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Unravelling Crystal Structures of Covalent Organi Frameworks by Electron Diffraction Tomography

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Chinese Journal of Chemistry 2020年第10期38卷 1153-1166页

作者： tu sun Wei Lei Yanhang Ma Yue-Biao Zhang School of Physical Science and Technology ShanghaiTech UniversityShanghai 201210China

Featuring the art of covalent chemistry on 2D and 3D with molecular precision,covalent organic frameworks(COFs)have attracted immense interests from inorganic,organic,polymer,materials and energy ***,due to the synthetic challenge of"crystallization problem",structural determination of COFs has been the bottle-neck in speeding up their discovery and design,as well as building up their structureproperty *** diffraction tomography(EDT)has been developed to determine crystal structures of COFs with only sub-micrometer sized single crystals,which enabled the ob initio determination of crystal structure,molecular connectivity,pore metrics,and host-guest interaction at the atomic *** this review,w e summarized the recent developments of EDT for addressing challenges in structure determinations of such e-beam sensitive,organic porous crystals,covering comprehensively automatic data collection,low dose,cryogenic protocols,structural solution method,powder X-ray diffraction refinement,and high-resolution transmission electron microscopy(HRTEM)imaging *** do believe the EDT will propel this field into the new era of COF chemistry with atomic precision,and we envision the wide application of artificial intelligence will promote the structural determination and particle analysis of COFs and related materials。

关键词： Electron valent refinement

REEs recovery from molten salt electrolytic slag:Challenges and opportunities for environmentally friendly techniques

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Journal of Rare Earths 2024年第6期42卷 1009-1019,I0001页

作者： Ziyan Yang Faxin Xiao Shuchen sun Heng Zhong Ganfeng tu School of Metallurgy Northeastern UniversityShenyang110819China Key Laboratory for Recycling of Nonferrous Metal Resources(Shenyang) Shenyang110819China

Due to the unique physical and chemical properties,rare earth elements(REEs)play a significant role in the high-tech *** the past few decades,the rare earth reserve in China has been gradually decreasing and more pressure has been exerted on the global rare earth supply for the increasing demand of REEs,which indicates that it is essential to recycle secondary resources to meet the rare earth *** for rare earth molten salt electrolytic slag(REMES),although its high rare earth content has potential huge economic value,its high fluorine content of approximately 10 wt%-20 wt%can pollute the *** methods are used to treat *** metallurgical and pyro-hydrometallurgical methods have gotten a big success for solving most of the hydrometallurgical problems,while some problems,like long route and waste water,need to be *** distillation is a new and promising method with a short process due to its harmlessness and high efficiency,but has shortcomings such as high energy consumption and material *** review presents these above three treatment methods,and the challenges and chances of using the recovery technique of REMES in an environmentally friendly way.

关键词： Rare earths Molten salt electrolytic slag Hydrometallurgy Pyro-hydrometallurgy Vacuum distillation Recovery

Assessment of the Characteristics of Demersal Fish Communities Using Species-and Trait-Based Approaches in the Coastal Habitats Along Rongcheng Bay,Shandong Peninsula,China

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Journal of Ocean University of China 2024年第3期23卷 786-796页

作者： YUAN Shunjie sun Xin tu Zhong sun Jie WANG Xianning ZHANG Peidong Key Laboratory of Mariculture(Ocean University of China) Ministry of EducationQingdao 266003China Shandong Fisheries Development and Resource Conservation Center Yantai 264003China

Biodiversity declines have motivated many studies on the relationship between species diversity and ecosystem *** this study,we described the spatial-temporal characteristics of demersal fish communities along a coastal habitat in Rongcheng Bay,Shandong Peninsula,China with both species-based and biological trait-based *** field survey was carried out monthly using traps from April to October of 2018,and divided into three seasons(spring:April and May;summer:June,July and August;autumn:September,October and November).The study area included five distinct habitats:seagrass bed,natural rocky reef,bare sand,artificial reef together with natural rocky reef,and artificial reef together with bare *** analyzed the fish communities with three taxonomic diversity indices,including Shannon-Wiener,Simpson,and Pielou Evenness,as well as four functional diversity indices,including FRic,FEve,FDiv,and FDis,based on 7 functional groups which are categorized into 27 *** results showed that there were no significant differences in taxonomic diversity indices among different habitats in the three ***,significant differences were found in the functional richness of fish communities among different habitats in three *** bed represented the highest functional richness in spring and *** study demonstrates that seagrass bed is very important in enhancing the functional diversity of fish communities in a complex *** study also indicates that the combination of taxonomic diversity and functional diversity will provide a more detailed description of the characteristics of fish communities.

