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Journal of Materials Science & Technology 2015年第9期31卷 881-887页

作者： Camelia Matei Ghimbeu Aleksandr I.Egunov Andrey S.Ryzhikov valeriy a.luchnikov Institut de Science des Matériaux de Mulhouse

Ensembles of freeze-dried self-rolled polymer micro-scrolls are explored as template media for produc- ing carbon-iron based composites with fibrous morphology. Polymer fibres impregnated with furfuryl alcohol and loaded with Fe2O3 particles, were thermally treated under inert atmosphere at 700 ℃ and subsequently analysed by scanning and transmission electron microscopy, X-ray diffraction, thermogravimetric analysis, and nitrogen adsorption. The resulting material has a micro-fibrous mor- phology and is basically composed of metallic Fe^0 and FeO particles, i.e., more than 98 wt% of the carbon/ iron-based composite mass. These particles are held together by amorphous porous carbon foam obtained by in-situ carbonization of the polymer/Fe2O3 composite with evacuation of carbon from the system via COx gases released by carbo-reduction of Fe2O3. The material has significant activity in the reaction of catalytic decomposition of hydrogen peroxide in water solutions.

关键词： Composite materialsPorous carbonPolymersIron particles

Theoretical and experimental studies of gas preparation system for pressurization and reactive control system of launch vehicle

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Chinese Journal of Aeronautics 2024年第7期37卷 168-177页

作者： valeriy TRUSHLYAKOV Vladislav URBANSKY Vadim YUDINTSEV Department of Aviation and Rocket Building Omsk State Technical UniversityOmsk 644050Russia

A new gas preparation system(GasPS-RCS)is proposed to solve two tasks:(A)to heat helium gas for tank pressurization;(B)to prepare gas for the Launch Vehicle(LV)Reactive Control System(RCS)at the LV orientation and stabilization sections of the LV on passive parts of the flight trajectory,to provide conditions for launching the Liquid Rocket Engine(LRE).The system includes a gas generator based on hydrogen peroxide,a separator for water separation,heat exchangers independent of the LRE,and gas-jet *** proposed new system allowed to reduce the length of pressurizing gas lines and reduce the increased helium gas consumption during the heat exchanger warm-up interval of the LRE during its launch.A special advantage of the proposed system is the possibility of ground testing of heat exchangers without an operating LRE.A mathematical model based on the first law of thermodynamics was used to perform a comparative analysis of GasPS-RCS with traditional pressurization and RCS *** validate the mathematical model,the experimental studies of helium pressurizing of a liquid nitrogen tank were *** results show that the deviation of experimental and calculated values for pressure is 1.1%and for temperature up to 2%.According to the results of comparative analysis,the GasPS-RCS is 259 kg lighter for the first stage and 80 kg lighter for the second stage of the LV.

关键词： Engine restart Reactive control system Tank pressurization Cryogenics Hydrogen peroxide Heat exchanger

Method for passivation of propellant residues in orbital stage tank of launch vehicle

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Chinese Journal of Aeronautics 2024年第1期37卷 64-76页

作者： valeriy TRUSHLYAKOV Ivan LESNYAK Alexey PANICHKIN Department of Aviation and Rocket Building Omsk State Technical UniversityOmsk 644050Russia Sobolev Institute of Mathematics of the Siberian Branch of Russian Academy of Sciences Novosibirsk 630090Russia

The problem of removing unused liquid propellant residues from the tanks of spent spacecraft and orbital stages of Launch Vehicles(LV)leads to their explosion and the formation of space debris in *** provide a solution to this problem,a method for removing liquid propellant residues from the LV tanks after the mission completion is *** method is based on the gasification of liquid propellant residues in the tanks under acoustic-vacuum exposure and the discharge of the gasification products into the surrounding outer *** investigations were carried out on a Ground-based Experimental Installation(GEI)to determine the coefficient of heat transfer from the surface of an acoustic radiator to a *** obtained coefficient was then used to calculate the energy costs for the gasification of *** estimates are given on the example of the tank with kerosene residues from a spent second stage of the LV“Soyuz-2.1 v”.The optimal discharge rate at which kerosene does not freeze is 0.14 m^(3)/***,the acoustic exposure leads to an increase in the mass of evaporated kerosene over a given time by96.1%,and the energy costs are 1756.7 kJ(approximately 50% of the remaining electrical energy).

