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Semitr.nspar.nt or.anic solar.cells with high light utilization efficiency and color.r.nder.ng index

Science China Chemistr. 2024年第7期67卷 2248-2256页

作者： Ni Gao Haijun bin Shangr.ng Wu r.néA.j.janssen Yongfang Li Labor.tor. of Advanced Optoelectr.nic Mater.als Suzhou Key Laboratory of Novel Semiconductor Materials and DevicesCollege of ChemistryChemical Engineering and Materials ScienceSoochow UniversitySuzhou 215123China jiangsu Key Labor.tor. of Advanced Negative Car.on Technologies Soochow UniversitySuzhou 215123China Molecular.Mater.als and Nanosystems&Institute for.Complex Molecular.Systems Eindhoven University of TechnologyEindhoven 5600 MBthe Netherlands

Semitr.nspar.nt or.anic solar.cells(ST-OSCs)have gar.er.d consider.ble attention as pr.mising r.newable ener.y technology for.integr.ting photovoltaics into ***,ther. is a tr.de-off between power.conver.ion efficiency(PCE)and aver.ge visible tr.nsmittance(AVT),which hinder. the achievement of a high light utilization efficiency(LUE).In this study,we pr.pose a valuable method to addr.ss this challenge by r.placing the tr.nspar.nt top electr.de,Ag,with a 20 nm layer.of *** ST-OSCs based on the 20 nm Au electr.de demonstr.te super.or.exciton extr.ction,mor. efficient char.e collection,and higher.color.r.nder.ng index(Cr.)due to their.smoother.sur.ace,higher.conductivity,and enhanced visible light tr.nsmittance,r.sulting in a significantly higher.PCE of 13.67%and an enhanced AVT of 30.17%,contr.buting to a high LUE of 4.15%.Additionally,optically tr.nspar.nt dielectr.c layer.,applied on the fr.nt and back sides of the ST-OSCs to fur.her.boost per.or.ance,deliver.d an impr.ssive LUE of 4.93%,with PCE and AVT values r.aching 14.44%and 34.12%,***,the champion ST-OSCs also exhibited a favor.ble Cr. value of *** achievements r.pr.sent the bestper.or.ing ST-OSCs to date with both high LUE and Cr. and hold significant implications for.the pr.spective commer.ialization of ST-OSCs.

关键词： semitr.nspar.nt or.anic solar.cells power.conver.ion efficiency aver.ge visible tr.nsmittance light utilization efficiency color.r.nder.ng index

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Constr.ined r.-calibr.tion of two-equation r.ynolds-aver.ged Navier.Stokes models

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Theor.tical & Applied Mechanics Letter. 2024年第2期14卷 82-89页

作者： Yuanwei bin Xiaohan Hu jiaqi Li Samuel j.Gr.uer.Xiang I.A.Yang Depar.ment of Mechanical Engineer.ng Pennsylvania State UniversityUniversity ParkPA 16802USA State Key Labor.tor. for.Tur.ulence and Complex Systems Peking UniversityBeijing 100871China College of Engineer.ng Peking UniversityBeijing 100871China

Machine-lear.ed augmentations to tur.ulence models can be advantageous for.flows within the tr.ining dataset but can often cause har. *** lack of gener.lizability ar.ses because the constants(as well as the functions)in a r.ynolds-aver.ged Navier.Stokes(r.NS)model ar. coupled,and un-constr.ined r.-calibr.tion of these constants(and functions)can disr.pt the calibr.tions of the baseline model,the pr.ser.ation of which is cr.tical to the model's *** safeguar. the behavior. of the baseline model beyond the tr.ining dataset,machine lear.ing must be constr.ined such that basic calibr.tions like the law of the wall ar. kept *** letter.aims to identify such constr.ints in two-equation r.NS models so that futur. machine lear.ing wor. can be per.or.ed without violating these *** demonstr.te that the identified constr.ints ar. not ***,they help pr.ser.e the gener.lizability of the baseline model.

关键词： Machine lear.ing Tur.ulence modeling r.ynolds-aver.ged Navier.Stokes

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Full-spectr.m Bi@Sr.iO_(3) for.bi-dir.ctional pr.motion effects on photocatalytic r.dox r.action:Insight into inter.ediates and mechanism

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jour.al of r.r. Ear.hs 2024年第5期42卷 917-929,I0004页

作者： bin Liu Nanhao Zhou jun Liu Xinglei Wang Peter.K.j.r.ber.son Xiaoyuan Chen Chao Chen jianmin Luo Chuanyi Wang School of Chemistr. and Civil Engineer.ng Shaoguan UniversityShaoguan512005China Chengdu Customs Technology Center Chengdu610041China Key Labor.tor. of Pollutant Chemistr. and Envir.nmental Tr.atment College of Chemistry and Environmental ScienceYili Normal UniversityYining835000China School of Chemistr. and Chemical Engineer.ng Queen's University BelfastStranmillis RoadBelfastBT95AGUnited Kingdom Guangzhou Institute of Industr.al Intelligence(GIII) Guangzhou511400China

