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Releases of phosphate fertilizer industry in the surrounding environment:Investigation on heavy metals and polonium-210 in soil

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Journal of Environmental Sciences 2010年第9期22卷 1387-1397页

作者： M.Aoun A.G.El Samrani B.S.Lartiges v.kazpard Z.Saad Lebanese Atomic Energy Commission Lebanese University Faculty of SciencesPlatform for Research and Analysis in Environmental Sciences Nancy University-LEM-ENSG/INPL-CNRS-15 Av.du Charmois

Distribution of Cu, Zn, Pb, Cr, Ni, Mn concentrations and the activity of polonium-210 in the surrounding area of a phosphate fertilizer industry located on the eastern coast of the Mediterranean Sea has been determined. Nineteen sampling sites were distributed around the industrial zone on a surface area of about 100,000 m^2. Atomic absorption spectroscopy and Alpha spectroscopy were used to quantify the heavy elements and polonium-210, respectively. Investigation on a particle scale was conducted by TEM and SEM coupled to EDX and X-ray cartography to determine the nature of heavy elements carriers and their distribution. Heavy elements were mainly concentrated inside the particle size fraction 〈 50 μm. Their levels decreased with distance increasing from the industry. According to the reference soil, enrichment factors were about 10, 15, 32 and 100 times for Zn, Pb, Cu, and Cr, respectively inside the particle size fraction 〈 50 μm on the closest sites to the industry. The main contaminant sources were transport and storage of row materials and the free release of phosphogypsum waste. Heavy elements were entrapped inside agglomerates of sulfates, phosphates and iron oxihydroxides in a diffused shape. Polonium-210 with an enrichment factor of about 56, showed the same behavior of the spatial distribution of the trace elements.

关键词： heavy elements phosphogypsum fortilizer industry polonium-210 Alpha spectrometry

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Surface Water Processes in Coping with Anthropogenic Impact in a Coastal Eastern Mediterranean Region

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Open Journal of Modern Hydrology 2024年第2期14卷 69-86页

作者： Nour Abboud Zeinab Matar Elias Maatouk véronique kazpard Research and Analysis Platform for Environmental Sciences (PRASE) Doctoral School of Sciences and Technology (EDST) Lebanese University Hadat Lebanon Laboratory of Georessources Geosciences and Environment (L2GE) Faculty of Sciences Lebanese University Fanar Lebanon Department of Earth and Life Sciences Faculty of Sciences Lebanese University Hadat Lebanon

Rivers are progressively being exposed to increased anthropogenic pollution stresses that are undermining their designated uses and affecting sensitive coastal areas. In this study, three adjacent eastern Mediterranean coastal rivers, Ibrahim, Kaleb and Beirut, were evaluated. Water quality samples were collected in dry and wet seasons from different sampling sites along the river from the source to the outlet which represent a gradient of increased urbanization. The spatiotemporal variability of the physio-chemical properties, heavy metals (Zn, Pb, Cu, Cr, and Cd) and organic matter (DOC) were statistically analyzed to better understand the contribution of point and nonpoint pollution sources. The three rivers (Beirut, Kaleb and Ibrahim) show a similar behavior in calcium and carbonate alkalinity due to the carbonate mineral weathering effect, so they are of calcium bicarbonate type due to their calcareous geological nature. The speciation of anions was affected by temporal variation. Moreover, it is obvious that the Beirut River has a different behavioral characteristic where the water is a sulfate type water with a preferable metal-OM complexation mainly with lead, zinc and copper, whereas Kaleb and Ibrahim are considered to be of a nitrate phosphate type with a preferable metal inorganic complexation, especially copper, that has a consistent behavior in both types of waters. This difference is attributed to the urbanization effect highly impacting the Beirut River.

关键词： Anions/Cations Metals DOC Complexation Coastal Rivers Spatiotemporal variability

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Effect of Cadmium on <i>Lactuca sativa</i>Grown in Hydroponic Culture Enriched with Phosphate Fertilizer

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Journal of Environmental Protection 2015年第12期6卷 1337-1346页

作者： valérie S. Azzi Ali Kanso Ahmad Kobeissi véronique kazpard Bruno Lartiges Antoine El Samrani Platform for Research and Analysis in Environmental Sciences Doctoral School of Sciences and Technology (EDST) Faculty of Science Lebanese University Hadat Lebanon Geosciences Environment Toulouse University of Toulouse III Toulouse France Lebanses Agriculture Research Institute Fanar Lebanon

Cadmium (Cd), one of the most toxic heavy metals added to soil after phosphate fertilizer treatment, was investigated. The effects of this metal on morphological and physiological changes of Lactuca sativa were studied in addition to its partitioning in different parts of the crop. In parallel, Lactuca sativa was allowed to grow under hydroponic conditions with modifications of the Hoagland nutrient solution. This solution was submitted to five Cd concentrations, 0, 0.093, 0.186, 0.279 and 0.372 mg Cd/L and three P concentrations, 0, 299 and 1420 mg P/L. The study showed a positive effect of phosphorus on root elongation, surface area while cadmium inhibited plant growth and sometimes the death of the plants. Cadmium was found to be accumulated in roots while zinc was preferably accumulated in the leaves and stems. The increase of performance of Lactuca sativa under hydroponic condition and Hoagland contaminated solution with cadmium was found to be better than the ones grown in Cd amended soil with or without phosphorus.

关键词： Cadmium Fertilizers Hydroponic Lactuca sativa Phosphorus

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