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A critical review towards the causes of the iron-based catalysts deactivation mechanisms in the selective oxidation of hydrogen sulfide to elemental sulfur from biogas

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Journal of Energy Chemistry 2024年第3期90卷 388-411,I0010页

作者： mostafa Tarek Janaina S.Santos victor márquez mohammad Fereidooni mohammad Yazdanpanah Supareak Praserthdam Piyasan Praserthdam Center of Excellence on Catalysis and Catalytic Reaction Engineering(CECC) Department of Chemical EngineeringFaculty of EngineeringChulalongkorn UniversityBangkok 10330Thailan High-Performance Computing Unit(CECC-HCU) Center of Excellence on Catalysis and Catalytic Reaction Engineering(CECC)Chulalongkorn UniversityBangkok 10330Thailand

Hydrogen sulfide(H_(2)S) not only presents significant environmental concerns but also induces severe corrosion in industrial equipment,even at low *** various technologies,the selective oxidation of hydrogen sulfide(SOH_(2)S) to elemental sulfur(S) has emerged as a sustainable and environmentally friendly *** to its unique properties,iron oxide has been extensively investigated as a catalyst for SOH_(2)S;however,rapid deactivation has remained a significant *** causes of iron oxide-based catalysts deactivation mechanisms in SOH_(2)S,including sulfur or sulfate deposition,the transformation of iron species,sintering and excessive oxygen vacancy formation,and active site loss,are thoroughly examined in this *** focusing on the deactivation mechanisms,this review aims to provide valuable insights into enhancing the stability and efficiency of iron-based catalysts for SOH_(2)S.

关键词： Selective oxidation of H_(2)S Iron-based Catalysts mechanism of deactivation Sulfur or sulfate deposition Transformation of iron species Sintering SDG 7

An improved pulse coupled neural networks model for semantic IoT

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Digital Communications and Networks 2024年第3期10卷 557-567页

作者： Rong ma Zhen Zhang Yide ma Xiping Hu Edith C.H.Ngai victor C.m.Leung School of Information Science and Engineering Lanzhou UniversityLanzhou 730000China School of medical Technology Beijing Institute of TechnologyBeijing100081China Department of Electrical and Electronic Engineer The University of Hong KongHong Kong 999077China College of Computer Science and Software Engineering Shenzhen UniversityShenzhen 518060China Department of Electrical and Computer Engineering the University of British ColumbiaVancouverBC V6T 1Z4Canada

In recent years,the Internet of Things(IoT)has gradually developed applications such as collecting sensory data and building intelligent services,which has led to an explosion in mobile data ***,with the rapid development of artificial intelligence,semantic communication has attracted great attention as a new communication ***,for IoT devices,however,processing image information efficiently in real time is an essential task for the rapid transmission of semantic *** the increase of model parameters in deep learning methods,the model inference time in sensor devices continues to *** contrast,the Pulse Coupled Neural Network(PCNN)has fewer parameters,making it more suitable for processing real-time scene tasks such as image segmentation,which lays the foundation for real-time,effective,and accurate image ***,the parameters of PCNN are determined by trial and error,which limits its *** overcome this limitation,an Improved Pulse Coupled Neural Networks(IPCNN)model is proposed in this *** IPCNN constructs the connection between the static properties of the input image and the dynamic properties of the neurons,and all its parameters are set adaptively,which avoids the inconvenience of manual setting in traditional methods and improves the adaptability of parameters to different types of *** segmentation results demonstrate the validity and efficiency of the proposed self-adaptive parameter setting method of IPCNN on the gray images and natural images from the matlab and Berkeley Segmentation *** IPCNN method achieves a better segmentation result without training,providing a new solution for the real-time transmission of image semantic information.