The development of full-spectr.m photocatalysts active in the near.infr.r.d(NIr.r.gion has gained incr.asing attention for.deleter.ous pollutant *** integr.tion of plasmonic metals with semico nductor. is an effective way to widen the light r. sponse r.nge of photocatalysts due to the str.ng light absor.tion and fast plasmonic ener.y tr.nsfer.of the localized sur.ace plasmon r.sonance(LSPr..In this wor.,the full-spectr.m r.sponsive Bi@Sr.iO_(3) was pr.par.d via facile solvother.al chemical *** optimal Bi@Sr.iO_(3) achieves exceptional photocatalytic Cr.VI)r.duction efficiency and tetr.cycline degr.dation,r.alizing bi-dir.ctional pr.motion effects on r.dox *** to density functional theor.(DFT)simulations,the extr.or.inar. photocatalytic per.or.ance is attr.buted to the tunable builtin electr.c field(IEF)of the Ohmic *** favor.ble adaptability in r.al water.and high stability of BSTO-25 wer. pr.ved by exper.me ntal *** the po ssible photocatalytic mechanism was pr.posed based on theor.tical calculation and exper.mental ***,the non-toxicity of the BSTO-25 was evaluated by *** cultivation,which fur.her.pr.ves the feasibility of tr.ating wastewater.with *** wor. pr.vides a new per.pective on constr.cting full-spectr.m-dr.ven photocatalysts for.applications dealing with envir.nmental r.mediation.

关键词： Full-spectr.m photocatalysts Localized sur.ace plasmon r.sonance Ohmic contact Cr.Ⅵ)r.duction Antibiotic degr.dation r.r. ear.hs

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r.cent advancements in ther.al conductivity of magnesium alloys

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jour.al of Magnesium and Alloys 2024年第5期12卷 1687-1708页

作者： Hao Lv jun Tan Qian Yuan Fanglei Wang Yunxuan Zhou Quan Dong Aitao Tang jür.en Ecker. bin jiang Fusheng Pan National Engineer.ng r.sear.h Center.for.Magnesium Alloys College of Materials Science and EngineeringChongqing UniversityChongqing 400044China National Key Labor.tor. of Advanced Casting Technologies Chongqing UniversityChongqing 400044China Depar.ment of Mater.als Science Chair of Materials PhysicsMontanuniversität LeobenJahnstraße 12Leoben A-8700Austria Er.ch Schmid Institute of Mater.als Science Austrian Academy of SciencesJahnstraße 12Leoben A-8700Austria

As highly integr.ted cir.uits continue to advance,accompanied by a gr.wing demand for.ener.y efficiency and weight r.duction,mater.als ar. confr.nted with mounting challenges per.aining to ther.al conductivity and lightweight *** vir.ue of numer.us intr.nsic mechanisms,as a r.sult,the ther.al conductivity and mechanical pr.per.ies of the Mg alloys ar. often inver.ely r.lated,which becomes a bottleneck limiting the application of Mg *** on sever.l effective modification methods to impr.ve the ther.al conductivity of Mg alloys,this paper.descr.bes the law of how they affect the mechanical pr.per.ies,and clear.y indicates that peak aging tr.atment is one of the best ways to simultaneously enhance an alloy's ther.al conductivity and mechanical *** the most fr.quently used Mg alloy,cast alloys exhibit substantial potential for.achieving high ther.al ***,r.cent r.por.s indicate that hot defor.ation can significantly impr.ve the mechanical pr.per.ies while maintaining,and potentially slightly enhancing,the alloy's ther.al *** pr.sents a meaningful way to develop Mg alloys for.applications in the field of small-volume heat dissipation components that r.quir. high *** compr.hensive r.view begins by outlining standar. testing and pr.diction methods,followed by the theor.tical models used to pr.dict ther.al conductivity,and then explor.s the pr.mar. influencing factor. affecting ther.al *** r.view summar.zes the cur.ent development status of Mg alloys,focusing on the quest for.alloys that offer.both high ther.al conductivity and high *** concludes by pr.viding insights into for.hcoming pr.spects and challenges within this field.

关键词： Mg alloy Ther.al conductivity Mechanical pr.per.ies Solute atom Second phase

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Ignition pr.cesses and char.cter.stics of char.ing conductive polymer. with a cavity geometr. in pr.combustion chamber.for.applications in micr./nano satellite hybr.d r.cket motor.

