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Tailoring properties of reticulated vitreous carbon foams with tunable density

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Frontiers of Materials Science 2016年第2期10卷 157-167页

作者： Oleg SMORYGO Alexander MARUKOVICH Vitali MIKUTSKI Vassilis STATHOPOULOS Siarhei HRYHORYEU vladislav sadykov Powder Metallurgy Institute National Academy of Sciences of Belarus 41 Platonov Str. Minsk 220005 Belarus Technological Educational Institute of Sterea Ellada Psahna Evias 34400 Greece Belarusian National Technical University 65 Nezavisimosty Ave. Minsk 220013 Belarus Boreskov Institute of Catalysis Sibrian Branch of Russian Academy of Sciences 5 Lavrentiev Ave. 630090 Novosibirsk Russia Novosibirsk State University 2 Pirogova Str. 630009 Novosibirsk Russia

Reticulated vitreous carbon （RVC） foams were manufactured by multiple replications of a polyurethane foam template structure using ethanolic solutions of phenolic resin. The aims were to create an algorithm of fine tuning the precursor foam density and ensure an open-cell reticulated porous structure in a wide density range. The precursor foams were pyrolyzed in inert atmospheres at 700℃, 1100℃and 2000℃, and RVC foams with fully open cells and tunable bulk densities within 0.09-0.42 g/cm3 were synthesized. The foams were characterized in terms of porous structure, carbon lattice parameters, mechanical properties, thermal conductivity, electric conductivity, and corrosive resistance. The reported manufacturing approach is suitable for designing the foam microstructure, including the strut design with a graded microstructure.

关键词： foam vitreous carbon reticulated cellular structure pyrolysis

Modified Ceria-Zirconia Fluorite-Like Catalysts for the Combustion of Methane

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Journal of Natural Gas Chemistry 2006年第3期15卷 149-163页

作者： Tatiana Kuznetsova vladislav sadykov Lubsan Batuev Ella Moroz Elena Burgina Vladimir Rogov Vladimir Kriventsov Dmitrii Kochubey Boreskov Institute of Catalysis SB RAS Pr. Lavrentieva5Novosibirsk630090Russia

For dispersed ceria-zirconia-based solid solutions prepared via the polymerized complex method and annealed at 700 ℃, effects of bulk doping by Ca, Mn, Co, Bi or Nb cations and surface modification by Mn and Pt on their structural features, surface/bulk oxygen reactivity and catalytic activity in methane combustion are considered. With up to 20 mol% doping, a structural type of homogeneous solid solutions of anion-deficient fluorite with disordered anion vacancies is formed. Doping by transition metal cations or Pt increases the mobility and reactivity of the surface/bulk oxygen. A broad variation in specific rates of methane combustion for the studied systems was observed, suggesting structural sensitivity of this reaction. In general, there is no universal relationship between the oxygen mobility, the reactivity and the catalytic activity in methane combustion, which is explained by the factor of specific methane activation on surface active sites. For the Pt-promoted samples, Pt efficiency in methane activation depends on the Pt-support interaction, and the most favorable ones being mixed Pt/MnOx and Pt/NbOx clusters on the surface of the supports that exhibit high lattice oxygen mobilities.

关键词： Ce-Zr-O Ca Mn Co Bi Nb structural features oxygen reactivity oxygen mobility methane combustion

Specific structural features of LnZrOx(Ln:La, Sm) mixed oxides prepared by different methods

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Progress in Natural Science:Materials International 2018年第4期28卷 437-446页

作者： Tatyana Kuznetsova Tamara Kriger Yurii Chesalov ANDrey Boronin Arcadii Ishchenko Pavlos K.PANDis Vladimir Krivensov Galina Litvak Tatyana Larina vladislav sadykov Vassilis N.Stathopoulos Boreskov Institute of Catalysis Novosibirsk State University Laboratory of Chemistry and Materials Technology Department of Electrical Engineering School of Technological Applications Technological Education Institute of Sterea Ellada

