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experimental research on the launching system of auxiliary charge with filter cartridge structure

Defence Technology（防务技术） 2024年第1期31卷 41-48页

作者： Zi-jun Chen ze He hong-Hao Ma Lu-Qing wang Zhao-Wu shen CAS Key Laboratory of Mechanical Behavior and Design of Materials Department of Modern MechanicsUniversity of Science and Technology of ChinaHefeiAnhui230027PR China State Key Laboratory of Fire Science University of Science and Technology of ChinaHefeiAnhui230026PR China

A launching system with a filter cartridge structure was proposed to improve the muzzle velocity of the *** combustion chamber of the launching system is divided into two fixed chambers,one is located in the breech chamber,and the other is arranged in the *** breech chamber charge was ignited first,and the charges in the auxiliary chambers were ignited by the high-temperature,highpressure combustible gas trailing the *** this way,the combustible gas in the auxiliary chambers could compensate for the pressure drop caused by the movement of the *** proposed device features the advantage of launching a projectile with high muzzle velocity without exceeding the maximum pressure in the *** order to obtain some internal ballistic characteristics of the launch system,some critical structure,such as the length of the filter cartridge auxiliary charge,the combustion degree of the propellant in the chamber,and the length of the barrel,are *** experimental results show that with the increased auxiliary charge length,a pressure plateau or even a secondary peak pressure can be formed,which is less than the peak *** projectile velocity increased by 23.57%,14.64%,and 7.65%when the diaphragm thickness was 0 mm,1 mm,and2 mm,*** muzzle velocity of the projectile can be increased by 13.42%by increasing the length of the *** the same charge condition,with the increase of barrel length,the energy utilization rate of propellant increases by 28.64%.

关键词： Interior ballistics Charge structures Launch system Charge design

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Core-shell heterostructure engineering of CoP nanowires coupled NiFe LDH nanosheets for highly efficient water/seawater oxidation

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Chinese Chemical Letters 2024年第8期35卷 549-553页

作者： guo-hong gao Run-ze Zhao Ya-jun wang Xiao Ma Yan Li Jian Zhang Ji-Sen Li School of Chemistry Chemical Engineering and MaterialsJining UniversityQufu 273155China Institute of Physical education Jining UniversityQufu 273155China Key Laboratory of Advanced energy Materials Chemistry(Ministry of education) Nankai UniversityTianjin 300071China

Searching for efficient nonprecious metal-based catalysts toward oxygen evolution reaction(OeR)are of significance for seawater ***,a core-shell-structured hybrid of cobalt phosphide nanowires@NiFe layered double hydroxide nanosheets grown on conductive nickel foam(CoP@NiFe LDH/NF)is prepared by a feasible approach at low *** charming structure can provide numerous phosphide/hydroxide heterogenous interfaces,expose abundant active sites,and boost elec-tron/mass transfer,synergistically enhancing catalytic OeR *** employed as an electrocatalyst toward the OeR,the resultant CoP@NiFe LDH/NF only requires a small overpotential of 287 mV to pro-vide 300 mA/cm^(2)current density as well as long-time durability in 1.0 mol/L KOH *** regula-tion of electronic states and surface reconstruction synergistically contribute to highly efficient seawater *** work provides an opportunity to construct efficient and inexpensive electrocatalysts for hydrogen production.

关键词： Cobalt phosphide NiFe layered double hydroxide Interfacial engineering Oxygen evolution reaction Seawater oxidation

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Unraveling role of double-exchange interaction in electrochemical water oxidation by external magnetic field

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Rare Metals 2024年第1期43卷 289-297页

作者： jun Li jun-Ming Li hong hong Dong-Xue Liu Qing-Qi Cao Dun-Hui wang National Laboratory of Solid State Microstructures and Jiangsu Provincial Key Laboratory for Nanotechnology Nanjing UniversityNanjing 210093China School of electronics and Information Hangzhou Dianzi UniversityHangzhou 310018China

