.,TIAN Jin 1 ,ZOU YanRong 1 &LIU JinZhong1 1State Key Laboratory of Organic geochemistry,guangzhou institute of geochemistry,Chinese Academy of Sciences,guangzhou 510640,china 2.5} of Geology,Research institute of Petroleum Exploration and Development,Petrochina,Beijing 100083,china State Key Laboratory of Organic geochemistry Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou China institute of Geology Research Institute of Petroleum Exploration and Development PetroChina Beijing China

Kinetic experiments of gas generation for typical samples of marine gas precursors including low-maturity kerogen,residual kerogen and oil as well as dispersed liquid hydrocarbon(DLH)in source rocks were performed by closed system,and the evolution trends of molecular and isotopic compositions of natural gases from different precursors against the maturity(R0%)at laboratory conditions were *** diagrams of gas origin were calibrated by using the experimental data.A diagram based on the ratio of normal and isomerous butane and pentane(i/nC4-i/nC5)was proposed and used to identify the origins of the typical marine natural gases in the Sichuan Basin and the Tarim Basin, *** the maturities of natural gases were estimated by using the statistical relationships between the gaseous molecular carbon isotopic data and maturities(δ13C-R 0 %)with different *** results indicate that the molecular and isotopic compositions of simulated gases from different precursors are different from each *** example,the dryness index of the oil-cracking gas is the lowest;the dryness indices of gases from DLH and kerogen in closed system are almost the same;and the dryness index of gases from residual kerogen is extremely high,indicating that the kerogen gases are very dry;the contents of non-hydrocarbon gases in kerogen-cracking gases are far higher than those in oil-cracking and DLH-cracking *** molecular carbon isotopes of oil-cracking gases are the lightest,those of kerogen in closed system and GLH-cracking gases are the second lightest,and those of cracking gases from residual kerogen are the *** calibration results indicate that the diagrams of ln(C1/C2.-ln(C2.C3)andδ13C2.δ13C3-ln(C2.C3)can discriminate primary and secondary cracking gases,but cannot be used to identify gas origin sources,while the diagram of i/nC4-i/nC5 can differentiate the gases from different *** application results of these diagrams show that gas mixtures ext

关键词： marine organic matter gas origin sources kerogen oil-cracking gas origin identification carbon isotope

The non-point source (NFS) information system based on remote sensing and GIS and its preliminary application

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Chinese Science Bulletin 2000年第S1期45卷 71-75,116页

作者： wang yunpengguangzhou institute of geochemistry, Chinese Academy of Sciences, guangzhou 510640,{2.

A non-point source information system (NPSIS) has been constructed by use of remote sensing and GIS technology, and a construction method of NPSIS introduced with Shenzhen as an example. With the remote sensing land-using images as an environment unit, the analysis modules based on NPSIS are built through combining the NPS model with NPSIS, and the preliminary NPS calculation and analysis performed.

关键词： remote sensing GIS non-point source NPS information system.