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Weight regain after intragastric balloon for pre-surgical weight loss

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World j.urnal of Gastrointestinal Surgery 2024年第7期16卷 2040-2046页

作者： Danielle Abbitt Kevin Choy Alexandra Kovar teresa S j.nes Krzysztof j.Wikiel Edward L j.nes Department of Surgery University of ColoradoAuroraCO 80045United States Department of Surgery Rocky Mountain Regional Veteran Affairs Medical CenterAuroraCO 80045United States

BACKGROUND Over one-third of Americans carry the diagnosis of obesity,many also with obesity-related *** can place patients at increased risk of operative and postoperative *** intragastric balloon has been shown to aid in minor weight loss,however its weight recidivism in patients requiring short interval weight loss has not been well *** To evaluate weight loss,ability to undergo successful elective surgery after intragastric balloon placement,and weight management after balloon *** This study is a retrospective review of patients in a single academic institution undergoing intragastric balloon placement from 2019-2023 to aid in weight loss prior to undergoing elective *** outcomes including weight loss,duration of balloon placement,successful elective surgery,weight regain postballoon and post-procedure complications were *** criteria included those with balloon in place at time of *** Thirty-three patients completed intragastric balloon therapy from 2019-2023 as a bridge to elective *** patients were required to participate in a 12-month weight management program to be eligible for balloon *** surgeries included incisional hernia repair,umbilical hernia repair,inguinal hernia repair,and knee and hip *** average age at placement was 53 years±11 years,maj.rity(91%)were *** average duration of intragastric balloon therapy was 186 days±41 *** average weight loss was 14.0 kg±7.4 kg and with an average percent excess body weight loss of 30.0%(7.9%-73.6%).Over half of the patients(52.0%)achieved the goal of 30-50 lbs(14-22 kg)weight ***-one patients(64%)underwent their intended elective surgery,2 patients(6%)deferred surgery due to symptom relief with weight loss ***-one of the patients(64%)have documented weights in 3 months after balloon removal,in these patients the maj.rity(76%)gained weight after balloon *** pat

关键词： Intragastric balloon Weight loss Obesity Bariatric Body mass index

Engineering heterostructured Ni@Ni(OH)_(2) core-shell nanomaterials for synergistically enhanced water electrolysis

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Green Energy & Environment 2022年第5期7卷 1024-1032页

作者： j.n-Wei Zhang Xian-Wei Lv Tie-Zhen Ren Zheng Wang teresa j.Bandosz Zhong-Yong Yuan Hebei Provincial Key Laboratory of Green Chemical Technology&High Efficient Energy Saving School of Chemical Engineering and TechnologyHebei University of TechnologyTianjin300130China Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) School of Materials Science and EngineeringNankai UniversityTianjin300350China State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering Ningxia UniversityYinchuan750021NingxiaChina Department of Chemistry and Biochemistry The City College of New YorkNY10031USA

Heterostructure engineering of electrocatalysts provides a fascinating platform to reasonably manipulate the physicochemical properties of nanomaterials and further improve their catalytic efficiency for water ***,it still remains a huge challenge to construct welldesigned core-shell heterostructured catalysts and identify the key role of components for synergistic ***,a melted polymeric salt tactics was innovatively developed to synthesize heterostructured Ni@Ni(OH)_(2) core-shell nanomaterials supported on porous carbon(named Ni@Ni(OH)_(2)/PC),wherein well-defined Ni(OH)_(2)-Ni heterostructure plays a pivotal role in improving electrocatalytic activity for water reduction and ***,the stable porous carbon support functions as a highway for continuous electron transfer between Ni and Ni(OH)_(2),and simultaneously enables the full exposure of accessible active *** fabricated Ni@Ni(OH)_(2)/PC exhibits outstanding bifunctional electrocatalytic performance for overall water splitting(η_(10)=1.55 V) with a good long-time *** work sheds new light on the design of engineering heterostructure of active bifunctional electrocatalysts for efficient energy conversion system.

