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Features of ^(90)Sr behavior in Crimean lakes with different salinity of their water environment

Acta Geochimica 2023年第1期42卷 89-102页

作者： N.yu.Mirzoeva S.I.Arkhipova v.yu.proskurnin O.N.Miroshnichenko I.N.Moseichenko A.O.Kovalevsky Institute of Biology of the Southern Seas of RAS SevastopolRussian Federation

The comparative study of technogenic ^(90)Sr behavior features in Crimea lakes’ ecosystems with different levels of salinity was carried out in *** sources of ^(90)Sr input were identified for all the studied lakes:the primary source concerned with atmospheric fallout immediately after the Chernobyl NPP accident and the secondary long-term input of this radionuclide by *** half-life of the ^(90)Sr concentration in the water of the hypers aline Lake Sasyk-Sivash was estimated to vary from 0.8 to 1.1 years after the closure of the North Crimean Canal(NCC).Biogeochemical processes in the lake under the absence of the secondary source of the radionuclide input were shown to decrease in the ^(90)Sr residence time in the water column by 131 *** brackish water bodies,a significant factor influencing the radionuclide concentration in ecosystems of lakes was the pH of their water,while for hypers aline lakes the level of water salinity was the main factor determining ^(90)Sr *** concentration of ^(90)Sr in bottom sediments of studied lakes depended mainly on this radionuclide concentration in a water *** ^(90)Sr distribution factors(Kd) for studied lakes’ bottom sediments varied in a range of n·10^(0)÷n·10^(2) for hypersaline lakes and of n·10^(1)÷n·10^(2) for lakes with brackish *** to the closure of the NCC,the ^(90)Sr redistribution took place in lake ecosystems only under the geochemical processes within the water bodies *** results obtained in this work are of particular importance as a starting point or a basis for further radioecological studies of the Crimean inland waters after the reopening of the NCC and the Dnieper waters re-entering the territory of Crimea in 2022after the 8 years of their absence.

关键词： ^(90)Sr Salt lakes Water Bottom sediments Chernobyl NPP accident Crimea

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Unveiling the Contribution of Lactic Acid to the Passivation Behavior of Ti-6Al-4v Fabricated by Laser Powder Bed Fusion in Hank’s Solution

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Acta Metallurgica Sinica(English Letters) 2024年第1期37卷 102-118页

作者： yu-Hang Chu Liang-yu Chen Bo-yuan Qin Wenbin Gao Fanmin Shang Hong-yu Yang Lina Zhang Peng Qin Lai-Chang Zhang School of Materials Science and Engineering Jiangsu University of Science and TechnologyZhenjiang212100China Foshan(Southern China)Institute for New Materials Foshan528200China Key Laboratory of Automobile Materials Ministry of Education and Department of Materials Science and EngineeringJilin UniversityChangchun130025China Centre for Advanced Materials and Manufacturing School of EngineeringEdith Cowan University270 Joondalup DriveJoondalupPerthWA6027Australia

In actual physiological environments,bacteria can activate the immune system and release lactic ***,the detailed contribution of lactic acid to the passivation behavior of titanium(Ti)alloys is still *** current work investigated the in vitro passivation behavior of Ti-6Al-4v(TC4)alloys fabricated by laser powder bed fusion in Hank's solution with and without adding lactic *** methods,inductively coupled plasma atomic emission spectrometer,and X-ray photoelectron spectroscopy were jointly *** lactic acid decreases the corrosion resistance of samples by degrading the formed passive *** film formed in the(lactic acid)-containing solution exhibits a higher level of oxygen vacancies and a lower thickness,attributed to the suppressed formation of Ti^(4+)transformed from Ti^(3+)and Ti^(2+).Moreover,the presence of lactic acid would increase the open circuit potential,relieve the ions release,and hinder the deposition of calcium phosphates within 24 h immersion.

关键词： Titanium alloy Corrosion behavior Passive film Lactic acid Laser powder bed fusion

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Tensor force impact on shell evolution in neutron-rich Si and Ni isotopes

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Chinese Physics C 2024年第4期48卷 95-106页

作者： S.v.Sidorov A.S.Kornilova T.yu.Tretyakova Faculty of Physics Lomonosov Moscow State UniversityMoscow 119991Russia Skobeltsyn Institute of Nuclear Physics Lomonosov Moscow State UniversityMoscow 119991Russia

The influence of the tensor interaction of nucleons on the characteristics of neutron-rich silicon and nickel isotopes was studied in this *** forces are considered within the framework of the Hartree-Fock approach with the Skyrme *** addition of a tensor component of interaction is shown to improve the description of the splittings between different single-particle states and decrease nucleon-nucleon pairing correlations in silicon and nickel *** attention was directed toward the role of isovector tensor forces relevant to the interaction of like nucleons.

