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Electrochemical deposited amorphous FeNi hydroxide electrode for oxygen evolution reaction

Journal of Energy Chemistry 2022年第6期31卷 585-592,I0016页

作者： Zhengzhi Yin Runze He Yongcai Zhang Ligang Feng Xiang wu thomas wågberg Guangzhi Hu College of Biological Chemical Sciences and EngineeringJiaxing UniversityJiaxing 314001ZhejiangChina School of Chemistry and Chemical Engineering Yangzhou UniversityYangzhou 225002JiangsuChina School of Materials Science and Engineering Shenyang University of TechnologyShenyang 110870LiaoningChina Institute for Ecological Research and Pollution Control of Plateau Lakes School of Ecology and Environmental ScienceYunnan UniversityKunming 650504LiaoningChina National Local Joint Engineering Laboratory to Functional Adsorption Material Technology for the Environmental Protection Soochow UniversitySuzhou 215123JiangsuChina Department of Physics UmeåUniversity90187 UmeåSweden

The electrodeposition approach is significant in electrode fabrication for practical ***,the electrodeposited amorphous NiFe hydroxide species for oxygen evolution reaction (OER) in water splitting reaction is demonstrated by revealing the synergistic effect influenced by the support electrode of Fe and Ni foil and the contents of Fe and Ni in the *** the electrodeposited samples have an amorphous structure and similar profiles of binding energy and chemical states for Fe and Ni as characterized by the spectroscopic *** the support effect and Fe/Ni synergistic effect are indeed observed for the varied catalytic performances observed for the different electrodes;the Ni foil supported catalyst exhibits much higher performance than that of the Fe foil supported catalyst,and the different redox potentials of Ni species in the different Fe/Ni electrode resulting from the Fe–Ni synergism are observed in the cyclic voltammetry curve *** surface roughness and the electrochemical surface area are also influenced by the support effect and the Fe/Ni ratio in the plating *** optimal electrode shows a very low overpotential of~200 mV to reach 10 mA cm^(-2),and very high catalytic stability by the consecutive cyclic voltammetry measurements and 20 h stability *** it has the largest electrochemical surface area,the highest catalytic efficiency for these active sites is also indicated by the specific activity and turnover frequency polarization *** current work shows the effective experience for the electrodeposited Fe/Ni based catalysts in large-scale fabrication,which can be more practical for hydrogen generation in the alkaline water electrolysis.

关键词： Electrodeposition Amorphous structure NiFe hydroxide Oxygen evolution reaction Alkaline water electrolysis

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Reversed charge transfer induced by nickel in Fe-Ni/Mo_(2)C@nitrogen-doped carbon nanobox for promoted reversible oxygen electrocatalysis

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Journal of Energy Chemistry 2024年第1期88卷 202-212,I0005页

作者： Zhicheng Nie Lei Zhang Qiliang Zhu Zhifan Ke Yingtang Zhou thomas wågberg Guangzhi Hu School of Materials Science and Engineering Anhui University of Science and TechnologyHuainan 232001AnhuiChina Institute for Ecological Research and Pollution Control of Plateau Lakes School of Ecology and Environmental ScienceYunnan UniversityKunming 650504YunnanChina National Engineering Research Center for Marine Aquaculture Marine Science and Technology CollegeZhejiang Ocean UniversityZhoushan 316004ZhejiangChina Department of Physics UmeåUniversityUmeåS-90187Sweden

