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Progress of gaseous arsenic removal from flue gas by adsorption:Experimental and theoretical calculations

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Journal of Environmental Sciences 2024年第2期136卷 470-485页

作者： Xuelei Yan Qingzhu Li Xiaowei Huang Bensheng Li Shengtu Li qingwei wang School of Metallurgy and Environment Central South UniversityChangsha 410083China National Engineering Research Centre for Control and Treatment of Heavy Metal Pollution Central South UniversityChangsha 410083China National Engineering Research Center for Rare Earth Materials General Research Institute for Non-Ferrous MetalsBeijing 100088China

Because of its high mobility and difficult capture,gaseous arsenic pollution control has become the focus of arsenic pollution *** mainly exists in the form of highly toxic As_(2)O_(3)in the flue ***,removing gaseous As_(2)O_(3)from flue gas is of great practical significance for arsenic pollution *** gaseous As_(2)O_(3)on the surface of adsorbents by physical or chemical adsorption is an effective way to reduce the content of arsenic in the flue gas and alleviate arsenic *** the past few decades,various adsorbents have been developed to capture gaseous As_(2)O_(3)in the flue gas,and their adsorption mechanisms have been studied in ***,it is necessary to review the strategies of arsenic removal from flue gas by adsorption,which can inspire further *** on summarizing the morphological distribution of gaseous As_(2)O_(3)in the flue gas,this review further summarizes the removal of gaseous As_(2)O_(3)by several adsorbents and the effect of temperature and the main components of the flue gas on arsenic *** addition,the mechanism of arsenic removal based on adsorption in the flue gas is discussed in depth through theoretical calculations,which is the particular focus of this ***,prospects based on the present research state of arsenic removal by adsorption are proposed to provide ideas for developing effective and stable adsorbents for arsenic removal from flue gas.

关键词： Gaseous arsenic Flue gas Adsorption Theoretical calculation Mechanism

CH_2,NH,and O heteroatom substitution effects on the electronic,optical,and charge transport properties of a 2,1,3-benzothiadiazole-based derivative:Insights from theory

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Science China Chemistry 2012年第7期55卷 1364-1369页

作者： HU Bo YAO Chan wang qingwei ZHANG Hao YU JianKang Faculty of Chemistry Jilin Normal UniversitySiping 136000China Key Laboratory of Preparation and Applications of Environmental Friendly Materials(Jilin Normal University) Ministry of EducationSiping 136000China State Key Laboratory of Theoretical and Computational Chemistry Jilin UniversityChangchun 130023China Institute of Applied Physics and Technology Foundation Department of Liaoning Technical UniversityHuludao 123000China

A set of CH2-,NH-,and O-substituted 2,1,3-benzothiadiazole(BTD)-based derivatives have been investigated theoretically in order to explore their electronic,optical,and charge transport *** calculation results show that the electronic and optical properties of the pristine molecule can be easily tuned through changing the S substituent in the central aromatic *** on the calculated maximum emission wavelength,we predict that CH2-,NH-,and O-substituted BTD-based derivatives could be used as red,green,and orange light-emitting materials,*** CH2-,NH-or O-substitution,the oscillator strengths of the emission spectra are enhanced with respect to that of the pristine molecule,implying that these compounds have larger fluorescence ***,it can be deduced that CH2-,NH-,and O-substituted BTD-based derivatives may act as hole transport materials in organic light-emitting diodes.

关键词： organic light-emitting devices (OLEDs) 2 1 3-benzothiadiazole electronic properties optical properties reorganizationenergy

The role of doped-Mn on enhancing arsenic removal by MgAl-LDHs

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Journal of Environmental Sciences 2022年第10期34卷 125-134页

作者： Kaizhong Li Hui Liu Qingzhu Li Wenming Yao LanyanWu Shuimei Li qingwei wang School of Metallurgy and Environment Central South UniversityChangsha 410083China Chinese National Engineering Research Center for Control&Treatment of Heavy Metal Pollution Changsha 410083China Water Pollution Control Technology Key Lab of Hunan Province Changsha 410004China

