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Luminescent and magnetic properties of multifunctional europium(Ⅲ) complex based nanocomposite

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Journal of Rare Earths 2019年第11期37卷 1237-1241页

作者： Hoang Thi Khuyen Nguyen Thanh huong tran thu huong Pham Thi Lien Do Thi Anh thu Nguyen Thi Anh huong Wieslaw Strek Le Quoc Minh Institute of Materials Science Vietnam Academy of Science and Technology18 Hoang Quoc VietCau CiayHanoiViet Nam Graduate University of Science and Technology Vietnam Academy of Science and Technology18 Hoang Quoc VietCau GiayHanoiViet Nam Department of Chemistry University of Natural SciencesHanoi National University19 Le Thanh TongHoan KiemHanoiViet Nam Institute of Low Temperature and Structure Research PASOkolna 2Wroclaw 50-422Poland Duy Tan University K7/25 Quang TrungDa DangViet Nam

The luminescent rare earth(RE)complex based multifunctional nanocomposites offer new potential applications of multimodal imaging(magnetic resonance imaging(MRI),fluorescent bioimaging,etc.)that can be associated with therapeutic *** this study,we report some results obtained with novel multifunctional Fe3O4/Si-amine/Eu(NTA)3 nanocomposites that are composed of europium(Ⅲ)complex with 1-(2-naphthoyl)-3,3,3-trifluoroacetone ligands(NTA)(Eu(NTA)3)and superparamagnetic Fe3O4 *** nanocomposites were functionalized with an amine group for biomedicine *** multifunctional Fe3O4/Si-amine/Eu(NTA)3 nanocomposites exhibit both good magnetic behavior of Fe3O4 nanoparticles as a core and strong fluorescent property of europium(Ⅲ)*** characterizations were analyzed by XRD,SEM,EDX and FTIR *** optical properties were studied in detail by UV-VIS spectra and luminescent emission *** magnetic property was estimated by *** effect of concentrations of luminescent Eu(NTA)3 complex on luminescent and magnetic properties is discussed.

关键词： Multifunctional nanocomposite Luminescence Magnetic Europium(Ⅲ)complex Fe3O4 Rare earths

Synthesis and characterization of core/shell structured nanophosphors CePO_4:Tb@LaPO_4 by solvothermal method

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Journal of Rare Earths 2011年第12期29卷 1147-1151页

作者： Dinh Xuan Loc tran Thi Kim Chi tran thu huong Nguyen Vu tran Kim Anh Wieslaw Strek Le Quoc Minh Institute of Materials Science Vietnam Academy of Science and Technology Institute of Low Temperature and Structure Research Polish Academy of Sciences(PAN) University of Engineering and Technology

Core/shell structured CePO4：Tb（Ⅲ）@LaPO4 and CePOa：Tb（Ⅲ） were successfully synthesized in tris（2-ethylhexyl） phosphate （TEHP） and diethylene glycol （DEG） solvents for comparison of the two techniques in open air and closed reaction vessel. Morphology and crystal structure of the core/shell nanophosphors were determined by using X-ray diffraction （XRD） and transmission electron microscopy （TEM）, which showed that nanophosphors had diameter of about 5-10 nm with the monoclinic monazite phase. The nanophosphors obtained by close vessel procedure showed smaller size, more homogeneity and pure crystallite. The luminescent measurements were done upon the different excitation wavelengths in ultraviolet region and at room temperatm＇e to elucidate the influences of the used solvents and the reaction temperatures. It was found that CePO4：Tb@LaPO4 preparedby the close vessel synthesis showed the intensity of green band of the transfer from 5D4 to 7F5 energy level, which was strongly increased, and the luminescent decay time was 3.2 ms, which was longer than that of naked CePO4：Tb phosphor.

关键词： solvothermal synthesis luminescence CePOn:Tb CePOa:Tb@LaPO4 rare earths

Fabrication and properties of high efficiency luminescent nanorods EuPO_4·H_2O by soft template method

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Journal of Rare Earths 2011年第12期29卷 1174-1177页

作者： tran thu huong tran Kim Anh Le Thi Vinh W.Strek Hoang Thi Khuyen Le Quoc Minh Institute of Materials Science Vietnam Academy of Science and Technology Department of Chemistry Hanoi University of Mining and Geology Institute of Low Temperature and Structure Research University of Engineering and Technology National University Hanoi