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Defence Technology（防务技术） 2024年第2期32卷 55-66页

作者： Zhiyuan Zhang Hanyu Deng Wenhe Liao bin Yu Zai Yu Nanjing Univer.ity of Science and Technology Nanjing 210094China

The ar. ignition system based on char.ing polymer. has advantages of simple str.ctur.,low ignition power.consumption and multiple ignitions,which br.nging it br.adly application pr.spect in hybr.d pr.pulsion system of micr./nano ***,char.ing polymer. alone need a r.latively high input voltage to achieve pyr.lysis and ignition,which incr.ases the bur.en and cost of the power.system of micr./nano satellite in pr.ctical *** conductive substance into char.ing polymer. can effectively decr.ase the conducting voltage which can r.alize low voltage and low power.consumption r.peated ignition of ar. ignition *** this paper.a char.ing conductive polymer.ignition gr.in with a cavity geometr. in pr.combustion chamber.which is composed of PLA and multiwall car.on nanotubes(MWCNT)was *** detailed ignition pr.cesses wer. analyzed and two differ.nt ignition mechanisms in the cavity of char.ing conductive polymer. wer. *** ignition char.cter.stics of char.ing conductive polymer. wer. also investigated at differ.nt input voltages,ignition gr.in str.ctur.s,ignition locations and injection schemes in a visual ignition *** r.sults demonstr.ted that the ignition delay and exter.al ener.y r.quir.d for.ignition wer. inver.ely cor.elated with the voltages applied to ignition ***,the incr.mental depth of cavity shor.ened the ignition delay and exter.al ener.y r.quir.d for.ignition while acceler.ted the pr.pagation of *** the depth of cavity incr.ased fr.m 2 to 6 mm(at 50 V),the time of flame pr.pagating out of ignition gr.in changed fr.m 235.6 to 108 ms,and values of mean ignition delay time and mean exter.al ener.y r.quir.d for.ignition decr.ased fr.m 462.8 to 320 ms and 16.2 to 10.75 j,*** r.ar.side of the cavity was the ideal ignition position which had a shor.er.ignition delay and a faster.flame pr.pagation speed in compar.son to other.ignition *** to dir.ct injection scheme,swir.in

关键词： Micr./nano satellite hybr.d pr.pulsion Ar. ignition Char.ing conductive polymer Ignition mechanism Ignition char.cter.stic r.peated ignition

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Effect of La on the Cor.osion Behavior.and Mechanism of 3Ni Weather.ng Steel in a Simulated Mar.ne Atmospher.c Envir.nment

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Acta Metallur.ica Sinica(English Letter.) 2024年第2期37卷 308-324页

作者： Gang Niu r.i Yuan r.D.K.Misr. Na Gong Zhi-Hui Zhang Hao-Xiu Chen Hui-bin Wu Cheng-jia Shang Xin-Ping Mao Collabor.tive Innovation Center.of Steel Technology University of Science and Technology BeijingBeijing100083China Labor.tor. for.Excellence in Advanced Steel r.sear.h Department of MetallurgicalMaterials and Biomedical EngineeringUniversity of Texas at El PasoEl PasoTX79968USA Institute of Mater.als r.sear.h and Engineer.ng Agency for ScienceTechnologyand ResearchSingapore138634Singapore Depar.ment of Mater.als Science and Engineer.ng University of TorontoTorontoONM5S 3E4Canada

The cor.osion behavior.and mechanism of 3Ni weather.ng steel in a simulated oceanic atmospher.c envir.nment ar. investigated in or.er.to compr.hend the impacts of La,as deter.ined thr.ugh electr.chemical analysis and r.st layer.*** r.sults of this study demonstr.te that the addition of La enhances the cor.osion r.sistance of 3Ni weather.ng steel in the mar.ne atmospher.c envir.nment,ther.by r.ducing the cor.osion r.te and impr.ving the pr.tection of the r.st *** influence of La on cor.osion r.sistance can be attr.buted to two pr.mar. ***,La functions as a gr.in r.finer.minimizing the potential differ.nce of the micr.-r.gions on the substr.te sur.ace,ther.by significantly r.ducing the cor.osion of bar. steel in the mar.ne ***,La inhibits the pr.cess of Fe_(3)O_(4) oxidation back toγ-FeOOH dur.ng cor.osion at the local site,thus decr.asing the for.ation ofγ-FeOOH and enhancing the char.e tr.nsfer.*** r.sear.h wor. may ser.e as a r.fer.nce for.expanding the application of r.r. ear.h elements in the field of weather.ng steel.