To meet the challenges posed by global arsenic water contamination, the Mg Al Mn-LDHs with extraordinary efficiency of arsenate removal was developed. In order to clarify the enhancement effect of the doped-Mn on the arsenate removal performance of the LDHs, the cluster models of the Mg Al Mn-LDHs and Mg Al-LDHs were established and calculated by using density functional theory(DFT). The results shown that the doped-Mn can significantly change the electronic structure of the LDHs and improve its chemical activity. Compared with the Mg Al-LDHs that without the doped-Mn, the HOMO-LUMO gap was smaller after doping. In addition, the-OH and Al on the laminates were also activated to improve the adsorption property of the LDHs. Besides, the doped-Mn existed as a novel active site. On the other hand, the Mg Al Mn-LDHs with the doped-Mn, the increased of the binding energy, as well as the decreased of the ion exchange energy of interlayer Cl^(-), making the ability to arsenate removal had been considerably elevated than the Mg Al-LDHs. Furthermore, there is an obvious coordination covalent bond between arsenate and the laminates of the Mg Al MnLDHs that with the doped-Mn.

关键词： Mechanism Arsenate removal Mn LDHs DFT

Current Status of the Research on Coal Geology in China

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Acta Geologica Sinica(English Edition) 2016年第4期90卷 1284-1297页

作者： wang Tong wang qingwei SHAO Longyi XIA Yucheng FU Xuehai NING Shuzheng XIE Zhiqing JIANG Tao China National Administration of Coal Geology Beijing 100039China College of Resources and Environment North China University of Water Resources and Electric PowerZhengzhou 450046China College of Geoscience and Surveying Engineering China University of Mining and Technology(Beijing)Beijing 100083China Xi'an University of Science and Technology Xi'an 710054China China University of Mining and Technology Xuzhou 221008China

Coal is the main energy in China, which has already played and will continue to play an important role in the national economy. Coal geology, as a practical science, has an access to gradual development with the growth and prosperity of China. From the meaning of the coalfield geology, this paper introduces the research progress and status of coalfield geology, including the research on coal basin, stratigraphy of coal-bearing stratigraphic sequences, coal-forming process, structural geology of coalfields, and exploration and development status of coal resources. The paper specially focuses on coal-forming process, including coal formation in terrestrial facies and transgressive / regression events, and introduces new technology which has been applied to research progress in structural geology of coalfield. This paper puts forward a new comprehensive exploration system for coal exploration and reviews regional coal geological exploration results in recent years, such as coal-poor regions of seven provinces in southern China and the coal resources area in northwest China, which will be an important coal-producing area in the future .

关键词： coal resource distribution exploration and exploitation new thought

Effect of surface retaining elements on rock stability:laboratory investigation with sand powder 3D printing

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International Journal of Coal Science & Technology 2023年第4期10卷 305-324页

作者： Hao Feng Lishuai Jiang qingwei wang Peng Tang Atsushi Sainoki Hani S.Mitri State Key Laboratory of Mining Disaster Prevention and Control Shandong University of Science and TechnologyQingdao 266590China Faculty of Advanced Science and Technology Kumamoto UniversityKumamoto 860-8555Japan International Research Organization for Advanced Science and Technology Kumamoto UniversityKumamoto 860-8555Japan Department of Mining and Materials Engineering McGill UniversityMontreal H3A 0E8Canada

This study aims to investigate the benefcial efects of surface retaining elements (SREs) on the mechanical behaviors of bolted rock and roadway stability. 3D printing (3DP) technology is utilized to create rock analogue prismatic specimens for conducting this investigation. Uniaxial compression tests with acoustic emission (AE) and digital image correlation techniques have been conducted on 3DP specimens bolted with diferent SREs. The results demonstrate that the strength and modulus of elasticity of the bolted specimens show a positive correlation with the area of the SRE;the AE characteristics of the bolted specimens are higher than those of the unbolted specimen, but they decrease with an increase in SRE area, thus further improving the integrity of the bolted specimens. The reinforcement efect of SREs on the surrounding rock of roadways is further analyzed using numerical modelling and feld test. The results provide a better understanding of the role of SREs in rock bolting and the optimization of rock bolting design. Furthermore, they verify the feasibility of 3DP for rock analogues in rock mechanics tests.

