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Circular Dichroism and Derivative Spectra Study of the Excitonic Aggregation of Pinacyanol by Aerosol-OT

Open Journal of Physical Chemistry 2012年第1期2卷 34-40页

作者： Sa’ib J. Khouri volker buss Department of Chemistry American University of Madaba Madaba Jordan

Different structures are proposed for the complexes formed from the interaction between the cationic cyanine dye 1, 1’-diethyl-2, 2’-carbocyanine chloride (Pinacyanol chloride) and the anionic surfactant sodium bis (2-ethylhexyl) sul- fosuccinate (Aerosol-OT) in ethanol-water solutions. UV/vis and electronic circular dichroism (CD) spectra provide tools to study the concentration and solvent dependence of this interaction. The aggregation spectra of the dye are dominated by a strongly blue-shifted, sharp and single visible band, which appears at concentrations much below the critical micelle concentration (cmc) of Aerosol-OT. Above the cmc, the spectra in pure aqueous solution indicate disso- ciation into monomer and dimer species, and the system becomes completely empty of chirality. Two different CD spectra with a distinct isosbestic point are observed for complexes with different surfactant to dye ratios. Both the addi- tion of ethanol (more than 7.5%) and increasing the temperature retards the metachromatic process between the dye and Aerosol-OT. By using the peakFit program, the two overlapping excitonic absorption bands together with the optically inactive absorption band for one spectrum (the most optimal one) at a specific Aerosol-OT concentration were sepa- rated.

关键词： Cyanine Dye Pinacyanol Surfactant Aerosol-OT Aggregation Circular Dichroism Derivative Spectra

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Interaction of cationic cyanine dye with algal alginates: evidence for a polymer bound dye dimer

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Journal of Biophysical Chemistry 2011年第4期2卷 380-385页

作者： Sa’ib J. Khouri volker buss 不详

Under certain conditions algal alginates bind pinacyanol chloride in the form of dimers – this is the conclusion drawn from a uv/vis and circular dichroism (CD) spectroscopic study of aqueous solutions of the dye in a 10-fold molar excess of the polysaccharide from different sources. With its easily detected features the dimer holds promise as a diagnostic tool for alginate conformational analysis. Binding of the strongly blue-shifted (maximum wavelength = 485 nm) dimer is probably mediated by the charged groups and involves guluronate units only. By using the peakFit program, the two overlapping excitonic absorption bands together with the optically inactive band resulted from the interaction of pinacyanol with a specific alginate concentration were separated. The standard Gibbs energy of the interaction was calculated as –27.02 ***–1. The dimers are sensitive against acid and divalent cations.

关键词： Guluronate Mannuronate Peakfit Association Constant Complexation Circular Dichroism

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Circular Dichroism and Derivative Spectra Study of the Excitonic Aggregation of Pinacyanol by Aerosol-OT

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Open Journal of Physical Chemistry（物理化学期刊） 2012年第1期

作者： Sa'ib J. Khouri volker buss

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Interaction of cationic cyanine dye with algal alginates: evidence for a polymer bound dye dimer

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Journal of Biophysical Chemistry（生物物理化学） 2011年第4期

作者： Sa'ib J. Khouri volker buss

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