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Isolation and characteristics of Arthrobacter *** CW-1 for biodegradation of PAEs

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2007年第9期8卷 1469-1474页

作者： mahmood Qaisar Department of Environmental Engineering Zhejiang UniversityHangzhou 310029China

Isolation of new bacterial strains and recognition of their metabolic activities are highly desirable for sustainability of natural ecosystems. Biodegradation of dimethyl phthalate （DMP） under anoxic conditions has been shown to occur as a series of sequential steps using strain CW-1 isolated from digested sludge of Sibao Wastewater Treatment Plant in Hangzhou, China. The microbial colony on LB medium was yellowish, 3-5 mm in diameter, convex in the center, and embedded in mucous externally. The individual cells of strain CW-1 are irregular rods, measuring （0.6-0.7）×（0.9-1.0） pm, V-shaped, with clubbed ends, Gram positive and without any filaments. 16S rDNA （ 1438 bp） sequence analysis showed that the strain was related to Arthrobacter sp. CW-1 and can degrade PAEs utilizing nitrate as electron acceptor, but cannot mineralize DMP completely. The degradation pathway was recommended as： dimethyl phthalate （DMP）→monomethyl phthalate （MMP）--,phthalic acid （PA）. DMP biodegradation was a first order reaction with degradation rate constant of 0.3033 d 1 and half-life 2.25 d. The DMP conversion to PA by CW-1 could be described by using sequential kinetic model.

关键词： Denitrifying bacteria Arthrobacter sp. strain CW-1 Dimethyl phthalate (DMP) Phthalic acid (PA) DMP degradation pathway

Control strategy of shortcut nitrification

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Journal of Environmental Sciences 2006年第1期18卷 58-61页

作者： QAISAR mahmood Department of Environmental Engineering Zhejiang University Hangzhou 310029 China.

Shortcut nitrification for ammonium-rich wastewater is energy-saving and cost-effective procedure that has become one of the hotspots in the field of biological denitrogenation. An orthogonal experiment was performed to study the combined effects of operational parameters on the performance of internal-loop airlift bioreactor for shortcut nitrification. The optimum operational parameters for the shortcut nitrification were fotmd as temperature 35 ℃, pH 8.0, dissolved oxygen concentration 1.0 mg/L, ammonium concentration 4 mmol/L and HRT 16 h, which have different influence on the performance of shortcut nitrification reactor. The pH, temperature and dissolved oxygen concentration have significant bearing on the process. The results showed that the shortcut nitrification reactor could be successfully started up within 42 d, and the reactor performance is steady with minimum NO2-/NOx- of 85.2%, maximum 93.4% and average value of 91.4% in effluent. Based on the analysis of experimental data, a new control strategy named “priority ＋ combination” for shortcut nitrification was suggested. Through this strategy, the startup and operation of shortcut nitrification for ammonium-rich sludge digester liquids were optimized. The control strategy works well to keep the reactor operation in steady state and in achieving high-efficiency for shortcut nitrification.

关键词： internal-loop airlift bioreactor shortcut nitrification orthogonal experiment control strategy sludge digester liquids

Investigations of mechanical, electronic, and magnetic properties of non-magnetic MgTe and ferro-magnetic Mg_(0.75)T M_(0.25)Te (TM = Fe, Co, Ni): An ab-initio calculation

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Chinese Physics B 2016年第4期25卷 303-313页

作者： mahmood Q Alay-e-Abbas S M mahmood I Asif mahmood Noor N A Department of Physics University of the Punjab Quaid-e-Azam Campus Department of Physics Government College University Faisalabad Department of Physics University of Sargodha Centre for High Energy Physics University of the Punjab Quaid-e-Azam Campus College of Engineering Chemical Engineering Department King Saud University