The interaction between metal and support is critical in oxygen catalysis as it governs the charge transfer between these two entities,influences the electronic structures of the supported metal,affects the adsorption energies of reaction intermediates,and ultimately impacts the catalytic *** this study,we discovered a unique charge transfer reversal phenomenon in a metal/carbon nanohybrid ***,electrons were transferred from the metal-based species to N-doped carbon,while the carbon support reciprocally donated electrons to the metal domain upon the introduction of *** led to the exceptional electrocatalytic performances of the resulting Ni-Fe/Mo_(2)C@nitrogen-doped carbon catalyst,with a half-wave potential of 0.91 V towards oxygen reduction reaction(ORR)and a low overpotential of 290 m V at 10 mA cm^(-2)towards oxygen evolution reaction(OER)under alkaline ***,the Fe-Ni/Mo_(2)C@carbon heterojunction catalyst demonstrated high specific capacity(794 mA h g_(Zn)~(-1))and excellent cycling stability(200 h)in a Zn-air *** calculations revealed that Mo_(2)C effectively inhibited charge transfer from Fe to the support,while secondary doping of Ni induced a charge transfer reversal,resulting in electron accumulation in the Fe-Ni alloy *** local electronic structure modulation significantly reduced energy barriers in the oxygen catalysis process,enhancing the catalytic efficiency of both ORR and ***,our findings underscore the potential of manipulating charge transfer reversal between the metal and support as a promising strategy for developing highly-active and durable bi-functional oxygen electrodes.

关键词： Metal-support interaction Charge transfer reversal Oxygen reduction reaction Oxygen evolution reaction Zinc-air battery

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A high‐performance transition‐metal phosphide electrocatalyst for converting solar energy into hydrogen at 19.6% STH efficiency

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Carbon Energy 2023年第1期5卷 206-217页

作者： Hua Zhang Abuduwayiti Aierke Yingtang Zhou Zitao Ni Ligang Feng Anran Chen thomas wågberg Guangzhi Hu Institute for Ecological Research and Pollution Control of Plateau Lakes School of Ecology and Environmental SciencesSchool of Materials and EnergyYunnan UniversityKunmingPeople's Republic of China School of Energy and Environment Science Yunnan Normal UniversityKunmingPeople's Republic of China National Engineering Research Center for Marine Aquaculture Marine Science and Technology CollegeZhejiang Ocean UniversityZhoushanPeople's Republic of China School of Chemistry and Chemical Engineering Yangzhou UniversityYangzhouPeople's Republic of China Department of Physics UmeåUniversityUmeåSweden

The construction of high-efficiency and low-cost non-noble metal bifunctional electrocatalysts for water electrolysis is crucial for commercial large-scale application of hydrogen ***,we report a novel strategy with erbiumdoped NiCoP nanowire arrays in situ grown on conductive nickel foam(Er-NiCoP/NF).Significantly,the developed electrode shows exceptional bifunctional catalytic activity,which only requires overpotentials of 46 and 225 mV to afford a current density of 10 mAcm^(−2) for the hydrogen evolution reaction(HER)and the oxygen evolution reaction(OER),*** functional theory calculations reveal that the appropriate Er incorporation into the NiCoP lattice can significantly modulate the electronic structure with the d-band centers of Ni and Co atoms by shifting to lower energies with respect to the Fermi level,and optimize the Gibbs free energies of HER/OER intermediates,thereby accelerating water-splitting *** assembled as a solar-driven overall water-splitting electrolyzer,the as-prepared electrode shows a high and stable solar-to-hydrogen efficiency of 19.6%,indicating its potential for practical storage of intermittent energy.

关键词： bifunctional electrocatalysts electronic regulation hydrogen evolution reaction oxygen evolution reaction solar-to-hydrogen efficiency

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Carbon nanodots:A metal-free,easy-to-synthesize,and benign emitter for light-emitting electrochemical cells

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Nano Research 2022年第6期15卷 5610-5618页

作者： Yongfeng Liu Shi Tang Xiuyu wu Nicolas Boulanger Eduardo Gracia-Espino thomas wågberg Ludvig Edman Jia wang Department of Physics UmeåUniversitySE-90187 UmeåSweden LunaLEC AB Linnaeus väg 24SE-90187 UmeåSweden College of Physical Science and Technology Yangzhou UniversityYangzhou 225009China

