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Current Efficiency, Corrosion and Structural Changes in SnO2-Sb2O3-CuO Inert Anodes for Aluminium Electrolysis

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Chinese Journal of Chemical Physics 2014年第3期27卷 368-372页

作者： Ana-Maria Popescu virgil constantin Ilie Mur&ulescu Institute of Physical Chemistry of the Romanian Academy Splaiul Independentei 202060021 Bucharest Romania

A systematic study was conducted on current efficiency （CE）, corrosion and structural changes in SnO2-based inert anodes （made of 96wt%SnO2＋2wt%Sb2O3＋2wt%CuO） on a laboratory Hall-Heroult aluminium cell. The influence of operating parameters and electrolyte composition on the CE and corrosion process were evaluated. The CE was found to be more than 90% and catastrophic corrosion took place at low percent of Al2O3, high percent of LiF, low cryolite ratio and high current densities. From all the structural changes that took place in the SnO2-based inert anodes, we assumed that the most important contribution was due to the migration of CuO towards the outer limits of the constituent grains of SnO2 based ceramic. The complex process occurred during the formation of various phases and their sintering ability both directly depended on Cu/Sb molar ratio.

关键词： Inert anode Aluminium electrowinning Current efficiency

Synthesis, Characterization and Thermophysical Properties of Three Neoteric Solvents-Ionic Liquids Based on Choline Chloride

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Chemical Research in Chinese Universities 2014年第1期30卷 119-124页

作者： POPESCU Ana-Maria constantin virgil Laboratory of Molten Salts llie Murgulescu Institute of Physical Chemistry of the Romanian Academy Bucharest 006021 Romania

The authors prepared,characterized and preliminary studied the properties of some neoteric solvents-ionic liquids based on choline chloride,i.e.,three ionic liquids based on the eutectics of choline chloride（2-hydroxyN,N,N-trimethylethanaminium chloride） with,respectively,urea,malonic acid and citric *** obtained mixtures were clear and colorless ionic liquids at room *** thermophysical properties,namely,density,viscosity,and electrical conductivity of these mixtures were investigated as a function of temperature within a range of 298-353 *** for the temperature dependence of the measured properties were generated and discussed in terms of Arrhenius *** the electrochemical windows of the eutectic liquids were determined.

关键词： Neoteric solvent Ionic liquid Choline chloride Malonic acid Citric acid Density Viscosity Conductivity

Electrochemical studies on cerium(Ⅲ) in molten fluoride mixtures

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Journal of Rare Earths 2010年第3期28卷 428-434页

作者： virgil constantin ANA-MARIA POPESCU MIRCEA OLTEANU Romanian Academy Institute of Physical Chemistry "Ilie Murgulescu"Department of Molten Salts Splaiul Independentei 202Bucharest-Romania

This study aims to determine the principal electrochemical characteristics of the electrodeposition of cerium metal from molten fluoride *** cathodic process of Ce3+ ions in LiF-NaF and LiF-NaF-CaF2 molten salts was studied using electrochemical techniques as steady state and cyclic voltammetry *** decomposition potential(Ed) and the overvoltage(η) were determined for NaCeF4 using current-potential curves under galvanostatic *** Ed was found to be 2.025 V in LiF-NaF and 2.045 V in...

关键词： cerium molten salts lanthanides NaCeF4 electrolysis cyclic voltammetry

维普期刊数据库

Electrochemical Study and Electrodeposition of Copper（I） in Ionic Liquid-reline

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Chemical Research in Chinese Universities 2013年第5期29卷 991-997页

作者： POPESCU Ana-Maria COJOCARU Anca DONATH Cristina constantin virgil Laboratory of Molten Salts "Hie Murgulescu" Institute of Physical Chemistry of Romanian Academy Bucharest 060021 Romania Department of Applied Physical Chemistry and Electrochemistry University Politehnica of Bucharest Bucharest 010737 Romania

