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Optimization, equilibrium, adsorption behavior and role of surface functional groups on graphene oxide-based nanocomposite towards diclofenac drug

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Journal of Environmental Sciences 2020年第7期32卷 137-150页

作者： Thuan Van tran Duyen Thi Cam Nguyen Hanh TNLe dai-Viet NVo Sonil Nanda Trinh Duy Nguyen Nguyen Tat Thanh Hi-Tech Institute Nguyen Tat Thanh UniversityHo Chi Minh City 755414Viet Nam Center of Excellence for Green Energy and Environmental Nanomaterials(CE@GrEEN) Nguyen Tat Thanh UniversityHo Chi Minh City 755414Viet Nam Institute of Hygiene and Public Health Ho Chi Minh City 700000Viet Nam Department of Chemical and Biochemical Engineering University of Western OntarioLondonOntarioCanada

Aquatic contamination of diclofenac(DCF),an emergent non-steroidal anti-inflammatory drug(NSAIDs),can result in adverse effects to many ecosystems through ***,introducing effective remediation techniques to sequester the pharmaceutical wastes is highly fundamental to prevent their accumulation in the ***,adsorption has been presented as a green and efficient ***,we report the characterization and application of the novel magnetic nanocomposite(GO@CoFe2O4)derived from cobalt-based ferrite(CoFe2O4)and graphene oxide(GO)for DCF *** the optimization procedure,the response surface methodology(RSM)was adopted to investigate the impacts of DCF concentration(1.6-18.4 mg/L),DCF dosage(0.08-0.92 g/L),and solution pH(2.6-9.4)to find the optimum conditions for DCF removal,at 10.5 mg/L,0.74 g/L,and pH 4,*** the adsorption experiments,the kinetic,isotherm,thermodynamic,and intraparticle diffusion models were systematically ***,we have elucidated the role of functional groups on the surface of GO@CoFe2O4 in enhancing the adsorption of DCF *** good removal efficiency(up to 86.1%),high maximum adsorption capacity(32.4 mg/g),GO@CoFe2O4 can be a potential candidate to eliminate DCF drug from water.

关键词： Diclofenac sodium Graphene oxide Magnetic nanocomposite Response surface methodology Pharmaceuticals adsorption

Surface PEGylation of hollow mesoporous silica nanoparticles via aminated intermediate

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Progress in Natural Science:Materials International 2019年第6期29卷 612-616页

作者： Thi Ngoc Tram Nguyen Diem-Huong Nguyen-tran Long Giang Bach tran Hoang Du Truong Ngoc Thuy trang Le dai Hai Nguyen Tra Vinh University Institute of Applied Materials Science Vietnam Academy of Science and Technology Graduate University of Science and Technology Vietnam Academy of Science and Technology Nguyen Tat Thanh University 5. Institute of Research and Development Duy Tan University

A hybrid of organic/inorganic system, hollow mesoporous silica nanoparticles functionalized with poly(ethylene glycol), was synthesized in the presence of coupling agent and aminated ends. Doxorubicin(DOX) was used as a model drug to evaluate the effect of PEGylation on the loading capacity and release pattern of the *** with transmission electron microscopy(TEM) and scanning electron microscopy(SEM), X-ray diffraction(XRD), nitrogen adsorption-desorption, thermogravimetric analysis(TGA) and Fourier transformed infrared(FTIR) confirmed the PEG conjugation, as well as the amorphous mesoporous nature of the synthesized particles. Due to the capping effect of PEG molecules over the pores in the silica structure, the synthesized system was able to retain higher amount of cargo and establish a controlled manner when releasing.

关键词： Hollow mesoporous silica nanoparticles mPEG PEGylation Surface modification

Testing of a Full-Scale Composite Floor Plate

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Engineering 2019年第2期5卷 223-233页

作者： Dennis lam Xianghe dai Therese Sheehan School of Engineering University of Bradford Bradford BD7 IDP United Kingdom

