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Acta Geologica Sinica(English Edition) 2021年第3期95卷 1008-1015页

作者： CHEN Yong wang Jiuyuan ZHOU Zhenzhu CHEN Xiaolan ZHAO Zhenyu shi Peng HAN Yun school of Geosciences China University of Petroleum(East China)QingdaoShandong 266580China Shandong Provincial Key Laboratory of Depositional mineralization&Sedimentary mineral Shandong University of Science and TechnologyQingdaoShandong 266590China Department of earth and Planetary sciences Yale UniversityNew HavenCT 06511USA Petrochina Exploration and Development Institute Beijing 100083China Bohai Oil Research Institute Tianjin Branch of CNOOC Ltd300459Tianjin 300459China

Trapped ancient microorganisms in halite fluid inclusions are of special interest to the understanding of biology and ecology in salt lake *** the integration of petrologic,microthermometric,and Raman spectroscopic analyses,this study utilizes fluid inclusions from Chaka Salt Lake,eastern Qaidam Basin,NW china,to assess the possibility of microorganism-trapping by fluid ***,we report that the solid phase of some primary fluid inclusions contains carotenoids,which is interpreted as evidence of Dunaliella algae,and that the coexisting liquid phase comprises SO_(4)^(2-).The homogenization temperatures of single-phase primary fluid inclusions indicate that the precipitation temperature of the Holocene halite in Chaka Salt Lake ranges from 13.5℃ to 36.4℃.This suggests that fluid inclusions in halite are a good medium for trapping and preserving ancient microorganisms and organic matter in salt lakes,and that Raman spectroscopy has good potential to identify halophilic archaea.

关键词： invertebrate paleontology halophile microorganisms halite fluid inclusions carotenoids Qinghai Province

Petrography and chronology of lunar meteorite Northwest Africa 6950

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science china(Information sciences) 2020年第4期63卷 182-194页

作者： Zemin BAO Yuruo shi J.Lawford ANDERSON Allen KENNEDY Zuokai KE Xiangping GU Peizhi wang Xiaochao CHE Yuelan KANG Huiyi SUN Chen wang beijing SHRIMP Center Institute of Geology Chinese Academy of Geological Sciences John de Laeter Centre Curtin University Department of earth and Environment Boston University school of Geosciences and Infophysics Central South University

Northwest Africa(NWA) 6950 is an olivine-gabbro lunar meteorite that has a distinctly different petrographic texture from other lunar basalts. In this contribution, we report the petrography, mineralogy,and U-Pb geochronology of baddeleyite and phosphate in this lunar meteorite and make a comparison with other NWA 773 paired meteorites. NWA 6950 consists mainly of coarse-grained olivine, pyroxene,and plagioclase, with minor ilmenite, chromite, troilite, baddeleyite, taenite, and apatite. The abundant rounded to euhedral olivine has a limited Fo ranging from 68 to 69. Pyroxenes include both augite and pigeonite, with a narrow range of Mg#=71–80, and composition, respectively, EnFsWoand EnFsWo. Plagioclase is mainly anhedral, conforming to the crystal margins of olivine and pyroxene. The plagioclase grains are elongated and several hundreds of microns in length. Raman spectra shows that plagioclase has been transformed into maskelynite, which is very calcic(An87-95) with low sodium and very low potassium(Ab4-9 Or 0.6-3.7). The weighted mean207 Pb/206 Pb ages of baddeleyite and phosphate measured using a sensitive high resolution ion micro probe(SHRIMP II) are 3119 ± 16 Ma(n = 9, MSWD= 2.5)(mean squared weighted deviates, MSWD) and 3119 ± 18 Ma(n = 15, MSWD = 2.1), respectively,giving the crystallization age of the meteorite. NWA 6950 has similar mineral compositions, geochemical characteristics, and an almost identical age of crystallization to the magnesian gabbro of the NWA 773 *** conclude that NWA 6950 and NWA 773 are paired meteorites, which crystallize at ca. 3119 Ma, and represent magmatic activities in the KREEP(potassium(K), rare earth elements(REE) and phosphorus(P) rich lunar material) region of the Moon.