关键词： stability synergistic splitting

Nitric oxide regulation of plant metabolism

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Molecular Plant 2022年第2期15卷 228-242页

作者： Kapuganti j.gadis Gupta Vemula Chandra Kaladhar teresa B.Fitzpatrick Alisdair R.Fernie Ian Max Møller Gary j.Loake National Institute of Plant Genome Research Aruna Asaf Ali MargNew DelhiDelhi 110067 India Vitamins and Environmental Stress Responses in Plants Department of Botany and Plant BiologyUniversity of GenevaGeneva 1211 Switzerland Max-Planck-Institute of Molecular Plant Physiology Am Mühlenberg 1Potsdam-Golm 14476 Germany Department of Molecular Biology and Genetics Aarhus UniversityForsøgsvej 14200 SlagelseDenmark Institute of Molecular Plant Sciences School of Biological SciencesUniversity of EdinburghEdinburgh EH93BFUK

Nitric oxide(NO)has emerged as an important signal molecule in plants,having myriad roles in plant *** addition,NO also orchestrates both biotic and abiotic stress responses,during which intensive cellular metabolic reprogramming *** to these responses is the location of NO biosynthetic and scavenging pathways in diverse cellular compartments,enabling plants to effectively organize signal transduction *** regulates plant metabolism and,in turn,metabolic pathways reciprocally regu-late NO accumulation and ***,these diverse cellular processes are inextricably *** re-view addresses the numerous redox pathways,located in the various subcellular compartments that pro-duce NO,in addition to the mechanisms underpinning NO *** focus on how this molecular dance is integrated into the metabolic state of the *** this context,a reciprocal relationship be-tween NO accumulation and metabolite production is often *** also showcase cellular pathways,including those associated with nitrate reduction,that provide evidence for this integration of NO function and ***,we discuss the potential importance of the biochemical reactions governing NO levels in determining plant responses to a changing environment.

关键词： hypoxi amitochondria metabolism nitric oxide S-nitrosylation pyridoxine reactive nitrogen species reactive oxygen species

Evaluation of alum-based water treatment residuals used to adsorb reactive phosphorus

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Water Science and Engineering 2020年第3期13卷 181-192页

作者： George Carleton teresa j.Cutright Department of Civil Engineering The University of AkronAkronOH 44235-3905USA

Excess reactive phosphorus(PO4)in waterways can lead to eutrophication.A low-cost approach to reducing PO4 levels in surface water was evaluated using the alum-based water treatment residual(Al-WTR)or Al-WTR augmented with powdered activated carbon(PAC-WTR).Batch adsorption-desorption and continuous flow column experiments were performed to assess the specific adsorption capacities under various concentration and flow *** Al-WTR and PAC-WTR exhibited the ability to adsorb *** overall,cumulative sorbed amount after a 28-d desorption step for Al-WTR was 33.93 mg/kg,significantly greater than the PAC-WTR value of 24.95 mg/kg(p<0.05).The continuous flow column experiments showed a theoretical PO4 uptake of 9.00 mg/g for Al-WTR and 7.14 mg/g for PAC-WTR over 720 *** surface water was used,the Al-WTR and PAC-WTR columns removed 67.4%and 62.1%of the PO4,*** results indicated that Al-WTR was more effective for in-field evaluation.

关键词： Phosphorous Alum Water treatment residuals Adsorption Desorption Powered activated carbon

Inorganic matter in rice husk derived carbon and its effect on the capacitive performance

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j.urnal of Energy Chemistry 2021年第6期30卷 639-649,I0016页

作者： Wanlu Li Meruyert Nazhipkyzy teresa j.Bandosz Department of Chemistry Saint Peter’s UniversityJersey CityNJ 07306USA Institute of Combustion Problems AlmatyKazakhstan 050012USA Al-Farabi Kazakh National University AlmatyKazakhstan 050038USA Department of Chemistry and Biochemistry The City College of New YorkNew YorkNY 10031USA