The mechanical, electronic and magnetic properties of non-magnetic MgTe and ferro-magnetic （FM） Mgo.75 TM025 Te （TM = Fe, Co, Ni） in the zinc-blende phase are studied by ab-initio calculations for the first time. We use the generalized gradient approximation functional for computing the structural stability, and mechanical properties, while the modified Becke and Johnson local （spin） density approximation （mBJLDA） is utilized for determining the electronic and magnetic properties. By comparing the energies of non-magnetic and FM calculations, we find that the compounds are stable in the FM phase, which is confirmed by their structural stabilities in terms of enthalpy of formation. Detailed descriptions of elastic properties of Mgo.75TMo.25Te alloys in the FM phase are also presented. For electronic properties, the spin- polarized electronic band structures and density of states are computed, showing that these compounds are direct bandgap materials with strong hybridizations of TM 3d states and Te p states. Further, the ferromagnetism is discussed in terms of the Zener free electron model, RKKY model and double exchange model. The charge density contours in the （110） plane are calculated to study bonding properties. The spin exchange splitting and crystal field splitting energies are also calculated. The distribution of electron spin density is employed in computing the magnetic moments appearing at the magnetic sites （Fe, Co, Ni）, as well as at the non-magnetic sites （Mg, Te）. It is found that the p-d hybridization causes not only magnetic moments on the magnetic sites but also induces negligibly small magnetic moments at the non-magnetic sites.

关键词： FP-LAPW + lo elastic parameters spin polarized electronic properties magnetic properties

Activated sludge-mediated biodegradation of dimethyl phthalate under fermentative conditions

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Journal of Environmental Sciences 2008年第8期20卷 922-926页

作者： mahmood Qaisar Department of Botany Federal Government Post Graduate College Sector H-8 IslamabadPakistan

The biodegradation of dimethyl phthalate(DMP)was investigated under fermentative conditions in this *** nature of the intermediate compounds and the extent of mineralization were probed using high-pressure liquid chromatography(HPLC)and liquid chromatography-mass spectrometry(LC-MS)*** fermentative bacteria were able to biodegrade the DMP under anaerobic conditions,with the biodegradation rate of 0.36 mg DMP/(L·h).The results demonstrated that the DMP degradation under fermentative conditions ...

关键词： activated sludge biodegradation dimethyl phthalate fermentation phthalic acid mineralization

Data driven models for compressive strength prediction of concrete at high temperatures

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Frontiers of Structural and Civil Engineering 2020年第2期14卷 311-321页

作者： mahmood AKBARI Vahid JAFARI DELIGANI Department of Civil Engineering Faculty of EngineeringUniversity of KashanKashan ***Iran

The use of data driven models has been shown to be useful for simulating complex engineering processes,when the only information available consists of the data of the *** this study,four data-driven models,namely multiple linear regression,artificial neural network,adaptive neural fuzzy inference system,and K nearest neighbor models based on collection of 207 laboratory tests,are investigated for compressive strength prediction of concrete at high *** addition for each model,two different sets of input variables are examined:a complete set and a parsimonious set of involved *** results obtained are compared with each other and also to the equations of NIST Technical Note standard and demonstrate the suitability of using the data driven models to predict the compressive strength at high *** addition,the results show employing the parsimonious set of input variables is sufficient for the data driven models to make satisfactory results.

关键词： data driven model compressive strength oncrete high temperature

Effects of loading rate and hydraulic residence time on anoxic sulfide biooxidation

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2007年第7期8卷 1149-1156页

作者： mahmood Qaisar ISLAM Ejazul Department of Environmental Engineering Zhejiang University

The optimal operation conditions in an anoxic sulfide oxidizing (ASO) bioreactor were investigated. The maximal removal rates for sulfide and nitrate were found to be 4.18 kg/(m3·d) and 1.73 kg/(m3·d), respectively. The volumetrical volumetric loading rates (LRs) observed through decreasing hydraulic retention time (HRT) at fixed substrate concentration are higher than those by increasing substrate concentration at fixed HRT. The sulfide oxidation in ASO reactor was partially producing both sulfate and sulfur; but the amount of sulfate produced was approximately one third that of sulfur. The process was able to tolerate high sulfide concentration, as the sulfide removal percentage always remained near 99% when influent concentration was up to 580 mg/L. It tolerated relatively lower nitrate concentration because the removal percentage dropped to 85% when influent con- centration was increased above 110 mg/L. The process can tolerate shorter HRT but careful operation is needed. Nitrate conversion was more sensitive to HRT than sulfide conversion since the process performance deteriorated abruptly when HRT was decreased from 3.12 h to 2.88 h. In order to avoid nitrite accumulation in the reactor, the influent sulfide and nitrate concentrations should be kept at 280 mg/L and 67.5 mg/L respectively. Present biotechnology is useful for removing sulfides from sewers and crude oil.