Europium orthophosphate monohydrate （EuPO4·H2O） nanorods with typical dimensions of about 10-30 nm in diameter and 300-500 nm in length were prepared by using the soft template method. The effects of using diethylene glycol （DEG） and polyethylene glycol （PEG） polymers as well as the pH values on the size, crystalline structure and morphology of EuPO4·H2O nanorods were investigated. Field emission scanning electron microscopy （FESEM） and X-ray diffraction （XRD） data of the prepared samples were elucidated. The nanorods were highly uniform and their mean length was reduced by using DEG and PEG as soft template agents. For all prepared samples, the rhabdophanetype hexagonal EuPO4·H2O was the dominated phase. The photoluminescence （PL） spectroscopy measurements of EuPO4·H2O nanorods revealed that, under UV excitation, EuPO4·H2O nanorods exhibited strong luminescence with narrow bands corresponding to the intra-4f transitions of ^5D0→^7Fj （j=1, 2, 3, 4） of Eu^3＋ ions. The peaks were found at 594 nm （^5D0→^7F1）, 619 nm （^5D0→^7F2）, 652 nm （^5D0→^7F3）, and 697 nm （^5D0→^7F4）, with the strongest emission at 594 nm.

关键词： soft template method EuPO4·H2O nanorods fluorescence rare earths

Synthesis and characterization of NaYF4:Yb3+,Er3+@silica-N=folic acid nanocomplex for bioimaginable detecting MCF-7 breast cancer cells

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Journal of Rare Earths 2019年第11期37卷 1183-1187页

作者： Ha Thi Phuong tran thu huong Le Thi Vinh Hoang Thi Khuyen Do Thi Thao Nguyen Thanh huong Pham Thi Lien Le Quoc Minh Institute of Materials Science Vietnam Academy of Science and Technology18 Hoang Quoc VietCau GiayHanoiViet Nam Graduate University of Science and Technology-Vietnam Academy of Science and Technology 18 Hoang Quoc VietCau GiayHanoiViet Nam Department of Chemistry Hanoi Medical University1-Ton That TungDong DaHanoiViet Nam Department of Chemistry Hanoi University of Mining and Geology18-Pho LienBac Tu LiemHanoiViet Nam Institute of Biotechnology Vietnam Academy of Science and Technology18-Hoang Quoc VietCau GiayHanoiViet Nam Duy Tan University K7/25 Quang TrungDa NangViet Nam

Upconversion nanophosphors are new promising nanomaterials to be used as biolabels for detection and imaging of cancer *** nanophosphors absorb long-wavelength excitation radiation in the infrared or near infrared region and emit shorter wavelength,higher energy radiation from ultraviolet to *** this paper,we studied the hydrothermal method and optical properties of the functionalized NaYF4:Yb^3+,Er^3+for biomedical *** synthesis,these NaYF4:Yb^3+,Er^3+nanophosphors were functionalized with aminosilanes and folic *** acid binds to the folate receptor on the surface of MCF-7 breast cancer cells and this binding promotes internalization of the nanophosphors via *** sizes of the functionalized NaYF4:Yb^3+,Er^3+@silica-N=FA(folic acid)nanophosphors can be controlled with length of the rod about 300-800 nm and diameter of the rod about 100-200 *** structure of NaYF4:Yb^3+,Er^3+is in hexagonal crystal *** photo luminescence(PL)spectra of the functionalized NaYF4:Yb^3+,Er^3+@silica-N=FA nanophosphors were *** nanophosphors emit in red color with the strongest band at 650 nm under 980 nm *** result can provide NaYF4:Er^3+,Yb^3+@silica-N=FA complex for developing fluorescence label and image tool in cancer biology and medicine.

关键词： Upconversion luminescence NaYF4:Yb^3+,Er^3+ Nanophosphors Bioimaging Cancer cell Rare earths

Push forward LC-MS-based therapeutic drug monitoring and pharmacometabolomics for anti-tuberculosis precision dosing and comprehensive clinical management

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Journal of Pharmaceutical Analysis 2024年第1期14卷 16-38页

作者： Nguyen Quang thu Nguyen tran Nam Tien Nguyen Thi Hai Yen thuc-Huy Duong Nguyen Phuoc Long Huy Truong Nguyen Department of Pharmacology and PharmacoGenomics Research Center Inje University College of MedicineBusan47392Republic of Korea Department of Chemistry University of EducationHo Chi Minh City700000Viet Nam Faculty of Pharmacy Ton Duc Thang UniversityHo Chi Minh City700000Viet Nam

