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Effects of temperature and thermally-induced microstructure change on hydraulic conductivity of Boom Clay

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Journal of Rock Mechanics and Geotechnical Engineering 2017年第3期9卷 1-13页

作者： w.z. chen Y.S. Ma H.D. Yu F.F. Li X.L. Li X. Sillen Research Centre of Geotechnical and Structural Engineering Shandong University Jinan Shandong 250061 China State Key Laboratory of Geomechanics and Geotechnical Engineering Institute of Rock and Soil Mechanics Chinese Academy of Sciences Wuhan 430071 China University of Chinese Academy of Sciences Beijing 100049 China European Underground Research Infrastructure for Disposal of Nuclear waste in Clay Environment EIG Euridice Mol 2400 Belgium ONDRAF/NIRAS Brussel 1210 Belgium

Boom Clay is one of the potential host rocks for deep geological disposal of high-level radioactive nuclear waste in Belgium. In order to investigate the mechanism of hydraulic conductivity variation under complex thermo-mechanical coupling conditions and to better understand the thermo-hydromechanical(THM) coupling behaviour of Boom Clay, a series of permeability tests using temperaturecontrolled triaxial cell has been carried out on the Boom Clay samples taken from Belgian underground research laboratory(URL) HADES. Due to its sedimentary nature, Boom Clay presents acrossanisotropy with respect to its sub-horizontal bedding plane. Direct measurements of the vertical(Kv)and horizontal(Kh)hydraulic conductivities show that the hydraulic conductivity at 80℃ is about 2.4 times larger than that at room temperature(23℃), and the hydraulic conductivity variation with temperature is basically reversible during heatingecooling cycle. The anisotropic property of Boom Clay is studied by scanning electron microscope(SEM) tests, which highlight the transversely isotropic characteristics of intact Boom Clay. It is shown that the sub-horizontal bedding feature accounts for the horizontal permeability higher than the vertical one. The measured increment in hydraulic conductivity with temperature is lower than the calculated one when merely considering the changes in water kinematic viscosity and density with temperature. The nuclear magnetic resonance(NMR) tests have also been carried out to investigate the impact of microstructure variation on the THM properties of clay. The results show that heating under unconstrained boundary condition will produce larger size of pores and weaken the microstructure. The discrepancy between the hydraulic conductivity experimentally measured and predicted(considering water viscosity and density changes with temperature) can be attributed to the microstructural weakening effect on the thermal volume change behaviour of Boom Clay. Based on the ex

关键词： Boom Clay Permeability Thermal effect Anisotropy Microstructure

An Analytical Solution of Melting around a Moving Elliptical Heat Source

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Journal of Thermal Science 1994年第1期3卷 23-27页

作者： w.z. chen S.M. cheng z. Luo H.Q. zhu(Huazhong University of Science and Technology,wuhan 430074, China) 1. Huazhong University of Science and Technology 430074 Wuhan China

This paper studies the close-contact melting around a moving, horizontal elliptical heat source thatmelts its way through a phase change material under its own weight. The heat source velocity andthe volume of the material melted are obtained by analysis. The effects of compression coefficient andtemperature distribution in the melt are investigated. The results include that for melting around amoving cylindrical heat source.

关键词： phase change close contact melting moving heat source analytical solution

AP-FIM STUDY ON THE MICROSTRUCTURES OF TiAlINTERMETALLIC COMPOUNDS FXBRICATED BY INGOTMETALLURGY AND CENTRIFUGAL SPRAY DEPOSITION

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Acta Metallurgica Sinica(English Letters) 2000年第6期13卷 1165-1173页

作者： D.G. Ren, w.z. chen and X.S. Fan ( Laboratory of Atomic Imaging of Solids, Institute of Metal Research, The Chinese Academy of Sciences,Shenyang 110015, China College of Materials Science and Engineering, Fuzhou University, Fuzhou 350002, China)

The microstructures of TiAl intermetallic compounds prepared by ingot metallurgy and centrifugal spray deposition (CSD) were compared by field ion microscopy and atom probe (AP-FIM). The samples used have nearly stoichiometric composition of TiAl but there is Mn addition for ingot metallurgy (IM) samples and Mn and Nb additions for CSD samples. The field ion image of TiAl showed two regions of ordered f.c.t crystal structure (γ-TiAl) and disordered α-Ti3Al, and the distribution of Ti and Al atoms in TiAl alloy showed a lamellar structure which was confirmed by AP profiles. AP profiles showed that the major constituent of IM TiAl alloy is γ-TiAl with some Ti-rich regions. The compositions of these Ti-rich regions are nearly Ti3Al and Ti2Al from the calculation of AP data. The sample of CSD has a similar microstructure as compared with IM sample. The effects of alloying elements (Mn and Nb) on the ordering extent ,their distribution, and their sites occupied in the lattice were explored for both TiAl alloys. But there are no obvious Ti3Al or Ti2Al phases as shown in IM sample. In addition, the distributions of Mn and Nb concentrations in the CSD sample have a characteristic of wave form.

