检索结果-南通市图书馆

Metal-organic frameworks with dinuclear metal centers for synergistically boosting CO_(2) photoreduction

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Science China Chemistry 2025年第1期68卷 201-208页

作者： Hui-Feng wang Wen-Jie Shi Yu-Xin Yang Bao-xia Dong Tong-Bu Lu Di-Chang Zhong School of Chemistry and Chemical Engineering Yangzhou UniversityYangzhou 225002China Institute for New Energy Materials and Low Carbon Technologies School of Materials Science and EngineeringTianjin University of TechnologyTianjin 300384China

Dinuclear metal synergistic catalysis(DMSC)has been proved powerful in boosting CO_(2)reduction,while this has not been achieved in heterogeneous catalysts with long-range order *** this study,we,by introduction of metal catalytic centers into an indium-based metal-organic framework(MOF),obtained a series of isostructural In-MOFs,including three MOFs with mononuclear metal catalytic center(M-In),three MOFs with dinuclear homometallic catalytic centers(MM-In),and three MOFs with dinuclear heterometallic catalytic centers(MM’-In,M/M’=Co(II),Ni(II),Zn(II)).It was found that all these MOFs can serve as catalysts for photochemical CO_(2)reduction to *** with M-In,the catalytic activities of MM-In were obviously enhanced,and that of MM’-In was further significantly *** example,the CO yield of Co Zn-In reaches a record value of 12,700μmol g^(-1)h^(-1),which is 4.0,8.1,9.4,and 18.6-fold higher than that of Co Co-In,Zn Zn-In,Co-In,and Zn-In,***,the catalytic activities of Co Ni-In and Ni Zn-In also show different fold increase than those of corresponding dinuclear homometallic and mononuclear metallic *** results of control experiments and theoretical calculation reveal that the higher catalytic activities of MM-In over M-In can be ascribed to the DMSC effect,and the higher catalytic activity of MM’-In over MM-In can be ascribed to the strengthened DMSC *** work reveals the relationship between DMSC effect and bimetal centers in CO_(2)reduction,which provides new insights into the DMSC and paves a new way to design highly active catalysts for photochemical CO_(2)reduction.

关键词： metal-organic frameworks dinuclear metal centers synergistic catalysis CO_(2)reduction photocatalysis

Inhibition of the cGAS–STING pathway:contributing to the treatment of cerebral ischemia-reperfusion injury

在线全文

学校读者我要写书评

暂无评论

Neural Regeneration Research 2025年第7期20卷 1900-1918页

作者： Hang Yang Yulei xia Yue Ma Mingtong Gao Shuai Hou Shanshan Xu Yanqiang wang School of Clinical Medicine Shandong Second Medical UniversityWeifangShandong ProvinceChina Department of Emergency The Affiliated Hospital of Weifang Medical UniversityWeifangShandong ProvinceChina Department of Neurology Ⅱ The Affiliated Hospital of Weifang Medical UniversityWeifangShandong ProvinceChina

The cGAS–STING pathway plays an important role in ischemia-reperfusion injury in the heart,liver,brain,and kidney,but its role and mechanisms in cerebral ischemia-reperfusion injury have not been systematically ***,we outline the components of the cGAS–STING pathway and then analyze its role in autophagy,ferroptosis,cellular pyroptosis,disequilibrium of calcium homeostasis,inflammatory responses,disruption of the blood–brain barrier,microglia transformation,and complement system activation following cerebral ischemia-reperfusion *** further analyze the value of cGAS–STING pathway inhibitors in the treatment of cerebral ischemia-reperfusion injury and conclude that the pathway can regulate cerebral ischemia-reperfusion injury through multiple *** of the cGAS–STING pathway may be helpful in the treatment of cerebral ischemia-reperfusion injury.