Double-exchange(De) interaction plays an important role in electrocatalytic oxygen evolution reaction(OeR).However,precise achievement of De interaction often requires foreign dopants or vacancy engineering,leading to destabilization of the catalysts and deterioration of *** contrast,the utilization of environmentally friendly,contactless,and continuously adjustable magnetic fields to study the OeR process is profitable to avoid aforementioned interference factors and further elucidate the direct relationship_(0.5)between De interaction and OeR ***,by using cobalt hydroxide carbonate(Co(OH)(CO_(3))·xH_(2)O,CoHC) nanostructures as a proof-of-concept study,external magnetic fields are carefully implemented to verify the role of De interaction during water oxidation *** studies reveal that external magnetic fields effectively enhance the reaction rate of the catalyst,the overpotential decreases from 386 to 355 mV(100 mA·cm^(-2)),while Tafel slopes drastically decline from 93 to 67 mV·dec^(-1)(1.0 T).Moreover,magnetic field increment exhibits robust *** in situ Raman and impedance measurements under external field,it can be found that magnetic field promotes the electron migration between Co^(2+) and Co^(3+) in the CoHC catalysts with the assistance of De interactions,thus boosting the OeR efficiency.

关键词： Magnetic field Double-exchange(De)interaction electrocatalysis Oxygen evolution reaction(OeR) Cobalt hydroxide carbonate

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A robust viscoelastic surfactant tolerating 20% HCl up to 150℃ for oil well stimulation

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Petroleum Science 2024年第3期21卷 1865-1874页

作者： Ji wang Ning Qi hong-Yao Yin Yu-jun Feng Polymer Research Institute State Key Laboratory of Polymer Materials EngineeringSichuan UniversityChengdu610065SichuanPR.China Tianfu Yongxing Laboratory New Theory and Technology of CO_(2) Capture Research CenterChengdu610065SichuanPR China School of Petroleum engineering China University of Petroleum(East China)Qingdao266580ShandongPR China

Viscoelastic surfactants(VeS)are often used as viscous diverters in acidizing stimulation to prolong the acid consumption time and maximize zonal coverage of the acid for improving well ***,the ceiling temperature of commercial VeS cannot exceed 120℃in practical use because of the poor thermal stability and fragile molecular structure,hindering their implementation in hightemperature oil reservoirs,i.e.,≥150℃.Here we synthesized a novel C22-tailed diamine,N-erucaminopropyl-N,N-dimethylamine(eDPA),and examined comparatively its rheological behavior,assemblies morphology and molecular stability in 20 wt%HCl with a commercial VeS,erucyl dimethyl amidopropyl betaine(eDAB).The feasibility of eDPA for acidizing stimulation was assessed by acid etching of carbonate rock with its HCl solution at 150℃.Rheological results showed that the 2.5 wt%eDPA—20 wt%HCl solution maintains stable viscosity of 90 m Pa s at 150℃for 60 min,while that of 2.0 wt%eDAB HCl solution is just 1 m Pa s under identical conditions.1H NMR spectra and cryo-TeM observations revealed that the chemical structure and self-assembled architectures of eDPA remained intact in such context,but the eDAB suffered from degradation due to the hydrolysis of the amide group,accounting for the poor heat-resistance and *** reaction rate of 2.5 wt%eDPA HCl solution with carbonate rock was one order of magnitude lower than that of 20 wt%HCl solution at 150℃,underpinning the potential of eDPA to be used in the high-temperature reservoirs *** work improved the thermal tolerance of VeS in highly concentrated HCl solution,paving a feasible way for the acidization of high-temperature reservoir environments(~150℃).

