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混凝土中应用粉煤灰—综述

山西建筑 1983年第Z1期 35-52页

作者： E·E·Berry v.m.malhotra 宋大为

以粉煤灰作火山灰材料,在混凝土中代替部分水泥,通常可节约能源,降低成本,并使混凝土强品具有某些特殊的技术性质。为信经济而有效地使用粉煤灰,必须了解粉煤灰混凝土与普通混凝土两者的差别,特别是要了解这两类混凝土在强度增去率方面... 详细信息

以粉煤灰作火山灰材料,在混凝土中代替部分水泥,通常可节约能源,降低成本,并使混凝土强品具有某些特殊的技术性质。为信经济而有效地使用粉煤灰,必须了解粉煤灰混凝土与普通混凝土两者的差别,特别是要了解这两类混凝土在强度增去率方面的差别,以及不同配合方法对这种差别影响的程度.当配比与浇注适当,粉煤灰混凝土一般能改进工作度,可泵性,粗聚性,成品后期强度与耐久性。粉煤灰在高强混凝土中具

关键词：粉煤灰减水剂烧失量粉尘塑化剂水泥外加剂混凝土无机非金属材料火山灰反应

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掺加大剂量粉煤灰与增塑剂的高强混凝土

公路工程 1986年第1期 61-67页

作者： P.K.mukherjee ,m.T.Loughborough ,v.m.malhotra ,孙浩然江西省公路局科研所

本文介绍了一种能替代普通波特兰水泥的、掺入增塑剂和大剂量粉煤灰的高强混凝土的研究成果。研制的混凝土混合料水/水泥+粉煤灰比率为0.28。水泥与粉煤灰的含量分别390和230kg/m3,并掺加了大剂量的增塑剂。152×305mm圆柱体的28天抗压... 详细信息

本文介绍了一种能替代普通波特兰水泥的、掺入增塑剂和大剂量粉煤灰的高强混凝土的研究成果。研制的混凝土混合料水/水泥+粉煤灰比率为0.28。水泥与粉煤灰的含量分别390和230kg/m3,并掺加了大剂量的增塑剂。152×305mm圆柱体的28天抗压强度达到51.0～53.8KPα、28天的抗弯强度大约为8KPα。它的干缩与徐变值和基准混合料的对应数值相似。已经发现、这种改进的混凝土具有良好的和易性和早期强度,并可以使用到高强度结构有件的预制混凝土施工中去。

关键词：粉煤灰粉尘波特兰水泥硅酸盐水泥混凝土无机非金属材料增塑剂防软剂塑料助剂混合料配合料烧结料棱柱体试件徐变试验力学性能试验掺加大剂量

Antibacterial HA-coatings on bioresorbable mg alloy

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Journal of magnesium and Alloys 2024年第5期12卷 1965-1985页

作者： K.v.Nadaraia D.v.mashtalyar m.A.Piatkova A.I.Pleshkova I.m.Imshinetskiy m.S.Gerasimenko E.A.Belov v.v.Kumeiko D.N.Kozyrev K.A.Fomenko v.v.mostovaya B.R.Torpanov A.R.Biktimirov I.S.Osmushko S.L.Sinebryukhov S.v.Gnedenkov Institute of Chemistry FEB RAS 159 Pr.100-letiya VladivostokaVladivostok 690022Russia Far Eastern Federal University 10 Ajax BayRussky IslandVladivostok 690922Russia A.v.Zhirmunsky National Scientific Center of marine Biology FEB RAS 17 St.PalchevskogoVladivostok 690041Russia Regional Clinical Dermatovenerological Dispensary 18 V St.GamarnikaVladivostok 690033Russia NmIC“Treatment and Rehabilitation Center” 3 Ivankovskoe highwayMoscow 125367Russia

In this study,a calcium-phosphate coating was formed on a mg-mn-Ce alloy by the plasma electrolytic oxidation(PEO).The antibiotic vancomycin,widely used in the treatment of infections caused by Staphylococcus aureus(***),was impregnated into the *** with vancomycin showed high bactericidal activity against *** mechanical and electrochemical properties of the formed coatings were studied,as well as in vitro cytotoxicity tests and in vivo tests on mature male rats were *** to SEm,EDS,XRD and XPS data,coatings had a developed morphology and contained hydroxyapatite,which indicates high *** analysis of roughness of coatings without and with vancomycin did not reveal any differences,confirming the high roughness of the *** electrochemical tests,an increase in corrosion resistance by more than two times after the application of PEO coatings was *** to the results of an in vivo study,after 28 days of the implantation of samples with calcium phosphate PEO coating and vancomycin,no signs of inflammation were observed,while an inflammatory reaction developed in the area of implantation of bare alloy,followed by *** release tests from the coatings show a sharp decrease in the concentration of the released antibiotic on day 7 and then a gradual decrease until day *** the experiment,no significant deviations in the condition and behavior of the animals were observed;clinical tests did not reveal a systemic toxic reaction.