关键词： calcium homeostasis cellular autophagy cerebral ischemia-reperfusion injury cGAS–STING pathway ferroptosis gut–brain–microbiota axis inflammatory light chain 3 microglial cells Syntaxin-17 protein

Hierarchically Porous Polypyrrole Foams Contained Ordered Polypyrrole Nanowire Arrays for Multifunctional Electromagnetic Interference Shielding and Dynamic Infrared Stealth

在线全文

学校读者我要写书评

暂无评论

Nano-Micro Letters 2025年第4期17卷 399-418页

作者： Yu-long Liu Ting-yu Zhu Qin wang Zi-jie Huang De-xiang Sun Jing-hui Yang xiao-dong Qi yong wang School of Chemistry Key Laboratory of Advanced Technologies of Materials(Ministry of Education)Southwest Jiaotong UniversityChengdu 610031People’s Republic of China

As modern communication and detection technologies advance at a swift pace,multifunctional electromagnetic interference(EMI)shielding materials with active/positive infrared stealth,hydrophobicity,and electric-thermal conversion ability have received extensive *** the aforesaid requirements simultaneously remains a huge *** this research,the melamine foam(MF)/polypyrrole(PPy)nanowire arrays(MF@PPy)were fabricated via one-step electrochemical *** hierarchical MF@PPy foam was composed of three-dimensional PPy micro-skeleton and ordered PPy nanowire *** to the upwardly grown PPy nanowire arrays,the MF@PPy foam possessed good hydrophobicity ability with a water contact angle of 142.00°and outstanding stability under various harsh ***,the MF@PPy foam showed excellent thermal insulation property on account of the low thermal conductivity and elongated ligament characteristic of PPy nanowire ***,taking advantage of the high conductivity(128.2 S m^(-1)),the MF@PPy foam exhibited rapid Joule heating under 3 V,resulting in dynamic infrared stealth and thermal camouflage *** importantly,the MF@PPy foam exhibited remarkable EMI shielding effectiveness values of 55.77 dB and 19,928.57 dB cm^(2)g^(-1).Strong EMI shielding was put down to the hierarchically porous PPy structure,which offered outstanding impedance matching,conduction loss,and multiple *** innovative approach provides significant insights to the development of advanced multifunctional EMI shielding foams by constructing PPy nanowire arrays,showing great applications in both military and civilian fields.

关键词： Polypyrrole nanowire arrays Hierarchical foam Hydrophobicity Infrared stealth Electromagnetic interference shielding

Numerical Simulation of Flow and Temperature Distribution in a Bottom-Blown Copper Bath

在线全文

学校读者我要写书评

暂无评论

Fluid Dynamics & Materials Processing 2025年第1期21卷 121-140页

作者： Teng xia xiaohui Zhang Ding Ma Zhi Yang Xinting Tong Yutang Zhao Hua wang State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization Kunming University of Science and TechnologyKunming650093China Faculty of Metallurgical and Energy Engineering Kunming University of Science and TechnologyKunming650093China Yimen COPPER Corp.Ltd Yuxi651100China Daye Nonferrous Metallurgical Ltd. Huangshi435000China

Smelting with oxygen bottom blowing is one of the main methods used in the frame of copper *** this approach,feed materials and oxygen-enriched air are introduced in reversed order to enhance multiphaseflow within the *** the flow structure and temperature distribution in this setup is crucial foroptimizing *** this study,gas-liquid interactions,and temperature profiles under varying air-injectionconditions are examined by means of numerical simulation for a 3.2 m×20 m *** results indicate that thehigh-velocity regions are essentially distributed near the lance within the reaction region and the flue gas outlet,while low-velocity regions are located close to the furnace walls on both side of the reaction *** regionsappear in the sedimentation region,with gas velocities surpassing those of the molten *** the injection rateincreases from 0.50 to 0.80 Nm3/s,the stabilization time of the average liquid surface velocity decreases from 2.6 sto 1.9 s,exhibiting a similar trend to the gas *** stabilization,the average liquid surface velocity risesfrom 0.505 to 0.702 m/*** average turbulent kinetic energy(TKE)of the fluid in the molten bath increases from0.095 to 0.162 m^(2)/s^(2).The proportion of the area distribution with TKE greater than 0.10 m^(2)/s^(2) and the gas holdupat steady state both rise with an increase in the injection *** maximum splashing height of the melt growsfrom approximately 0.756 to 1.154 m,with the affected area expanding from 14.239 to 20.498 m^(2).Under differentworking conditions with varying injection quantities,the average temperature changes in melt zone and flue gaszone of the furnace are *** temperature in the melt and in the flue-gas zone spans the interval 1200℃–1257℃,and 1073℃–1121℃,*** temperature distribution of the melt and flue gas reveals a patterncharacterized by elevated temperatures in the reaction zone,gradually transitioning

