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Dielectric-ion-conductive ZnNb2O6 layer enabling rapid desolvation and diffusion for dendrite-free Zn metal batteries

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Journal of Energy Chemistry 2025年第1期100卷 693-701页

作者： Haifeng Yang jian wang Panpan Zhang Xiaomin Cheng Qinghua Guan Jing Dong Bixian Chen Lujie Jia Jing Zhang Yongzheng Zhang Yunjian Liu Hongzhen Lin School of Materials Science and Engineering Jiangsu University i-Lab & CAS Key Laboratory of Nanophotonic Materials and Devices Suzhou Institute of Nano-Tech and Nano-Bionics Chinese Academy of Sciences Helmholtz Institute Ulm (HIU) Karlsruhe Institute of Technology (KIT) School of Materials Science and Engineering Xi'an University of Technology State Key Laboratory of Chemical Engineering East China University of Science and Technology

Rechargeable aqueous zinc-metal batteries （AZMBs） are promising candidates for large-scale energy storage systems due to their low cost and high ***,their performance and sustainability are significantly hindered by the sluggish desolvation kinetics at the electrode/electrolyte interface and the corresponding hydrogen evolution reaction where active water molecules tightly participate in the Zn（H2O）62+solvation ***,learnt from self-generated solid electrolyte interphase （SEI） in anodes,the dielectric but ion-conductive zinc niobate nanoparticles artificial layer is constructed on metallic Zn surface （ZNB@Zn）,acting as a rapid desolvation *** zincophilic and dielectric-conductive properties of ZNB layer accelerate interfacial desolvation/diffusion and suppress surface corrosion or dendrite formation,achieving uniform Zn plating/stripping behavior,as confirmed by electronic/optical microscopies and interface spectroscopical measurements together with theoretical ***,the as-prepared ZNB@Zn electrode exhibits excellent cycling stability of over 2000 h and robust reversibility （99.54%） even under high current density and depth of discharge ***,the assembled ZNB@Zn-based full cell displays high capacity-retention rate of 80.21%after 3000 cycles at 5 A g-1and outstanding rate performance up to 10 A *** large-areal pouch cell is stabilized for hundreds of cycles,highlighting the bright prospects of the dielectric but ion-conductive layer in further application of AZMBs.

关键词： Zn metal battery Dielectric artificial layer Rapid ion diffusion Zincophilic diffusion Active water inhibition

Clinicopathological differences between patients with schistosomal appendicitis and non schistosomal appendicitis:A retrospectively study of past ten years

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World Journal of Clinical Cases 2025年第2期13卷 24-32页

作者： Xiao-Yi wang Yao Hao Zi-jian wang Xiu-Liang Xu jiang-Hua Yang Department of Infectious Diseases The First Affiliated of Wannan Medical CollegeWuhu 241001Anhui ProvinceChina

BACKGROUND Chronic schistosomiasis causes multiple organ and multiple system diseases,especially the digestive *** eggs are mainly deposited in the stomach,liver and colorectal,but a few eggs are deposited in the appendix and cause *** present,there are few studies on schistosomal *** To explore the differences in epidemiological,clinical and pathological characteristics between schistosomal appendicitis and non-schistosomal appendicitis over the past decade in order to assess the impact of schistosomiasis on *** The differences of general data,clinical data and laboratory examination data of patients with appendicitis from October 2013 to October 2023 were retrospectively *** patients were divided into two groups for *** were 136 patients in schistosomal appendicitis group and 5418 patients in non-schistosomal appendicitis *** Schistosomal appendicitis accounted for 2.45%of all patients with appendicitis,and the annual proportion in the past decade was 2.2%,2.9%,1.8%,1.9%,3.4%,3.1%,1.9%,1.6%,3%,2.6%,*** prevalence of schistosomal appendicitis was middle-aged and elderly males,with an average age of 61.73±15.335 *** main population of non-schistosomal appendicitis was middle-aged men,with an average age of 35.8±24.013 years(P<0.001).The distribution of pathological types of appendicitis was different between the two groups(P<0.001).The incidence of acute suppurative appendicitis in non-schistosomal appendicitis was higher than that in schistosomal appendicitis[odds ratio(OR)=0.504;95%confidence interval(CI):0.349-0.728;P<0.001].The proportion of acute attack of chronic appendicitis in schistosomal appendicitis was higher than that in non-schistosomal appendicitis(OR=2.614;95%CI:1.815-3.763;P<0.001).The proportion of schistosomal appendicitis patients complicated with colorectal cancer was higher than that of nonschistosomal appendicitis patients(OR=5.087;95%CI:1.427-