A full-scale composite floor plate was tested to investigate the flexural behavior and in-plane effects of the floor slab in a grillage of composite beams that reduces the tendency for longitudinal splitting of the concrete slab along the line of the primary beams. This is important in cases where the steel decking is discontinuous when it is orientated parallel to the beams. In this case, it is important to demonstrate that the amount of transverse reinforcement required to transfer local forces from the shear connectors can be reduced relative to the requirements of Eurocode 4. The mechanism under study involved in-plane compression forces being developed in the slab due to the restraining action of the floor plate, which was held in position by the peripheral composite beams;while the secondary beams acted as transverse ties to resist the forces in the floor plate that would otherwise lead to splitting of the slab along the line of the primary beams. The tendency for cracking along the center line of the primary beam and at the peripheral beams was closely monitored. This is the first large floor plate test that has been carried out under laboratory conditions since the Cardington tests in the early 1990s, although those tests were not carried out to failure. This floor plate test was designed so that the longitudinal force transferred by the primary beams was relatively high (i.e., it was designed for full shear connection), but the transverse reinforcement was taken as the minimum of 0.2% of the concrete area. The test confirmed that the primary beams reached their plastic bending resistance despite the discontinuous decking and transverse reinforcement at the minimum percentage given in Eurocode 4. Based on this test, a reduction factor due to shear connectors at edge beams without U-bars is proposed.

关键词： Floor plate test Composite beams Edge beams Eurocode 4 In-plane effect Column removal Robustness

Zirconium metal organic framework for design of tetragonal rare earth-doped zirconia nanoparticles

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Journal of Rare Earths 2019年第11期37卷 1230-1236页

作者： lam Thi Kieu Giang Lukasz Marciniak Krzysztof Kamil Zur Dinh Manh Tien Nguyen Vu Nguyen Thanh Binh tran Kim Anh Le Quoc Minh Institute of Materials Science Vietnam Academy of Science and Technology18 Hoang Quoc VietCau GiayHanoiViet Nam Graduate University of Science and Technology Vietnam Academy of Science and Technology18 Hoang Quoc VietCau GiayHanoiViet Nam Institute of Low Temperature and Structural Research Polish Academy of Sciencesul.Okolna 250-422 WroclawPoland Faculty of Mechanical Engineering Bialystok University of TechnologyWiejska 45C15-351 BialystokPoland Institute of Applied Physics and Scientific Instrument Vietnam Academy of Science and Technology18 Hoang Quoc VietCau GiayHanoiViet Nam Duy Tan University 03 Quang TrungDa NangViet Nam

Zirconium metal-organic frameworks ZrOBDC(where BDC=C6H4(COOH)2,terephthalic acid)doped and co-doped with rare earth ions Ln(ZrOBDC:Ln^3+,where Ln^3+=Eu3+and Tb^3+as well as Er^3+and Yb^3+)were used as precursors for the design of tetragonal rare earth doped zirconia nanoparticles(t-ZrO2:Ln^3+NPs)through annealing ***,characterization and luminescence properties of ZrOBDC:Ln^3+and ZrO2:Ln^3+NPs were *** as-obtained t-ZrO2:Ln^3+NPs have high purity with an average size of 20-30 *** luminescence spectra of ZrOBDC:Tb^3+and ZrOBDC:Eu3+display strong green and red emission at around 544 and 611 nm which correspond to 5D4→7F5 and 5D0→7F2 transitions of Tb^3+and Eu3+ions,*** green and red up-conversion emissions of ZrO2:Er^3+,Yb^3+NPs due to 2H11/2,4S3/2→4I15/2 and 4F9/2→4I15/2 transitions of the Er^3+ions are observed under 976 nm laser excitation.

关键词： Zirconium Rare earth ZrOBDC ZrOBDC:Ln3+ ZrO2:Ln3+ Up-conversion

Strigolactones interact with other phytohormones to modulate plant root growth and development

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The Crop Journal 2022年第6期10卷 1517-1527页

作者： Huwei Sun Weiqiang Li David J.Burritt Hongtao Tian Heng Zhang Xiaohan Liang Yuchen Miao Mohammad Golam Mostofa lam-Son Phan tran Laboratory of Rice Biology in Henan Province Collaborative Innovation Center of Henan Grain CropsCollege of AgronomyHenan Agricultural UniversityZhengzhou 450046HenanChina Jilin Da’an Agro-ecosystem National Observation Research Station Changchun Jingyuetan Remote Sensing Experiment StationKey Laboratory of Mollisols AgroecologyNortheast Institute of Geography and AgroecologyChinese Academy of SciencesChangchun 130102JilinChina State Key Laboratory of Cotton Biology Henan Joint International Laboratory for Crop Multi-Omics ResearchSchool of Life SciencesHenan UniversityKaifeng 475001HenanChina d Department of Botany University of OtagoDunedin 9054New Zealand Institute of Genomics for Crop Abiotic Stress Tolerance Department of Plant and Soil ScienceTexas Tech UniversityLubbockTX 79409USA Institute of Research and Development Duy Tan University03 Quang TrungDa Nang 550000Vietnam