关键词： Roadway stability Surface retaining element Sand-powder 3D printing Rock bolting Numerical modelling

Ratio of photosynthetically active radiation to global solar radiation above forest canopy in complex terrain: measurements and analyses based on Qingyuan Ker Towers

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Ecological Processes 2024年第2期13卷 204-217页

作者： Shuangtian Li Qiaoling Yan Tian Gao Xingchang wang qingwei wang Fengyuan Yu Deliang Lu Huaqi Liu Jinxin Zhang Jiaojun Zhu CAS Key Laboratory of Forest Ecology and Silviculture Institute of Applied Ecology Chinese Academy of Sciences Qingyuan Forest CERN National Observation and Research Station Chinese Academy of Sciences CAS-CSI Joint Laboratory of Research and Development for Monitoring Forest Fluxes of Trace Gases and Isotope Elements Institute of Applied Ecology Chinese Academy of Sciences (CAS) University of Chinese Academy of Sciences Center for Ecological Research Northeast Forestry University

Background Understanding of the ratio of photosynthetic photon flux density（Qp） to global solar radiation（Rs）(Qp/Rs) is crucial for applying Rsto ecology-related *** studies reported Qp/Rsand its variations based on measurements from a single observatory tower,instead of multi-site-based measurements over complex *** may neglect spatial heterogeneity in the terrain,creating a gap in an understanding of how terrain affects Qp/Rsand how this effect interacts with meteorological *** Here the Qingyuan Ker Towers（three towers in a valley with different terrains:T1,T2,and T3） were utilized to measure Qpand Rsover mountainous forests of Northeast *** airborne LiDAR system was used to generate a digital elevation model,and sky view factor of sectors（SVFs） divided from the field of view of tower's pyranometer was calculated as a topographic factor to explain the variations of Qp/*** The results identified significant differences in Qp/Rsof the three towers at both daily and half-hour scales,with larger differences on clear days than on overcast ***/Rswas positively correlated with SVFsof T1 and T3,while this correlation was negative with that of *** effect of SVFson Qp/Rsinteracted with clearness index,water vapor pressure and solar zenith *** forest-based importance assessment demonstrated that explanation（R2） on Qp/Rswas improved when SVFswas included in the predictor variable set,indicating that incorporating terrain effects enhances the prediction accuracy of Qp/*** improvement in the R2values was more pronounced on clear days than on overcast days,suggesting that the effect of terrain on Qp/Rsdepended on sky *** All findings suggested that Qp/Rsis affected by terrain,and integrating terrain information into existing Qp/Rsmodels is a feasible solution to improve Qp/Rsestimates in mountainous areas.

关键词： Photosynthetic photon flux density Clearness index Water vapor pressure Solar zenith angle Terrain Sky view factor

Mechanisms of Pb(Ⅱ) coprecipitation with natrojarosite and its behavior during acid dissolution

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Journal of Environmental Sciences 2022年第12期34卷 128-137页

作者： Meiqing Shi Xiaobo Min Chen Tian Taixu Hao Sijie Zhu Yun Ge qingwei wang Xu Yan Zhang Lin Institute of Environmental Engineering School of Metallurgy and EnvironmentCentral South UniversityChangsha 410083China Chinese National Engineering Research Center for Control&Treatment of Heavy Metal Pollution Changsha 410083China Water Pollution Control Technology Key Lab of Hunan Province Changsha 410004China

Lead(Pb) coprecipitation with jarosite is common in natural and engineered environments,such as acid mine drainage(AMD) sites and hydrometallurgical industry. Despite the high relevance for environmental impact, few studies have examined the exact interaction of Pb with jarosite and the dissolution behavior of each phase. In the present work, we demonstrate that Pb mainly interacts with jarosite in four modes, namely incorporation, occlusion,physically mixing, and chemically mixing. For comparison, the four modes of Pb-bearing natrojarosite were synthesized and characterized separately. Batch dissolution experiments were undertaken on these synthetic Pb-bearing natrojarosites under pH_(2) to simulate the AMD environments. The introduction of Pb decreases the final Fe releasing efficiency of jarosite-type compounds from 18.18% to 3.45%-5.01%, showing a remarkable inhibition of their dissolution. For Pb releasing behavior, PbSO_(4) dissolves in preference to Pb-substituted natrojarosite, i.e.,(Na, Pb)-jarosite, which primarily results in the sharp increase of Pb releasing concentration(> 40 mg/L). PbSO_(4) occlusion by jarosite-type compounds can significantly reduce the release of Pb. The results of this study could provide useful information regarding Fe and Pb cycling in acidic natural and engineered environments.