关键词： Schistosomal appendicitis Schistosomiasis Appendix Colorectal cancer Clinicopathological characteristics

Recent progress in the applications of presynaptic dopaminergic positron emission tomography imaging in parkinsonism

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Neural Regeneration Research 2025年第1期20卷 93-106页

作者： Yujie Yang Xinyi Li Jiaying Lu Jingjie Ge Mingjia Chen Ruixin Yao Mei Tian jian wang Fengtao Liu Chuantao Zuo Key Laboratory of Arrhythmias Ministry of EducationDepartment of Medical GeneticsShanghai East HospitalSchool of MedicineTongji UniversityShanghaiChina Department of Neurology National Research Center for Aging and MedicineNational Center for Neurological Disordersand State Key Laboratory of Medical NeurobiologyHuashan HospitalFudan UniversityShanghaiChina Department of Nuclear Medicine&PET Center National Center for Neurological Disordersand National Clinical Research Center for Aging and MedicineHuashan HospitalFudan UniversityShanghaiChina International Human Phenome Institutes(Shanghai) ShanghaiChina Human Phenome Institute Fudan UniversityShanghaiChina

Nowadays,presynaptic dopaminergic positron emission tomography,which assesses deficiencies in dopamine synthesis,storage,and transport,is widely utilized for early diagnosis and differential diagnosis of *** review provides a comprehensive summary of the latest developments in the application of presynaptic dopaminergic positron emission tomography imaging in disorders that manifest *** conducted a thorough literature search using reputable databases such as PubMed and Web of *** criteria involved identifying peer-reviewed articles published within the last 5 years,with emphasis on their relevance to clinical *** findings from these studies highlight that presynaptic dopaminergic positron emission tomography has demonstrated potential not only in diagnosing and differentiating various Parkinsonian conditions but also in assessing disease severity and predicting ***,when employed in conjunction with other imaging modalities and advanced analytical methods,presynaptic dopaminergic positron emission tomography has been validated as a reliable in vivo *** validation extends to screening and exploring potential neuropathological mechanisms associated with dopaminergic *** summary,the insights gained from interpreting these studies are crucial for enhancing the effectiveness of preclinical investigations and clinical trials,ultimately advancing toward the goals of neuroregeneration in parkinsonian disorders.

关键词： aromatic amino acid decarboxylase brain imaging dopamine transporter Parkinson’s disease parkinsonism positron emission tomography presynaptic dopaminergic function vesicle monoamine transporter type 2

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优化县域义务教育资源配置的实践审视与路径

北京教育学院学报 2025年第1期39卷 14-20页

作者：王建中国教育科学研究院教育财政研究所北京100088

我国义务教育实行“以县为主”的管理体制。随着学龄人口的变化、新型城镇化的发展、地方财政紧缩以及义务教育优质均衡发展的要求,县域义务教育学校出现“城挤、乡弱、村空”的现象,义务教育资源配置面临新的挑战。各地在优化县域义务... 详细信息

我国义务教育实行“以县为主”的管理体制。随着学龄人口的变化、新型城镇化的发展、地方财政紧缩以及义务教育优质均衡发展的要求,县域义务教育学校出现“城挤、乡弱、村空”的现象,义务教育资源配置面临新的挑战。各地在优化县域义务教育资源配置时,注重党政协同推进,强化办学标准引领,完善配套服务与加大投入力度,教育资源整合有力促进了义务教育优质均衡发展。同时,建立同人口变化相协调的基本公共教育服务供给机制,需要理性看待和因地制宜推进新一轮乡村学校布局调整,加强顶层设计,完善县域义务教育学校办学标准;加大教育投入,改进县域义务教育经费保障机制;统筹师资配置,促进县域义务教育强校提质扩优;盘活闲置资源,出台闲置校舍处置指导意见。