关键词： Propellant Weightlessness Liquid evaporation Heat and mass transfer Acoustics Vacuum Vapor bubbles

Phase transitions and degradation/oxidation mechanisms in lead-free CsSnI_(3)halide perovskites

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Clean Energy 2024年第3期8卷 109-115页

作者： Alexandra Ivanova Margarita Golikova Lev luchnikov Pavel Gostishchev Igor Shetinin Victor Voronov Danila Saranin Vladimir Khovaylo National University of Science and Technology MISIS(NUST MISIS) Leninsky av.4Moscow119049Russia Belgorod State University Pobedy st.85Belgorod308015Russia

Halide perovskites possess ultra-low thermal conductivity and show high potential for thermoelectric *** chemical properties and molecular structure of halide perovskite materials are not completely stable under ambient conditions,which hinders their use in thermoelectric *** in the properties of bulk halide perovskite thermoelectrics are accompanied by partial phase transitions and surface oxidation *** this paper,we conducted a comprehensive study of the transport and structural properties of CsSnI_(3),which were pristine by vacuum melting followed by spark plasma *** research results on the electrical transport of these materials revealed that exposure to an inert atmosphere does not deteriorate stability and the properties of the materials remain ***,prolonged exposure to air leads to a significant degradation of the electrical transport *** to thin-film samples,the shift to the double perovskite structure from the perovskite one is limited to a specific surface *** change significantly influences the electrical transport of the material while maintaining the essential properties of both perovskite types.

关键词： halide perovskites degradation oxidation transport properties surface

Synthetic polymers:A review of applications in drilling fluids

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Petroleum Science 2024年第1期21卷 475-518页

作者： Shadfar Davoodi Mohammed Al-Shargabi David A.Wood valeriy S.Rukavishnikov Konstantin M.Minaev School of Earth Sciences&Engineering Tomsk Polytechnic UniversityLenin AvenueTomskRussia DWA Energy Limited LincolnUnited Kingdom

With the growth of deep drilling and the complexity of the well profile,the requirements for a more complete and efficient exploitation of productive formations increase,which increases the risk of various ***,reagents based on modified natural polymers(which are naturally occurring compounds)and synthetic polymers(SPs)which are polymeric compounds created industrially,are widely used to prevent emerging complications in the drilling ***,compared to modified natural polymers,SPs form a family of high-molecular-weight compounds that are fully synthesized by undergoing chemical polymerization *** provide substantial flexibility in their ***,their size and chemical composition can be adjusted to provide properties for nearly all the functional objectives of drilling *** can be classified based on chemical ingredients,type of reaction,and their responses to ***,some of SPs,due to their structural characteristics,have a high cost,a poor temperature and salt resistance in drilling fluids,and degradation begins when the temperature reaches 130℃.These drawbacks prevent SP use in some medium and deep ***,this review addresses the historical development,the characteristics,manufacturing methods,classification,and the applications of SPs in drilling *** contributions of SPs as additives to drilling fluids to enhance rheology,filtrate generation,carrying of cuttings,fluid lubricity,and clay/shale stability are explained in *** mechanisms,impacts,and advances achieved when SPs are added to drilling fluids are also *** typical challenges encountered by SPs when deployed in drilling fluids and their advantages and drawbacks are also *** issues also impact the applications of SPs in drilling ***,the cost of the most relevant SPs,and the monomers used in their synthesis,are *** impacts of SPs when deployed in drilling fluids,and t

关键词： Synthetic versus natural polymers Nanopolymers Drilling fluid additives Lubricity Clay swelling Hole cleaning

Influence of supercritical CO_(2)on the physical property of tight sandstone

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Petroleum 2024年第3期10卷 520-526页

作者： Huan Peng Jian Yang Junliang Peng Huifen Han Xinghao Gou Yucheng Jia Yibo Li valeriy Kadet Engineering Technology Research Institute of Southwest Oil&Gas Field Company PetroChinaChengdu610017China Key Laboratory of Oil&Gas Well Stimulation Technology of Southwest Oil&Gas Field Company Chengdu610017China State Key Laboratory of Oil&Gas Reservoir Geology and Exploitation Southwest Petroleum UniversityChengdu610500China Gubkin Russia State University of Oil and Gas Moscow119991Russia

In low-pressure gas reservoirs,water-based fracture fluid is difficult to flowback,which is unfavorable for several tight sandstone gas reservoirs in the Sichuan Basin with low pressure and high permeability geological *** CO_(2)possesses a number of remarkable physical and chemical features,including a density near to water,a viscosity close to gas,and high *** CO_(2)fracturing is a new type of non-aqueous fracturing method that is favorable to fracturing flowback in low-pressure tight sandstone and has a wide range of *** discuss on whether supercritical CO_(2)fracturing with low pressure tight sandstone is *** sandstone cores from the Jinqiu gas field in the Sichuan Basin were used to study the influence of supercritical CO_(2)on the physical properties of sandstone *** CO_(2)was used to interact with tight sandstone samples,and then the changes in porosity,permeability,and rock microstructure of tight sandstone were observed under various time,pressure,and temperature *** the interaction between tight sandstone and supercritical CO_(2),new dissolution pores will appear,or the original pores will be increased,and the width of some natural fractures will also be increased,and the porosity will increase by 1.09%-8.85%,and the permeability will increase by 2.34%-21.26%,quantifying the influence of supercritical CO_(2)on physical properties of tight sandstone,and further improving the interaction mechanism between supercritical CO_(2)and tight *** study improves in the understanding of the tight sandstone-supercritical CO_(2)interaction mechanism,as well as providing an experimental foundation and technological guarantee for field testing and use of supercritical CO_(2)in low-pressure tight sandstone gas reservoirs.