关键词： Northwest Africa 6950 lunar meteorite U-Pb chronology baddeleyite phosphate

Most root-derived carbon inputs do not contribute to long-term global soil carbon storage

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science china earth sciences 2023年第5期66卷 1072-1086页

作者： Guocheng wang Liujun XIAO Ziqi LIN Qing ZHANG Xiaowei GUO Annette COWIE Shuai ZHANG Mingming wang Songchao CHEN Ganlin ZHANG Zhou shi Wenjuan SUN Zhongkui LUO Institute of Agriculture Remote Sensing and Information Technology College of Environmental and Resource SciencesZhejiang UniversityHangzhou310058China LAPC Institute of Atmospheric PhysicsChinese Academy of SciencesBeijing100029China school of Atmospheric sciences Guangdong Province Key Laboratory for Climate Change and Natural Disaster StudiesSun Yat-sen UniversityZhuhai519082China New South Wales Department of Primary Industries University of New EnglandArmidaleNSW2351Australia State Key Laboratory of Soil and Sustainable Agriculture Institute of Soil ScienceChinese Academy of SciencesNanjing210008China Academy of Ecological Civilization Zhejiang UniversityHangzhou310058China Key Laboratory of Environment Remediation and Ecological Health Ministry of EducationZhejiang UniversityHangzhou310058China State Key Laboratory of Vegetation and Environmental Change Institute of BotanyChinese Academy of SciencesBeijing100093China Key Laboratory of Agricultural Remote Sensing and Information System Zhejiang ProvinceHangzhou310058China

Plant root-derived carbon(C)inputs(I_(root))are the primary source of C in mineral bulk ***,a fraction of I_(root)may lose quickly(I_(loss),e.g.,via rhizosphere microbial respiration,leaching and fauna feeding)without contributing to long-term bulk soil C storage,yet this loss has never been quantified,particularly on a global *** this study we integrated three observational global data sets including soil radiocarbon content,allocation of photo synthetically assimilated C,and root biomass distribution in 2,034 soil profiles to quantify I_(root)and its contribution to the bulk soil C *** show that global average I_(root)in the 0-200 cm soil profile is 3.5 Mg ha^(-1)yr^(-1),~80%of which(i.e.,I_(loss))is lost rather than co ntributing to long-term bulk soil C storage.I_(root)decreases exponentially with soil depth,and the top 20 cm soil contains>60%of total I_(root).Actual C input contributing to long-term bulk soil storage(i.e.,I_(root)-I_(loss))shows a similar depth distribution to I_(root).We also map I_(loss)and its depth distribution across the *** results demonstrate the global significance of direct C losses which limit the contribution of I_(root)to bulk soil C storage;and provide spatially explicit data to facilitate reliable soil C predictions via separating direct C losses from total root-derived C inputs.

关键词： Carbon inputs Root biomass Soil organic carbon Depth distribution Bulk soil carbon Radiocarbon

江陵凹陷西南部始新世盐湖卤水演化和钾锂来源——来自石盐流体包裹体的证据

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岩石矿物学杂志 2024年第4期43卷 905-917页

作者：颜开王春连陈仁义刘雪刘延亭尹传凯孙珮婕赵雨欣廖世龙中国地质科学院矿产资源研究所自然资源部成矿作用与资源评价重点实验室北京100037 冰岛大学地球科学学院雷克雅未克102 昆明理工大学国土资源工程学院云南昆明650093 东华理工大学地球科学学院江西南昌330013 成都理工大学沉积地质研究院四川成都610059 长江大学地球物理与石油资源学院湖北武汉430100

江陵凹陷中部和北部发现了富钾锂卤水的存在,而西南部地区则以不含钾锂的固体蒸发岩为主。本次研究旨在通过ZK0303井石盐流体包裹体中的化学成分来揭示凹陷西南部古盐湖卤水的演化和钾锂的来源。根据镜下观察,在始新世的3个石盐层中找... 详细信息

江陵凹陷中部和北部发现了富钾锂卤水的存在,而西南部地区则以不含钾锂的固体蒸发岩为主。本次研究旨在通过ZK0303井石盐流体包裹体中的化学成分来揭示凹陷西南部古盐湖卤水的演化和钾锂的来源。根据镜下观察,在始新世的3个石盐层中找到了具有人字形和堆积形的原生流体包裹体,并利用激光剥蚀电感耦合等离子体质谱仪(LA-ICP-MS)技术测试了石盐单个原生流体包裹体中Li、K、Mg、Ca、Br的浓度。通过实验数据的分析,凹陷西南部始新世石盐流体包裹体中卤水为Na-K-Mg-Ca-Cl型,其中K的浓度最高达到3362.15 mg/L,Li的浓度最高达到15.10 mg/L。ZK0303井3组石盐层中Mg-Ca-2K之间的关系表明,凹陷西南部盐湖卤水达到钾石盐沉积阶段。3个石盐组中各离子浓度的变化说明,盐湖卤水的蒸发程度经历了由低升高再降低的变化。根据前人的研究,卤水中钾锂的来源与凹陷内的玄武岩密切相关。但是凹陷西南部地区离玄武岩分布区较远难以获得足够的物质补给,该地区始新世盐湖卤水中的钾锂元素除蒸发外,还可能来源于早期岩盐的溶解。