关键词： Internet of things(IoT) Semantic information Real-time application Improved pulse coupled neural network Image segmentation

Dynamics of Low-Viscosity Liquids Interface in an Unevenly Rotating Vertical Layer

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Fluid Dynamics & materials Processing 2024年第4期20卷 693-703页

作者： victor Kozlov Vladimir Saidakov Nikolai Kozlov Laboratory of Vibrational Hydromechanics Perm State Humanitarian Pedagogical UniversityPerm614990Russia Institut de mécanique des Fluides de Toulouse Toulouse INPToulouse31400France

The behavior of two immiscible low-viscosity liquids differing in density and viscosity in a vertical flat layer undergoing modulated rotation is experimentally *** layer has a circular axisymmetric *** the absence of modulation of the rotation speed,the interphase boundary has the shape of a short axisymmetric cylinder.A new effect has been discovered,under the influence of rotation speed modulation,the interface takes on a new dynamic equilibrium state.A more viscous liquid covers the end boundaries of the layer in the form of thin films,which have the shape of round spots of almost constant radius;with increasing amplitude of the velocity modulation,the wetting boundary *** is found that upon reaching the critical amplitude of oscillations,the film of a viscous liquid loses stability,and the outer edge of the wetting spot collapses and takes on a feathery *** is shown that this threshold is caused by the development of the Kelvin-Helmholtz oscillatory instability of the *** spreading radius of a spot of light viscous liquid and its stability are studied depending on the rotation rate,amplitude,and frequency of rotation speed *** discovered averaged effects are determined by different oscillatory interaction of fluids with the end-walls of the cell,due to different *** effect of films forming can find application in technological processes to intensify mass transfer at interphase boundaries.

关键词： Rotation oscillations immiscible fluids contact line interface film dynamic equilibrium Nomenclature frot

Hepatic rupture secondary to HELLP syndrome: outcomes in three cases

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World Journal of Emergency medicine 2024年第1期15卷 56-58页

作者： Salvador Gomez-Carro Ruben R.Lozano-Salazar Kassandra Santos-Zaldívar victor Andres Villasuso-Alcocer Nina méndez-Domínguez O'Horan General Hospital Merida 97000Mexico Highly Specialized Hospital of the Yucatan Peninsula Merida 97134Mexico National Institute of Perinatology.mexico City 11000 Mexico

Hypertensive disorders of pregnancy,including chronic hypertension,gestational hypertension,and preeclampsia,are the most common complications in pregnant women,affecting approximately 15%of pregnancies.[1,2]Hemolysis,elevated liver enzymes,and low platelet count(HELLP syndrome)can occur in 0.2%-0.6%of all pregnancies,and 10%-15%of patients are diagnosed with preeclampsia.[3,4]Among its severe complications,liver hematoma is remarkable and may lead to liver *** identification of HELLP syndrome is crucial for proper therapeutic management and to avoid fatal outcomes[4,5]since when a hepatic hematoma occurs,the risk of rupture increases to 12%.[3,5]

关键词： rupture HELLP hypertension pregnancy

Coffee Leaf Rust(Hemileia vastatrix)Disease in Coffee Plants and Perspectives by the Disease Control

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Phyton-International Journal of Experimental Botany 2024年第5期93卷 923-949页

作者： Alexis Salazar-Navarro victor Ruiz-Valdiviezo Jose Joya-Dávila Daniel Gonzalez-mendoza Instituto de Ciencias Agrícolas de la Universidad Autónoma de Baja California(ICA-UABC) Nuevo LeónBaja California21705México Laboratorio de Biología molecular del Instituto Tecnológico Nacional de Tuxtla Gutierrez(TecNm) Tuxtla GutierrezChiapas29050México Facultad de Ciencias Agronómicas Campus V.Universidad Autónoma de Chiapas(UNACH) VillafloresChiapas30470México

Coffee Leaf Rust(CLR)is caused by Hemileia vastatrix in Coffea *** is one of the most dangerous phytopathogens for coffee plantations in terms of coffee productivity and coffee cup *** this review,we resume the problem of CLR in mexico and the pathogenesis of *** review abord plant-pathogen interactions which lead a compatible or incompatible interactions and result in CLR disease or resistance,*** review abord Coffea *** response pathways involved in *** ***,current measures to control *** proliferation and germination were aborded focused on phytosanitary actions,and biological and chemical ***,new trendlines to reduce the impact of CLR as nanoparticles and nanotechnology were analyzed.

