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China's Refractories 2022年第2期31卷 1-6页

作者： valeriy v.MARTYNENKO vladimir v.primachenko Pavlo O.KUSHCHENKO Iri na G.SHULIK Ludmyla K.SAvINA The Ukrainian Research Institute of Refractories named after A.S.Berezhnoy Kharkiv 61024Ukraine

The use of a combined additive consisting of silica-containing additives“F”(thinning)and“S”(accelerating castable hardening)instead of the previously used silica-containing additive“A”and a mixture of dispersing additives based on polyethylene glycol in low-cement silicon carbide castable allows to improve the castable workability by increasing(in 5.4 times)the flowability of a freshly prepared castable,and increase by 1.2 and 1.1 times the cold crushing strength of heat-treated at temperatures of 110 and 1580°C,respectively,castable samples from low-cement silicon carbide castable with practically equal values of open porosity(15.8%and 16.0%).The petrographic studies of the castable sample microstructure after firing at a temperature of 1580°C showed that the investigated silica-containing additives“F”and“S”contribute to the denser and more uniform structure *** a result of the carried out research,the manufacturing technology of a low-cement silicon carbide castable was improved,of which the production was mastered at JSC“URIR named after ***”.

关键词： low-cement silicon carbide castable additives flowability structure strength

Advanced Ramming Mix Based on Fused Zirconia Stabilized by Com-bined Additives of CaO and MgO for Lining of Carbon Black Production Reactor

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China's Refractories 2017年第3期26卷 1-7页

作者： valeriy v.MARTYNENKO vladimir v.primachenko Irina G.SHULIK Dmitriy A.SHISHKOvSKIY Eleonora L.KARYAKINA vladimir v.vARGANOv PJSC "The Ukrainian Research Institute of Refractories named after A.S.Berezhnoy"

Fused materials from ZrO2 stabilized by CaO or MgO, or the combined additive consisting of CaO and MgO are made. With using chemical, petrographic, X-ray phase and electron microscopic researches the main characteristics of these materials are determined. It is shown that, the materials of all compositions have low water absorption; they are characterized by equal struc-ture. The materials stabilized by the combined additive consisting of CaO and MgO are presented by generally the cubic phase and a small amount of tetragonal and monoclinic ZrO2 phases. Depending on CaO： MgO ratio in the materials the tetragonal ZrO2 phase settles down in a cubic matrix in the form of separate grains, and sites of net like structure in the form of a ＂woven＂ interlacing （2.9% of CaO and 2. 6% of MgO ）. An influence of the above mentioned fused stabilized ZrO2 materials and quantity of monoclinic zirconia, on the forming of zirconia mix on a phosphate bond and properties of＂ .fired samples is studied. The samples from mix based on ZrO2 stabilized by the combined additive consisting of 2.9% CaO and 2.6% MgO with 20% of monoclinic Zr02 are characterized by the highest properties： after .firing at 1 580 ~C open porosity of 14. 3% - 14. 8%, apparent density of 4. 67 -4. 69 g · cm^-5, cold crushing strength of 62 - 68 MPa, thermal shock resistance （ 1 300℃←→air） of 15 thermal cycles, linear growth of 0. 2%. The manufacturing technology of powders mix-ture for ramming mix based on the new fused material .from ZrO2 stabilized by the combined additive is developed and its production is mastered. From this mixture the large-size, shaped products on the phosphate bond are made at one carbon black production plant, which are installed in the combustion chamber of the carbon black production reactor.

关键词： fused stabilized zirconia combined additives calcia and magnesia ramming mix carbon black production reactor

New Refractories Developed by the Ukrainian Research Institute of Refractories Named after ***

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China's Refractories 2003年第3期12卷 25-29页

作者： vladimir v.primachenko valeriy v.Martynenko OJSC"The Ukrainianrsearch Institute of Refractories Named after A.S.Berezhnoy" OJSC"The Ukrainianrsearch Institute of Refractories Named after A.S.Berezhnoy"

The article gives an introduction to the Ukrainian Research Institute of Refractories and especially its R & D and refractory products for the industries of iron and steel, nonferrous , glass and chemistry etc.