关键词： Copper smelting bottom-blown melting furnace flow characteristics temperature distribution numerical simulation

Molecular Mechanism Behind the Capture of Fluorinated Gases by Metal–Organic Frameworks

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Nano-Micro Letters 2025年第5期17卷 407-462页

作者： Qian wang yong Hu Yifan Gu College of Environmental Science and Engineering State Key Laboratory of Pollution Control and Resource ReuseTongji UniversitySiping Rd 1239Shanghai 200092People’s Republic of China Department of Polymeric Materials School of Materials Science and EngineeringTongji UniversityCaoan Road 4800Shanghai 201804People’s Republic of China Shanghai Institute of Pollution Control and Ecological Security Shanghai 200092People’s Republic of China Key Laboratory of Cities’Mitigation and Adaptation to Climate Change China Meteorological Administration(CMA)Tongji UniversityShanghai 200092People’s Republic of China

Fluorinated gases(F-gases)play a vital role in the chemical industry and in the fields of air conditioning,refrigeration,health care,and organic ***,the direct emission of waste gases containing F-gases into the atmosphere contributes to greenhouse effects and generates toxic *** porous materials for the energy-efficient capture,separation,and recovery of F-gases is highly ***,as a highly designable porous adsorbents,metal–organic frameworks(MOFs)exhibit excellent selective sorption performance toward F-gases,especially for the recognition and separation of different F-gases with highly similar properties,showing their great potential in F-gases control and *** this review,we discuss the capture and separation of F-gases and their azeotropic,near-azeotropic,and isomeric mixtures in various application scenarios by MOFs,specifically classify and analyze molecular interaction between F-gases and MOFs,and interpret the mechanisms underlying their high performance regarding both adsorption capacity and selectivity,providing a repertoire for future materials *** faced in the transformation research roadmap of MOFs adsorbent separation technologies toward F-gases are also discussed,and areas for future research endeavors are highlighted.

关键词： Fluorinated gas Metal–organic framework Adsorption Separation Molecular interaction

Weak KAM theory for two classes of almost periodic Hamiltonian systems

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Science China Mathematics 2025年

作者： Xun Niu Kaizhi wang yong Li School of Mathematics and Statistics Center for Mathematics and Interdisciplinary SciencesNortheast Normal University School of Mathematical Sciences Shanghai Frontier Science Center of Modern Analysis (CMA-Shanghai)Shanghai Jiao Tong University Institute of Mathematics Jilin University

The purpose of this paper is to investigate the dynamics of Bohr almost periodic and Levitan almost periodic Hamiltonian systems via the weak KAM theory. We obtain minimal measures and weak KAM solutions in both cases. The weak KAM solution is a weak solution to the Hamilton-Jacobi equation, which formally transforms the original Hamiltonian systems into an integrable one. Consequently, we get the existence of an invariant torus in the aforementioned weak sense.