The authors made the electrochemical studies on the electrode processes during copper electrodeposition with ionic liquids-reline as an electrolytic medium. Reline is a commercial name for a eutectic mixture of choline chloride and urea（1：2, molar ratio）. This new proposed method of copper deposition is an ecological one because the ionic liquids are recyclable, non-volatile and non-toxic. Cyclic voltammetry investigations were conducted at 343 and 353 K in choline chloride-urea（Reline） deep eutectic solvent with single salt CuCl（generally in 0.05--0.38 mol/L concentration range）. Electrochemical impedance spectroscopy investigations were conducted in choline chloride- urea ionic liquid with CuCI（0.05 mol/L）. We investigated both cathodic and anodic processes of Cu＋ ions at different sweep rates in this new electrolytic system based on choline chloride. We have proposed by this an alternative to the classical copper electrodeposition. Coefficient of diffusion, Do, for the system Reline-CuCl is presented and the value of D0 is 1.22× 10^-8 cm2/s.

关键词： Ionic liquid Reline Electrodeposition Cu(I) Coefficient of diffusion

Electromagnetic Characteristics and Corrosion Resistance of New Magnetosoft Materials Based on Capsulated Iron Powders

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Chemical Research in Chinese Universities 2020年第6期36卷 1326-1331页

作者： Alexander VETCHER Gennady GOVOR Olga DEMIDENKO virgil constantin Ana Maria POPESCU Scientific-Practical Materials Research Centre National Academy of BelarusP.Brovki 19 Str.220072 MinskBelarus “IlieMurgulescu”Institute of Physical Chemistry of Romanian Academy Laboratory of Electrochemistry and CorrosionSplaiullndependentei 202Bucharest 060021Romania

A new method of depositing an insulating multifunctional oxide coating on metal particles was *** coatings increase corrosion resistance and insulate metal particles from each *** base of capsulated by oxide coating water-atomized iron powder ASC100.29,new composite soft magnetic materials were synthesized,which are able of replacing electrical steel in ***,electromagnetic properties and corrosion characte-ristics of the obtained composites were *** was found that the synthesized composite materials have low elec-tromagnetic losses,high values of magnetic induction(up to 2.1 T)and good corrosion *** results demon-strate that the use of such materials in power supplies,c hokes,transformers,stators and rotors of electric machines and other products ensures their stable operation under various conditions.

关键词： Soft magnetic composite material Iron powder Insulating cover High-frequency transformer Stators and rotors of electro machine

Influence of the operating parameters over the current efficiency and corrosion rate in the Hall–Heroult aluminum cell with tin oxide anode substrate material

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Chinese Journal of Chemical Engineering 2015年第4期23卷 722-726页

作者： virgil constantin "Ilie Murgulescu" Institute of Physical Chemistry of the Romanian Academy Laboratory of Molten Salts Splaiul Independentei 202 Bucharest 060021 Romania Technology Transfer Center-ICF Splaiul Independentei 202 Bucharest 060021 Romania

A systematic laboratory study was conducted on current efficiency and corrosion obtained in cryolite-alumina melts with SnO2-Sb203-CuO ceramic inert anodes. The current efficiency （CE） was determined by measuring the total amount of oxygen evolved at the anode and was found to be ~ 95%. The influence of operating parameters （inter-elec- trode distance, temperature and current density） was evaluated. The quantitative interdependencies as well as the ranges of CE optima[ values were established （2-3 cm, 940-960 ℃ and 0.7-0.8 *** 2）. The corrosion process of these anodes was evaluated by the mass loss method. The evaluation also took care of the corrosion data, as the prob- lem of the anode corrosion appeared to be the main obstacle for the use of those anodes in the commercial ***-ering of the ACD up to 2 cm did not aggravate anode corrosion.