Light-emitting electrochemical cells(LECs)can be fabricated with cost-efficient printing and coating methods,but a current drawback is that the LEC emitter is commonly either a rare-metal complex or an expensive-to-synthesize conjugated ***,we address this issue through the pioneering employment of metal-free and facile-to-synthesize carbon nanodots(CNDs)as the emitter in functional LEC ***-shaped(average diameter=4.4 nm)and hydrophilic CNDs,which exhibit narrow cyan photoluminescence(peak=485 nm,full width at half maximum=30 nm)with a high quantum yield of 77%in dilute ethanol solution,were synthesized with a catalyst-free,one-step solvothermal process using low-cost and benign phloroglucinol as the sole starting *** propensity of the planar CNDs to form emission-quenching aggregates in the solid state was inhibited by the inclusion of a compatible 2,7-bis(diphenylphosphoryl)-9,9’-spirobifluorene host compound,and we demonstrate that such pristine host-guest CND-LECs turn on to a peak luminance of 118 cd·m^(−2)within 5 s during constant current-density driving at 77 mA·cm^(−2).

关键词： carbon nanodot light-emitting electrochemical cell phloroglucinol sustainable synthesis solution-based fabrication

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The influence of the capping ligands on the optoelectronic performance,morphology,and ion liberation of CsPbBr_(3)perovskite quantum dots

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Nano Research 2023年第7期16卷 10626-10633页

作者： Yongfeng Liu Shi Tang Zhaoju Gao Xiuwen Shao Xiaolin Zhu Joan Ràfols Ribé thomas wågberg Ludvig Edman Jia wang College of Physical Science and Technology Yangzhou UniversityYangzhou 225002China Department of Physics UmeåUniversityUmeåSE-90187Sweden LunaLEC AB UmeåSE-90187Sweden Microelectronics Industry Research Institute Yangzhou UniversityYangzhou 225002China

Perovskite quantum dots(PeQDs)endowed with capping ligands exhibit impressive optoelectronic properties and enable for costefficient solution processing and exciting application *** synthesize and characterize three different PeQDs with the same cubic CsPbBr_(3)core,but which are distinguished by the ligand composition and ***-1 features a binary didodecyldimethylammonium bromide(DDAB)and octanoic acid capping ligand system,with a high surface density of 1.53 nm^(-2),whereas PeQD-2 and PeQD-3 are coated by solely DDAB at a gradually lower surface *** show that PeQD-1 endowed with highest ligand density features the highest dispersibility in toluene of 150 g/L,the highest photoluminescence quantum yield of 95%in dilute solution and 59%in a neat film,and the largest core-to-core spacing in neat thin *** further establish that ions are released from the core of PeQD-1 when it is exposed to an electric field,although it comprises a dense coating of one capping ligand per four surface core *** finally exploit these combined findings to the development of a light-emitting electrochemical cell(LEC),where the active layer is composed solely of solution-processed pure PeQDs,without additional *** this device,the ion release is utilized as an advantage for the electrochemical doping process and efficient emissive operation of the LEC.

关键词： CsPbBr_(3)quantum dots capping ligand ion liberation light-emitting electrochemical cell

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Ni–Co bimetallic coordination effect for long lifetime rechargeable Zn–air battery

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Journal of Energy Chemistry 2020年第8期29卷 146-154,I0005页

作者： Mengfei Qiao Ying wang thomas wagberg Xamxikamar Mamat Xun Hu Guoan Zou Guangzhi Hu Key Laboratory of Xinjiang Indigenous Medicinal Plants Resource Utilization and Key Laboratory of Plant Resources and Chemistry in Arid RegionsXinjiang Technical Institute of Physics and ChemistryChinese Academy of SciencesUrumqi 830011XinjiangChina Department of Physics Umea UniversityS-90187 UmeaSweden School of Material Science and Engineering University of JinanJinan 250022ShandongChina University of Chinese Academy of Sciences Beijing 100049China