关键词： Coffee leaf rust Coffea arabica pathogenesis nanoparticles biological control

Advancements in Web3 Infrastructure for the metaverse

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ZTE Communications 2024年第2期22卷 1-2页

作者： victor C.m.LEUNG CAI Wei the Artificial Intelligence Research Institute Shenzhen MSU-BIT University Shenzhen mSU-BIT University Shenzhen University the Wireless Networks and mobile Systems(WiNmoS)Laboratory at UBC the School of Science and Engineering at The Chinese University of Hong Kong Shenzhen the Human-Crypto Society Laboratory the CUHK(SZ)White matrix Joint metaverse Laboratory

Web3,also known as Web 3.0,has recently been attracting increasing attention from industry and *** the potential of blockchain technologies,Web3 has emerged as a pivotal foundation in the realm of metaverse development,which is considered by many as the next-generation ***,Web3 technologies such as smart contracts and protocols like non-fungible tokens(NFTs)have supported the immersive and content-rich experience of current Web3 metaverse projects.

关键词： Web token attracting

Specificity of electrophysical and gas-sensitive properties of nanocomposite ZnO–TiO_(2) films formed by solid-phase pyrolysis

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ChemPhysMater

ChemPhysmater 2024年第3期3卷 314-319页

作者： victor V.Petrov maria G.Volkova Alexsandra P.Ivanishcheva Gleb V.Tolstyak Ekaterina m.Bayanb Institute of Nanotechnologies Electronicsand Equipment EngineeringSouthern Federal UniversityTaganrog 347922Russia Faculty of Chemistry Southern Federal UniversityRostov-on-Don 344090Russia

ZnO–TiO_(2) thin films containing 0.5 mol%,1.0 mol%,and 5.0 mol%ZnO were synthesized by oxidative solidphase *** materials contained anatase and rutile phases with particle size of 6–13 nm,as confirmed using X-ray phase analysis and scanning electron *** a certain number of ZnO crystallites appeared in the TiO_(2) film structure in the temperature range of room temperature to 220℃,a two-level response of the film resistance was observed,differing by approximately 10%,as obtained by electrophysical *** two-level response correlates with the formation of two donor energy levels of 0.28 and 0.33 eV in the band structure of the ZnO–TiO_(2) *** donor level with a higher activation energy corresponded to the Ti vacancy(V−Ti),and that with a lower activation energy corresponded to the Zn vacancy(V−Zn).Two levels of gas-sensitive properties were noted for 0.5ZnO–TiO_(2),1ZnO–TiO_(2),and 5ZnO–TiO_(2) under the influence of 50 ppm NO_(2) at 250℃.Such two-level responses can be ascribed to the pinning of the Fermi level on ZnO and TiO_(2) *** mechanism of the beak-shaped and two-level responses of sensors based on composite nanomaterials when exposed to various gases was elucidated.

关键词： Thin film ZnO TiO_(2) Nanocomposites Pyrolysis Gas sensors

ENSO impacts on litter stocks and water holding capacity in secondary forests in eastern Amazonia

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Journal of Forestry Research 2024年第1期35卷 83-89页

作者： Julia Isabella de matos Rodrigues Walmer Bruno Rocha martins victor Pereira de Oliveira myriam Suelen da Silva Wanzerley Hélio Brito dos Santos Júnior Francisco de Assis Oliveira Graduate Program in Forestry Sciences Av.Presidente Tancredo Neves2501BelémPará66077-530Brazil Federal Rural University of Amazonia Av.Presidente Tancredo Neves2501BelémPará66077-530Brazil Federal Rural University of Amazonia Tv.Pau-AmareloCapitão PoçoPará68650-000Brazil National Institute of Amazonia Research Av.Constelação Cruzeiro do SulManausAmazonas 69060-062Brazil