关键词： Bioactive coatings Biocompatibility mg alloy Plasma electrolytic oxidation Hydroxyapatite vancomycin

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The multi-impurity system in CdSe nanoplatelets:electronic structure and thermodynamic properties

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Communications in Theoretical Physics 2024年第3期76卷 165-173页

作者： D A Baghdasaryan v A Harutynyan E m Kazaryan H A Sarkisyan Russian-Armenian University H Emin 1230051YerevanArmenia Institute of Applied Problems of Physics 25 Nersisyan St0014YerevanArmenia

This paper theoretically studies the impurity states and the effects of impurity concentration and configuration on the optical,electrical,and statistical properties of CdSe nanoplatelets(NPLs).An image charge-based model of electron-impurity interaction is *** charge-carrier energy spectra and corresponding wave functions depending on the impurity number and configuration are *** electron binding energies are calculated for different NPL *** is shown that the image charge-based interaction potential that arises due to the dielectric constants mismatch is much stronger than the interaction potential that does not take such a mismatch into ***,it is demonstrated that the binding energies are increasing with the number of *** calculate the canonical partition function using the energy levels of the electron,which in turn is used to obtain the mean energy,heat capacity,and entropy of the non-interacting electron *** thermodynamic properties of the non-interacting electron gas that depend on the geometric parameters of the NPL,impurity number,configuration,and temperature are studied.

关键词： nanoplateletes thermodynamic properties impurity states

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Intertype superconductivity evoked by the interplay of disorder and multiple bands

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Frontiers of physics 2024年第4期19卷 81-89页

作者： P.m.marychev A.A.Shanenko A.v.vagov HSE University 101000 MoscowRussia Center for Advanced mesoscience and Nanotechnology MIPTDolgoprudny141700Russia

Nonmagnetic impurity scattering is known to shift up the Ginzburg-Landau parameter k of a *** this case,when the system is initially in type I,it can change its magnetic response,crossing the intertype domain with k~1 between the two standard superconductivity types and arriving at type *** the present work we demonstrate that the impact of disorder can be much more profound in the presence of the multiband structure of the charge carrier *** particular,when the band diffusivities differ from each other,the intertype domain tends to expand significantly,including points with k>1 that belong to deep type-Ⅱ in conventional single-band *** finding sheds light on the nontrivial disorder effect and significantly complements earlier results on the enlargement of the intertype domain in clean multiband superconductors.

关键词： superconductivity disorder intertype superconductivity twoband model

Effect of Ta2O5 nanoparticles on bioactivity, composition, structure, in vitro and in vivo behavior of PEO coatings on mg-alloy

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JOURNAL OF mAGNESIUm AND ALLOYS 2024年第6期12卷 2360-2379页

作者： mashtalyar, D. v. Imshinetskiy, I. m. Kashepa, v. v. Nadaraia, K. v. Piatkova, m. A. Pleshkova, A. I. Fomenko, K. A. Ustinov, A. Yu. Sinebryukhov, S. L. Gnedenkov, S. v. Russian Acad Sci Inst Chem Far Eastern Branch Vladivostok 690022 Russia Far Eastern Fed Univ Vladivostok 690950 Russia Reg Clin Dermatovenerol Dispensary Vladivostok 690033 Russia

The present study investigates the physical and chemical characteristics, behavior in vitro and in vivo , and biocompatibility of coatings containing Ta2 O5 , which are obtained by plasma electrolytic oxidation (PEO) on mA8 magnesium alloy. The obtained coatings demonstrate in vivo biocompatibility and in vitro bioactivity. Compared to the base PEO coating, the layers containing Ta2 O5 facilitate the development of apatite in simulated body fluid, suggesting that the inclusion of nanoparticles improves bioactivity of the coatings. It was found that incorporation of Ta2 O5 nanoparticles increases roughness and porosity of the formed layers by increasing particle concentration in electrolytes for the PEO process contributing to sufficient soft tissue ingrowth in vivo . Based on in vivo studies, these coatings also provide favorable tissue response and minimal inflammatory reaction in comparison with the bare magnesium alloy due to protection of living tissues from deleterious corrosion events of magnesium implant such as local alkalization and intense hydrogen evolution. The results obtained in the present study concluded biocompatibility, tissue integration of the PEO coatings containing Ta2 O5 nanoparticles making them a promising protective layer for biodegradable magnesium implants. (c) 2024 Chongqing University. Publishing services provided by Elsevier B.v. on behalf of KeAi Communications Co. Ltd. This is an open access article under the CC BY-NC-ND license ( http://***/licenses/by-nc-nd/4.0/ ) Peer review under responsibility of Chongqing University

关键词： Plasma electrolytic oxidation Bioactive coatings Tantalum pentoxide Simulated body fluid (SBF) Apatite formation Histology. AmORPHOUS CALCIUm-PHOSPHATE APATITE FORmATION mAGNESIUm ALLOY TANTALUm mETAL BONE ImPLANTS OXIDE-FILmS THIN-FILmS HYDROXYAPATITE BIOmATERIALS DEGRADATION