Porous carbons were obtained from rice husk using two different chemical activation methods and they were investigated as *** properties were studied using X-ray photoelectron spectroscopy,thermal analysis,potentiometric titration,and nitrogen adsorption *** specific capacitance measured in both H_(2) SO_(4) and KOH electrolytes in two-electrode cell was up to-150 F/*** activation method used affected the resulting carbons’*** expected,the dependence of the capacitance on porosity was *** ash content reached 36 wt.%and that inorganic mater blocked some pores and limited their accessibility to electrolyte ions and increased the charge transfer ***,the main ash constituents such as CaCO_(3),MgCO_(3),Ca_(3)(PO_(4))2(or P_(2)O_(5)),and Fe-and Zn-containing species did not affect the specific capacitance to a large *** SiO2,even in a relatively large amount(~20 wt.%)T did not play a detrimental role in the capacitance *** results showed that in spite of a high ash content,carbon can exhibit a good capacitive performance provided that it has a favorable porosity and is rich in sp_(2) configurations.

关键词： Inorganic matter Capacitive performance SiO2 Carbonates Pore accessibility

Development of a standardized in vitro approach to evaluate microphysical,chemical,and toxicological properties of combustion-derived fine and ultrafine particles

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j.urnal of Environmental Sciences 2022年第3期34卷 104-117页

作者： Ana teresa j.arez-Facio Clement Castilla Cecile Corbiere Helene Lavanant Carlos Afonso Christophe Morin Nadine Merlet-Machour Laurence Chevalier j.an-Marie Vaugeois j.rome Yon Christelle Monteil Normandie Univ UNIROUENUNICAEN ABTE76000 RouenFrance Normandie Univ UNIROUENINSA RouenCNRSCOBRA76000 RouenFrance Normandie Univ UNIROUENINSA RouenCNRSGPM-UMR663476000 RouenFrance Normandie Univ UNIROUENINSA RouenCNRSCORIA76000 RouenFrance

Ultrafine particles represent a growing concern in the public health community but their precise role in many illnesses is still unknown. This lack of knowledge is related to the experimental difficulty in linking their biological effects to their multiple properties, which are important determinants of toxicity. Our aim is to propose an interdisciplinary approach to study fine(FP) and ultrafine(UFP) particles, generated in a controlled manner using a mini CAST(Combustion Aerosol Standard) soot generator used with two different operating conditions(CAST1 and CAST3). The chemical characterization was performed by an untargeted analysis using ultra-high resolution mass spectrometry. In conj.nction with this approach, subsequent analysis by gas chromatography–mass spectrometry(GC–MS) was performed to identify polycyclic aromatic hydrocarbons(PAH). CAST1 enabled the generation of FP with a predominance of small PAH molecules, and CAST3 enabled the generation of UFP, which presented higher numbers of carbon atoms corresponding to larger PAH molecules. Healthy normal human bronchial epithelial(NHBE) cells differentiated at the air-liquid interface(ALI) were directly exposed to these freshly emitted FP and UFP. Expression of MUC5AC, FOXj., OCLN and ZOI as well as microscopic observation confirmed the ciliated pseudostratified epithelial phenotype. Study of the mass deposition efficiency revealed a difference between the two operating conditions, probably due to the morphological differences between the two categories of particles. We demonstrated that only NHBE cells exposed to CAST3 particles induced upregulation in the gene expression of IL-8 and NQO1. This approach offers new perspectives to study FP and UFP with stable and controlled properties.

关键词： In vitro Air-liquid interface MiniCAST Fine and ultrafine particles Organic compounds OC/TC

S-doped carbon aerogels/GO composites as oxygen reduction catalysts

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j.urnal of Energy Chemistry 2016年第2期25卷 234-243页

作者： Mykola Seredych Krisztina László Enrique Rodríguez-Castellón teresa j.Bandosz The City College of New York and The Graduate Center of CUNY Department of Chemistry 160 Convent Avenue New York NY 10031 USA Department of Physical Chemistry and Materials Science Budapest University of Technology and Economics Budapest 1521 Hungary Departamento de Quimica Inorganica Universidad de Malaga Malaga 29071 Spain