Strigolactones(SLs),which are biosynthesized mainly in roots,modulate various aspects of plant growth and ***,we review recent research on the role of SLs and their cross-regulation with auxin,cytokinin,and ethylene in the modulation of root growth and *** nutrientsufficient conditions,SLs regulate the elongation of primary roots and inhibit adventitious root formation in eudicot *** promote the elongation of seminal roots and increase the number of adventitious roots in grass plants in the short term,while inhibiting lateral root development in both grass and eudicot *** effects of SLs on the elongation of root hairs are variable and depend on plant species,growth conditions,and SL *** or phosphate deficiency induces the accumulation of endogenous SLs,modulates root growth and *** analyses indicate cross-regulation of SLs with auxin,cytokinin,and ethylene in regulation of root growth and *** discuss the implications of these studies and consider their potential for exploiting the components of SL signaling for the design of crop plants with more efficient soil-resource utilization.

关键词： Cross-regulation Development Phytohormones Roots Signaling Strigolactones

Automatic quantification of superficial foveal avascular zone in optical coherence tomography angiography implemented with deep learning

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Visual Computing for Industry,Biomedicine,and Art 2019年第1期2卷 205-213页

作者： Menglin Guo Mei Zhao Allen M.Y.Cheong Houjiao dai Andrew K.C.lam Yongjin Zhou School of Biomedical Engineering Health Science CenterShenzhen UniversityShenzhen University Xili CampusRoom 208Block A2Taoyuan StreetShenzhen 518055China Centre for Myopia Research School of OptometryFaculty of Health and Social SciencesThe Hong Kong Polytechnic UniversityKowloonHong KongChina

An accurate segmentation and quantification of the superficial foveal avascular zone(sFAZ)is important to facilitate the diagnosis and treatment of many retinal diseases,such as diabetic retinopathy and retinal vein *** proposed a method based on deep learning for the automatic segmentation and quantification of the sFAZ in optical coherence tomography angiography(OCTA)images with robustness to brightness and contrast(B/C)variations.A dataset of 405 OCTA images from 45 participants was acquired with Zeiss Cirrus HD-OCT 5000 and the ground truth(GT)was manually segmented subsequently.A deep learning network with an encoder–decoder architecture was created to classify each pixel into an sFAZ or non-sFAZ ***,we applied largestconnected-region extraction and hole-filling to fine-tune the automatic segmentation results.A maximum mean dice similarity coefficient(DSC)of 0.976±0.011 was obtained when the automatic segmentation results were compared against the *** correlation coefficient between the area calculated from the automatic segmentation results and that calculated from the GT was *** all nine parameter groups with various brightness/contrast,all the DSCs of the proposed method were higher than *** proposed method achieved better performance in the sFAZ segmentation and quantification compared to two previously reported *** conclusion,we proposed and successfully verified an automatic sFAZ segmentation and quantification method based on deep learning with robustness to B/C *** clinical applications,this is an important progress in creating an automated segmentation and quantification applicable to clinical analysis.

关键词： Optical coherence tomography angiography Deep learning Foveal avascular zone Automatic segmentation and quantification

Using a stand-level model to predict light absorption in stands with vertically and horizontally heterogeneous canopies

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Forestry Studies in China 2014年第3期16卷 158-176页

作者： David I Forrester Ruben Guisasola Xiaolu Tang Axel T Albrecht tran lam Dong Guerric le Maire Chair of Silviculture Faculty of Environment and Natural ResourcesFreiburg University Chair of Forest Inventory and Remote Sensing Georg-August-Universitt Gttingen Forest Research Institute of Baden-Wrttemberg Tasmanian Institute of Agriculture(TIA) Vietnamese Academy of Forest Sciences Silviculture Research Institute CIRAD UMR Eco & Sols2 Place VialaMontpellier 34060France