LnZrOx(Ln: La, Sm) mixed oxides of Ln: Zr = 1 were prepared by different methods(complex polymerized method, sorption of cations on starch from aqueous salt solution and conventional co-precipitation with additional redispersion of precipitate by ultra sound) and calcined at 700–1300 °C. Their specific structural features and changes were studied and discussed. Various characterization methods were used such as X-ray diffraction,Electron microscopy, Fourier-transform infrared and Raman spectroscopy, UV–Vis spectroscopy, X-Ray absorption fine structure and X-ray photoelectron *** formation of pyrochlore structure occurred at 1100–1300 °C from fluorite-like pseudocubic phase ZrO2regardless the method of preparation. This phase had a block-like structure consisting of ZrO2nanocrystals stabilized by Ln cations and residual anions such as hydroxyls and carbonates. The desorption of such anions with heating already started at 900 °C and lead to local changes of Zr cations coordination to octahedral and to the formation of pyrochlore nanodomains inclusions within fluorite-like phase. The increased cation mobility and further elimination of anions caused by further heating was accompanied by the formation of bulk pyrochlore phase at 1100–1300 °C. Even after calcination at 1300 °C the local microheterogeneity as well as defects were identified at domains boundaries or sintered microstructure. These specific features of the formed pyrochlores depend on the method of preparation.

关键词： Fluorites Pyrochlores Synthesis Powders Structure

Formation of Micro, Nano and Atomic-Level Structure of CoAIOICo-AI Cermets Prepared by Mechanical Alloying

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材料科学与工程（中英文A版） 2012年第2期2卷 121-136页

作者： Andrey Andreev Aleksey Salanov Serguei Tikhov Svetlana Cherepanova Vladimir Zaikovskii Vladimir Usoltsev vladislav sadykov Olga Lapina Boreskov Institute of Catalysis SB RAS 630090 pr. Lavrentieva 5 Novosibirsk Russian Federation

Mesoporous Alumina in an AI2O3/Al Cermet Prepared from Powdered Aluminum

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材料科学与工程（中英文版） 2011年第3期5卷 281-292页

作者： Tikhov Serguei Khabibulin Djalil Lapina Olga Salanov Aleksey Bespalko Yulia sadykov vladislav Ratko Anatoly Kouznetsova Tatyana Romanenkov Vladimir Eremenko Svetlana Department of Heterogeneous Catalysis Boreskov Institute of Catalysis SD RAS 630090 Lavrentieva St. 5 Russia Department of Natural Sciences Novosibirsk State University Novosibirsk 630090 Russia Institute of General and Inorganic Chemistry NAS of Belarus Laboratory of Adsorption Minsk 220072 Belarus

Novel materials for solid oxide fuel cells cathodes and oxygen separation membranes:Fundamentals of oxygen transport and performance

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Carbon Resources Conversion 2020年第1期3卷 112-121页

作者： vladislav A.sadykov Ekaterina M.Sadovskaya Nikita F.Eremeev Elena Yu.Pikalova Nina M.Bogdanovich Elena A.Filonova Tamara A.Krieger Yulia E.Fedorova Alexey V.Krasnov Pavel I.Skriabin Anton I.Lukashevich Robert Steinberger-Wilckens Izaak C.Vinke Federal Research Center Boreskov Institute of Catalysis SB RAS 630090 NovosibirskRussia Novosibirsk State University 630090 NovosibirskRussia Institute of High Temperature Electrochemistry UB RAS 620137 YekaterinburgRussia Ural Federal University 620002 YekaterinburgRussia University of Birmingham EdgbastonBirmingham B152TTUK Forschungszentrum Jülich GmbH 52425 JülichGermany

In the field of modern hydrogen energy,obtaining pure hydrogen and syngas and then being able to use them for green energy production are significant *** solid oxide fuel cells(SOFC)and catalytic membranes for oxygen separation as well as materials for these devices is one of the most likely ways to solve these *** this work,the authors’recent studies in this field are reviewed;the fundamentals of developing materials for SOFC cathodes and oxygen separation membranes’permselective layers based on research of their oxygen mobility and surface reactivity are ***-Popper phases Ln_(2-x)Ca_(x)NiO_(4+δ)(LnCNO)and perovskite-fluorite nanocomposites PrNi_(0.5)Co_(0.5)O_(3-δ)-Ce_(0.9)Y_(0.1)O_(2-δ)(PNC-YDC)were studied by isotope exchange of oxygen with C_(18)O_(2)and^(18)O_(2)in flow and closed *** LnCNO a high oxygen mobility was shown(D*~10^(-7)cm^(2)/s at 700℃),being provided by the cooperative mechanism of oxygen migration involving both regular and highly-mobile interstitial *** PNC-YDC dominated a wide fast diffusion channel via fluorite phase and interphases due to features of the redistribution of cations resulting in superior oxygen mobility(D*~10^(-8)cm^(2)/s at 700℃).After optimization of composition and nanodomain structure of these materials,as cathodes of SOFC they provided a high power density,while for asymmetric supported oxygen separation membranes-a high oxygen permeability.