关键词： nuclear shell model tensor interaction silicon isotopes nickel isotopes

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Constructing oxygen deficiency-rich v_(2)O_(3)@PEDOT cathode for high-performance aqueous zinc-ion batteries

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Rare Metals 2024年第2期43卷 635-646页

作者： Dong-Fei Sun Zi-Juan Wang Tian Tian Xin yu Dan-Dan yu Xiao-Zhong Zhou Guo-Fu Ma Zi-Qiang Lei Key Laboratory of Eco-functional Polymer Materials of the Ministry of Education Key Laboratory of Eco-environmental Polymer Materials of Gansu ProvinceSchool of College of Chemistry and Chemical EngineeringNorthwest Normal UniversityLanzhou730070China

Aqueous zinc-ion batteries(AZIBs)have attracted widespread attention due to the advantages of high safety and environmental *** v_(2)O_(3) is a promising cathode,the strong electrostatic interaction between Zn^(2+) and v_(2)O_(3) crystal,and the sluggish reaction kinetics still limit their application in ***,the oxygen defects rich v_(2)O_(3) with conducive poly(3,4-ethylenedioxythiophene)(PEDOT)shell(v_(2)O_(3)-Od@PEDOT)was fabricated for AZIBs by combining the sulfur-assisted thermal reduction and in-situ polymerization *** introduced oxygen vacancies of v_(2)O_(3)–Od@PEDOT weaken the electrostatic interaction between Zn^(2+) and the host material,improving the interfacial electron transport,while the PEDOT coating enhances the structural stability and conductivity of v_(2)O_(3),thus accelerating the reaction *** on the advantages,v_(2)O_(3)–Od@PEDOT electrode delivers a reversible capacity of 495 mAh·g^(−1) at 0.1 A·g^(−1),good rate capability(189 mAh·g^(−1)at 8.0 A·g^(−1)),and an impressive cycling stability with 90.1%capacity retention over 1000 cycles at 8.0 A·g^(−1).The strategy may provide a path for exploiting the other materials for high performance AZIBs.

关键词： Oxygen defects v_(2)O_(3) PEDOT Electrochemical self-optimization Aqueous zinc-ion batteries

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Effect of Ta2O5 nanoparticles on bioactivity, composition, structure, in vitro and in vivo behavior of PEO coatings on Mg-alloy

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JOURNAL OF MAGNESIUM AND ALLOYS 2024年第6期12卷 2360-2379页

作者： Mashtalyar, D. v. Imshinetskiy, I. M. Kashepa, v. v. Nadaraia, K. v. Piatkova, M. A. Pleshkova, A. I. Fomenko, K. A. Ustinov, A. yu. Sinebryukhov, S. L. Gnedenkov, S. v. Russian Acad Sci Inst Chem Far Eastern Branch Vladivostok 690022 Russia Far Eastern Fed Univ Vladivostok 690950 Russia Reg Clin Dermatovenerol Dispensary Vladivostok 690033 Russia

The present study investigates the physical and chemical characteristics, behavior in vitro and in vivo , and biocompatibility of coatings containing Ta2 O5 , which are obtained by plasma electrolytic oxidation (PEO) on MA8 magnesium alloy. The obtained coatings demonstrate in vivo biocompatibility and in vitro bioactivity. Compared to the base PEO coating, the layers containing Ta2 O5 facilitate the development of apatite in simulated body fluid, suggesting that the inclusion of nanoparticles improves bioactivity of the coatings. It was found that incorporation of Ta2 O5 nanoparticles increases roughness and porosity of the formed layers by increasing particle concentration in electrolytes for the PEO process contributing to sufficient soft tissue ingrowth in vivo . Based on in vivo studies, these coatings also provide favorable tissue response and minimal inflammatory reaction in comparison with the bare magnesium alloy due to protection of living tissues from deleterious corrosion events of magnesium implant such as local alkalization and intense hydrogen evolution. The results obtained in the present study concluded biocompatibility, tissue integration of the PEO coatings containing Ta2 O5 nanoparticles making them a promising protective layer for biodegradable magnesium implants. (c) 2024 Chongqing University. Publishing services provided by Elsevier B.v. on behalf of KeAi Communications Co. Ltd. This is an open access article under the CC BY-NC-ND license ( http://***/licenses/by-nc-nd/4.0/ ) Peer review under responsibility of Chongqing University

关键词： Plasma electrolytic oxidation Bioactive coatings Tantalum pentoxide Simulated body fluid (SBF) Apatite formation Histology. AMORPHOUS CALCIUM-PHOSPHATE APATITE FORMATION MAGNESIUM ALLOY TANTALUM METAL BONE IMPLANTS OXIDE-FILMS THIN-FILMS HYDROXYAPATITE BIOMATERIALS DEGRADATION