关键词： Viscoelastic surfactants Thermal stability Self-diverting acid Wormlike micelles Acidizing stimulation

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enhanced hydrogen evolution reaction in FePt film with remanence due to decrease in domain walls

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Rare Metals 2024年第3期43卷 1108-1115页

作者： hong hong Dong-Xue Liu jun Li jun-Ming Li Li-Qian Wu Bo Yang Qing-Qi Cao Dun-Hui wang National Laboratory of Solid State Microstructures Collaborative Innovation Center of Advanced MicrostructuresJiangsu Provincial Key Laboratory for NanotechnologySchool of PhysicsNanjing UniversityNanjing210093China Hangzhou Dianzi University Hangzhou310018China Key Laboratory for Anisotropy and Texture of Materials(Ministry of education) School of Material Science and EngineeringNortheastern UniversityShenyang110819China

As an effective strategy to improve the properties of electrocatalysts,magnetic field-assisted electrocatalytic water splitting has attracted increasing attention ***,the corresponding enhancements mostly depend on the exertion of an external magnetic field during electrochemical reactions,which results in a high cost of industrial production,and makes the magnetic field manipulation of electrocatalysis become a challenging *** this work,instead of the external magnetic field,a bias magnetic field is self-supplied by the remanence state of a ferromagnetic electrocatalyst of *** to the assistance of this bias magnetic field,the FePt film in the remanence state shows the overpotential of 229 mV during hydrogen evolution reaction,which is much lower than that in its demagnetization state(283 mV).Our findings demonstrate that the remanence in ferromagnetic electrocatalysts can improve the catalytic performance,which is attributed to the decrease in domain walls.

关键词： Remanence Magnetic domains electrocatalysis Hydrogen evolution reaction(HeR)

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Recent advances in heterogeneous catalysis of solar-driven carbon dioxide conversion

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Journal of environmental Sciences 2024年第6期140卷 165-182页

作者： jun Xu Farzaneh Arabpour Roghabadi Ying Luo Vahid Ahmadi Qian wang Zheng wang hong He State Key Joint Laboratory of environment Simulation and Pollution Control Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China College of Chemistry and Chemical engineering Henan Polytechnic UniversityJiaozuoHenan 454000China Department of Process engineering Faculty of Chemical EngineeringTarbiat Modares UniversityTehranIran Optoelectronics and Nanophotonics Research group Faculty of Electrical and Computer EngineeringTarbiat Modares UniversityTehranIran graduate School of engineering Nagoya UniversityFuro-choChikusa-kuNagoya 464-8603Japan

Solar-driven carbon dioxide(CO_(2))conversion including photocatalytic(PC),photoelectrochemical(PeC),photovoltaic plus electrochemical(PV/eC)systems,offers a renewable and scalable way to produce fuels and high-value chemicals for environment and energy *** review summarizes the basic fundament and the recent advances in the field of solar-driven CO_(2)*** the visible-light absorption is an important strategy to improve solar energy conversion *** separation and migration of photogenerated charges carriers to surface sites and the surface catalytic processes also determine the photocatalytic *** engineering including co-catalyst loading,defect engineering,morphology control,surface modification,surface phase junction,and Z-scheme photocatalytic system construction,have become fundamental strategies to obtain high-efficiency *** to photocatalysis,these strategies have been applied to improve the conversion efficiency and Faradaic efficiency of typical PeC *** PV/eC systems,the electrode surface structure and morphology,electrolyte effects,and mass transport conditions affect the activity and selectivity of electrochemical CO_(2)***,the challenges and prospects are addressed for the development of solar-driven CO_(2)conversion system with high energy conversion efficiency,high product selectivity and stability.

关键词： Solar-driven CO_(2)reduction Photocatalytic system Photoelectrochemical system Photovoltaic plus electrochemical system Surface/interface engineering

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energy Harvesting in the Wake of An Inverted C-Shaped Bluff Body

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China Ocean engineering 2024年第1期38卷 68-80页

作者： wang jun-lei LI shen-fang Md.Mahbub ALAM ZHU hong-jun HU guo-biao School of Mechanical and Power engineering Zhengzhou UniversityZhengzhou 450000China Center for Turbulence Control Harbin Institute of Technology(Shenzhen)Shenzhen 518055China State Key Laboratory of Oil and gas Reservoir geology and exploitation Southwest Petroleum UniversityChengdu 610500China Internet of Things Thrust The Hong Kong University of Science and Technology(Guangzhou)Guangzhou 511400China

