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Insights into microscopic oil occurrence characteristics in shales from the Paleogene Funing Formation in Subei Basin, China

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Petroleum Science 2025年第1期22卷 55-75页

作者： Jun-Jie wang peng-Fei zhang Shuang-fang Lu Zi-Zhi Lin Wen-Biao Li Jun-jian zhang Wei-Zheng Gao Neng-Wu Zhou Guo-hui Chen Ya-Jie Yin Han Wu Sanya Offshore Oil & Gas Research Institute of Northeast Petroleum University College of Earth Science and Engineering Shandong University of Science and Technology Key Laboratory of Continental Shale Hydrocarbon Accumulation and Efficient Development Ministry of Education Northeast Petroleum University School of Geoscience China University of Petroleum (East China)

The microscopic occurrence characteristics primarily constrain the enrichment and mobility of shale *** study collected the lacustrine shales from the Palaeogene Funing Formation in the Gaoyou Sag, Subei Basin. Conventional and multistage Rock-Eval, scanning electron microscopy, and nuclear magnetic resonance(NMR) T1-T2were performed to analyze the contents and occurrence characteristics of shale oil. Low-temperature nitrogen adsorption-desorption(LTNA/D) experiments were conducted on the shales before and after extraction. The relationships between shale oil occurrence with organic matter and pore structures were then discussed. Predominantly, the shale oil in the Funing Formation is found within fractures, with secondary occurrences in interparticle pores linked to brittle minerals and sizeable intraparticle pores associated with clay minerals. The selected shales can be categorized into two types based on the nitrogen isotherms. Type A shales are characterized by high contents of felsic and calcareous minerals but low clay minerals, with larger TOC and shale oil values. Conversely, Type B shales are marked by abundant clay minerals but diminished TOC and shale oil contents. The lower BET specific surface area(SSA), larger average pore diameter, and simpler pore surfaces and pore structures lead to the Type A shales being more conducive to shale oil enrichment and mobility. Shale oil content is predominantly governed by the abundance of organic matter, while an overabundance of organic matter typically equates to a reduced ratio of free oil and diminished fluidity. The BET SSA, volumes of pores less than 25 and 100 nm at extracted state all correlate negatively with total and adsorbed oil contents but display no correlation with free oil, while they have positive relationships with capillary-bound ***, pore water is mainly saturated in micropores(<25 nm) and minipores(25-100 nm), as well as adsorbed oil, while free oil, i.e., bound and movable

关键词： Occurrence characteristic Shale oil content Pore structure Low-temperature nitrogen adsorption-desorption Gaoyou Sag

Non-Noether Conserved Quantity of Poincaré-Chetaev Equations of a Generalized Classical Mechanics

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Communications in Theoretical Physics 2006年第6期45卷 961-964页

作者： zhang peng-yu fang jian-hui wang peng ding ning College of Physics Science and Technology China University of Petroleum （East China） Dongying 257061 China

In the present paper the Lie symmetrical non-Noether conserved quantity of the Poincaré Chetaev equations of a generalized classical mechanics under the general infinitesimal transformations of Lie groups is discussed. First, we establish the determining equations of Lie symmetry of the equations. Second, the Lie symmetrical non-Noether conserved quantity of the equations is deduced. Finally, an example is given to illustrate the application of the results.

关键词： Poincaré-Chetaev equations generalized classical mechanics Lie symmetry non-Noether conserved quantity

Two New Types of Conserved Quantities of Mei Symmetry for Holonomic Mechanical System

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Communications in Theoretical Physics 2008年第1期49卷 53-56页

作者： fang jian-hui wang peng ding ning College of Physics Science and Technology China University of Petroleum Dongying 257061 China

Two new types of conserved quantities directly deduced by Mei symmetry of holonomic mechanical system are studied. The definition and criterion of Mei symmetry for holonomic system are given. A coordination function is introduced, the conditions under which the Mei symmetry can directly lead to the two types of conserved quantities and the forms of the two types of conserved quantities are obtained. An illustrative example is given. The result indicates that the coordination function can be selected properly according to the demand of the gauge function, thereby the gauge function can be found out more easily. Furthermore, since the choice of the coordination function has multiformity, much T more conserved quantity of Mei symmetry for holonomic mechanical system can be obtained.