关键词： complex habitat biological traits biodiversity fish communities

Non-cooperative Game Based Optimal Dispatch Model for Integrated Energy Systems

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CSEE Journal of Power and Energy Systems 2024年第3期10卷 1195-1207页

作者： Jiandong Duan Qian sun Chen Wu Yao Yang Siyu tu School of Electrical Engineering Xi’an University of TechnologyXi’an710056China IEEE CSEE

In order to improve the efficiency of energy utilization,the integrated energy system(IES)has *** IES typically acts as a whole system during operations,the subsystems are separated,and the interests of each system are *** this paper,considering the relationship between the various energy systems,non-cooperative game theory is used to establish the optimal dispatch *** proposed model mainly relies on the relationship between the cooperation and competition among various subsystems to obtain the maximum benefit they can ***,the basic definition is combined with the particle swarm optimization algorithm to solve the *** results show that the optimization strategy proposed in this paper can operate safely and reliably,and effectively distribute the benefits of each energy system.

关键词： Integrated energy system multi-energy complimentarily non-cooperative game theory

Absolute Structure Determination of Chiral Organic Nanocrystals Using Zone-Axis Electron Diffraction

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CCS Chemistry 2023年第11期5卷 2466-2472页

作者： Lijin Wang Junyan Li Yang Ling tu sun Yaqi Fan Yanhang Ma Shanghai Key Laboratory of High-Resolution Electron Microscopy School of Physical Science and TechnologyShanghaiTech UniversityShanghai 201210 State Key Laboratory of Inorganic Synthesis and Preparative Chemistry College of ChemistryJilin UniversityChangchun 130012

Enantiomorphic identification of chiral molecules is essential in organic chemistry and the pharmaceutical industry,as two enantiomorphic structures can show distinctively different ***,we illustrate the absolute structural determination of organic nanocrystals using zone-axis electron diffraction by taking advantage of electron multiple *** enantiomorphs are distinguished by comparing the reflection intensities of Friedel pairs in the zone-axis electron diffraction pattern,after confirming the absolute indices of reflections by locating relative positions of diffraction spots from two patterns that deviate from a certain *** demonstrate the protocol with successful applications in two chiral drug nanocrystals.

关键词： chiral organic nanocrystal absolute structure electron diffraction multiple scattering absolute configuration

UDT:U-shaped deformable transformer for subarachnoid haemorrhage image segmentation

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CAAI Transactions on Intelligence Technology 2024年第3期9卷 756-768页

作者： Wei Xie Lianghao Jin Shiqi Hua Hao sun Bo sun Zhigang tu Jun Liu Hubei Provincial Key Laboratory of Artificial Intelligence and Smart Learning Central China Normal UniversityWuhanChina School of Computer Science Central China Normal UniversityWuhanChina National Language Resources Monitoring and Research Center for Network Media Central China Normal UniversityWuhanChina The First Affiliated Hospital of Dalian Medical University DalianChina State Key Laboratory of Information Engineering in Surveying Mapping and Remote SensingWuhan UniversityWuhanChina Information Systems Technology and Design Pillar Singapore University of Technology and DesignSingaporeSingapore

Subarachnoid haemorrhage(SAH),mostly caused by the rupture of intracranial aneu-rysm,is a common disease with a high fatality *** lesions are generally diffusely distributed,showing a variety of scales with irregular *** complex characteristics of lesions make SAH segmentation a challenging *** cope with these difficulties,a u-shaped deformable transformer(UDT)is proposed for SAH ***,first,a multi-scale deformable attention(MSDA)module is exploited to model the diffuseness and scale-variant characteristics of SAH lesions,where the MSDA module can fuse features in different scales and adjust the attention field of each element dynamically to generate discriminative multi-scale ***,the cross deformable attention-based skip connection(CDASC)module is designed to model the irregular edge char-acteristic of SAH lesions,where the CDASC module can utilise the spatial details from encoder features to refine the spatial information of decoder ***,the MSDA and CDASC modules are embedded into the backbone Res-UNet to construct the proposed *** experiments are conducted on the self-built SAH-CT dataset and two public medical datasets(GlaS and MoNuSeg).Experimental results show that the presented UDT achieves the state-of-the-art performance.