关键词：

Reversible phase transition poly(benzyl methacrylate)/ionic liquid electrolytes for effective overheating protection in lithium batteries

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2025年第2期101卷 76-86页

作者： Qian Yu Wei Sun Jialing Zhu Haoxiang Li Shuai wang Longqing Huang Qian Qiu Haoran Tian He Miao Fu wang Chunfei Zhang Jinliang Yuan Lan xia Ningbo Innovation Team on New Energies and Marine Applications Faculty of Maritime and Transportation Ningbo University Technical University of Munich TUM School of Natural Sciences Department of Physics Chair for Functional Materials

Battery safety is influenced by various factors,with thermal runaway being one of the most significant *** most studies have concentrated on developing one-time,self-activating mechanism for thermal protection,such as temperature-responsive electrodes,and thermal-shutdown separators,these methods only provide irreversible ***,reversible temperature-sensitive electrolytes have emerged as promising alternatives,offering both thermo-reversibility and self-protective ***,further research is crucial to fully understand these thermal-shutdown *** this study,we propose lower critical solution temperature(LCST) phase behavior poly(benzyl methacrylate)/imidazolium-based ionic liquid mixtures to prepare temperature-sensitive electrolytes that provide reversible thermal shutdown protection of *** electrolyte features an appropriate protection temperature(～105℃) and responds quickly within a 1 min at 105℃,causing cells to hardly discharge as the voltage suddenly drops to 3.38 V,and providing efficient thermal shutdown protection within 30 *** cooling back to room temperature,the battery regains its original ***,the electrolyte exhibits excellent cycling stability with the capacity retention of the battery is 91.6% after 500 *** work provides a viable solution for preventing batteries from thermal runaway triggered by overheating.

关键词： Ionic liquid Lithium-ion battery Lower critical solution temperature Overheating Safety Thermal runaway

Data-driven output regulation control for constrained linear systems

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Science China(Information Sciences) 2025年

作者： Chaoyu xia Yi DONG Chaoli wang Shengyuan XU Shanghai Research Institute for Intelligent Autonomous Systems Tongji University College of Electronic and Information Engineering Shanghai Research Institute for Intelligent Autonomous SystemsTongji University Department of Control Science and Engineering School of Optical-Electrical and Computer EngineeringUniversity of Shanghai for Science and Technology Department of Automation Nanjing University of Science and Technology

This study introduces a data-driven approach for state and output feedback control addressing the constrained output regulation problem in unknown linear discrete-time systems. Our method ensures effective tracking performance while satisfying the state and input constraints, even when system matrices are not available. We first establish a sufficient condition necessary for the existence of a solution pair to the regulator equation and propose a data-based approach to obtain the feedforward and feedback control gains for state feedback control using linear programming. Furthermore, we design a refined Luenberger observer to accurately estimate the system state, while keeping the estimation error within a predefined set. By combining output regulation theory, we develop an output feedback control strategy. The stability of the closed-loop system is rigorously proved to be asymptotically stable by further leveraging the concept of λ-contractive sets.

关键词：

Red-mud treatment using oxalic acid by UV irradiation assistance

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Transactions of Nonferrous Metals Society of China 2012年第2期22卷 456-460页

作者：余章龙石志霞陈咏梅钮因健王永霞万平玉北京化工大学理学院北京100029 北京有色金属研究总院矿物资源与冶金材料研究所北京100088 中国有色金属学会北京100814

Red-mud is the residue from the Bayer process, in which the iron minerals should be removed before red-mud is used to produce refractory materials. The iron minerals in red-mud were extracted by oxalic acid solution. The content of Fe （calculated in Fe203） in red-mud was reduced from 17.6% to less than 1% after being treated by 1 mol/L oxalic acid solution at 75 ℃ for 2 h. The Fe（Ⅲ） oxalate solution obtained was then irradiated by UV light, resulting in the precipitation of Fe（Ⅱ） oxalate. Under UV photocatalysis, more than 90% of Fe（Ⅲ） oxalate in the extracted solution was transformed into the precipitation of Fe（Ⅱ） oxalate crystallite （fl-FeC2O4·2H2O）. The filtrate from the Fe（Ⅱ） oxalate precipitate filtration could be reused in the next cycle. The mechanism ofUV photocatalysis precipitation was also discussed.

关键词： red-mud iron minerals oxalic acid UV irradiation