Among the impacts of climate change,there is the intensification of phenomena such as the El Niño South-ern Oscillation(ENSO)responsible for El Niño and La Niñ***,understanding their effects on the functional pro-cesses of forests is ***,this study evaluated the effects of ENSO on litter stock and water holding capac-ity(WHC)in a successional forest in eastern *** occurred in periods with the most rainfall in El Niño(2019)and least in La Niña(2021)*** permanent plots were used to sample *** effects were evident for WHC,higher during El Niñ***,this influence was not clear for litter,as only in the rainy season effects were *** was a positive correlation of WHC with precipitation and humidity,while litter stocks were negatively correlated with temperature and wind *** the subject of this study requires long-term assessments,preliminary results suggests that,depending on the intensity of ENSO,forest functional processes can be strongly impacted and *** conclusion reinforces warnings by the scientific community about the impacts of climate change on the maintenance of litter stocks,decomposition and,consequently,the biogeochemical cycle and essential ecosystem services for the maintenance of Amazonia *** need to develop long-term research to understand the effects of climatic change on litter stocks and water holding capacity is highlighted,especially in Amazonia.

关键词： Seasonality Climate change Succession ecosystem Biogeochemical cycle Amazonia biodiversity

Study of boundary layer characteristics during the landfalling of a Nisarga cyclone

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TROPICAL CYCLONE RESEARCH AND REVIEW 2024年第2期13卷 55-71页

作者： Pawar, Rani P. Priyadarshini, Prajna Dharmaraj, T. Nade, Dada P. Patil, mahendra N. Patil, Omkar m. victor, N. Jeni Pawar, Sambhaji m. Kanase, D. G. Pawar, Sunil D. Indian Inst Trop meteorol Minist Earth Sci Pune Maharashtra India Bharati Vidyapeeths Dr Patangrao Kadam mahavidya Dept Phys Sangli India IIG KSK Geomagnet Res Lab Allahabad Uttar Pradesh India Sanjay Ghodawat Univ Kolhapur Dept Phys Kolhapur India

One of the most important parameters in meteorology is the mean wind pro fi le in the tropical cyclone boundary layer. The vertical pro fi le of wind speed and wind direction were measured during the period of the Nisarga cyclone from may 31st, 2020, to June 5th, 2020, using the newly installed Phased Array Doppler Sodar system at the Center for Space and Atmospheric Science (CSAS), Sanjay Ghodawat University, Kolhapur (16.74 degrees N, 74.37 degrees E; near India ' s western coast). Our analysis revealed that the maximum mean wind speed was 17 m/s on June 3, 2020, at 10:00 IST. It also shows the change in wind direction from southwest to southeast on June 2 and 3, 2020. Daily high-resolution reanalysis data in the domain, 0 - 25 degrees N, 65 - 110 degrees E, during the period from may 31st to June 5th, 2020, revealed the variation of the atmospheric pressure of the Nisarga cyclone from 1000 to 1008 hPa, sea surface temperature (SST) between 30 degrees C and 31 degrees C, outgoing longwave radiation (OLR) between 100 and 240 Wm-2 , wind speed between 3 and 15 m/s, and low values of vertical wind shear (VWS) were observed to the north of Nisarga track. These observations may provide more insights for the study of boundary layer turbulence during cyclonic activities. (c) 2024 The Shanghai Typhoon Institute of China meteorological Administration. Publishing services by Elsevier B.V. on behalf of KeAi Communication Co. Ltd. This is an open access article under the CC BY license (http://***/licenses/by/4.0/).

关键词： Phased Array Doppler Sodar Tropical cyclone Atmospheric boundary layer Vertical turbulence intensity VERTICAL WIND SHEAR TROPICAL CYCLONES SODAR OBSERVATIONS GRAVITY-WAVES PERSPECTIVES TEmPERATURE INTENSITY mONSOON BENGAL BAY