The development of bifunctional oxygen electrocatalysts with high efficiency, high stability, and low cost is of great significance to the industrialization of rechargeable Zn–air batteries. A widely accepted view is that the oxygen reduction reaction(ORR) and the oxygen evolution reaction(OER) follow different catalytic mechanisms, and accordingly they need different active sites for catalysis. Transition metal elements have admirable electronic acceptance ability for coordinating with reactants, and this can weaken the bond energy between reactants, thus promoting the ORR or OER reactions. Herein, the ORR and OER activities of different transition metal supported nitrogen-doped carbon nanotubes were systematically studied and compared. The optimal catalyst for synchronous ORR and OER was obtained by pyrolyzing melamine, cobalt nitrate, and nickel nitrate on carbon nanotubes, called cobalt–nickel supported nitrogenmixed carbon nanotubes(CoNi–NCNT), which were equipped with two types of high-performance active sites—the Co/Ni–N–C structure for the ORR and Co Ni alloy particles for the OER—simultaneously. Remarkably, the optimized Co Ni–NCNT exhibited a satisfactory bifunctional catalytic activity for both the ORR and OER. The value of the oxygen electrode activity parameter,△E, of CoNi–NCNT was 0.81 V, which surpasses that of catalysts Pt/C and Ir/C, and most of the non-precious metal-based bifunctional electrocatalysts reported in previous literatures. Furthermore, a specially assembled rechargeable Zn–air cell with Co Ni–NCNT loaded carbon paper as an air cathode was used to evaluate the practicability. As a result, a superior specific capacity of 744.3 mAh/gZn, a peak power density of 88 mw/cm2, and an excellent rechargeable cycling stability were observed, and these endow the Co Ni–NCNT with promising prospects for practical application.

关键词： Bifunctional catalysis Oxygen reduction reaction Oxygen evolution reaction Carbon nanotubes Zn–air battery

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NiCo_(2)O_(4) hollow microsphere-mediated ultrafast peroxymonosulfate activation for dye degradation

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Chinese Chemical Letters 2021年第8期32卷 2495-2498页

作者： Pengjia Ding Jianrui Niu Fengqin Chang Zhuang He thomas wagberg Zaixing Li Guangzhi Hu College of Environmental Science and Engineering Hebei University of Science and TechnologyShijiazhuang 050018China Institute for Ecological Research and Pollution Control of Plateau Lakes School of Ecology and Environmental ScienceYunnan UniversityKunming 650504China Department of Physics Umea UniversityUmeå90187Sweden

Morphology and dispersity are key factors for activating peroxymonosulfate(PMS).In this study,we designed a recyclable open-type NiCo_(2)O_(4) hollow microsphere via a simple hydrothermal method with the assistance of an NH_(3) *** physical structure and chemical properties were characterized using techniques such as scanning electron microscope(SEM),transmission electron microscope(TEM),X-ray diffraction(XRD),N2 adsorption and X-ray photoelectron spectroscopy(XPS).The test results confirm that the inner and outer surfaces of open-type NiCo_(2)O_(4) hollow-sphere can be efficiently utilized because of the hole on the surface of the catalyst,which can minimize the diffusion resistance of the reactants and *** optimized conditions,the total orga nic carbon(TOC) removal efficiency of rhodamine B(RhB) can reach up to 80% in 40 min,which is almost 50% shorter than the reported *** reactive radicals were identified and the proposed reaction mechanism was well ***,the disturbances of HCO_(3)^(-),NO_(3)^(-),Cl^(-)and H_(2) PO_(4)^(-)were further *** a result,HCO_(3)-and NO_(3)-suppressed the reaction while Cl-and H_(2) PO4-had a double effect on reaction.

