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Formulation of Motor Oil from Blends of Rubber Latex Cup Bottom Oil (RLBO) and Used Frying Oil (UFO)

Journal of Sustainable Bioenergy Systems 2024年第3期14卷 35-43页

作者： kona. Edmond Kouassi Abollé Abolle Dogafolô Soro tindo sylvie kona. David Boa Kouassi Benjamin Yao Laboratoire de Thermodynamique et Physico-Chimie du Milieu (LTPCM) UFR-SFA UNA Abidjan Cte dIvoire Laboratoire des Procds Industriels de synthse de lEnvironnement et des Energies nouvelles (LAPISEN) de lInstitut National Polytechnique Flix Houphout Boigny de Yamoussoukro Yamoussoukro Cte dIvoire

Most motor oils are made from mineral oils derived from petroleum, the reserves of which are limited and exhaustible. The aim of this study is to produce and characterize motor oil formulations based on mixtures of rubber latex cup bottom oil (RLCBO) and used frying oil (UFO). The results show that these formulations have a density between 0.91 and 0.92. These densities evolve linearly with the proportion of cup bottom oil and temperature. Similarly, the kinematic viscosity of the blends follows an exponential relationship with temperature. By plotting the logarithm of these kinematic viscosities against the inverse of the temperature, we were able to determine the activation energy of the various blends and deduce that the formulations behave Newtonian.

关键词： Formulation Oils Blend Motor Oils Latex Bottoms Oil

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Physical and Chemical Characterizations of Rubber Latex Cup Bottom Oil

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Advances in Bioscience and Biotechnology 2024年第9期15卷 511-521页

作者： Kouassi kona. Edmond Abolle Abollé Aketchi Tanoé Lucien kona. Affoué tindo sylvie Boa David Yao Kouassi Benjamin Laboratoire de Thermodynamique et Physico-Chimie du Milieu (LTPCM) Unit de Formation et de Recherche Sciences Fondamentales et Appliques Universit Nangui Abrogoua Abidjan Cte dIvoire Laboratoire des Procds Industriels de synthse de lEnvironnement et des Energies Nouvelles (LAPISEN) de lInstitut National Polytechnique Flix Houphout Boigny de Yamoussoukro Yamoussoukro Cte dIvoire

Rubber latex is an important economic resource. However, the residues from its harvesting are thrown away, even though they contain lipids that can be recycled. This recovery of the residues from the bottom of the cup requires first and foremost their characterization. The aim of this study is therefore to determine the main physical and chemical characteristics of rubber latex cup bottom oil. Oil’s physical parameters determination shows that it has a density of 951 kg∙m−3, a kinematic viscosity of 48.57 cSt and a water content of 0.0845%. Chemical parameters, meanwhile, indicate that this cup bottom residue has a fat content of 95.96%, an acid number of 2.805 mg KOH/g and an iodine number of 92.42 g I2/100g. Therefore, rubber latex cup bottom oil can be used in the formulation of biofuels, biolubricants, paints, varnishes, alkyd resins, polishing oils, soaps, and insecticides.

关键词： Rubber Latex Cup Bottoms Oil Density Viscosity Characterizations

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Abundance and Source Identification of Polycyclic Aromatic Hydrocarbons in Sediments of the Ivory Coastal Zone (Toukouzou Hozalem-Assinie)

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American Journal of Analytical Chemistry 2023年第1期14卷 12-27页

作者： Laure Emma Oura Vanh Eric-Simon Zran Georges Kouadio Horo Koné Affoué tindo sylvie kona. Albert Trokourey Kouassi Benjamin Yao Fofana Bakary Laboratoire des Procédés Industriels de Synthèse de l’Environnement et des Energies Nouvelles (LAPISEN) de l’Institut National Polytechnique Félix Houphouë t Boigny de Yamoussoukro Yamoussoukro C&ocirc te d’Ivoire Centre Analyses et Recherche (CAR) Petroci Holding Abidjan C&ocirc te d’Ivoire Laboratoire de Constitution et Réaction de la Matière (LCRM) Université Félix Houphouet Boigny Abidjan Cote d’Ivoire Department of Science and Technology Université Alassane Ouattara de Bouaké Bouaké C&ocirc te d’Ivoire Laboratoire de Thermodynamique et de Physico Chimie du Milieu Université Nangui Abrogoua Abidjan C&ocirc te d’Ivoire Centre D’Analyse et de Recherche de la PETROCI (DCAR) Cô te d’Ivoire. Immeuble les Hevéas-14 Bd Carde Abidjan Cote d’Ivoire