关键词： Aluminum electrolysisCurrent efficiencyCorrosionInert anodes

维普期刊数据库

Recovery of Metals from Anodic Dissolution Slime of Waste from Electric and Electronic Equipment（WEEE） by Extraction in Ionic Liquids

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Chemical Research in Chinese Universities 2018年第1期34卷 113-118页

作者： Ana Maria POPESCU Kazimir YANUSHKEVICH Vasile SOARE Cristina DONATH Elena Ionela NEACSU virgil constantin "Ilie Murgulescu" Institute of Physical Chemistry of Romanian Academy Laboratory of Electrochemistry and Corrosion Splaiul lndependentei 202 Bucharest 060021 Romania Scientific-Practical Materials Research Centre National Academy of Belarus P. Brovki 19 str. 220072 Minsk Belarus National R&D Institute for Nonferrous and Rare Metals-IMNR 102 Biruintei Blvd. Pantelimon Ilfov County Romania

The recovery of metals from a multi-component alloy obtained by crushing, melting and anodic dissolution of waste from electric and electronic equipment（WEEE） was investigated. The anodic dissolution of the alloy was carried out in an electrolysis cell with one copper cathode and a central cast anode, immersed in the electrolyte formed by choline chloride-ethylene glycol-iodine. The temperature of the electrolyte during the process was 343 K. Depending on the electrolysis parameters（current density and cell voltage）, cathodic deposits of Sn, Pb and Zn of 〉99% purity were obtained. Cyclic voltammetry was used in order to determine the deposition potentials of the studied metals. The obtained metallic deposits were subject of determination of XRD, SEM/EDX and AFM in order to evidence the deposits structure and morphology. The experiments performed demonstrated the possibility of separating/selective recovery of metals from the multi-component alloy resulted from the waste from electrical and electronic equipment by anodic dissolution in ionic liquids.

关键词： Metals recovery Ionic liquid Waste from electric and electronic equipment(WEEE)

Kabbalah Logic and Semantic Foundations for a Postmodern Fuzzy Set and Fuzzy Logic Theory

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Applied Mathematics 2014年第9期5卷 1375-1385页

作者： Gabriel Burstein constantin virgil Negoita Menachem Kranz Department of Computer Science Hunter College City University of New York New York USA

Despite half a century of fuzzy sets and fuzzy logic progress, as fuzzy sets address complex and uncertain information through the lens of human knowledge and subjectivity, more progress is needed in the semantics of fuzzy sets and in exploring the multi-modal aspect of fuzzy logic due to the different cognitive, emotional and behavioral angles of assessing truth. We lay here the foundations of a postmodern fuzzy set and fuzzy logic theory addressing these issues by deconstructing fuzzy truth values and fuzzy set membership functions to re-capture the human knowledge and subjectivity structure in membership function evaluations. We formulate a fractal multi-modal logic of Kabbalah which integrates the cognitive, emotional and behavioral levels of humanistic systems into epistemic and modal, deontic and doxastic and dynamic multi-modal logic. This is done by creating a fractal multi-modal Kabbalah possible worlds semantic frame of Kripke model type. The Kabbalah possible worlds semantic frame integrates together both the multi-modal logic aspects and their Kripke possible worlds model. We will not focus here on modal operators and axiom sets. We constructively define a fractal multi-modal Kabbalistic L-fuzzy set as the central concept of the postmodern fuzzy set theory based on Kabbalah logic and semantics.

关键词： L-Fuzzy Sets Fuzzy Sets Fuzzy Logic Modal Logic Fuzzy Semantics Kripke Possible Worlds Model Kabbalah Sefirot Partzufim Tree of Life Tikkun Postmodernism Deconstruction Logic Humanistic Systems

铝电解中SnO2+Sb2O3+CuO惰性阳极的电流效率、腐蚀性及结构变化（英文）

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Chinese Journal of Chemical Physics 2014年第3期 368-372+374页

作者： Ana-Maria Popescu virgil constantin 罗马尼亚科学院物理化学“Ilie Murgulescu"研究所

系统研究了霍尔赫鲁特铝电解池中SnO2基惰性阳极（96%SnO2+2%Sb2O3+2%CuO）的电流效率,腐蚀性以及结构变化。评价了各种操作参数（温度、电流密度、阴阳两级的距离、冰晶石量比、Al2O3浓度和电解质组成）对电流效率和腐蚀性的影响。

关键词：惰性阳极铝电解电流效率