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Forced boiling of nonazeotropic immiscible mixture in a supercapillary microchannel array for ultra-high heat flux removal with chip junction temperature below 85℃

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Science China(Technological Sciences) 2024年第5期67卷 1364-1380页

作者： SUN Bo BAO YuChen tian Tong LI Ji School of Engineering Science University of Chinese Academy of SciencesBeijing100049China Laboratory of Advanced Thermal Management Technologies School of Engineering ScienceUniversity of Chinese Academy of SciencesBeijing100049China

In this study,a structure-optimized two-phase microchannel heat sink with sintered submicron nucleation sites was developed and *** copper-based microchannels had a rectangular cross-section with an equivalent hydraulic diameter of 222μ*** subcooled flow boiling characteristics were comprehensively compared between pure HFE-7100 and a non-azeotropic,immiscible binary mixture of HFE-7100 and water,considering heating areas of 1 and 5 cm^(2).The total heating power input to the test section were 100–1500 and 250–3000 w for a 1 and 5 cm^(2)heat source,respectively,with a flow rate ranging from 50 to150 L/*** to pure HFE-7100,the non-azeotropic immiscible binary mixture of HFE-7100/water in the sintered porous microchannels exhibited a much higher overall heat transfer coefficient and lower power *** maintain the junction temperature of a high power electronic chip below 85℃,the proposed supercapillary microchannel heat sink could effectively dissipate the heat flux of 1275 w/cm^(2)over 1 cm^(2)heat source and 500 w/cm^(2)over 5 cm^(2)heat *** addition,the volume ratio of the binary mixture strongly influence the two-phase flow heat transfer *** optimal volume ratio exist in terms of the thermal resistance–pumping power minimization(HFE-7100:water=2:8 is recommended in this study).The findings of this investigation on the flow boiling properties of non-azeotropic immiscible mixtures help fill a gap in the related field.

关键词： microchannel sintered powder coating submicron nucleation cavities nonazeotropic immiscible ultra-high heat flux

Hollow Metal-Organic Framework/MXene/Nanocellulose Composite Films for Giga/Terahertz Electromagnetic Shielding and Photothermal Conversion

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Nano-Micro Letters 2024年第9期16卷 161-179页

作者： tian Mai Lei Chen Pei‑Lin w.ng Qi Liu Ming‑Guo Ma Research Center of Biomass Clean Utilization MOE Engineering Research Center of Forestry Biomass Materials and BioenergyBeijing Key Laboratory of Lignocellulosic ChemistryCollege of Materials Science and TechnologyBeijing Forestry UniversityBeijing 100083People’s Republic of China State Silica-Based Materials Laboratory of Anhui Province Bengbu 233000People’s Republic of China

with the continuous advancement of communication technology,the escalating demand for electromagnetic shielding interference(EMI)materials with multifunctional and wideband EMI performance has become *** the electrical and magnetic components and designing the EMI material structure have attracted extensive interest,but remain a huge ***,we reported the alternating electromagnetic structure composite films composed of hollow metal-organic frameworks/layered MXene/nanocellulose(HMN)by alternating vacuum-assisted filtration *** HMN composite films exhibit excellent EMI shielding effectiveness performance in the GHz frequency(66.8 dB at Kaband)and THz frequency(114.6 dB at 0.1-4.0 THz).Besides,the HMN composite films also exhibit a high reflection loss of 39.7 dB at 0.7 THz with an effective absorption bandwidth up to 2.1 ***,HMN composite films show remarkable photothermal conversion performance,which can reach 104.6℃under 2.0 Sun and 235.4℃under 0.8 w cm^(−2),*** unique micro-and macrostructural design structures will absorb more incident electromagnetic waves via interfacial polarization/multiple scattering and produce more heat energy via the local surface plasmon resonance *** features make the HMN composite film a promising candidate for advanced EMI devices for future 6G communication and the protection of electronic equipment in cold environments.