关键词： Introduction Ukrainian Research Insti- tute of Refractories Refractory products

Mesh-supported v2O5-WO3/TiO2 nanosheet array catalysts for efficient removal of NOx

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Tungsten 2025年第1期7卷 100-111页

作者： Zhi-Qi Zhang Liu Yang Wen Luo vladimir An Jing Li Bao-Dan Liu School of Materials Science and Engineering Northeastern University Foshan Graduate School of Innovation Northeastern University Kizhner Research Center School of Advanced Manufacturing Technologies Tomsk Polytechnic University

The design and synthesis of vanadium-based denitration catalysts with low-temperature activity pose significant challenges in the field of toxic gas *** this study,we have developed a novel approach to fabricate highly efficient v2O5-WO3/TiO2monolithic mesh catalysts for NOxreduction at low ***,TiO2nanosheets with strong adhesion and large surface area were grown on Ti mesh using plasma electrolytic oxidation technology and hydrothermal ***,super-small traces of WO3and v2O5active nano-species were subsequently deposited on TiO2nanosheets using the deposition-precipitation *** to traditional ceramic-based v2O5-WO3/TiO2catalysts,our v2O5-WO3/TiO2monolithic mesh catalyst exhibits superior mechanical performance,excellent thermal conductivity,lower pressure drop,higher utilization of active components,and stronger synergistic ***,the v2O5-WO3/TiO2monolithic mesh catalysts exhibited excellent low-temperature catalytic activity with 98% of NOxconversion at 220℃,and remarkable long-term SO2tolerance and water resistance in the selective catalytic reduction（SCR） of NOxwith *** SCR reaction of tiny v2O5and WO3active species supported on TiO2nanosheets directly demonstrated to follow the Eley-Rideal mechanism by in situ infrared spectra.

关键词： Low temperature activity Monolithic mesh catalysts NH3-SCR SO2 tolerance v2O5-WO3/TiO2

Influence Researches of Fused Calcium Hexaluminate Amount on Metal Corrosion Resistance of Alumina Refractories

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China's Refractories 2016年第1期25卷 1-6页

作者： vladimir v. primachenko valeriy v. MARTYNENKO Irina G. SHULIK Lyudmila N. ZOLOTUKHINA Andrey B. KOvALYOv PJSC "The Ukrainian Research Institute of Refractories named after A.S. Berezhnoy" Kharkiv 61024 Ukraine

Calcium hexaluminate is one from such perspective materials. It is characterized by high refractoriness （ above 1 830 ~C ） , as well as properties stability in reducing atmosphere, high alkali- and slag-resistance, low thermal conductivity and wettability by molten metals. In this work influence researches of fused calcium hexaluminate material additive in amount of 5%, 15% amt 25% on the main properties of alumina refractories were carried out. It is established that, the refractories containing the additive of 25% calcium hexaluminate material are characterized by the highest properties, slightly impregnated with metal melt and the highest metal corrosion resistance. The alumina purging plugs fi）r blowing of metal with calcium hexaluminate material additive are produced and intended to one metallurgical plant of Ukraine for carrying out tests.

关键词： calcium hexaluminate alumina refracto-ries metal resistance purging plugs

Elaboration of a conceptual solution for the development of the Arctic shelf from seasonally flooded coastal areas

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International Journal of Mining Science and Technology 2022年第1期32卷 113-119页

作者： vladimir S.Litvinenko Mikhail v.Dvoynikov vladimir L.Trushko Saint-Petersburg Mining University Saint-Petersburg 199106Russia

Currently,construction of facilities in the Arctic is carried out on sand islands,but there are limitations for remote coastal *** restrictions are associated with the lack of quarries with construction sand in the immediate vicinity of the work site,as well as the risk of seasonal flooding of the *** article includes conceptual solutions for construction of modular piling in Arctic nearshore conditions,upon which drilling rigs and auxiliary equipment can be placed for the purpose of subsequent wildcatting,development and exploratory extended reach drilling wells(with measured depth about 15000 m).During the construction of the modular piling foundations,a mathematical simulation of the thermodynamic condition of the frozen ground was conducted,and the bearing capacity of the foundations was *** proposed solutions will solve these problems by constructing modular pile foundations and placing the necessary infrastructure on them,taking into account the distribution of loads during operation in seasonally flooded areas.

关键词： Drilling&drillholes Stress analysis Offshore engineering Infrastructure planning Geotechnical engineering Extended reach drilling

Provenance of Precambrian Fe- and Al-rich Metapelites in the Yenisey Ridge and Kuznetsk Alatau, Siberia: Geochemical Signatures

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Acta Geologica Sinica(English Edition) 2007年第3期81卷 409-423页

作者： Igor I. LIKHANOv vladimir v. REvERDATTO Institute of Geology and Mineralogy Siberian Branch Russian Academy of SciencesPr. Acad. Koptyuga3Novosibirsk630090Russian Federation

Major, trace and rare earth element contents of Fe- and Al-rich metapelites from the Korda （Yenisey Ridge） and Amar （Kuznetsk Alatau） formations were determined to examine the nature, origin and evolution of their protoliths. Results indicate that these rocks are the redeposited and metamorphosed products of Precambrian kaolinitic weathering crusts, while the geochemical distinctions between the studied metapelites are determined by different weathering conditions in the source area and tectonic settings. The protolith of the Korda Formation metapelites was produced by erosion products of the post-Archean granitoid rocks, which accumulated under humid climate conditions in shallow-water basins along the continental margin. The geochemical characteristics of the deeper primary deposits of the Amar Formation suggest that volcanogenic material of mafic composition derived from an island-arc environment had a major role in supplying the erosion zone. These results agree with lithofacies data and with the geodynamic reconstruction of the evolution of the Yenisey Ridge and Kuznetsk Alatau during the Mesoproterozoic and Neoproterozoic, respectively. It was shown that REEs had limited mobility during contact metamorphism. The coherent mobility of REEs during collisional metamorphism may be attributed both to mineral reactions responsible for modal changes and to local chemical heterogeneity inherited from the initial protolith.