关键词： Pb-bearing natrojarosite Interaction mechanism Acid dissolution Releasing behavior

Preparation and Characterization of Glass-Ceramic Basalt Fiber

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Journal of Harbin Institute of Technology(New Series) 2022年第6期29卷 27-33页

作者： Lida Luo Tan Yan Jin Liu Linfeng Ding qingwei wang Wan Jiang State Key Laboratories for Modification of Chemical Fiber and Polymer Materials Donghua UniversityShanghai 201620China Engineering Research Center of Advanced Glass Manufacturing Technology Ministry of EducationDonghua UniversityShanghai 201620China Institute of Functional Materials Donghua UniversityShanghai 201620China

Basalt fiber(BF)is widely applied in the construction industry to improve the mechanical properties of construction *** studies show that BF has the potential to further enhance its performance via a crystallization *** this work,the glass-ceramic basalt fibers(GCBFs)were prepared through nucleation and crystallization treatments according to the crystallization kinetics *** from XRD and SEM show that GCBFs have main crystalline phases of Diopside and Augite reach crystallinity of around 46%±10%.In particular,the GCBFs sample with the largest mean crystal size maintains the lowest tensile strength of~197 MPa(compared with the pristine BFs of~737 MPa).Moreover,the weight loss and ion dissolution of GCBFs were explored in seawater environments and it was investigated that,GCBFs have better anti-seawater corrosion than the pristine BFs and have the potential to apply in the marine industry.

关键词： glass-ceramic basalt fiber tensile strength crystallization seawater environment

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Nanosize-effect on the distribution of heavy metals in copper smelting dust:Based on sophisticated dust sorting approach

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Nano Research 2024年第1期17卷 312-320页

作者： Ken Li Zuwu Liao Hengdi Ye Qingzhu Li Fenghua Shen Qian Li Hui Liu qingwei wang Xu Yan Zhang Lin Liyuan Chai School of Metallurgy and Environment Central South UniversityChangsha 410083China Chinese National Engineering Research Center for Control&Treatment of Heavy Metal Pollution Changsha 410083China National Engineering Research Center of Sintering and Pelletizing Equipment System Zhongye Changtian International Engineering Co.LtdChangsha 410205China

Dust particles emitted from smelters can be hazardous to ecosystems and humans,as they are often enriched in metallic ***,we combined multi-method mineralogical analysis with a sophisticated size sorting approach for copper smelting dust to study the nanosize-effect on heavy metal distribution,which has hitherto been *** types of dust were collected from a copper flash smelter and then size-sorted using a Dekati low-pressure *** showed that all three samples could easily sort out nanoscale dust particles(<1μm,grades 10–2)and even those smaller than 100 nm(grades 5–2).Especially for electrostatic precipitators dust,the mass fraction of nanoscale dust(<1μm)could reach 10.71%.The presence of heavy metals(Pb,Zn,Cu,and As)and their mineral species in dust was examined at various particle *** was discovered that different heavy metals are enriched on nanoparticles in specific *** micron-sized particles,heavy metals are generally found in discrete phases(e.g.,CuSO_(4),PbSO_(4),and As_(2)O_(3)).In nanoscale particles,the dominant phase is Fe_(3)O_(4),while heavy metals are mostly found in lattice substitution(e.g.,CuFe_(2)O_(4)and ZnFe_(2)O_(4)).Two distinct nano-dust morphologies were found:One with irregular mesh or chain structures consisting of particles of a few nanometers,and the other with polygonal crystals in larger sizes of hundreds of *** enrichment of heavy metals in the latter morphology is more pronounced,possibly because lattice substitution of heavy metals is more likely to occur when polycrystalline particles are formed.

关键词： copper flue dust size-sorted heavy metal distribution morphology nano-sized effects