The spread of tuberculosis(TB),especially multidrug-resistant TB and extensively drug-resistant TB,has strongly motivated the research and development of new anti-TB *** strategies to facilitate drug combinations,including pharmacokinetics-guided dose optimization and toxicology studies of first-and second-line anti-TB drugs have also been introduced and *** chromatography-mass spectrometry(LC-MS)has arguably become the gold standard in the analysis of both endo-and exo-genous *** technique has been applied successfully not only for therapeutic drug monitoring(TDM)but also for pharmacometabolomics *** improves the effectiveness of treatment,reduces adverse drug reactions,and the likelihood of drug resistance development in TB patients by determining dosage regimens that produce concentrations within the therapeutic target *** on TDM,the dose would be optimized individually to achieve favorable *** is essential in generating and validating hypotheses regarding the metabolism of anti-TB drugs,aiding in the discovery of potential biomarkers for TB diagnostics,treatment monitoring,and outcome *** article highlighted the current progresses in TDM of anti-TB drugs based on LC-MS bioassay in the last two ***,we discussed the advantages and disadvantages of this technique in practical *** pressing need for non-invasive sampling approaches and stability studies of anti-TB drugs was ***,we provided perspectives on the prospects of combining LC-MS-based TDM and pharmacometabolomics with other advanced strategies(pharmacometrics,drug and vaccine developments,machine learning/artificial intelligence,among others)to encapsulate in an all-inclusive approach to improve treatment outcomes of TB patients.

关键词： Tuberculosis Therapeutic drug monitoring LC-MS MIPD Pharmacometabolomics Precision medicine

Tungsten-based nanocatalysts with different structures for visible light responsive photocatalytic degradation of bisphenol A

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Journal of Environmental Sciences 2024年第5期139卷 569-588页

作者： Hai Bang Truong Thi thu Loan Doan Nguyen Tien Hoang Nguyen Van Tam Minh Kim Nguyen Le Gia Trung Jin Seog Gwag Nguyen Tien tran Optical Materials Research Group Science and Technology Advanced InstituteVan Lang UniversityHo Chi Minh CityViet Nam Faculty of Applied Technology School of TechnologyVan Lang UniversityHo Chi Minh CityViet Nam The University of Da Nang University of Science and Technology54 Nguyen Luong BangDa NangViet Nam The University of Da Nang University of Science and Education459 Ton Duc Thang St.Lien ChieuDa Nang 550000Viet Nam Institute of Veterinary Science and Technology 31ha zoneTrau QuyGia LamHa Noi 12400Viet Nam Department of Physics Yeungnam UniversityGyeongsanGyeongbuk 38541Republic of Korea Center for Advanced Chemistry Institute of Research and DevelopmentDuy Tan University03 Quang TrungDa Nang 550000Viet Nam Faculty of Natural Sciences Duy Tan University03 Quang TrungDa Nang 550000Viet Nam

Environmental pollution,such as water contamination,is a critical issue that must be absolutely ***,three different morphologies of tungsten-based photocatalysts(WO_(3)nanorods,WO_(3)/WS_(2)nanobricks,WO_(3)/WS_(2)nanorods)are made using a simple hydrothermal method by changing the solvents(H_(2)O,DMF,aqueous HCl solution).The as-prepared nanocatalysts have excellent thermal stability,large porosity,and high *** results show all materials have good photocatalytic activity in aqueous media,with WO_(3)/WS_(2)nanorods(NRs)having the best activity in the photodegradation of bisphenol A(BPA)under visible-light *** may originate from increased migration of charge carriers and effective prevention of electron–hole recombination in WO_(3)/WS_(2)NRs,whereby this photocatalyst is able to generate more reactive·OH and·O_(2)^(–)species,leading to greater photocatalytic *** 99.6% of BPA is photodegraded within 60 min when using 1.5 g/L WO_(3)/WS_(2)NRs and 5.0 mg/L BPA at pH ***,the optimal conditions(pH,catalyst dosage,initial BPA concentration)for WO_(3)/WS_(2)NRs are also elaborately *** rod-like heterostructures are expressed as potential catalysts with excellent photostability,efficient reusability,and highly active effectivity in different types of *** particular,the removal efficiency of BPA by WO_(3)/WS_(2)NRs reduces by only 1.5% after five recycling runs and even reaches 89.1%in contaminated lake *** study provides promising insights for the nearly complete removal of BPA from wastewater or different water resources,which is advantageous to various applications in environmental remediation.