关键词：江陵凹陷石盐原生流体包裹体钾石盐沉积岩盐溶解

Growth structures and growth strata of the Qianjiadian Basin in the western Yanshan fold and thrust belt, North china

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science china earth sciences 2019年第7期62卷 1092-1109页

作者： Xiaofei shi Shaofeng LIU Chengfa LIN State Key Laboratory of Geological Processes and mineral resources and school of Geosciences and resources China University of Geosciences (Beijing)

The northwestward subduction of the Izanagi Plate beneath the eastern Eurasian Plate during the Late Mesozoic caused a series of compressional deformation events in the Yanshan fold and thrust belt(YFTB), but the tectonic deformation timing, tectonic properties and relationship between tectonic uplift and sediment accumulation in the intermontane basins continue to be debated. For this reason, the sedimentology, sediment provenance, and basin structure of the Qianjiadian Basin(QJB) in the northern beijing region during the Late Jurassic and Early Cretaceous were studied in detail. The results suggest that a fault-propagation fold-type(FPFT) growth structure and growth strata developed on the western edge of the QJB and that the top part of Member 2 and Member 3 of the Tuchengzi Formation are growth strata controlled by the limb rotation mechanism. In two small thrust faults in the QJB, the Mesoproterozoic Xiamaling Formation is thrust over the Tuchengzi Formation, and these faults may have controlled the development of the fault-bend fold-type growth strata. An analysis of the "source-to-sink" process suggests that the hanging wall succession of the Shangyi-Pingquan fault(SPF) was the main source area of the Late Jurassic to early Early Cretaceous strata in the QJB. A zircon206 Pb/238 U age of 140.8±2.4 Ma for the volcanic rocks at the bottom of the FPFT growth strata represents the timing of the initiation of FPFT growth structure development. The discovery of the FPFT growth structure and growth strata in the QJB indicate that the QJB was an intermontane flexural basin controlled by fold and thrust structures during the early Early Cretaceous. Near the E-W-trending SPF, the NE-SW-trending Qianjiadian thrust fault(QJTF) and two small intrabasinal thrust faults may constitute a unified right-lateral strike-slip system that formed in response to the northwestward flat subduction of the Izanagi Plate beneath the East Asian continent during the Jurassic-Early Cretaceou

关键词： Yanshan fold and thrust belt Qianjiadian Basin Tuchengzi Formation Growth structure Growth strata Izanagi Plate

Carboniferous and Permian integrative stratigraphy and timescale of North china Block

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science china earth sciences 2022年第6期65卷 983-1011页

作者： Boheng SHEN Shuzhong SHEN Qiong WU Shuichang ZHANG Bin ZHANG Xiangdong wang Zhangshuai HOU Dongxun YUAN Yichun ZHANG Feng LIU Jun LIU Hua ZHANG Yukun shi Jun wang Zhuo FENG State Key Laboratory for mineral Deposits Research School of Earth Sciences and Engineering and Frontiers Science Center for Critical Earth Material CyclingNanjing UniversityNanjing 210023China Research Institute of Petroleum Exploration and Development PetroChinaBeijing 100083China school of resources and Geosciences China University of Mining and TechnologyXuzhou 221116China State Key Laboratory of Palaeobiology and Stratigraphy Nanjing Institute of Geology and Palaeontology and Center for Excellence in Life and PaleoenvironmentChinese Academy of SciencesNanjing 210008China Key Laboratory of Vertebrate Evolution and Human Origins of Chinese Academy of sciences Institute of Vertebrate Paleontology and Paleoanthropology and Center for Excellence in Life and PaleoenvironmentChinese Academy of SciencesBeijing 100044China Institute of Palaeontology Yunnan UniversityKunming 650500China