关键词：教育资源配置县域义务教育城镇化基本公共教育服务

纳米粒子在骨组织工程化基因修饰治疗中的应用

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中国组织工程研究 2025年第22期29卷 4771-4783页

作者：李光照裴锡波王剑口腔疾病防治全国重点实验室国家口腔医学中心国家口腔疾病临床医学研究中心四川大学华西口腔医院修复科四川省成都市610041

背景:传统的骨组织工程技术治疗临界骨缺损存在成骨效率低、安全性差等问题。而以非病毒纳米粒子为基因载体构建的基因强化型骨组织工程移植物,具有更高的成骨效率和安全性,引起了国内外学者的广泛关注和研究。目的:对当前国内外有关纳... 详细信息

背景:传统的骨组织工程技术治疗临界骨缺损存在成骨效率低、安全性差等问题。而以非病毒纳米粒子为基因载体构建的基因强化型骨组织工程移植物,具有更高的成骨效率和安全性,引起了国内外学者的广泛关注和研究。目的:对当前国内外有关纳米粒子在组织工程成骨基因治疗研究中取得的新技术、新方法以及面临的挑战等进行综述,旨在为纳米粒子介导的骨组织工程基因治疗研究提供参考。方法:第一作者在Pub Med、Web of Science和中国知网数据库上进行文献检索,并以“Bone defect repair,Bone tissue engineering,Gene delivery,Nanoparticles,Non-viral gene vector,Sustained release technology,Sequential release,Targeted delivery”作为英文检索词,以“骨缺损修复,骨组织工程,基因递送,纳米粒子,非病毒基因载体,缓释技术,序贯释放,靶向递送”作为中文检索词,最终纳入84篇文献进行总结。结果与结论:(1)在骨缺损愈合的各个生理阶段进行针对性的基因递送可以显著增强骨修复效果。在早期炎症阶段,通过纳米粒子递送抗炎基因来调节炎症反应,可以为后续骨愈合奠定基础;在血管新生期,向局部递送促血管化基因有助于形成高度组织化、可灌注的血管系统,加快骨愈合速度;随着血管化的进行,骨骼的神经再支配也开始发生,此时递送促神经再生的功能性基因有利于促进神经化骨再生;在成骨阶段,通过构建纳米粒子-成骨基因复合物,可以直接提升支架及体内新骨形成的效率。(2)各种有机、无机纳米颗粒、金属有机框架和外泌体等非病毒纳米载体,在骨组织工程基因治疗中具有巨大的潜力,这些纳米基因载体各有其独特的优势和不足,因此在实际应用时,需要根据基因转染效率、生物安全性和成骨特性等因素选择最合适的类型。(3)为了全面提升递送基因的效果,目前主要通过对纳米载体进行各种功能设计来增强基因转染效率,包括增强缓释性和多基因递送序贯性等时间调控能力、增强对骨组织和成骨相关细胞的空间靶向能力、增强跨膜运输效率和细胞核靶向能力等全过程调控手段。(4)未来要进一步推动纳米粒子介导的骨组织工程基因治疗在临床上的应用,还需要克服诸多技术挑战,包括提高有机纳米基因载体的基因转染效率、降低无机纳米载体的生物安全性风险、优化新型纳米载体的生产工艺以及促进其它生理过程与成骨交互作用等,这些问题也是未来骨组织工程基因治疗的研究热点和潮流。

关键词：骨缺损修复骨组织工程基因递送纳米粒子非病毒基因载体缓释技术序贯释放靶向性递送

Superconductivity in topological semimetals

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National Science Review 2019年第2期6卷 199-202页

作者： jian wang International Center for Quantum Materials School of Physics Peking University Collaborative Innovation Center of Quantum Matter CAS Center for Excellence in Topological Quantum Computation University of Chinese Academy of Sciences Beijing Academy of Quantum Information Sciences

Topological superconductors, where the bulk state shows superconducting gap and Majorana fermions constitute gapless edge states, have become one of the most important topics in physical sciences. Majorana fermions are their own antiparticles and Majorana quasiparticles in a solid-state system obey non-Abelian statistics, and thus can be used for faulttolerant topological quantum computation.

