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Journal of Iron and Steel Research International 2022年第7期29卷 1063-1072页

作者： Qian Sun En-hui Wang Xin-mei Hou Zhi-jun He tong-xiang liang Collaborative Innovation Center of Steel Technology University of Science and Technology BeijingBeijing 100083China School of Material and Metallurgy University of Science and Technology LiaoningAnshan 114501LiaoningChina School of Materials Science and Engineering Jiangxi University of Science and TechnologyGanzhou 341000JiangxiChina

Calcium aluminate cement(CAC)is widely used as a binder for refractory materials,and thus the improvement in compressive strength is of vital importance for CAC applied at high *** this purpose,nano-Ca_(10)(PO_(4))_(6)(OH)_(2)additive with a ratio of 0.5–1.5 mass%was added with the water-cement ratio to be 0.4.X-ray diffraction and isothermal calorimetry analysis demonstrate that nano-Ca_(10)(PO_(4))_(6)(OH)_(2)additive can shorten the hydration process and promote the formation of main hydrates of CaAl2O4·10H2O(CAH10)and Ca2Al2O5·8H2O(C2AH8).In addition,scanning electron microscopy results suggest that nano-Ca_(10)(PO_(4))_(6)(OH)_(2)can protect CAH10 and C2AH8 from being destroyed during the calcination,guaranteeing that these thin lamellar crystals are intertwined to form the denser *** from above effects,nano-Ca_(10)(PO_(4))_(6)(OH)_(2)can obviously improve the compressive strength of the CAC mortar samples cured for 7 d after calcination at 1100°C,while the improving effect is dependent upon its ***,compared with the one without the additive,the compressive strength of the sample with 1.0%nano-Ca_(10)(PO_(4))_(6)(OH)_(2)is increased by 14%.

关键词： Nano-Ca_(10)(PO_(4))_(6)(OH)_(2) Cement Calcination Microstructure Compressive strength

Preparation and tribological behavior of electrodeposited Ni-W-GO composite coatings

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Rare Metals 2019年第7期38卷 695-703页

作者： Xue-Hui Zhang Xiao-Xian Li Wei-Jiang Liu Yu-Qi Fan Hao Chen tong-xiang liang School of Materials Science and Engineering Jiangxi University of Science and Technology Ganzhou 341000 China School of Metallurgy and Chemical Engineering Jiangxi University of Science and Technology Ganzhou 341000 China

Ni-W-GO composite coatings were successfully plated on 45# steel substrate by co-electrodeposition technique in a Ni-W electrolyte solution, with different contents of graphene oxide (GO) nanoparticles in suspen? sion. The structure, phase composition and surface morphology of as-plated composite coatings were characterized by Raman, X-ray diffraction (XRD), scanning electron microscopy (SEM) attached with energy disperse spectroscopy (EDS), respectively. The hardness and tribological behavior of the present coatings were also evaluated by Vickers Hardness tester and high-speed reciprocating friction and wear tester, and the wear mechanism was discussed as well. The results show that layer-structured GO nanoparticles significantly affect the microstructure and grain size of the Ni-W-GO composite coatings. Meanwhile, GO nanoparticles embedded in Ni- W-GO coatings can obviously improve the hardness and wear resistance in comparison with the corresp on ding Ni- W coatings. The highest microhardness and wear resistance of Ni-W-GO composite coatings are obtained with 0.15 g·L^-1 GO employing.

关键词： Ni-W-GO composite coatings Graphene oxide Electrodeposition Microstructure Tribological behavior Microhardness

Constructing Z-schemeβ-Bi_(2)O_(3)/ZrO_(2)heterojunctions with 3D mesoporous SiO_(2)nanospheres for efficient antibiotic remediation via synergistic adsorption and photocatalysis

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Rare Metals 2022年第6期41卷 2094-2107页

作者： Chong Xu Qin Zhou Wei-Ya Huang Kai Yang Yong-Cai Zhang tong-xiang liang Zhao-Qing Liu Faculty of Materials Metallurgical and ChemistryJiangxi University of Science and TechnologyGanzhou 341000China School of Chemisiry and Chemical Engineering Yangzhou UniversityYangzhou 225009China College of Rare Eaths Jiangxi University of Science and TechnologyGanzhou 341000China School of Chemistry and Chemical Engineering/Institute of Clean Energy and Materials.Guangzhou Key Laboratory for Clean Energy and Materials/Huangpu Hydrogen Innovation Center Guangzhou UniversityGuangzhou 510006China