关键词： image segmentation medical image processing

Effects of Recrystallization Parameters on the Formation of Hollow Silicalite-1 Zeolite

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China Petroleum Processing & Petrochemical Technology 2019年第4期21卷 1-8页

作者： Tan Cheng Dong Zhuoya sun tu Zhang Yaping Zhang Guanqun Xia Changjiu Ma Yanhang Shanghai Advanced Research Institute Chinese Academy of SciencesShanghai 201210 School of Physical Science and Technology ShanghaiTech UniversityShanghai 201210 University of Chinese Academy of Sciences Beijing100049 State Key Laboratory of Catalytic Materials and Reaction Engineering Research Institute of Petroleum ProcessingSINOPECBeijing 100083

Hollow silicalite-1 zeolite can be readily fabricated by hydrothermally treating the parent silicalite-1 with tetrapropylammonium hydroxide. A dissolution-recrystallization mechanism has been previously proposed to explain the formation of such hollow structures, but detailed information of this formation process still remains unclear. Herein, by tracking the evolvement of the hollow voids and morphology of the silicalite-1 under various treatments using XRD, SEM, TEM and N2 adsorption/desorption techniques, we systematically studied the formation process of the hollow structure of silicalite-1 zeolite and discovered that the organic template, water, treating temperature and time can significantly influence the morphology and size of hollow structure inside silicalite-1 zeolite crystals. Generally, a diluted synthesis medium with high template content under suitable temperature(for instance 170 °C) and extended treatment time favors the formation of single hexagonal hollow structure within silicalite-1 zeolites;while other conditions favor the formation of rounded hollow voids or even multiple-voids within silicalite-1 zeolites.

关键词： hollow silicalite-1 hydrothermal synthesis dissolution,recrystallization

A New Method for Image Input in Internet-based Telerobotic Control System

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微计算机信息 2006年第14期 226-227+64页

作者： Li,Ping Yan,Baoding tu,Wenke sun,LiGong Ye,Yucheng

Camera- card method is a classical image input method in Internet- based telerobotic control system. However, there are some disadvantages like high- cost and complicated application in the classical *** on TWAIN criterion, a new single USB camera method is proposed in this paper. This method has been implemented by VC++ to drive universal digital image devices like USB camera. Compared to the camera- card method, the proposed method has a lower cost and a more flexible structure in applica- tions such as Internet- based telerobotic control system.

关键词： Telerobot image input USB TWAIN VC++

Controllable synthesis of one-dimensional silicon nanostructures based on the dual effects of electro-deoxidation and the Kirkendall effect

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Nano Research 2024年第9期17卷 7814-7823页

作者： Jianxin tu Shuo Yu Kui Hao Le sun Ruicheng Bai Fangzhou Zhang Aijun Li Hong Liu Institute of Materials School of Materials Science and EngineeringShanghai UniversityShanghai 200444China Department of Applied Physics The Hong Kong Polytechnic UniversityKowloon 999077Hong KongChina Shaoxing institute of technology Shanghai UniversityShanghai 200444China

In this study,we successfully synthesized silicon nanotubes(Si-NTs)and silicon nanowires(Si-NWs)in a controllable manner using a catalyst-and template-free method through the direct electrolysis of SiO_(2)in a molten CaCl_(2)-CaO system,while also proposing a novel formation mechanism for ***-NWs are formed through electro-deoxidation when the cell voltage is within the range of CaO decomposition voltage and SiO_(2)decomposition *** subsequently adjusting the voltage to a value between the decomposition potentials of CaCl_(2)and CaO,in-situ electro-deoxidation of CaO takes place on the surface of the synthesized Si-NWs,leading to the formation of a Ca *** formation of Ca-Si diffusion couple leads to the creation of vacancies within the Si-NWs,as the outward diffusion rate of Si exceeds the inward diffusion rate of *** differential diffusion rates between Si and Ca in a diffusion couple exhibit an analogy to the Kirkendall *** vacancies gradually accumulate and merge,forming large voids,which ultimately result in the formation of hollow *** a subsequent dealloying process,the removal of the embedded calcium leads to the formation of *** the application of a carbon coating,the Si-NTs@C composite showcases a high initial discharge capacity of 3211 mAh·g^(-1)at 1.5 A·g^(-1)and exhibits exceptional long-term cycling stability,maintaining a capacity of 977 mAh·g^(-1)after 2000 cycles at 3.0 A·g^(-1).

关键词： silicon nanotubes silicon nanowires lithium-ion battery Kirkendall effect