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Recent update on electrochemical CO_(2)reduction catalyzed by metal sulfide materials

Materials Reports(Energy) 2023年第2期3卷 103-123,I0003页

作者： An niza El Aisnada Masahiro Miyauchi Min Liu Akira Yamaguchi Department of Materials Science and Engineering School of Materials and Chemical TechnologyTokyo Institute of Technology2-12-1 OokayamaMeguro-kuTokyo152=8552Japan Biofunctional Catalyst Research Team RIKEN Center for Sustainable Resource Science2=1 HirosawaWakoSaitama351-0198Japan Hunan Joint international Research Center for Carbon Dioxide Resource Utilization State Key Laboratory of Powder MetallurgySchool of Physical and ElectronicsCentral South UniversityChangsha410083China

Seeking and developing efficient CO_(2)reduction reaction(CO_(2)RR)electrocatalysts is a hot topic in this era of global *** material candidates for sustainable and cost-effective applications,metal sulfides have attracted attention as promising nature-inspired materials due to multiple adsorption sites which are enhanced by the covalent character of *** article summarizes the current status regarding the utilization and development of metal sulfide materials as CO_(2)RR ***,the research background and basic principles of electrochemical CO_(2)RR are ***,an overview of the main obstacles to developing efficient CO_(2)RR electrocatalysts is *** section is followed by a summary of the empirical evidence supporting the application of metal sulfides as CO_(2)RR electrocatalysts beside nature-inspired *** summary of synthesis methods of various metal sulfides is also ***,the paper also highlights the recent works on metal sulfide as efficient CO_(2)RR including the undertaking strategy on the activity enhancement,and finally,discusses the challenges and prospect of metal sulfides-based CO_(2)RR *** recent efforts,metal sulfides remain relatively unexplored as materials for CO_(2)RR electrocatalytic ***,this review aims to stimulate novel ideas and research for improved catalyst designs and functionality.

关键词： Metal sulfides Electrocatalyst Electrochemical CO_(2)reduction Bi-metal sulfides Active site Defect engineering Selectivity Faradaic efficiency

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Antidiabetic and antioxidant activities of Nypa fruticans Wurmb. vinegar sample from Malaysia

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Asian Pacific Journal of Tropical Medicine 2015年第8期8卷 589-597页

作者： Nor Adlin Yusoff Mun Fei Yam Hooi Kheng Beh Khairul niza Abdul Razak Tri Widyawati Roziahanim Mahmud Mariam Ahmad Mohd Zaini Asmawi School of Pharmaceutical Sciences Universiti Sains Malaysia integrative Medicine Cluster Advanced Medical and Dental InstituteUniversiti Sains Malaysia Pharmacology Department Medical FacultyUniversity of Sumatera Utara

Objective: To study the antidiabetic and antioxidant activities of nipa palm vinegar(NPV) used in traditional Malay medicine for treating diabetes. Methods: NPV was extracted using liquid-liquid extraction method and the obtained samples were subjected to antidiabetic studies using normal and streptozotocin-induced diabetic rat models whereas antidoxidant activities were investigated via in vitro antioxidant tests namely 2,2-diphenyl-1-picrylhydrazyl and 2,2'-azinobis-3-ethylbenzothiozoline-6-sulfonic acid free radicals scavenging activities and the reducing power assay. Results: Single administration of NPV and its extracts were not effective in both normal and diabetic rats. in intraperitoneal glucose tolerance test, NPV and its aqueous extract showed significant blood glucose lowering effect. in the sub-acute study, compared with the diabetic control, aqueous extract of NPV showed the most notable blood glucose lowering effect(56.6%) and a significant improvement in serum insulin levels(79.8%, Pioxidant activity, three in vitro antioxidant tests were employed: 2,2-diphenyl-1-picryhydrazyl and 2,2'-azinobis-3-ethylbenzothiozoline-6-sulfonic acid free radical-scavenging assays, and the reducing power assay. Ethyl acetate extract had the greatest antioxidant potential and content of phenolic and flavonoid compounds. A linear positive correlation between the antioxidant parameters was observed. Chemical profiling analysis of aqueous extract of NPV revealed the presence of acetic acid(35.25%), the main active constituent which significantly contributed to the observed antidiabetic activity. Conclusions: Aqueous extract of NPV possesses antihyperglycaemic activities comparable to the metformin, while the ethyl acetate extract precipitated significant antioxidant effects attributable to its high phenolic content. These findings suggest that antioxidant compounds of NPV do not contribute much towards the overall observed antidiabetic effect.

关键词： Nypa fruticans Wurmb. Vinegar Antidiabetic Streptozotocin-induced diabetes Antioxidant Phenolics

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Jurassic-Cretaceous Stratigraphy of Malaysia

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Open Journal of Geology 2019年第10期9卷 668-670页

作者： Mat niza Bin Abdul Rahman Technical Services Division Department of Mineral and Geoscience Malaysia Ipoh Perak Malaysia

in Peninsular Malaysia, the Jurassic-Cretaceous sequences are represented by continental deposits in several isolated basins. Generally, the sequences are characterised by the fining upward sequences, comprising reddish brown to red siltstone, sandstone and conglomerate often interpreted as molasse sequences. in Sabah and Sarawak, the Jurassic-Cretaceous sequences are represented by the marine deposits comprising argillaceous, some arenaceous and calcareous rocks and associated chert, lava, and pyroclastics.

关键词： Jurassic-Cretaceous Peninsular Malaysia Continental Deposits Sabah and Sarawak Marine Deposits

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