A series of Z-schemeβ-Bi_(2)O_(3)/ZrO_(2)hetero-junction composites containing three-dimensional(3D)mesoporous silica nanospheres(MSNs)were synthesized as efficient catalysts for antibiotic *** obtained MSN/β-Bi_(2)O_(3)/ZrO_(2)ternary composites possess novel lamellar cross structure,which is well constructed byβ-Bi_(2)O_(3)nanosheets,3D MSNs,and ZrO_(2)*** optimal sample BZS-2(Bi∶Zr∶Si=1∶0.4∶0.33)shows an adsorptive-photocatalytic removal efficiency of 92.7%towards levofloxacin(LVF)and a total organic carbon(TOC)removal efficiency of 60.0%under simu-lated solar light irradiation for 100 ***-2 can also remove 90.1%and 91.2%of tetracycline hydrochloride(TC)and oxytetracycline hydrochloride(OTC),respectively,and themaximum adsorptioncapacityof TCover BZS-2is almost 10 times that *** ofphotocatalytic activitycan bemainly attributed to the enhanced visible-light adsorption capacity and more efficientseparationof photogenerated electron-hole pairs.A possible Z-scheme photocatalytic mechanism of p BiO/ZrOheterojunctions based on valence band offset(AEvBo)andconduction band offset(EcBo)*** study provides an efficient way to construct novel mesoporous ternary photocatalyst with increased accessible surface area and active sites for treatment of antibiotics by synergistic adsorption and photocatalysis.

关键词： Mesoporous silica nanospheres β-Bi_(2)O_(3) ZiO_(2) Adsorption Photoc atalysis

First principles study of post-boron carbide phases with icosahedra broken

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Chinese Physics B 2020年第10期29卷 214-221页

作者： Ming-Wei Chen Zhao liang Mei-Ling Liu Uppalapati Pramod Kumar Chao Liu tong-xiang liang Faculty of Materials Metallurgy and Chemistry Jiangxi University of Science and TechnologyGanzhou 341000China

Boron carbide (B4C) is a rhombic structure composed of icosahedra and atomic chains, which has an important application in armored materials. The application of B4C under super high pressure without failure is a hot spot of research. Previous studies have unmasked the essential cause of B4C failure, i.e., its structure will change subjected to impact, especially under the non-hydrostatic pressure and shear stress. However, the change of structure has not been clearly understood nor accurately determined. Here in this paper, we propose several B4C polymorphs including B4C high pressure phases with non-icosahedra, which are denoted as post-B4C and their structures are formed due to icosahedra broken and may be obtained through high pressure and high temperature (HPHT). The research of their physical properties indicates that these B4C polymorphs have outstanding mechanical and electrical properties. For instance, aP10, mC10, mP20, and oP10-B4C are conductive superhard materials. We hope that our research will enrich the cognition of high pressure structural deformation of B4C and broaden the application scope of B4C.

关键词： boron carbide structural transformation icosahedra broken physical properties first principles

Framework for Preventive Control of Power Systems to Defend Against Extreme Events

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CSEE Journal of Power and Energy Systems 2024年第2期10卷 856-870页

作者： Yuwei xiang tong Wang Zengping Wang State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources North China Electric Power UniversityBeijing 102206China

Enhancing power system resilience against extreme events is becoming increasingly critical. This paper discusses a unified framework for preventive control of power systems to enhance system resilience, which includes three parts: resilience assessment, resilience grading, and resilience enhancement. First, the resilience assessment contains facility-level and system-level resilience assessment. The concept of fragility curve is used in the facility-level resilience assessment. Various resilience indices are developed in system-level resilience assessment to roundly depict the impacts of extreme events on power systems and determine the system resilience. On this basis, the resilience is divided into different levels by resilience grading strategy, which can efficiently quantify the severity of the impact of extreme events and provide decision-making for the resilience enhancement strategies. Then, control strategies for enhancing power system resilience are also divided according to different resilience levels. A controlled islanding based preventive control is proposed to enhance system resilience, which aims to strengthen the first defensive line of power systems to deal with extreme events. Finally, taking the typhoon disaster in extreme events as an example, two tests carried out with two typhoons demonstrate the efficiency of the proposed method.