This paper proposes a novel wake-induced vibration(WIV)-based energy harvesting system consisting of two bluff *** inverted C-shaped bluff body is stationary installed at the upstream position to generate an interference wake street,and a cylinder bluff body equipped with a transducer is elastically suspended at the downstream position to harness WIV *** hydrodynamics and energy harvesting(eH)performance of the proposed system are investigated via experimental *** reduced velocity(U*)ranging from 2 to 14(the corresponding Reynolds number ranging from 15100 to 106200)is considered in the present *** is found that the wake generated by the inverted C-shaped bluff body significantly affects the eH *** the opening angle(α)of the C-shaped bluff body increases the vibration amplitude of the downstream cylinder,thereby increasing the harvested *** the spacing(L)between two bluff bodies is two times the cylinder diameter(D),the wake-induced vibration(WIV)mode is observed,while the combined WIV and wake galloping(Wg)mode occurs whenαis 150°,and L equals 3D or *** average drag coefficient becomes negative when L is 2D,3D,or *** carefully configuring a C-shaped bluff body,the wake generated by it can bring an augmenting effect on the vibration of the downstream eH *** example,the RMS power output of the proposed eH system reaches a maximum of 0.31 W at U*=8 and L=4D,which is 300%greater than that of its traditional ***,after a number of case stud-ies,it is identified that the proposed eH system can achieve the best performance whenαis 150°and L=2D.

关键词： wake-induced vibration vortex-induced vibration galloping energy harvesting bluff body

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Strain‑Induced Surface Interface Dual Polarization Constructs PML‑Cu/Bi_(12)O_(17)Br_(2) High‑Density Active Sites for CO_(2) Photoreduction

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Nano-Micro Letters 2024年第5期16卷 169-183页

作者： Yi Zhang Fangyu guo jun Di Keke wang Molly Meng‑jung Li Jiayu Dai Yuanbin she Jiexiang Xia Huaming Li School of Chemistry and Chemical engineering Institute for Energy ResearchSchool of the Environment and Safety EngineeringJiangsu UniversityZhenjiang 212013People’s Republic of China State Key Laboratory Breeding Base of green Chemistry‑Synthesis Technology College of Chemical EngineeringZhejiang University of TechnologyHangzhou 310014People’s Republic of China College of Science and Hunan Key Laboratory of Extreme Matter and ApplicationsNational University of Defense TechnologyChangsha 410073People’s Republic of China Department of Applied Physics The Hong Kong Polytechnic UniversityHung HomHong KongPeople’s Republic of China School of Chemistry and Chemical engineering National Special Superfine Powder Engineering Research CenterNanjing University of Science and TechnologyNanjing 210094People’s Republic of China Key Laboratory of the Ministry of education for Advanced Catalysis Materials Zhejiang Normal UniversityJinhua 321004People’s Republic of China

The insufficient active sites and slow interfacial charge trans-fer of photocatalysts restrict the efficiency of CO_(2) *** synchronized modulation of the above key issues is demanding and ***,strain-induced strategy is developed to construct the Bi–O-bonded interface in Cu porphyrin-based monoatomic layer(PML-Cu)and Bi_(12)O_(17)Br_(2)(BOB),which triggers the surface interface dual polarization of PML-Cu/BOB(PBOB).In this multi-step polarization,the built-in electric field formed between the interfaces induces the electron transfer from con-duction band(CB)of BOB to CB of PML-Cu and suppresses its reverse ***,the surface polarization of PML-Cu further promotes the electron converge in Cu *** introduction of PML-Cu endows a high density of dispersed Cu active sites on the surface of PBOB,significantly promoting the adsorption and activation of CO_(2) and CO *** conversion rate of CO_(2) photoreduction to CO for PBOB can reach 584.3μmol g-1,which is 7.83 times higher than BOB and 20.01 times than *** work offers valuable insights into multi-step polarization regulation and active site design for catalysts.