关键词： As Superconductivity in topological semimetals

MULTISYMPLECTIC FOURIER PSEUDOSPECTRAL METHOD FOR THE NONLINEAR SCHR■DINGER EQUATIONS WITH WAVE OPERATOR

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Journal of Computational Mathematics 2007年第1期25卷 31-48页

作者： jian wang Department of Mathematics Shanghai Jiaotong University Division of Computational Science E-Institute of Shanghai Universities Shanghai 200240 China

In this paper, the multisymplectic Fourier pseudospectral scheme for initial-boundary value problems of nonlinear SchrSdinger equations with wave operator is considered. We investigate the local and global conservation properties of the multisymplectic discretization based on Fourier pseudospectral approximations. The local and global spatial conservation of energy is proved. The error estimates of local energy conservation law are also derived. Numerical experiments are presented to verify the theoretical predications.

关键词： Multisymplecticity Fourier pseudospectral method Local conservation laws

Twisted optical communications using orbital angular momentum

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Science China(Physics,Mechanics & Astronomy) 2019年第3期62卷 1-21页

作者： jian wang Wuhan National Laboratory for Optoelectronics School of Optical and Electronic Information Huazhong University of Science and Technology

Angular momentum, a fundamental physical quantity, can be divided into spin angular momentum(SAM) and orbital angular momentum(OAM) in electromagnetic waves. Helically-phased or twisted light beams carrying OAM that exploit the spatial structure physical dimension of electromagnetic waves have benefited wide applications ranging from optical manipulation to quantum information processing. Using the two distinct properties of OAM, i.e., inherent orthogonality and unbounded states in principle, one can develop OAM modulation and OAM multiplexing techniques for twisted optical communications. OAM multiplexing is an alternative space-division multiplexing approach employing an orthogonal mode basis related to the spatial phase structure. In this paper, we review the recent progress in twisted optical communications using OAM in free space and fiber. The basic concept of momentum, angular momentum, SAM, OAM and OAM-carrying twisted optical communications,key techniques and devices of OAM generation/(de)multiplexing/detection, high-capacity spectrally-efficient free-space OAM links, fiber-based OAM links, and OAM processing functions are presented. Ultra-high spectral efficiency and petabit-scale freespace data links are achieved benefiting from OAM multiplexing. The key techniques and challenges of twisted optical communications are also discussed. Twisted optical communications using OAM are compatible with other existing physical dimensions such as frequency/wavelength, amplitude, phase, polarization and time, opening a possible way to facilitate continuous increase of the aggregate transmission capacity and spectral efficiency through N-dimensional multiplexing.

关键词： fiber optical communications free-space optical communications modulation multiplexing orbital angular momentum space-division multiplexing spectral efficiency twisted optical communications twisted light structured light

Metasurfaces enabling structured light manipulation:advances and perspectives [Invited]

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Chinese Optics Letters 2018年第5期16卷 21-26页

作者： jian wang Wuhan National Laboratory for Optoelectronics School of Optical and Electronic Information Huazhong University of Science and Technology Wuhan 430074 China

Metasurfaces and structured light have rapidly advanced over the past few years, from being paradigms to forming functional devices and tailoring special light beams for wide emerging applications. Here, we focus on harnessing metasurfaces for structured light manipulation. We review recent advances in shaping structured light by metasurfaces on different platforms（metal, silica, silicon, and fiber）. Structured light manipulation based on plasmonic metasurfaces, reflection-enhanced plasmonic metasurfaces, metasurfaces on fiber facets, dielectric metasurfaces, and sub-wavelength structures on silicon are presented, showing impressive *** trends, challenges, perspectives, and opportunities are also discussed.

关键词： Metasurfaces enabling structured light manipulation:advances and perspectives OAM