关键词： Controlled islanding extreme events power system resilience preventive control

Cyclohexanol optimizes Pt/ionomer interface in fuel cell cathodes

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Science China Chemistry 2024年第2期67卷 417-419页

作者： Lei tong Hai-Wei liang Hefei National Research Center for Physical Sciences at the Microscale Department of ChemistryUniversity of Science and Technology of ChinaHefei230026China

This highlight is based on a recent article published in Nature Catalysis, in which Wei's group [1] from Chongqing University proposes a novel approach to enhance the performance of proton exchange membrane fuel cells(PEMFCs)by adjusting the interface between Pt and ionomer in the cathode catalyst layer. Their strategy involves adding cyclohexanol to the cathode catalyst ink to impede the adsorption of sulfonate groups from the ionomer onto Pt nanoparticles, which results in the release of Pt activity sites and a significant improvement in the mass transport efficiency.

关键词： interface catalyst adding

d-Orbital steered FeN_(4)moiety through N,S dual-site adjustation for zinc-air flow battery

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Journal of Energy Chemistry 2024年第5期92卷 8-15页

作者： Chunzhu Bao Mingwei tong Xueli Li Zhonghua xiang State Key Laboratory of Organic-Inorganic Composites Beijing University of Chemical TechnologyBeijing 100029China

The implementation of pristine covalent organic polymer(CO_(2)P)with well-defined structure as air electrode may spark fresh vitality to rechargeable zinc-air flow batteries(ZAFBs),but it still remains challenges in synergistically regulating their electronic states and structural porosity for the great device ***,we conquer these issues by exploiting N and S co-doped graphene with COP rich in metal-ligand nitrogen to synergistically construct an effective catalyst for oxygen reduction reaction(ORR).Among them,the N and S co-doped sites with high electronegativity properties alter the number of electron occupations in the d orbital of the iron centre and form electron-transfer bridges,thereby boosting the selectivity of the ORR-catalysed four-electron ***,the introduction of COP materials aids the formation of pore interstices in the graphene lamellae,which both adequately expose the active sites and facilitate the transport of reactive *** from the synergistic effect,as-prepared catalyst exhibits excellent half-wave potentials(E_(1/2)=912 mV)and stability(merely 8.8%drop after a long-term durability test of 50000 s).Further,ZAFBs assembled with the N/SG@CO_(2)P catalyst demonstrate exceptional power density(163.8 mW cm^(-2))and continuous charge and discharge for approximately 140 h at 10 mA cm^(-2),outperforming the noble-metal benchmarks.

关键词： Nitrogen/sulfurdual sites Metal-coordinated nitrogen sites Covalent organic polymer Oxygen reduction reaction Zn-airflow battery

Securing offshore resources development: A mathematical investigation into gas leakage in long-distance flexible pipes

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Petroleum Science 2024年第4期21卷 2734-2744页

作者： xiang-An Lu liang-liang Jiang Jian-Sheng Zhang Min-Gui Wang Guangling College of Yangzhou University Department of Chemical and Petroleum Engineering University of Calgary Department of Energy and Power Engineering Tsinghua University

Gas flexible pipes are critical multi-layered equipment for offshore oil and gas development. Under high pressure conditions, small molecular components of natural gas dissolve into the polymer inner liner of the flexible pipes and further diffuse into the annular space, incurring annular pressure build-up and/or production of acidic environment, which poses serious challenges to the structure and integrity of the flexible pipes. Gas permeation in pipes is a complex phenomenon governed by various factors such as internal pressure and temperature, annular structure, external temperature. In a long-distance gas flexible pipe, moreover, gas permeation exhibits non-uniform features, and the gas permeated into the annular space flows along the metal gap. To assess the complex gas transport behavior in long-distance gas flexible pipes, a mathematical model is established in this paper considering the multiphase flow phenomena inside the flexible pipes, the diffusion of gas in the inner liner, and the gas seepage in the annular space under varying permeable properties of the annulus. In addition, the effect of a variable temperature is accounted. A numerical calculation method is accordingly constructed to solve the coupling mathematical equations. The annular permeability was shown to significantly influence the distribution of annular pressure. As permeability increases, the annular pressure tends to become more uniform, and the annular pressure at the wellhead rises more rapidly. After annular pressure relief followed by shut-in, the pressure increase follows a convex function. By simulating the pressure recovery pattern after pressure relief and comparing it with test results, we deduce that the annular permeability lies between 123 and 512 m D. The results help shed light upon assessing the annular pressure in long distance gas flexible pipes and thus ensure the security of gas transport in the emerging development of offshore resources.