关键词： Solid oxide fuel cells Oxygen separation membranes Oxygen mobility Perovskites Nanocomposites Ruddlesden-Popper phases

Central Asia—A Global Model for the Formation of Epigenetic Deposits in a Platform Sedimentary Cover

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Journal of Earth Science 2022年第2期33卷 278-288页

作者： Igor Pechenkin vladislav Petrov FSBI All-Russian Scientific-Research Institute of Mineral Resources MoscowRussia Institute of Geology of Ore Deposits Petrography Mineralogy and Geochemistry RAS MoscowRussia

Metallogenic specialization of sedimentary cover in Central Asia is determined by its tectonic setting that governs the hydrodynamic regime(exfiltrational or infiltrational)and as a consequence,the hydrogeochemical zonality(type of water and its gaseous and microcomponent composition).Hydrodynamic conditions(distribution of recharge and discharge areas)determine the direction of stratal water flow and location of mineralization resulted from the change in geochemical,thermodynamic,lithological,structural and other *** exfiltrational regime suggests a dependence of the epigenetic mineralization upon the distribution and degree of preservation of hydrocarbon ***,hydrocarbon matter serves as a reducing barrier and ore-concentrating factor during the formation of polymineral concentrations related to stratal oxidation *** supergene epigenetic ore-forming processes are induced by the interaction between the Earth’s sedimentary cover and *** rocks themselves commonly serve as a source of ore *** ore deposition zones on geochemical barriers and ore material source are often located significantly apart from each *** trend of these processes is determined by the position of ore-bearing depressions in large tectonic blocks.

关键词： Central Asia Kyzyl Kum Bukantau ore-forming systems epigenetic ore deposit geology

Interactive mobile equipment safety task-training in surface mining

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International Journal of Mining Science and Technology 2021年第4期31卷 743-751页

作者： Lazar Zujovic vladislav Kecojevic Dragan Bogunovic Department of Mining Engineering West Virginia UniversityMorgantown 26501USA North American Coal Corporation Farmington 87401USA

Improving the quality of equipment training for the Heavy Equipment Operators(HEO)is a critical task in improving safety and eliminating equipment-related injuries in *** of major responsibilities for the HEOs is proper machine *** miner safety training includes the use of hardcopy documents and video ***,modern mobile and computer technology offers tremendous potential to improve the training *** this study,we apply a 360-degree camera,opensource platform WordPress^(TM),and the software Unity3D in order to create materials and tools for the HEOs safety training to help trainees better understand the pre-shift safety machine *** computer-based safety task training developed in this research is tested and implemented at a surface mine in the southern United States.

关键词： Heavy equipment operators Safety task training 360-degree image/video Virtual reality

Theoretical and experimental studies of gas preparation system for pressurization and reactive control system of launch vehicle

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Chinese Journal of Aeronautics 2024年第7期37卷 168-177页

作者： Valeriy TRUSHLYAKOV vladislav URBANSKY Vadim YUDINTSEV Department of Aviation and Rocket Building Omsk State Technical UniversityOmsk 644050Russia

A new gas preparation system(GasPS-RCS)is proposed to solve two tasks:(A)to heat helium gas for tank pressurization;(B)to prepare gas for the Launch Vehicle(LV)Reactive Control System(RCS)at the LV orientation and stabilization sections of the LV on passive parts of the flight trajectory,to provide conditions for launching the Liquid Rocket Engine(LRE).The system includes a gas generator based on hydrogen peroxide,a separator for water separation,heat exchangers independent of the LRE,and gas-jet *** proposed new system allowed to reduce the length of pressurizing gas lines and reduce the increased helium gas consumption during the heat exchanger warm-up interval of the LRE during its launch.A special advantage of the proposed system is the possibility of ground testing of heat exchangers without an operating LRE.A mathematical model based on the first law of thermodynamics was used to perform a comparative analysis of GasPS-RCS with traditional pressurization and RCS *** validate the mathematical model,the experimental studies of helium pressurizing of a liquid nitrogen tank were *** results show that the deviation of experimental and calculated values for pressure is 1.1%and for temperature up to 2%.According to the results of comparative analysis,the GasPS-RCS is 259 kg lighter for the first stage and 80 kg lighter for the second stage of the LV.

关键词： Engine restart Reactive control system Tank pressurization Cryogenics Hydrogen peroxide Heat exchanger