关键词： Metal-organic frameworks MXene Nanocellulose Electromagnetic shielding Photothermal conversion

Optoelectronic Synapses Based on MXene/Violet Phosphorus van der waals Heterojunctions for Visual‑Olfactory Crossmodal Perception

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Nano-Micro Letters 2024年第6期16卷 38-52页

作者： Hailong Ma Huajing Fang Xinxing Xie Yanming Liu He tian Yang Chai Center for Advancing Materials Performance From the Nanoscale(CAMP‑Nano) State Key Laboratory for Mechanical Behavior of MaterialsXi’an Jiaotong UniversityXi’an 710049People’s Republic of China Institute of Microelectronics and Beijing National Research Center for Information Science and Technology(BNRist) Tsinghua UniversityBeijing 100084People’s Republic of China Department of Applied Physics The Hong Kong Polytechnic UniversityHong KongPeople’s Republic of China

The crossmodal interaction of different senses,which is an important basis for learning and memory in the human brain,is highly desired to be mimicked at the device level for developing neuromorphic crossmodal perception,but related researches are ***,we demonstrate an optoelectronic synapse for vision-olfactory crossmodal perception based on MXene/violet phosphorus(VP)van der waals *** from the efficient separation and transport of photogenerated carriers facilitated by conductive MXene,the photoelectric responsivity of VP is dramatically enhanced by 7 orders of magnitude,reaching up to 7.7 A w^(−1).Excited by ultraviolet light,multiple synaptic functions,including excitatory postsynaptic currents,pairedpulse facilitation,short/long-term plasticity and“learning-experience”behavior,were demonstrated with a low power ***,the proposed optoelectronic synapse exhibits distinct synaptic behaviors in different gas environments,enabling it to simulate the interaction of visual and olfactory information for crossmodal *** work demonstrates the great potential of VP in optoelectronics and provides a promising platform for applications such as virtual reality and neurorobotics.

关键词： Violet phosphorus MXene Van der waals heterojunctions Optoelectronic synapses Crossmodal perception

Polyoxometalates coupled covalent organic frameworks as highly active photothermal nanoreactor for CO_(2)cycloaddition

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Nano Research 2024年第7期17卷 5975-5984页

作者： tian w.ng Yunqing Zhu wei w.ng Junfeng Niu Zhiyi Lu Peilei He School of Environmental Science and Engineering Shaanxi University of Science and TechnologyXi’an 710021China Key Laboratory of Advanced Fuel Cells and Electrolyzers Technology of Zhejiang Province Ningbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo 315201China College of Environmental Science and Engineering North China Electric Power UniversityBeijing 102206China University of Chinese Academy of Sciences Beijing 100049China

Covalent organic frameworks(COFs)-based nanoreactors have attracted broad interest in many fields due to their voidconfinement ***,the inherent drawback of conventional nanoreactors is the lack of internal active sites,which limits their widespread ***,we report the construction of hierarchical COF(EB-TFP)nanoreactor with pre-synthesized polyoxometalates(POM,[PV_(2)w_(10)O_(40)]^(5–)(PV_(2)w_(10)))clusters encapsulated inside of COF(POM@COF).PV_(2)w_(10)@EB-TFP anchors nucleophilic-group(Br–ions)and PV_(2)w_(10)anion cluster within the COF framework via electrostatic interactions,which not only simplifies the reaction system but also enhances catalytic *** reaction performance of the PV_(2)w_(10)@EB-TFP nanoreactor can be tuned to achieve excellent catalytic activity in CO_(2)cycloaddition reaction(CCR)for~97.63%conversion and~100%selectivity under visible light irradiation.A mechanistic study based on density functional theory(DFT)calculations and insitu characterization was also carried *** summary,we have reported a method for achieving the uniform dispersion of POM single clusters into COF nanoreactor,demonstrating the potential of POM@COF nanoreactor for synergistic photothermal catalytic CO_(2)cycloaddition.