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Effect of Y_(2)O_(3) on microstructure and properties of CoCrFeNiTiNb high entropy alloy coating on Ti-6Al-4v surface by laser cladding

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Journal of Rare Earths 2024年第3期42卷 586-599,I0006页

作者： Zhen Li Wei Zhao Kedong yu Ning Guo Guangchun Xiao Zhiming Wang Hui Zhang College of Mechanical Engineering Qilu University of Technology(Shandong Academy of Sciences)Jinan250353China Shandong Institute of Mechanical Design and Research Jinan250031China

The effects of Y_(2)O_(3) on the microstructure, microhardness, wear resistance, high-temperature oxidation resistance, hot corrosion resistance, and electrochemical corrosion behaviour of CoCrFeNiTiNb high entropy alloy coatings formed on Ti-6Al-4v alloy surfaces were studied. The results show that the addition of Y_(2)O_(3) changes the proportion of the phase but does not change its type. The average grain size is only 1/4.7 of that of the high entropy alloy(HEA) coating, and the fine-grained strengthening leads to increases in the microhardness and wear resistance of 21.8% and 26.9%, respectively. The addition of Y_(2)O_(3) enhances the denseness and bonding properties of the oxide and corrosion product layers, reducing the oxidation and hot corrosion rates by 60.3% and 40.3%, respectively. The addition of Y_(2)O_(3) doubles the corrosion resistance which is attributed to the refinement of the grains, the increased proportion of HCP and TiN, and the weakening of galvanic coupling corrosion.

关键词： Laser cladding High entropy alloy coatings Rare earths Wear properties High temperature properties Electrochemical corrosion

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Phase transition of multi-component(TiZrvNb)C ceramics—Part II:From single phase to multiple phases via adjusting v content

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Journal of Advanced Ceramics 2024年第5期13卷 689-698页

作者： Qingyi Kong Lei Chen Sijia Huo Kunxuan Li Wenyu Lu yujin Wang yu Zhou Institute for Advanced Ceramics School of Materials Science and EngineeringHarbin Institute of TechnologyHarbin 150080China Key Laboratory of Advanced Structure‒Function Integrated Materials and Green Manufacturing Technology Harbin Institute of TechnologyHarbin 150001China National Key Laboratory of Precision Hot Processing of Metals Harbin Institute of TechnologyHarbin 150001China

To address the relatively mediocre mechanical properties of single-phase multi-component carbide ceramics,a phase transition from a single phase to multiple phases was proposed to achieve superior mechanical properties.A series of(TiZrv_(x)Nb)C_(0.8) ceramics with different v contents were fabricated by spark plasma sintering(SPS).The influence of the v content on the phase composition,microstructural evolution,and mechanical properties was investigated in *** transition behavior from a single phase to multiple phases is discovered and *** formation of the Zr-rich phase and Zr-poor phase can be attributed to the increase in lattice distortion and mixed enthalpy caused by the addition of v.A nanometer lamellar structure with a semi-coherent interface obtained via in situ decomposition is reported for the first time in multi-component carbide *** semi-coherent interfaces with high dislocation density and strain concentration effectively improve the mechanical properties,grain refinement,and multi-phase *** optimal comprehensive mechanical properties of the vickers hardness(26.3 GPa),flexural strength(369 MPa),and fracture toughness(3.1 MPa·m^(1/2))were achieved for the sample with 20 mol%v.

关键词： multi-component ceramics multiple phases microstructure evolution phase decomposition mechanical properties

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High-resolution recognition of FOAM modes via an improved EfficientNet v2 based convolutional neural network

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Frontiers of physics 2024年第3期19卷 175-183页

作者： Youzhi Shi Zuhai Ma Hongyu Chen Yougang Ke yu Chen Xinxing Zhou International Collaborative Laboratory of 2D Materials for Optoelectronics Science and Technology Institute of Microscale OptoelectronicsShenzhen UniversityShenzhen 518060China Key Laboratory of Low-Dimensional Quantum Structures and Quantum Control of Ministry of Education Synergetic Innovation Center for Quantum Effects and ApplicationsSchool of Physics and ElectronicsHunan Normal UniversityChangsha 410081China Key Laboratory of Hunan Province on Information Photonics and Freespace Optical Communications School of Information Science and EngineeringHunan Institute of Science and TechnologyYueyang 414006China

vortex beam with fractional orbital angular momentum (FOAM) is the excellent candidate for improving the capacity of free-space optical (FSO) communication system due to its infinite modes. Therefore, the recognition of FOAM modes with higher resolution is always of great concern. In this work, through an improved EfficientNetv2 based convolutional neural network (CNN), we experimentally achieve the implementation of the recognition of FOAM modes with a resolution as high as 0.001. To the best of our knowledge, it is the first time this high resolution has been achieved. Under the strong atmospheric turbulence (AT) (C_(n)^(2)=10^(-15)m^(-2/3)), the recognition accuracy of FOAM modes at 0.1 and 0.01 resolution with our model is up to 99.12% and 92.24% for a long transmission distance of 2000 m. Even for the resolution at 0.001, the recognition accuracy can still remain at 78.77%. This work provides an effective method for the recognition of FOAM modes, which may largely improve the channel capacity of the free-space optical communication.