关键词： Anaerobic processes Anoxic nitrate removal Biodesulfurization Biotransformation Fluidized bed bioreactors Hydraulic residence time (HRT)

Analysis of highly efficient perovskite solar cells with inorganic hole transport material

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Chinese Physics B 2019年第12期28卷 393-399页

作者： I Kabir S A mahmood Department of Electrical and Electronics Engineering Bangladesh University of Engineering and Technology

Organo-halide perovskites in planar heterojunction architecture have shown considerable promise as efficient light harvesters in solar cells. We carry out a numerical modeling of a planar lead based perovskite solar cell(PSC) with Cu2ZnSnS4(CZTS) as the hole transporting material(HTM) using the one-dimensional solar cell capacitance simulator(SCAPS-1 D). The effects of numerous parameters such as defect density, thickness, and doping density of the absorber layer on the device performance are investigated. The doping densities and electron affinities of the electron transporting material(ETM) and the HTM are also varied to optimize the PSC performance. It has been observed that a thinner absorber layer of220 nm with a defect density of 1014 cm-3 compared to the reference structure improves the device performance. When doping density of the absorber layer increases beyond 2×1016 cm-3, the power conversion efficiency(PCE) reduces due to enhanced recombination rate. The defect density at the absorber/ETM interface reduces the PCE as well. Considering a series resistance of 5 ?·cm2 and all the optimum parameters of absorber, ETM and HTM layers simultaneously, the overall PCE of the device increases significantly. In comparison with the reference structure, the PCE of the optimized device has been increased from 12.76% to 22.7%, and hence the optimized CZTS based PSC is highly efficient.

关键词： CH3NH3PbI3 Cu2ZnSnS4(CZTS) SCAPS-1D absorption coefficient

CuCrW(Al2O3) nanocomposite: mechanical alloying, microstructure, and tribological properties

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International Journal of Minerals,Metallurgy and Materials 2017年第11期24卷 1321-1334页

作者： Mohammad Baghani mahmood Aliofkhazraei Department of Materials Science Faculty of Engineering Tarbiat Modares University Tehran Iran P.O. Box: 14115-143

The effect of alumina nanoparticle addition on the microstructure and tribological properties of a CuCrW alloy was investigated in this work. Mechanical alloying was carried out in a satellite ball mill. The tribological properties of the samples were evaluated using pin-on-disk wear tests with different pins(alumina, tungsten carbide, and steel pins). The results indicated that the tungsten carbide pin had a lower coefficient of friction than the alumina and steel pins because of its high hardness and low surface roughness. In addition, when the sliding rate was decreased, the weight-loss rate increased. The existence of alumina nanoparticles in the nanocomposite led to a lower weight-loss rate and to a change in the wear mechanism from adhesive to abrasive.

关键词： wear mechanicalalloying nanocomposite tribologicalproperties metalmatrix

Theoretical investigation of optical properties and band gap engineering for Zn1-xTMxTe(TM=Fe,Co)alloys by modified Becke-Johnson potential

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Chinese Physics B 2017年第8期26卷 491-498页

作者： Q mahmood M Yaseen M Hassan Shahid M Ramay Asif mahmood Materials Growth and Simulation Laboratory Department of PhysicsUniversity of the PunjabQuaid-i-Azam Campus54590LahorePakistan Department Of Physlcs University of Agriculture UniversityFaisalabad 38040Pakistan Physics and Astronomy Department College of ScienceKing Sand UniversityRiyadhSaudi Arabia Chemical Engineering Department College of EngineeringKing Saud UniversityRiyadhSaudi Arabia

The direct band gap ZnTe with transition metal （TM） impurities plays a vital role in optoelectronic and spintronic applications. In the present study, we use the advanced modified Becke-Johnson （mBJ） functional for performing the structural computations and detailed investigations of the optical characters in Zn1_xTMxTe （TM = Fe, Co） alloys with 0 ≤ x ≤1. By employing the FP-LAPW method, we determine various optical parameters for the ternary alloys and for the end binaries. The calculated static dielectric constants and optical band gaps for Zn1_xTMxTe （TM = Fe, Co） have an inverse relation that verifies the Penn model. We find that the static dielectric constant is nearly equal to the square of the static refractive index, and both increase with TM content. Furthermore, we also find a slight shift of peaks to a higher energy region with increasing TM concentration. The decreasing band gap and high value of the absorption in the visible region of electromagnetic spectrum make these alloys suitable for photonic and solar cell applications.

关键词： amorphous semiconductors transition metal-doped ZnTe structural computation optical property