关键词： geochemistry protolith pelitic schists Kuznetsk Alatau Yenisey Ridge Russia

Role of the Rossiter-McLaughlin effect in the study of close binaries

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Research in Astronomy and Astrophysics 2019年第3期19卷 21-30页

作者： Galina N.Dryomova vladimir v.Dryomov Russian Federal Nuclear Centre

This paper is devoted to binary stars belonging to the class of eclipsing-variable *** and spectroscopic analysis of eclipses allows us to determine geometric parameters of the orbit and physical characteristics of stellar components as well as inclinations of stellar equators to the orbital plane. Estimations of inclinations can be obtained from measurement of the Rossiter-McLaughlin effect, which is discussed using examples of some eccentric binaries with an anomalous apsidal effect. Our task is to find the complete spectrum of solutions of the equation of apsidal motion, depending on the inclinations of the polar axes of the components to the orbital one for these systems, based on their individual spectroscopic and photometric observational data. The matrix of solutions allows us to select those pairs of polar inclinations that provide agreement with the observational apsidal period.

关键词： Rossiter-McLaughlin effect: eclipsing-variable stars apsidal effect individual binaries: AI Hya,NY Cep,EW Ori,DI Her,AS Cam

Arrestins:structural disorder creates rich functionality

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Protein & Cell 2018年第12期9卷 986-1003页

作者： vsevolod v.Gurevich Eugenia v.Gurevich vladimir N.Uversky Department of Pharmacology Vanderbilt UniversityNashvilleTN 37232USA Department of Molecular Medicine and USF Health Byrd Alzheimer's Research Institute Morsani College of Medicine University of South FloridaTampaFL 33612USA Institute for Biological Instrumentation Russian Academy of SciencesPushchinoMoscow RegionRussia 142290

Arrestins are soluble relatively small 44-46 kDa proteins that specifically bind hundreds of active phosphorylated GPCRs and dozens of non-receptor partners. There are binding partners that demonstrate preference for each of the known arrestin conformations: free, receptor-bound, and microtubule-bound. Recent evidence suggests that conformational flexibility in every functional state is the defining characteristic of arrestins. Flexibility, or plasticity, of proteins is often described as structural disorder, in contrast to the fixed conformational order observed in high-resolution crystal structures. However, protein-protein interactions often involve highly flexible elements that can assume many distinct conformations upon binding to different partners. Existing evidence suggests that arrestins are no exception to this rule: their flexibility is necessary for functional versatility. The data on arrestins and many other multi-functional proteins indicate that in many cases, "order" might be artificially imposed by highly non-physiological crystallization conditions and/or crystal packing forces. In contrast, conformational flexibility (and its extreme case, intrinsic disorder) is a more natural state of proteins, representing true biological order that underlies their physiologically relevant functions.

关键词： EPR GPCR NMR arrestin crystal structure disorder protein-protein interactions

Sensing Characteristics of Mixed-Potential-Type YSZ-Based NO_x Sensor Using Au-Doped NiO Sensing Electrode

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稀有金属材料与工程 2006年第A3期35卷 36-39页

作者： vladimir v.Plashnitsa Taro Ueda Norio Miura Art Science and Technology Center for Cooperative ResearchKyushu UniversityKasuga-ShiFukuoka 816-8580Japan Interdisciplinary Graduate School of Engineering Sciences Kyushu UniversityKasuga-shiFukuoka 816-8580Japan

The nano-structured NiO powder obtained by sol-gel method was doped with 10 wt% gold in order to modify its morphology as well as its electrochemical catalytic *** NO_x sensing characteristics of mixed-potential-type YSZ-based planar sensors attached with each of the nano-NiO and the Au-doped nano-NiO materials as a sensing electrode SE) were examined at temperatures of 700℃～800℃.The Au-doped NiO-SE was found to give a large enhancement in the NO_2 sensitivity as well as the NO_2 selectivity at 800℃under wet condition,in comparison with the pure *** reason for the improvement in the NO_2 sensitivity was examined based on the data of polarization curves,impedance spectra and catalytic activity for the gas-phase NO_2 decomposition.

关键词： NO_x sensor mixed potential NiO nanostructure YSZ Au