关键词： holonomic mechanical system Mei symmetry new conserved quantity

Noether-Mei Symmetry of Mechanical System in Phase Space

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Communications in Theoretical Physics 2006年第5期45卷 882-884页

作者： fang jian-hui wang peng ding ning College of Physical Science and Technology China University of Petroleum Dongying 257061 China

In this paper, a new kind of symmetry and its conserved quantities of a mechanical system in phase space are studied. The definition of this new symmetry, i,e., a Noether-Mei symmetry, is presented, and the criterion of this symmetry is also given. The Noether conserved quantity and the Mei conserved quantity deduced from the Noether-Mei symmetry of the system are obtained. Finally, two examples are given to illustrate the Bpplication of the results.

关键词： Noether-Mei symmetry conserved quantity mechanical system phase space

Unified Symmetry and Conserved Quantities of Mechanical System in Phase Space

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Communications in Theoretical Physics 2006年第1X期46卷 97-100页

作者： fang jian-hui ding ning wang peng College of Physics Science and Technology China University of Petroleum Dongying 257061 China

In this paper, a new symmetry and its conserved quantities of a mechanical system in phase space are studied. The defition of this new symmetry, i.e., a unified one is presented, and the criterion of this symmetry is also given. The Noether, the generalized Hojman and the Mei conserved quantities of the unified symmetry of the system are obtained. The unified symmetry contains the Noether, the Lie and the Mei symmetries, and has more generalized significance.

关键词： unified symmetry mechanical system conserved quantity phase space

Perturbation and Adiabatic Invariants of Mei Symmetry for Nonholonomic Mechanical Systems

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Communications in Theoretical Physics 2007年第4期47卷 594-596页

作者： ding ning fang jian-hui wang peng College of Physical Science and Technology China University of Petroleum Dongying 257061 China

Based on the concept of adiabatic invariant, the perturbation and adiabatic invariants of the Mei symmetry for nonholonomic mechanical systems are studied. The exact invariants of the Mei symmetry for the system without perturbation are given. The perturbation to the Mei symmetry is discussed and the adiabatic invariants of the Mei symmetry for the perturbed system are obtained.

关键词： Mei symmetry perturbation adiabatic invariant nonholonomic mechanical system

A New Type of Conserved Quantity of Mei Symmetry for Lagrange Systems

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Communications in Theoretical Physics 2007年第5X期48卷 799-800页

作者： ding ning fang jian-hui wang peng zhang Xiao-Ni College of Physics Science and Technology China University of Petroleum Dongying 257061 China

A new type of conserved quantity, which is induced from the Mei symmetry of Lagrange systems, is studied. The conditions for that the new type of conserved quantity exists and the form of the new type of conserved quantity are obtained. An illustrated example is given. The Noether conserved quantity induced from the Mei symmetry of Lagrange systems is a special case of the new type of conserved quantity given in this paper.

关键词： Mei symmetry new type of conserved quantity Lagrange system

Perturbation to Lie Symmetry and Lutzky Adiabatic Invariants for Lagrange Systems

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Communications in Theoretical Physics 2008年第1期49卷 57-60页

作者： ding ning fang jian-hui wang peng zhang Xiao-Ni College of Physics Science and Technology China University of Petroleum Dongying 2570617 China

Based on the concept of adiabatic invariant, perturbation to Lie symmetry and Lutzky adiabatic invariants for Lagrange systems are studied by using different methods from those of previous works. Exact invariants induced from Lie symmetry of the system without perturbation are given. Perturbation to Lie symmetry is discussed and Lutzky adiabatic invariants of the system subject to perturbation are obtained.

关键词： symmetry perturbation Lutzky adiabatic invariant Lagrange system

Perturbation to Lie Symmetry and Hojman Exact and Adiabatic Invariants of Generalized Raitzin Canonical Equation of Motion

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Communications in Theoretical Physics 2007年第4X期48卷 615-618页

作者： wang peng fang jian-hui ding ning zhang Xiao-Ni College of Physics and Technology China University of Petroleum Dongying 257061 China

In this paper, firstly, we get the Hojman exact invariants by Lie symmetry for an undisturbed generalized Raitzin equation of motion. Secondly, we study the perturbation to Lie symmetry of generalized Raitzin canonical equation of motion and get Hojman adiabatic invariants. Lastly, an example is given to illustrate the application of the results.

关键词： generalized mechanics symmetry Raitzin canonical equation perturbation adiabatic invariant