Composites of carbon aerogel and graphite oxide（GO） were synthesized using a self-assembly method based on dispersive forces. Their surface was modified by treatment in hydrogen sulfide at 650 and800 ℃. The samples obtained were characterized by adsorption of nitrogen, TA-MS, XPS, potentiometric titration, and HRTEM and tested as catalysts for oxygen reduction reactions（ORR） in an alkaline *** synergistic effect of the composite（electrical conductivity, porosity and surface chemistry） leads to a good ORR catalytic activity. The onset potential for the composite of carbon aerogel heated at 800 ℃ is shifted to a more positive value and the number of electron transfer was 2e-at the potential 0.68 V versus RHE and it increased to 4e-with an increase in the negative values of the potential. An excellent tolerance to methanol crossover was also recorded.

关键词： Oxygen reduction reaction Carbon aerogel/GO composites Porosity Surface chemistry Specific interactions

The Influence of Water Hyacinth Floating Meadows on Limnological Characteristics in Shallow Subtropical Waters

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American j.urnal of Plant Sciences 2014年第13期5卷 1983-1994页

作者： sylvina L. Casco Romina P. Carnevali Alicia S.G. Poi j.an j. Neiff Centro de Ecología Aplicada del Litoral (CONICET-UNNE) Corrientes Argentina Centro de Ecología Aplicada del Litoral (CONICET-UNNE) Corrientes Argentina Facultad de Ciencias Exactas y Naturales y Agrimensura (UNNE) Corrientes Argentina

The effects of free-floating mats of the water hyacinth Eichhornia crassipes (Mart.) Solms on the limnological characteristics of two lakes located on the fringing floodplain of the lower Paraná River (27°27'S, 58°55'W) were studied monthly between April 1998 and April 1999. The mobility of the free-floating vegetation at both locations prevented continual observation. Therefore, to carry out the intensive sampling needed for this study, two experimental ponds (A and B) were filled with water from the Paraná River in 1996. Pond A was designed to reproduce conditions similar to those of lakes vegetated with water hyacinth. Pond B was designed to recreate the limnological conditions of these lakes, such as a high concentration of dissolved and fine particulate organic matter and a peat layer on the bottom;however, pond B lacked macrophytes. Natural lakes covered with free-floating vegetation were very similar to pond A, but these water bodies showed a lower temperature, dissolved oxygen level and pH and a higher conductivity than the non-vegetated pond. Our results indicated that water hyacinth has a strong local influence on the limnological conditions in subtropical shallow lakes. Our results may assist in developing cause-consequence models by demonstrating the relevance of the effect of thermal damping produced by floating meadows.

关键词： Eichhornia crassipes Subtropical Lakes Temperature Dissolved Oxygen Electrical Conductivity pH

S掺杂纳米多孔碳的光催化活性:表面化学和孔隙率的重要性(英文)

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催化学报 2014年第6期35卷 807-814页

作者： teresa j.Bandosz Mykola Seredych Department of Chemistry The City College of New York 160 Convent Ave New York NY 10031 USA

This minireview summarizes our recent findings on the photoactivity of S-doped nanoporous carbons. The materials were either synthesized from the sulfur-containing polymers or obtained by heat treatment of commercial carbon with hydrogen sulfide. Their surface was extensively charac terized from the points of view of its surface chemistry, porosity, morphology, and electronic properties. The carbons showed enhanced activity towards oxidation of arsine and removal of diben-zothiophenes from model diesel fuel. The latter were oxidized to various oxygen containing intermediates and the cleavage of C–C bonds in aromatic ring was detected when carbon with adsorbed species was exposed to UV or visible light. Irradiation resulted in generation of photocurrent in a broad range of wavelength. The presence of sulfur led to the reduction of oxygen and contributed to an increased capacitive performance. We link these effects to the presence of reduced sulfur in the small pores which enhances the dispersive interactions via inducing a positive charge to carbon atoms, to sulfur in oxygenated forms which contribute to Faradaic reactions and increase the polar interactions, and to the hydrophobicity of a surface in small pores where oxygen can be reduced by excited electrons from chromophoric-like sulfur containing groups.

关键词：光催化活性表面化学多孔碳孔隙率纳米掺杂色散相互作用聚合物合成