关键词： intermetallic compound microstructure AP-FIM

Highly conductive and stable iodine doped argyrodite electrolyte for all-solid-state lithium batteries

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Journal of Energy Chemistry 2025年第1期100卷 50-58页

作者： Gaozhan Liu Jing zhang Jing Yang Jinghui chen Xingyue Xiao Xiayin Yao Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences

Lithium argyrodites with high ionic conductivity and low cost are considered as one of the most prospective solid electrolytes for all-solid-state lithium ***,the poor chemical stability and compatibility with lithium metal limit their ***,Li5.4PS4.4Cl1.4I0.2solid electrolyte with high ionic conductivity of 11.49 m S cm-1and improved chemical stability is synthesized by iodine *** ultra-thin Li5.4PS4.4Cl1.4I0.2membrane with thickness of 10μm can be obtained by wet coating process,exhibiting a high ionic conductivity of 2.09 mS cm-1and low areal resistance of 1.17Ω***,iodine doping could in-situ form LiI at the lithium/electrolyte interface and improve the critical current density of Li5.4PS4.4Cl1.6from 0.8 to 1.35 mA *** resultant LiCoO2/Li5.4PS4.4Cl1.4I0.2/Li battery shows excellent cycling stability at 1 C,with a reversible specific capacity of 110.1 mA h g-1and a retention of 80.5% after 1000 *** addition,the assembled LiCoO2/Li5.4PS4.4Cl1.4I0.2membrane/Li pouch cell delivers an initial discharge capacity of 110.4 mA h g-1and 80.5% capacity retention after 100 cycles.

关键词： Argyrodite electrolytes Iodine doping Ionic conductivity Stability All-solid-state lithium battery

Analysis of Contact Melting Driven by Surface Heat Flux Around a Cylinder

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Journal of Thermal Science 2008年第1期17卷 64-68页

作者： Y.S.zhao w.z.chen F.R.Sun z.Y.chen Faculty of Thermal Engineering College of Power and ShippingNaval University of EngineeringWuhan 430033China Faculty of Thermal Engineering College of Power and ShippingNaval University of EngineeringWuhan 430033China Professor

The contact melting of phase change material around a moving horizontal cylindrical heat source, which descended under its own weight, is investigated in this article. A melting model under constant surface heat flux is established. The analytical results for thickness and pressure distributions inside melt layer and steady melting velocity are obtained by using contact melting theory. The melting law is discussed, and compared with that of contact melting driven by temperature difference. It is found that quasi-steady melting velocity is determined by heat flux of heat source, and the variation of heat source density has less effect on melting velocity.

关键词： Contact melting horizontal cylinder phase change phenomena

The Novel Mechanical Property of Tongue of a woodpecker

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Journal of Bionic Engineering 2009年第3期6卷 214-218页

作者： P zhou X Q Kong C w wu z chen National Key Laboratory for Structural Analysis of Industrial Equipment Dalian University of Technology Department of Civil and Environmental Engineering University of Missouri

Biomaterials such as bone,teeth,nacre and silk are known to have superior mechanical properties due to their specific nanocomposite *** we report that the woodpecker's tongue exhibits a novel strength and flexibility due to its special composite micro/*** tongue consists of a flexible cartilage-and-bone skeleton covered with a thin layer tissue of high strength and *** the interface between the cartilage-and-bone skeleton and the tissue layer,there is a hierarchical fiber-typed *** is this special design of the tongue that makes the woodpeckers efficient in catching the insects inside *** special micro/nanostructures of the woodpecker's tongue show us a potential method to enhance the interfacial connection between soft and hard material layers for bio-inspired composite system designs.