关键词： Supercritical CO_(2) Low pressure tight sandstone Porosity Permeability Microstructure

Green synthesis of biocompatible Gd^(3+)-doped ultrasmall carbon-based nanohybrids from coffee wastes

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Carbon Resources Conversion 2024年第2期7卷 64-73页

作者： Konstantin Paliienko Anna Topchylo Sergei Alekseev Alain Géloën Yurii Milovanov Tetiana Lysenko valeriy Skryshevsky Tatiana Borisova Vladimir Lysenko Department of Neurochemistry Palladin Institute of BiochemistryNational Academy of Sciences of Ukraine9 Leontovicha strKyiv 01054Ukraine Corporation Science Park Taras Shevchenko University of Kyiv60 Volodymyrska Str.Kyiv 01033Ukraine Institute of High Technologies Taras Shevchenko National University of Kyiv64 Volodymyrska Str.01601 KyivUkraine Faculty of Chemistry Taras Shevchenko National University of Kyiv64 Volodymyrska Str.01601 KyivUkraine UMR Ecologie Microbienne Lyon(LEM) CNRS 5557INRAE 1418Claude Bernard University of LyonVetAgro SupResearch Team“Bacterial Opportunistic Pathogens and Environment”(BPOE)University of LyonF-69622 VilleurbanneFrance Light Matter Institute UMR-5306Claude Bernard University of Lyon/CNRSUniversitéde Lyon69622 Villeurbanne CedexFrance

A cheap method allowing fabrication of biocompatible,ultra-small(2-10 nm)and fluorescent(λ_(em)=425-500 nm)nanohybrids(NHs)from coffee wastes is *** gadolinium-doped nanohybrids(GDNHs)or gadolinium-free carbon dots(GFCDs)can be synthesized in a domestic microwave oven according to green synthesis *** sizes,chemical composition,impact on proton magnetic resonance relaxation time and optical properties of the GDNHs and GFCDs were studied in details and *** particular,doping of the NHs with Gd^(3+)ions,up to 1.87%w/w of gadolinium per particles’weight,will allow their application for magnetic resonance imaging(MRI).Furthermore,cell culture tests on human adenocarcinomic alveolar basal epithelial cells line(A549)have shown high biocompatibility of the GDNHs and in a wide concentration range 100-1000μg/ml.

关键词： Carbon dots from coffee waste Carbon dots for MRI Gadolinium-doped carbon dots Microwave-assisted synthesis

Investigation of Microstructure and Phase Composition of Chromic Oxide, AZS/Cr and High-alumina Refractories after Exposure of Basalt and Aluminaboronsilicate Glasses Melts

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China's Refractories 2024年第1期33卷 1-6页

作者： valeriy V.MARTYNENKO Iryna G.SHULYK Yuliya Ye.MISHNYOVA Tetyana G.TYSHYNA The Ukrainian Research Institute of Refractories named after A.S.Berezhnoy Kharkiv 61024Ukraine

The microstructure and phase composition of high-alumina,chromic oxide,and AZS/Cr refractories containing 30%and 60%(by mass)Cr_(2)O_(3) after exposure to aluminaboronsilicate glasses and basalt melts depending on the type of melts and temperature have been *** mechanisms of refractory corrosion by the used melts and the factors contributing to the inhibition of corrosion development have been investigated by the method of petrographic *** the basis of obtained results,the use of high-alumina,chromic oxide,and AZS/Cr refractories in the sections of glass furnace linings,experiencing the intensive impact of aluminaboronsilicate glasses and basalt melts,has been confirmed and scientifically substantiated.