关键词： Photodegradation Bisphenol A Tungsten-based nanocatalyst Structure Nanorod

Spiritual Forests—A Nature Conservation Model of Ethnic Minority Communities in Central Viet Nam

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Open Journal of Forestry 2024年第1期14卷 74-86页

作者： tran Huu Nghi Nguyen Quynh thu Tropenbos Viet Nam 149 Tran Phu Street Hue City Thua Thien Hue Province Viet Nam

This paper aims to analyze and evaluate a model of forest conservation and management of ethnic minority (or indigenous) people in central Vietnam, often referred to as the spiritual forest. These forests, called sacred forest or ghost forests by the ethnic minority people in thua Thien Hue province, have existed for a long time among forest residents. However, they have recently declined, both in quality and quantity, due to various factors, including changes in society, economy, environment, and perception, among other reasons. Based on research conducted in A Luoi district, thua Thien Hue province with household interviews, group discussions, and field surveys, we find that spiritual forest retains religious and human significance. They are also often among the last remaining natural forests left due to deforestation by human activities. The research results indicate challenges that conservation of spiritual forest may face, while giving recommendations derived from communities for sustainable forest development and conservation in the region.

关键词： Forest Conservation Ethnic Minority Spiritual Forest

Ntic and Teenagers in the South： Case of High-School Students in Recife, Aignan, and Hanoi

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Psychology Research 2017年第12期7卷 627-638页

作者： Elaine Magalhaes Costa Femandez tran thu huong Trinh Thi Linh Federal University of Pernambuco (UFPE) Recife Brazil University of Social Sciences and Humanities (USSH) of Hanoi Hanoi Vietnam

From the work on the Eurocentric critical thinking and on the territorialisation of the Internet, three researchers will present the theoretical and epistemological bases of an international research on the intercultural aspects of the impact of the New Technologies of Information and Communication (NTIC) on the process of socialization and subjectivation of high-school students from three continents. It will be the issues of a methodological triangulation based on the ecology of knowledge and the intercultural perspective, in the respect for the cultural context of the participants, their pluralities and particular isms. Online questionnaire consisting of 50 questions was developed in Portuguese in Brazil and translated according to the method of trans-cultural adaptation in French and then in Vietnamese. It will be a question of a critical analysis of the construction and validation of the instrument, its cross-cultural adaptations, as well as the method of result analysis through the Program Statistical Package for the Social Sciences (SPSS), the objective of which is to describe the modalities of use of social networks, and video games of high-school students in Hanoi. thus it is hoped to compare the characteristics of the population studied (number, age, schooling, and sexes), the rhythm and modalities of use of video games and social networks, the relationships between different members of the family and their peers, to the data of the other two populations studied. The parallel between the data obtained in Vietnam, France, and Brazil will contribute to the understanding on the part of the context and the cultural affiliation in the establishment of relationships between the users and the NTIC and consequently to the definition of the methods of prevention of risks more adapted to the realities of young people and their families.

关键词：中学生大小写南方少年社会科学视频游戏跨文化研究人员

Highly enhanced UV absorption and light emission of monolayer WS_(2)through hybridization with Ti_(2)N MXene quantum dots and g-C_(3)N_(4)quantum dots

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Opto-Electronic Advances 2024年第6期7卷 31-39页

作者： Anir S.Sharbirin Rebekah E.Kong Wendy B.Mato trang thu tran Eunji Lee Jolene W.P.Khor Afrizal L.Fadli Jeongyong Kim Department of Energy Science Sungkyunkwan UniversitySuwon 16419Republic of Korea

Two-dimensional(2D)transition metal dichalcogenides(TMD)are atomically thin semiconductors with promising optoelectronic applications across the visible ***,their intrinsically weak light absorption and the low photoluminescence quantum yield(PLQY)restrict their performance and potential use,especially in ultraviolet(UV)wavelength light *** dots(QD)derived from 2D materials(2D/QD)provide efficient light absorption and emission of which energy can be tuned for desirable light *** this study,we greatly enhanced the photon absorption and PLQY of monolayer(1L)tungsten disulfide(WS_(2))in the UV range via hybridization with 2D/QD,particularly titanium nitride MXene QD(Ti_(2)N MQD)and graphitic carbon nitride QD(GCNQD).With the hybridization of MQD or GCNQD,1LWS_(2)showed a maximum PL enhancement by 15 times with 300 nm wavelength excitation,while no noticeable enhancement was observed when the excitation photon energy was less than the bandgap of the QD,indicating that UV absorption by the QD played a crucial role in enhancing the light emission of 1L-WS_(2)in our 0D/2D hybrid *** findings present a convenient method for enhancing the photo-response of 1L-WS_(2)to UV light and offer exciting possibilities for harvesting UV energy using 1L-TMD.

关键词： monolayer TMD WS_(2) 2D-derived quantum dots UV absorption energy transfer