The Carboniferous-Permian strata in the North china Block(NCB) contain abundant fossils, coals and natural *** a high-resolution timescale for the Carboniferous and Permian in the NCB is essential to understand the geologic events and explore the spatial and temporal distributions of the natural resources. The upper Carboniferous and the basal part of Permian are relatively well correlated because they yield marine conodont and fusuline fossils. However, the Permian terrestrial strata mostly rely on poorly constrained palynostratigraphy and phytostratigraphy and are short of the precise geochronologic constraints on the correlation with the marine strata. This study provides a critical review on the state-of-the-art of the latest Carboniferous and Permian chronostratigraphic and biostratigraphic frameworks and stratigraphic correlation in the NCB. The Penchi Formation ranges from lower Bashkirian to lower Gzhelian;the Taiyuan Formation is assigned to the upper Gzhelian to lower Asselian;the Shansi and Lower shihhotse formations are from middle Asselian to lower Sakmarian;the Upper shihhotse Formation is assigned to upper Artinskian to lower Kungurian, and the Sunjiagou Formation was assigned to Lopingian, respectively. A long hiatus up to ~20 Myr between the Upper shihhotse and Sunjiagou formations, mainly marked by a large-scale erosional surface at the base of a coarse conglomeratic sandstone unit and/or multiple paleosol layers as well as significant differences of floras between these two lithostratigraphic units, is present probably due to tectonic uplift in association with the closure of the Paleo Asian Ocean(PAO) during the Cisuralian and Guadalupian. The possible amplitude of sea-level changes from Carboniferous to Permian on the NCB is estimated from 0 to 40 *** floral succession, depositional records and organic carbon isotope profiles suggest that the latest Carboniferous and earliest Permian was a favorable period for coal accumulation

关键词： North china Block Carboniferous-Permian Geochronology Biostratigraphy Correlation

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纳米矿物在地球科学的研究进展

矿物学报 2024年第4期44卷 457-477页

作者：石爱国许成韦春婉范朝熙付伟易泽邦北京大学地球与空间科学学院造山带与地壳演化教育部重点实验室北京100871 桂林理工大学地球科学学院有色金属矿产勘查与资源高效利用省部共建协同创新中心广西壮族自治区桂林541006

纳米矿物广泛存在于岩石圈、大气圈、水圈和生物圈内,是地球系统的重要组成部分。纳米矿物的微小尺寸使其具有不同于宏观矿物的特殊结构、物理化学性质和地质行为,研究固体地球系统中各类纳米矿物的形成机制、分布特征和转变规律进而从... 详细信息

纳米矿物广泛存在于岩石圈、大气圈、水圈和生物圈内,是地球系统的重要组成部分。纳米矿物的微小尺寸使其具有不同于宏观矿物的特殊结构、物理化学性质和地质行为,研究固体地球系统中各类纳米矿物的形成机制、分布特征和转变规律进而从微观角度深入理解地质过程已成为国际地学的研究热点。本文总结了地学常用的纳米矿物研究方法,介绍了纳米矿物参与下的“非传统”矿物生长、微量元素吸附和矿物相变等过程。同时本文结合实例梳理了地球系统不同地质过程中非生物相关纳米矿物的成因机制及其对地质过程的指示意义,包括发生在岩浆、热液或胶体体系中从无到有的结晶过程,先存矿物的溶解-再沉淀过程(水岩反应作用),以及先存岩石或矿物的应变破碎过程(陨石冲击、构造活动、火山活动)等,讨论了纳米矿物与成矿的关系,并对纳米地球科学未来的研究方向提出了展望。

关键词：纳米矿物纳米地球科学非传统矿物学成因机制地质意义纳米矿物与成矿

Applications of the IAPWS-95 formulation in fluid inclusion and mineral-fluid phase equilibria

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Geoscience Frontiers 2012年第1期3卷 51-58页

作者： Lanlan shi shide Mao State Key Laboratory of Geological Processes and mineral resources School of Earth Sciences and ResourcesChina University of GeosciencesBeijing 100083China

The IAPWS-95 formulation explicit in Helmholtz free energy proposed by Wagner and Pruβ （2002） is the best equation of state of water, from which all thermodynamic properties can be obtained over a wide T-p range from 273.16 to 1273 K and from 0 to 1000 MPa with experimental accuracy. This paper reports the applications of the IAPWS-95 formulation in fluid inclusion and mineral-water phase equilibria. A reliable and highly efficient calculation method is presented for the saturated properties of water so that the formulation can be conveniently applied in the study of fluid inclusion, such as calculating homogenization pressures, homogenization densities （or molar volumes）, volume fractions and isochores. Meanwhile, the uni- variant curves of some mineral-dehydration reactions are calculated based on the IAPWS-95 formulation. The computer code of the IAPWS-95 formulation can be obtained from the corresponding author.