关键词： high-alumina refractories chromic oxide refractories AZS/Cr refractories microstructure phase composition aluminaboronsilicate glasses melts basalt melt

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超临界二氧化碳与页岩相互作用机制

石油与天然气地质 2024年第4期45卷 1180-1194页

作者：李一波陈耀旺赵金洲王志强魏兵 Kadet valeriy 西南石油大学油气藏地质及开发工程全国重点实验室四川成都610500 中国石油塔里木油田分公司泽普采油气管理区新疆泽普8448003 古勃金国立石油与天然气大学莫斯科119991

超临界二氧化碳与页岩相互作用机制及规律对页岩油气开发非常重要。目前缺少对超临界二氧化碳注入页岩储层后页岩润湿性、孔隙度和渗透率变化规律的研究。为了明确在不同条件下经过超临界二氧化碳浸泡处理后页岩矿物成分和微观结构的变... 详细信息

超临界二氧化碳与页岩相互作用机制及规律对页岩油气开发非常重要。目前缺少对超临界二氧化碳注入页岩储层后页岩润湿性、孔隙度和渗透率变化规律的研究。为了明确在不同条件下经过超临界二氧化碳浸泡处理后页岩矿物成分和微观结构的变化规律,以四川盆地龙马溪地区页岩为研究对象,对其总有机碳含量、矿物成分、表面形貌及低压N2和CO_(2) 吸附进行了测试。通过对不同浸泡时间、压力和含水条件下页岩处理前、后的物理性质和微观结构进行定量表征,研究了超临界二氧化碳对页岩孔隙度、渗透率以及润湿性的影响。研究结果表明:①随着浸泡时间和浸泡压力的增加,页岩中的黏土矿物和碳酸盐矿物(方解石和白云石)含量降低,石英含量增加,有机质含量降低明显。②扫描电镜图像显示页岩中微观孔隙结构变化受萃取作用、溶蚀作用和吸附膨胀作用共同影响。页岩中微观孔隙结构的变化导致了页岩孔隙度和渗透率的改变。页岩渗透率变化受到黏土矿物、碳酸盐矿物和有机质含量的影响。③超临界二氧化碳浸泡处理后页岩的润湿性发生改变,随着浸泡时间和压力的增加,页岩-水接触角增大,页岩的润湿性由强水湿转变为弱水湿和中等润湿。

关键词：溶蚀萃取渗透率润湿性超临界二氧化碳页岩四川盆地

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Polariton lasing in Mie-resonant perovskite nanocavity

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Opto-Electronic Advances 2024年第4期7卷 27-42页

作者： Mikhail A.Masharin Daria Khmelevskaia valeriy I.Kondratiev Daria I.Markina Anton D.Utyushev Dmitriy M.Dolgintsev Alexey D.Dmitriev Vanik A.Shahnazaryan Anatoly P.Pushkarev Furkan Isik Ivan V.Iorsh Ivan A.Shelykh Hilmi V.Demir Anton K.Samusev Sergey V.Makarov UNAM-Institute of Materials Science and Nanotechnology National Nanotechnology Research CenterDepartment of Electrical and Electronics EngineeringDepartment of PhysicsBilkent UniversityAnkara 06800Turkey ITMO University School of Physics and EngineeringSt.Petersburg 197101Russia Abrikosov Center for Theoretical Physics MIPTDolgoprudnyiMoscow Region 141701Russia LUMINOUS!Center of Excellence for Semiconductor Lighting and Displays School of Electrical and Electronic EngineeringSchool of Physical and Mathematical SciencesSchool of Materials Science and EngineeringNanyang Technological UniversitySingapore 639798Singapore Department of Physics Engineering Physics and AstronomyQueen’s UniversityKingstonOntario K7L 3N6Canada Science Institute University of IcelandDunhagi 3IS-107ReykjavikIceland Experimentelle Physik 2 Technische Universität DortmundDortmund 44227Germany Qingdao Innovation and Development Center Harbin Engineering UniversityQingdao 266000China

Deeply subwavelength lasers(or nanolasers)are highly demanded for compact on-chip bioimaging and sensing at the *** of the main obstacles for the development of single-particle nanolasers with all three dimensions shorter than the emitting wavelength in the visible range is the high lasing thresholds and the resulting *** we ex-ploit exciton-polariton condensation and mirror-image Mie modes in a cuboid CsPbBr3 nanoparticle to achieve coherent emission at the visible wavelength of around 0.53μm from its ultra-small(≈0.007μm3 or≈λ3/20)semiconductor *** polaritonic nature of the emission from the nanocavity localized in all three dimensions is proven by direct com-parison with corresponding one-dimensional and two-dimensional waveguiding systems with similar material *** a deeply subwavelength nanolaser is enabled not only by the high values for exciton binding energy(≈35 meV),re-fractive index(>2.5 at low temperature),and luminescence quantum yield of CsPbBr3,but also by the optimization of po-laritons condensation on the Mie resonances with quality factors improved by the metallic ***,the key parameters for optimal lasing conditions are intermode free spectral range and phonons spectrum in CsPbBr3,which govern polaritons condensation *** chemically synthesized colloidal CsPbBr3 nanolasers can be potentially de-posited on arbitrary surfaces,which makes them a versatile tool for integration with various on-chip systems.

关键词： nanolaser perovskite polariton Mie resonance exciton-polariton