关键词： OAM free-space optical communication deep learning convolutional neural network

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Ignition processes and characteristics of charring conductive polymers with a cavity geometry in precombustion chamber for applications in micro/nano satellite hybrid rocket motors

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Defence Technology（防务技术） 2024年第2期32卷 55-66页

作者： Zhiyuan Zhang Hanyu Deng Wenhe Liao Bin yu Zai yu Nanjing University of Science and Technology Nanjing 210094China

The arc ignition system based on charring polymers has advantages of simple structure,low ignition power consumption and multiple ignitions,which bringing it broadly application prospect in hybrid propulsion system of micro/nano ***,charring polymers alone need a relatively high input voltage to achieve pyrolysis and ignition,which increases the burden and cost of the power system of micro/nano satellite in practical *** conductive substance into charring polymers can effectively decrease the conducting voltage which can realize low voltage and low power consumption repeated ignition of arc ignition *** this paper,a charring conductive polymer ignition grain with a cavity geometry in precombustion chamber,which is composed of PLA and multiwall carbon nanotubes(MWCNT)was *** detailed ignition processes were analyzed and two different ignition mechanisms in the cavity of charring conductive polymers were *** ignition characteristics of charring conductive polymers were also investigated at different input voltages,ignition grain structures,ignition locations and injection schemes in a visual ignition *** results demonstrated that the ignition delay and external energy required for ignition were inversely correlated with the voltages applied to ignition ***,the incremental depth of cavity shortened the ignition delay and external energy required for ignition while accelerated the propagation of *** the depth of cavity increased from 2 to 6 mm(at 50 v),the time of flame propagating out of ignition grain changed from 235.6 to 108 ms,and values of mean ignition delay time and mean external energy required for ignition decreased from 462.8 to 320 ms and 16.2 to 10.75 J,*** rear side of the cavity was the ideal ignition position which had a shorter ignition delay and a faster flame propagation speed in comparison to other ignition *** to direct injection scheme,swirlin

关键词： Micro/nano satellite hybrid propulsion Arc ignition Charring conductive polymer Ignition mechanism Ignition characteristic Repeated ignition

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Measurement of yields and angular distributions ofγ-quanta from the interaction of 14.1 Mev neutrons with oxygen,phosphorus,and sulfur

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Chinese Physics C 2024年第3期48卷 79-92页

作者： D.N.Grozdanov N.A.Fedorov S.B.Dabylova yu.N.Kopatch I.N.Ruskov v.R.Skoy T.yu.Tretyakova C.Hramco P.I.Kharlamov G.v.Pampushik P.G.Filonchik A.v.Andreev Joint Institute for Nuclear Research(JINR) DubnaRussia Institute for Nuclear Research and Nuclear Energy Bulgarian Academy of SciencesSofiaBulgaria Faculty of Physics Lomonosov Moscow State UniversityMoscowRussia L.N.Gumilyov Eurasian National University AstanaKazakhstan Skobeltsyn Institute of Nuclear Physics Moscow State UniversityMoscowRussia Institute of Chemistry of Moldova ChisinauRepublic of Moldova Moscow Institute of Physics and Technology MoscowRussia

A study of the inelastic scattering of neutrons with an energy of 14.1 Mev on the nuclei of oxygen,phosphorus,and sulfur was performed at the TANGRA facility at JINR(Dubna).The experiment aimed to refine existing data and obtain new data on the yields and angular distributions ofγ-quanta emitted by the studied nuclei due to neutron-induced nuclear reactions using the tagged neutron *** types of detector systems were used to registerγ-***γ-ray yields were measured using a high-purity germanium(HPGe)*** angular distributions ofγ-rays were obtained using a system of 18 scintillation detectors based on bismuth germanite Bi_(4)Ge_(3)O_(12)(BGO)located around the *** performed experiments measured the yields of two transitions for the reaction of tagged neutrons with 16O,nine transitions for the reaction with ^(31)P,and nine transitions for the reaction with ^(32)S for the first *** angular anisotropy of theγ-radiation accompanying the inelastic scattering of neutrons with an energy of 14.1 Mev on ^(31)P nuclei was also measured for the first time.

关键词： tagged neutron method yields of gamma-quanta high-resolution gamma-spectrometry neutron-nuclear reactions neutron scattering

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