关键词： Offshore resources development Transport security Long-distance flexible pipes Gas leakage Heat and mass transfer model Finite difference calculation

Efficacy of ginseng-based Renshenguben oral solution for cancer-related fatigue among patients with advanced-stage hepatocellular carcinoma:A prospective multicenter cohort study

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Hepatobiliary & Pancreatic Diseases International 2024年第3期23卷 249-256页

作者： Ming-Da Wang Chen Yuan Ke-Chun Wang Nan-Ya Wang Ying-Jian liang Hong Zhu xiang-Min tong Tian Yang Department of Hepatobiliary and Pancreatic Surgery General Surgery CenterFirst Hospital of Jilin UniversityChangchun 130021China Department of Hepatobiliary Surgery Eastern Hepatobiliary Surgery HospitalSecond Military Medical University(Naval Medical University)Shanghai 200438China Department of Clinical Laboratory Laboratory Medicine CenterZhejiang Provincial People’s HospitalHangzhou Medical CollegeHangzhou 310000China Department of Hepatobiliary Surgery First Affiliated Hospital of Harbin Medical UniversityHarbin 150007China Department of Medical Oncology First Affiliated Hospital of Soochow UniversitySuzhou 215006China fDepartment of Central Laboratory Affiliated Hangzhou First People’s HospitalWestlake University School of MedicineHangzhou 310006China

Background:Cancer-related fatigue(CRF)is a common and debilitating symptom experienced by patients with advanced-stage cancer,especially those undergoing antitumor *** study aimed to evaluate the efficacy and safety of Renshenguben(RSGB)oral solution,a ginseng-based traditional Chinese medicine,in alleviating CRF in patients with advanced hepatocellular carcinoma(HCC)receiving antitumor ***:In this prospective,open-label,controlled,multicenter study,patients with advanced HCC at BCLC stage C and a brief fatigue inventory(BFI)score of≥4 were *** were assigned to the RSGB group(RSGB,10 mL twice daily)or the control group(with supportive care).Primary and secondary endpoints were the change in multidimensional fatigue inventory(MFI)score,and BFI and functional assessment of cancer therapy-hepatobiliary(FACT-Hep)scores at weeks 4 and 8 after *** events(AEs)and toxicities were ***:A total of 409 participants were enrolled,with 206 assigned to the RSGB *** week 4,there was a trend towards improvement,but the differences were not statistically *** week 8,the RSGB group exhibited a significantly lower MFI score(P<0.05)compared to the control group,indicating improved fatigue ***,the RSGB group showed significantly greater decrease in BFI and FACT-Hep scores at week 8(P<0.05).Subgroup analyses among patients receiving various antitumor treatments showed similar *** linear regression analyses revealed that the RSGB group experienced a significantly substantial decrease in MFI,BFI,and FACT-Hep scores at week *** serious drug-related AEs or toxicities were ***:RSGB oral solution effectively reduced CRF in patients with advanced HCC undergoing antitumor therapy over an eight-week period,with no discernible *** findings support the potential of RSGB oral solution as an adjunctive treatment for managing CRF in this patient population.

关键词： Cancer-related fatigue Hepatocellular carcinoma Renshenguben oral solution Efficacy Safety Ginseng

Critical observability of partially observed discrete event systems under cyber attacks

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Science China(Information Sciences) 2024年第2期67卷 333-334页

作者： Liyun tong Jinling liang Yang LIU Department of Mathematics School of SciencesHangzhou Dianzi University School of Mathematics Southeast University College of Mathematics and Computer Science Zhejiang Normal University

The discrete event system(DES) is a dynamic system driven by asynchronous/sudden events and has been widely used in many critical infrastructures, such as electric transportation networks and intelligent transportatio...

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