关键词： photothermal nanoreactor CO_(2)cycloaddition polyoxometalate photothermal-synergistic catalysis covalent organic frameworks

The impact of broad glutamine metabolism inhibition on the tumor microenvironment

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Genes & Diseases 2024年第3期11卷 2-4页

作者： tianhe Li Yun-Ta Chuang tian-Li w.ng Departments of Pathology Oncologyand Gynecology and ObstetricsThe Sidney Kimmel Comprehensive Cancer CenterJohns Hopkins University School of MedicineBaltimoreMD 21231USA

Glutamine is an importantα-amino acid that provides carbon and nitrogen sources for the biosynthesis of nucleotides,proteins,and *** also generates metabolites that fuel the tricarboxylic acid cycle and maintain intracellular redox *** cells have a heightened metabolic dependence on glutamine to support incessant tumor growth and mitigate tumor microenvironmental stresses including hypoxia,nutrient depletion.

关键词： metabolism tumor microenvironment

Optimizing electronic structure of Mo_(2)TiC_(2)T_(x) MXene through Nb doping for enhanced electrochemical performance

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Nano Research 2024年第8期17卷 7174-7181页

作者： Jingyuan Zhao wenzheng Yan Zhaoxi Liu Xiaobin Liu Yapeng tian Xinwei Cui Henan Institute of Advanced Technology College of Materials Science and EngineeringZhengzhou UniversityZhengzhou 450003China College of Physics and Electronic Information Engineering Guilin University of TechnologyGuilin 514004China

MXene is a promising electrode material for both high volumetric capacitance and high-rate performance in ***,the current study has mainly focused on the monometallic element Ti_(3)C_(2)T_(x) MXene until now,while the bimetallic and multimetallic MXene have received comparatively less *** this work,we demonstrate that the electronic structure of the Mo_(2)TiC_(2)T_(x) MXene could be regulated by fine-tuning the content of doped Nb *** enhanced electron cloud density of surface–O termination and the electron spin of the Mo atoms in the Mo_(2)TiC_(2)T_(x) MXene,leads to the boost of electric double-layer capacitor(EDLC)and improvement of *** a consequence,the electrochemical performance of Nb-doped Mo_(2)TiC_(2)T_(x) MXene(Nb-0.3-MXene)demonstrates a capacitance of 398 F·cm^(−3),roughly doubling that of the pristine Mo_(2)TiC_(2)T_(x) MXene electrode at 197 F·cm^(−3) in the 3 M H_(2)SO_(4) *** the same time,the Nb-0.3-MXene could even maintain a capacitance of 82.75% at 200 mV·s−1,with high cyclic stability for 19,000 cycles at 10 A·g−***,Nb-0.3-MXene-based hybrid supercapacitors deliver a remarkable volumetric energy density of 48.1 w·h·L^(−1)at 230.7 w·L^(−1),and 34.4 w·h·L^(−1)at a high power density of 82.6 kw·L^(−1).There exists a balance between the volumetric capacitance and rate performance with different ratios of Nb atoms in the Nb-doped MXene due to the strong interaction between the Nb-doped MXene and the intercalated ***,optimizing the electronic structure of MXene through heteroatom doping is of great potential for enhanced supercapacitor performance.

关键词： niobium doping electronic structure Mo_(2)TiC_(2)T_(x)MXene electron spin rate performance volumetric capacitance

Deformation of Rigid Conjugate Self-dual Galois Representations

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Acta Mathematica Sinica,English Series 2024年第7期40卷 1599-1644页

作者： Yi Feng LIU Yi Chao tian Liang XIAO wei ZHAng Xin wen ZHU Institute for Advanced Study in Mathematics Zhejiang UniversityHangzhou 310058P.R.China Morningside Center of Mathematics AMSSChinese Academy of SciencesBeijing 100190P.R.China New Cornerstone Lab Beijing International Center for Mathematical ResearchPeking Ui Beijing 100871P.R.China Department of Mathematics Massachusetts Institute of TechnologyCambridge MA 02139United States Department of Mathematics Stanford UniversityStanfordCA 94305United States

In this article,we study deformations of conjugate self-dual Galois *** study is ***,we prove an R=T type theorem for a conjugate self-dual Galois representation with coefficients in a finite field,satisfying a certain property called ***,we study the rigidity property for the family of residue Galois representations attached to a symmetric power of an elliptic curve,as well as to a regular algebraic conjugate self-dual cuspidal representation.