关键词： woodpeckcr hyoid cartllage multilevel structure tensile strength

Interactions of molten salts with cathode products in the FFC Cambridge Process

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International Journal of Minerals,Metallurgy and Materials 2020年第12期27卷 1572-1587页

作者： George z.chen Department of Chemical and Environmental Engineering Faculty of EngineeringUniversity of NottinghamNottingham NG72RDUK Department of Chemical and Environmental Engineering Faculty of Science and EngineeringUniversity of Nottingham Ningbo ChinaNingbo 315100China

Molten salts play multiple important roles in the electrolysis of solid metal compounds,particularly oxides and sulfides,for the extraction of metals or *** of these roles are positive in assisting the extraction of metals,such as dissolving the oxide or sulfide anions,and transporting them to the anode for discharging,and offering the high temperature to lower the kinetic barrier to break the metal-oxygen or metal-sulfur ***,molten salts also have unfavorable effects,including electronic conductivity and significant capability of dissolving oxygen and carbon dioxide *** addition,although molten salts are relatively simple in terms of composition,physical properties,and decomposition reactions at inert electrodes,in comparison with aqueous electrolytes,the high temperatures of molten salts may promote unwanted electrode-electrolyte *** article reviews briefly and selectively the research and development of the F ray-F arthing-chen(FFC)Cambridge Process in the past two decades,focusing on observations,understanding,and solutions of various interactions between molten salts and cathodes at different reduction states,including perovskitization,non-wetting of molten salts on pure metals,carbon contamination of products,formation of oxychlorides and calcium intermetallic compounds,and oxygen transfer from the air to the cathode product mediated by oxide anions in the molten salt.

关键词： FFC Cambridge Process molten salts electrolysis extraction oxides sulfides metals alloys reaction mechanisms

Construction of 3D porous Cu_(1.81)S/nitrogen-doped carbon frameworks for ultrafast and long-cycle life sodium-ion storage

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 191-200页

作者： chen chen Hongyu Xue Qilin Hu Mengfan wang Pan Shang ziyan Liu Tao Peng Deyang zhang Yongsong Luo Key Laboratory of Microelectronics and Energy of Henan Province Henan Joint International Research Laboratory of New Energy Storage TechnologyCollege of Physics and Electronic EngineeringXinyang Normal UniversityXinyang 464000China School of Physics and Electronic Engineering Nanyang Normal UniversityNanyang 473061China

Transition metal sulfides have great potential as anode mterials for sodium-ion batteries(SIBs)due to their high theoretical specific ***,the inferior intrinsic conductivity and large volume variation during sodiation-desodiation processes seriously affect its high-rate and long-cyde performance,unbeneficial for the application as fast-charging and long-cycling SIBs ***,the three-dimensional porous Cu_(1.81)S/nitrogen-doped carbon frameworks(Cu_(1.81)S/NC)are synthesized by the simple and facile sol-gel and annealing processes,which can accommodate the volumetric expansion of Cu_(1.81)S nanoparticles and accelerate the transmission of ions and electrons during Na^(+)insertion/extraction processes,exhibiting the excellent rate capability(250.6 mA·g^(-1)at 20.0 A·g^(-1))and outstanding cycling stability(70% capacity retention for 6000 cycles at 10.0 A·g^(-1))for ***,the Na-ion full cells coupled with Na_(3)V_(2)(PO_(4))_(3)/C cathode also demonstrate the satisfactory reversible specific capacity of 330.5 mAh·g^(-1)at 5.0 A·g^(-1)and long-cycle performance with the 86.9% capacity retention at 2.0 A·g^(-1)after 750 *** work proposes a promising way for the conversionbased metal sulfides for the applications as fast-charging sodium-ion battery anode.

关键词： copper sulfide nanoparticles porous carbon framework fast charging long-cycle performance sodium-ion full batteries

Stellar X-ray Sources in the Rosette Nebula

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Chinese Journal of Astronomy and Astrophysics 2004年第2期4卷 153-165页

作者： w.P.chen P.S.Chiang J.z.Li Institute of Astronomy National Central UniversityChung-Li 32054Taiwan National Astronomical Observatories Chinese Academy of SciencesBeijing 100012

we present optical photometric and spectroscopic studies of ROSAT X-ray stellar sources in the Rosette Nebula star-forming region. The brightest X-ray sources are either massive stars or active T Tauri stars associated with the open cluster NGC 2244, or are foreground stars. Some of the spectra of the young stars newly identified in the region are presented.

关键词： stars: early-type stars: pre-main sequence stars: formation HII regions