关键词： Equation of state Water Fluid inclusion Application

Molecular signatures of soil-derived dissolved organic matter constrained by mineral weathering

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Fundamental Research 2023年第3期3卷 377-383页

作者： Ying-Hui wang Peng Zhang Chen He Jian-Chun Yu Quan shi Randy A.Dahlgren Robert G.M.Spencer Zhi-Bing Yang Jun-Jian wang State Environmental Protection Key Laboratory of Integrated Surface Water-Groundwater Pollution Control School of Environmental Science and EngineeringSouthern University of Science and TechnologyShenzhen 518055China Guangdong Provincial Key Laboratory of Soil and Groundwater Pollution Control School of Environmental Science and EngineeringSouthern University of Science and TechnologyShenzhen 518055China State Key Laboratory of Water resources and Hydropower Engineering science Wuhan UniversityWuhan 430072China State Key Laboratory of Heavy Oil Processing China University of PetroleumBeijing 102249China Shanghai Engineering Research Center of Hadal science and Technology College of Marine SciencesShanghai Ocean UniversityShanghai 201306China Department of Land Air and Water ResourcesUniversity of California DavisDavis 95616United States Department of earth Ocean and Atmospheric ScienceFlorida State UniversityTallahassee 32306United States

Dissolved organic matter(DOM)in soils drives biogeochemical cycling and soil functions in different directions depending on its molecular ***,there is a distinct paucity of information concerning how the molecular signatures of soil DOM vary with different degrees of weathering across wide geographic ***,we resolved the DOM molecular signatures from 22 diverse Chinese reference soils and linked them with soil organic matter and weathering-related mineralogical *** mixed-effects models revealed that the yields of DOM were determined by soil organic carbon content,whereas the molecular signature of DOM was primarily constrained by the weathering-related *** soil weathering index showed a positive effect on the lability and a negative effect on the aromaticity of ***,DOM in highly weathered acidic soils featured more amino sugars,carbohydrates,and aliphatics,as well as less O-rich polyphenols and condensed aromatics,thereby conferring a higher DOM biolability and lower DOM *** study highlights the dominance of the weathering-related dimension in constraining the molecular signatures and potential functions of DOM in soils across a wide geographic scale.

关键词： Soil organic matter Dissolved organic matter Chemical composition Molecular signature mineral weathering

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驱油流体吸附抑制剂的合成与评价

石油与天然气化工 2024年第1期53卷 98-103页

作者：赵帅田雨吴澳回安锋涛杨林师永民陕西科技大学陕西省轻化工助剂重点实验室北京大学地球与空间科学学院

目的在化学驱的实施过程中,地层对驱油剂的吸附滞留是表面活性剂进入地层后含量损失的一种主要原因,为了减少驱油流体在地层的损耗成本而展开对驱油液体吸附抑制剂的研究。方法以二氰二胺(DCD)、1-十八胺盐酸盐(OHC)为原料,基于亲核加... 详细信息

目的在化学驱的实施过程中,地层对驱油剂的吸附滞留是表面活性剂进入地层后含量损失的一种主要原因,为了减少驱油流体在地层的损耗成本而展开对驱油液体吸附抑制剂的研究。方法以二氰二胺(DCD)、1-十八胺盐酸盐(OHC)为原料,基于亲核加成的原理采用熔融法在150℃下合成了一种针对驱油流体的吸附抑制剂OHCB,该表面活性剂同时具备强疏水基、强极性原子和阳离子基团,因此具有较强的占据黏土矿物表面吸附位点的能力。对其进行了红外吸收、紫外吸收、元素分析、质谱等结构表征,采用静态吸附法研究了其作为添加剂的最佳配比,并验证在最佳配比下对驱油剂AEO7的吸附抑制效果,以及该体系相较AEO7单一体系的静态洗油效率、乳化性及润湿性的变化。结果OHCB抑制驱油剂AEO7在黏土矿物表面的吸附效果较好,在驱油剂与吸附抑制剂质量比为5∶1的情况下,抑制效果可达27%以上。结论OHCB不仅具有较好的吸附抑制效果,且其加入使AEO7的静态洗油效率提升至27.3%、γc m c降至27.1 mV/m,CMC降至38 mg/L、油-水界面张力降至0.5 mV/m以下,对体系性能起到了协同增效的作用,并且相较于需要预吸附的牺牲剂,其使用更为便捷。

关键词：吸附抑制驱油静态洗油效率表面张力界面张力