关键词： Galois deformation rigid conjugate self-dual Galois representations

Understanding the cooperative effects in the catalysis of homodimeric fluoroacetate dehalogenase

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Science China Chemistry 2024年第7期67卷 2382-2391页

作者： Ke-wei Chen Jia-Nan Chen Jun Zhang Chao w.ng tian-Yu Sun Yun-Dong wu Key Laboratory of Computational Chemistry and Drug Design State Key Laboratory of Chemical OncogenomicSchool of Chemical Biology and BiotechnologyPeking University Shenzhen Graduate SchoolShenzhen 518055China Institute of Chemical Biology Shenzhen Bay LaboratoryShenzhen 518132China College of Chemistry and Molecular Engineering Peking UniversityBeijing 100871China Changping Laboratory Beijing 102200China

Fluoroacetate dehalogenases(FAcD),a homodimeric enzyme,catalyzes the conversion of fluoroacetic acid to glycolic acid(GoA).It has been proved that the enzyme has a half-of-the-site ***,its catalytic(C)subunit converts the first substrate to a covalent intermediate;then,the non-catalytic(NC)subunit binds a second substrate and promotes the conversion of the intermediate in the C subunit into the final *** the release of the product,the C subunit becomes the NC subunit,and the previous NC subunit becomes the C *** elucidate the detailed mechanism behind this cooperative catalysis,we have conducted microsecond-scale MD simulations along the reaction *** simulations indicate that the substrate in the NC subunit induces w185 and Y141 adopting an open conformation in the C *** opening of w185(C)facilitates the entry of catalytic water,enhancing the catalytic activity for product formation,while the opening of Y141(C)creates an unfavorable environment for product binding,promoting its *** interaction network analysis reveals that the substrate in the NC subunit can induce conformational changes through a conserved water chain at the interface.

关键词： enzyme catalysis molecular dynamics cooperative effect pre-reaction state

High-throughput calculations combining machine learning to investigate the corrosion properties of binary Mg alloys

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Journal of Magnesium and Alloys 2024年第4期12卷 1406-1418页

作者： Yaowei w.ng tian Xie Qingli Tang Mingxu w.ng Tao Ying Hong Zhu Xiaoqin Zeng University of Michigan-Shanghai Jiao Tong University Joint Institute Shanghai Jiao Tong University200240ShanghaiChina State Key Laboratory of Metal Matrix Composites Shanghai Jiao Tong UniversityShanghai200240China

Magnesium(Mg)alloys have shown great prospects as both structural and biomedical materials,while poor corrosion resistance limits their further *** this work,to avoid the time-consuming and laborious experiment trial,a high-throughput computational strategy based on first-principles calculations is designed for screening corrosion-resistant binary Mg alloy with intermetallics,from both the thermodynamic and kinetic *** stable binary Mg intermetallics with low equilibrium potential difference with respect to the Mg matrix are firstly ***,the hydrogen adsorption energies on the surfaces of these Mg intermetallics are calculated,and the corrosion exchange current density is further calculated by a hydrogen evolution reaction(HER)kinetic *** intermetallics,e.g.Y_(3)Mg,Y_(2)Mg and La_(5)Mg,are identified to be promising intermetallics which might effectively hinder the cathodic ***,machine learning(ML)models are developed to predict Mg intermetallics with proper hydrogen adsorption energy employing work function(w_(f))and weighted first ionization energy(wFIE).The generalization of the ML models is tested on five new binary Mg intermetallics with the average root mean square error(RMSE)of 0.11 *** study not only predicts some promising binary Mg intermetallics which may suppress the galvanic corrosion,but also provides a high-throughput screening strategy and ML models for the design of corrosion-resistant alloy,which can be extended to ternary Mg alloys or other alloy systems.

关键词： Mg intermetallics Corrosion property High-throughput Density functional theory Machine learning