Background： Forest ecosystem functioning is strongly influenced by the absorption of photosynthetically active radiation （APAR）, and therefore, accurate predictions of APAR are critical for many process-based forest growth models. The lambert-Beer law can be applied to estimate APAR for simple homogeneous canopies composed of one layer, one species, and no canopy gaps. However, the vertical and horizontal structure of forest canopies is rarely homogeneous. Detailed tree-level models can account for this heterogeneity but these often have high input and computational demands and work on finer temporal and spatial resolutions than required by stand-level growth models. The aim of this study was to test a stand-level light absorption model that can estimate APAR by individual species in mixed-species and multi-layered stands with any degree of canopy openness including open-grown trees to closed canopies. Methods： The stand-level model was compared with a detailed tree-level model that has already been tested in mixed-species stands using empirical data. Both models were parameterised for five different forests, including a wide range of species compositions, species proportions, stand densities, crown architectures and canopy structures. Results： The stand-level model performed well in all stands except in the stand where extinction coefficients were unusually variable and it appears unlikely that APAR could be predicted in such stands using （tree- or stand-level） models that do not allow individuals of a given species to have different extinction coefficients, leaf-area density or analogous parameters. Conclusion： This model is parameterised with species-specific information about extinction coefficients and mean crown length, diameter, height and leaf area. It could be used to examine light dynamics in complex canopies and in stand-level growth models.

关键词： Complex forests Mixed-species Stand structure Extinction coefficient lambert-Beer law Light absorption

Selective Smoothed Finite Element Method

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Tsinghua Science and Technology 2007年第5期12卷 497-508页

作者： T. T. Nauven G. R. Liu K. Y. dai K. Y. lam Center for Advanced Computations in Engineering Science Department of Mechanical Engineering National University of Singapore 9 Engineering Drive 1 Singapore 117576 Singapore Singapore-MIT Alliance (SMA) E4-04-10 4 Engineering Drive 3 Singapore 117576 Singapore School of Mechanical and Aerospace Engineering Nanyang Technological University 50 Nanyang Avenue Singapore 639798 Singapore

The paper examines three selective schemes for the smoothed finite element method （SFEM） which was formulated by incorporating a cell-wise strain smoothing operation into the standard compatible finite element method （FEM）. These selective SFEM schemes were formulated based on three selective integration FEM schemes with similar properties found between the number of smoothing cells in the SFEM and the number of Gaussian integration points in the FEM. Both scheme 1 and scheme 2 are free of nearly incompressible locking, but scheme 2 is more general and gives better results than scheme 1. In addition, scheme 2 can be applied to anisotropic and nonlinear situations, while scheme 1 can only be applied to isotropic and linear situations. Scheme 3 is free of shear locking. This scheme can be applied to plate and shell problems. Results of the numerical study show that the selective SFEM schemes give more accurate results than the FEM schemes.

关键词： finite element method (FEM) smoothed finite element method (SFEM) strain smoothing smoothing cell selective

Monday blues of deceased-donor liver transplantation

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Hepatobiliary & Pancreatic Diseases International 2011年第1期10卷 26-29页

作者： See Ching Chan Wing Chiu dai Chung Mau Lo Banny lam Yuen Man Kwan Wai Yi Ho Sheung Tat Fan Department of Surgery Queen Mary HospitalThe University of Hong Kong

BACKGROUND:There is a constant and global shortage of deceased-donor organs for *** to identify areas for securing potential deceased-donor organs may improve the supply and hence benefit more patients in need of transplantation. METHODS:We looked into the disparity of the number of deceased-donor liver transplantation(DDLT)performed at our hospital on different days of the weeks from January 2000 to the end of December 2009(237 DDLTs).The number of DDLT performed on each day was compared with the other days of the week. RESULTS:It was apparent that there were fewer DDLTs on Mondays,as shown by the numbers of DDLT performed on different days of the week in an ascending order:Monday 18(7.6%),Sunday 30(12.7%),Thursday 34(14.3%),Friday 36(15.2%),Wednesday 38(16.0%),Tuesday 40(16.9%), and Saturday 41(17.3%).The difference reached statistical significance when Monday was compared with Tuesday (P=0.019),Wednesday(P=0.010),Friday(P=0.021),and Saturday(P=0.007).It was twice as unlikely a DDLT would be performed on Monday as compared with other *** a trend did not change even with an increase in the number of deceased-donor liver grafts in the last *** consent to donation was obtained from the donor family the day before DDLT,fewer consents were thus obtained on ***:These findings suggested that deceased-donor organ donation activities were less active on Sundays and could be *** further raises the concern of possible wastage of potential cases of organ donation.

关键词： deceased-donor liver transplantation graft shortage organ donation