关键词： Bi_(12)O_(17)Br_(2) Porphyrin CO_(2)photoreduction Polarization Active sites

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experimental and first-principles calculation of TiN growth mechanism on CeAlO_(3) surface in steel

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Journal of Iron and Steel Research International 2024年第2期31卷 452-463页

作者： Fei-hu He jun Peng Fang Zhang Yong-bin wang hong-tao Chang School of Materials and Metallurgy Inner Mongolia University of Science and TechnologyBaotou014010Inner MongoliaChina

Regular TiN is harmful to the toughness of steel,and its shape and size need to be *** the behavior of TiN precipitation on CeAlO_(3) surfaces is critical for controlling the morphology and formation process of CeAlO_(3)–TiN composite inclusions in the *** results showed that TiN had a square morphology on the CeAlO3 surface,and electron backscatter diffraction phase identification results revealed the orientation relationship between CeAlO_(3) and TiN as follows:(001)_(CeAlO_(3))//(110)_(TiN),(100)_(CeAlO_(3))/(001)_(TiN),and[010]_(CeAlO_(3))/[110]_(TiN).The CeAlO3 crystal structure was studied using the first-principles calculation method,and the adsorption and growth process of TiN on the CeAlO_(3) surface were investigated from the atomic *** calculation results indicate that there is no metallic bonding present in the CeAlO_(3) *** the low-index crystal planes of CeAlO_(3),the(110)planes terminated with O and CeAlO have the highest and lowest surface energies,respectively,with values of 0.373 and 0.051 eV/Å^(2).On the high surface energy plane of CeAlO_(3),the TiN atomic permutation structure is consistent with the arrangement of Ti and N atoms in TiN(100)or(110).For the low surface energy plane of CeAlO_(3),the Ti and N atoms are arranged in a ring-like structure.

关键词： CeAlO_(3)-TiN inclusion Orientation relationship Crystal structure First principle Surface energy

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Rapid lithium-ion insertion/extraction and migration behavior of Na_(2)WO_(4)-encapsulated lithium-rich layered oxide cathode

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Rare Metals 2024年第8期43卷 3647-3660页

作者： Yu-shen Zhao Fan-Fan wang Jian-Cang wang Peng-Fei wang Ting-Feng Yi jun-hong Zhang School of Materials Science and engineering Northeastern UniversityShenyangShenyang 110819China Key Laboratory of Dielectric and electrolyte Functional Material Hebei Province School of Resources and MaterialsNortheastern University at QinhuangdaoQinhuangdao 066004China Shandong Provincial Key Laboratory of Chemical energy Storage and Novel Cell Technology College of Chemistry and Chemical EngineeringLiaocheng UniversityLiaocheng 252059China

Due to the low cost,high working voltage and high storage capacity,Li-rich Mn-based layered compounds show promise as the cathode materials for lithiumion batteries(LIBs).However,the side reactions at the solid-liquid interface of the cathode will lead to rapid capacity decay and inferior rate ***,this article proposes a liquid-phase dispersion strategy to introduce a Na_(2)WO_(4)layer on the Li_(1.2)Ni_(0.13)-Co_(0.13)Mn_(0.54)O_(2) cathode,which can reduce the side effects between raw materials and electrolyte and promote the insertion/extraction rate of Li^(+),thus enhancing the material stability and rate *** a result,the capacity retention rate is 96.9%after 200 cycles under ***,the capacities are 177.5,149.5,111.1 and58.3 mAh·g^(-1)at 1C,2C,5C and 10C,implying a superior fast charging *** exceptional performance can be ascribed to both the increased conductivity and enhanced structural stability of the cathode ***'s more,based on the investigation of ion insertion/extraction behavior in electrode materials and the ion migration kinetics in the electrolyte,this study suggests that coating Li-rich Mn-based materials with Na_(2)WO_(4)can be a promising strategy to improve their performance in LIBs.

关键词： Li-ion battery Coating Rate performance Li_(1.2)Ni_(0.13)Co_(0.13)Mn_(0.54)O_(2) Reaction kinetics

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