关键词： Open-type sphere Hollow NiCo_(2)O_(4) Vesicle Inner and outer surface Ultra peroxymonosulfate activation

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One-pot synthesis of Pd-Au-alloy-nanoparticle-decorated graphene oxide functionalized with dodecahydrododecaborate cluster for rapid and complete reduction of 4-nitrophenol at room temperature

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Rare Metals 2023年第11期42卷 3622-3629页

作者： Yu-Bo Ma Yu-wen wang Da-Feng Zhang Xiu-Xiu Jia Yin wang Shu-Xing Zhou thomas wagberg Guang-Zhi Hu School of Chemical Engineering Chongqing Chemical Industry Vocational CollegeChongqing401220China School of Materials and Energy Institute for Ecological Research and Pollution Control of Plateau LakesYunnan UniversityKunming650504China School of Materials Science and Engineering Liaocheng UniversityLiaocheng252000China Hubei Key Laboratory of Low Dimensional Optoelectronic Materials and Devices Hubei University of Arts and ScienceXiangyang441053China Department of Physics UmeåUniversity90187UmeåSweden

The treatment of nitroaromatics in wastewater is a significant issue that must be addressed because of their high *** catalytic reduction of 4-nitrophenol(4-NP)to the widely used 4-aminophenol(4-AP)is an excellent method for 4-NP ***,performing this reaction is *** this study,two-dimensional(2D)graphene oxide(GO)with oxygen-containing surface groups was used as a substrate for the in situ anchoring ofPdAu alloy nanocrystals.

关键词： alloy rapid cluster

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Tuning beneficial calcineurin phosphatase activation to counterα-synuclein toxicity in a yeast model of Parkinson’s disease

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Neural Regeneration Research 2025年第1期20卷 199-200页

作者： Srishti Chawla Mikael Molin thomas Nystrom Institute for Biomedicine Sahlgrenska AcademyCentre for Ageing and Health-AgeCapUniversity of GothenburgGothenburgSweden Department of Life Sciences Chalmers University of TechnologyGothenburgSweden

Calcineurin(CN)is a calcium-and calmodulindependent serine/threonine that has been studied in many model organisms including yeast,filamentous fungi,plants,and *** biological functions range from ion homeostasis and virulence in lower eukaryotes to T-cell activation in humans by human nuclear factors of activated *** is a heterodimeric protein consisting of a catalytic subunit,calcineurin A(Cna1p),which contains an active site with a dinuclear metal center,and a regulatory Ca^(2+) binding subunit called calcineurin B(Cnb1p)required to activate *** calcineurin B subunit has been highly conserved through evolution:For example,the mammalian calcineurin B shows 54%identity with calcineurin B from Saccharomyces cerevisiae.

关键词： activation dinuclear conserved

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Microglia:a promising therapeutic target in spinal cord injury

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Neural Regeneration Research 2025年第2期20卷 454-463页

作者： Xiaowei Zha Guoli Zheng thomas Skutella Karl Kiening Andreas Unterberg Alexander Younsi Department of Neurosurgery Heidelberg University HospitalHeidelbergGermany Department of Neuroanatomy Institute for Anatomy and Cell BiologyHeidelberg UniversityHeidelbergGermany

Microglia are present throughout the central nervous system and are vital in neural repair,nutrition,phagocytosis,immunological regulation,and maintaining neuronal *** a healthy spinal cord,microglia are accountable for immune surveillance,however,when a spinal cord injury occurs,the microenvironment drastically changes,leading to glial scars and failed axonal *** this context,microglia vary their gene and protein expression during activation,and proliferation in reaction to the injury,influencing injury responses both favorably and unfavorably.A dynamic and multifaceted injury response is mediated by microglia,which interact directly with neurons,astrocytes,oligodendrocytes,and neural stem/progenitor *** a clear understanding of their essential nature and origin,the mechanisms of action and new functions of microglia in spinal cord injury require extensive *** review summarizes current studies on microglial genesis,physiological function,and pathological state,highlights their crucial roles in spinal cord injury,and proposes microglia as a therapeutic target.

关键词： astrocytes cytokines functional recovery immune regulation M1/M2 activation macrophages microglia neuroinflammation spinal cord injury therapy

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