Polycyclic aromatic hydrocarbons (PAHs) are strongly associated with agricultural, residential, transportation, industrial and petroleum activities. In this study, the presence of PAHs (polycyclic aromatic hydrocarbons) was investigated in sediments of the ivory coastal zone (Toukouzou Hozalem-Assinie). The main objectives of this study were to determine the abundance and to predict the source of PAHs in the sediments. Gas chromatography-mass spectrometry (GC-MS) was used to analyze sixteen priority PAHs. Total PAHs concentrations were from 1.31 to 3992.68 mg/kg in sediment with an average concentration of (307.54 ± 16.10) mg/kg. Among all PAHs, Naphthalene (Nap = 332.72 mg/kg) and Phenanthrene (Phe = 41.75 mg/kg) were found in the highest concentration, whereas Benzo (k) Fluoranthene was found in the least concentration in the range of 0 - 0.85 mg/kg (mean 0.24 mg/kg). Bassam-Modeste Lagune (BML) sampling site was the site with the highest concentration of total PAHs (all 16 PAHs) compared to the others due to their location in a highly populated estuary area that receives commercial, tourism, port, petroleum and heavy industrial activities. Diagnostic ratios were used to determine the sources of PAHs and suggested that the PAH profile in the sediments was dominated by 2 and 3 ring PAHs. The patterns of PAH compounds in sediment indicated that contamination is from mixed sources, with a strong indication of petrogenic contamination potentially from spills of fuel, oil and industrial activities.

关键词： Polycyclic Aromatic Hydrocarbons Sediment Source Abundance Ivorian Coastal

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Dimensioning of an Anaerobic Digester for the Treatment of Chicken Manure and for the Production of Biogas: The Case Study of a Chicken Farm in Yaokokoroko (Côte d’Ivoire)

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Green and Sustainable Chemistry 2022年第4期12卷 91-103页

作者： Kouakou Adjoumani Rodrigue Ehouman Ahissan Donatien kona. Affoué tindo sylvie Teki Adjoba Marie-Emmanuelle Kouadio Marc Cyril Adou Kouakou Eric kona. Gbangbo Remis Laboratoire de Thermodynamique et de Physico-Chimie du Milieu (LTPCM) UFR Sciences Fondamentales Appliquées Université Nangui Abrogoua Abidjan C&#244 te d’Ivoire Département de Formation et de Recherche des Sciences de la Terre et des Ressources Minières Ressources en Eaux et Risques Hydrologiques Institut National Polytechnique Felix Houphou&#235 t-Boigny Yamoussoukro C&#244 te d’Ivoire Institut de Recherche sur les Energies Nouvelles Université Nangui Abrogoua Abidjan C&#244 te d’Ivoire Laboratoire des Procédés Industriels de Synthèse de l’Environnement et des énergies Nouvelles (LAPISEN) Institut National Polytechnique Houphou&#235 t-Boigny Yamoussoukro C&#244 te d’Ivoire

This study allowed us to highlight the level of pollution of a BAYA River water near several poultry farms and the sizing of an anaerobic digester that will be able to treat chicken manure from a poultry farm (BRIN FOUNDATION). To evaluate this pollution, the parameters such as ammonium (NH4+), Phosphate (PO43-), Biochemical Oxygen Demand (DBO5) and Nitrate (NO3-) were determined. For sampling point P1, the concentrations in mg/L of these parameters are (25.00 ± 4.25), (0.40 ± 0.20), (98.00 ± 6.35) and (96.00 ± 5.35), respectively. On the other hand, for sampling point P2, the concentrations in mg/L of these parameters are respectively (33.00 ± 9.05), (0.70 ± 0.12), (123 ± 7.13) and (93 ± 7.10). These values indicate a strong organic pollution of the BAYA River. The determination of the different concentrations of the organic pollution parameters allowed us to evaluate the degradation and the quality of the water of the BAYA River water, by the poultry activity. However, considering the physicochemical properties of the waste (chicken manure), which is the main source of organic pollution, we have considered an energy recovery through the production of biogas. This requires the design, sizing, and implementation of an anaerobic digester in a poultry farm. Therefore, the project would require the construction of an adapted masonry type anaerobic digester with a capacity of 10 m3.

关键词： Biogas Organic Pollution Surface Water Biodigester Chicken Manure Anaerobic Digestion

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