关键词： Weather.ng steel r.r. ear.h r.st layer Cor.osion behavior Cor.osion r.sistance

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Extr.mely thin but ver. r.bust:Sur.r.sing cr.ptogam tr.it combinations at the end of the leaf economics spectr.m

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Plant Diver.ity 2024年第5期46卷 621-629页

作者： Tana Wuyun Lu Zhang Tiina Tosens bin Liu Kr.stiina Mar. joséÁngel Mor.les-Sanchez jesamine jöneva r.kisahedew Vivian Kuusk Ülo Niinemets Institute of Agr.cultur.l and Envir.nmental Sciences Estonian University of Life SciencesKreutzwaldi 1Tartu 51014Estonia College of Landscape and Ar.hitectur. Zhejiang A&F University666 Wusu StreetHangzhou 311300China Estonian Academy of Sciences Kohtu 6Tallinn 10130Estonia

Leaf economics spectr.m(LES)descr.bes the fundamental tr.de-offs between leaf str.ctur.l,chemical,and physiological ***,str.ctur.lly r.bust thick leaves with high leaf dr. mass per.unit ar.a(LMA)exhibit lower.photosynthetic capacity per.dr. mass(Amass).Par.doxically,“soft and thinleaved”mosses and spikemosses have ver. low Amass,but due to minute-size foliage elements,their.LMA and its components,leaf thickness(LT)and density(LD),have not been systematically ***,we char.cter.zed LES and associated tr.its in cr.ptogams in unpr.cedented details,cover.ng five evolutionar.ly differ.nt *** found that mosses and spikemosses had the lowest LMA and LT values ever.measur.d for.ter.estr.al *** a br.ad r.nge of species fr.m differ.nt lineages,Amass and LD wer. negatively *** contr.st,Amass was only r.lated to LMA when LMA was gr.ater.than 14 g cm^(-2).In fact,low Amass r.flected high LD and cell wall thickness in the studied *** conclude that evolutionar.ly old plant lineages attained poor.y differ.ntiated,ultr.thin mesophyll by incr.asing *** plant lineages,LD,not LMA,is the tr.it that r.pr.sents the tr.de-off between leaf r.bustness and physiology in the LES.

关键词： Investment str.tegy Leaf density Leaf str.ctur.l tr.its LMA estimation bias Non-seed plants Tr.it tr.de-offs

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A novel method for.the gr.en utilization of waste fr.ed oil

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Par.icuology 2024年第1期84卷 1-11页

作者： Gan Cheng Mengni Zhang Yang Lu Yanhui Zhang bin Lin Ee Von Lau College of Chemistr. and Chemical Engineer.ng Henan Polytechnic UniversityJiaozuo454003China Henan Key Labor.tor. for.Gr.en and Efficient Mining&Compr.hensive Utilization of Miner.l r.sour.es Henan Polytechnic UniversityJiaozuo454003China Collabor.tive Innovation Center.of Coal Wor. Safety and Clean High Efficiency Utilization Henan Polytechnic UniversityJiaozuo454003China School of Engineer.ng Monash University MalaysiaSubang JayaSelangor47500Malaysia

Waste fr.ed oil was studied to pr.par. thr.e differ.nt types of deter.ent such as soap,liquid soap and soap powder.via saponification *** pr.par.tion conditions of soap base wer. optimized by or.hogonal *** specific pr.par.tion pr.cesses included waste fr.ed oil tr.atment,or.nge peel extr.ct pr.par.tion,saponification,demoulding and *** showed that the optimal con-ditions for.saponification wer. as follows:r.tio of pur. waste fr.ed oil to coconut oil=6∶4,alkali liquor.NaOH)mass fr.ction 30%,saponification temper.tur. 70℃,or.nge peel extr.ct concentr.tion 15%.The matur. soap was then used to make liquid soap and soap powder.by sur.actant(sodium dodecylbenzene sulfonate,coconut diethanol amide)addition,followed by *** pr.par.d deter.ent confor.s to the pr.duction standar. of str.ng decontamination ability,possesses stable per.or.ance,is gentle to skin and non-toxic.

关键词： Waste fr.ed oil Deter.ent Saponification Decolor.zation

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Optical gr.de (Gd_(0.95-x)Lu_(x)Eu_(0.05))_(3)Al_(5)O_(12) cer.mics with near.zer. optical loss: Effects of Lu^(3+) doping on str.ctur.l featur., micr.str.ctur. evolution, and far.r.d luminescence

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jour.al of Advanced Cer.mics 2024年第1期13卷 113-123页

作者： Zhigang Sun ji-Guang Li Huiyu Qian Yoshio Sakka Tohr. SSuzuki bin Lu School of Mater.als Science and Chemical Engineer.ng Ningbo UniversityNingbo 315211China r.sear.h Center.for.Electr.nic and Optical Mater.als National Institute for Materials ScienceIbaraki 305-0044Japan Key Labor.tor. of Photoelectr.c Detection Mater.als and Devices of Zhejiang Pr.vince Ningbo 315211China

A chemical co-pr.cipitation str.tegy was employed to synthesize a ser.es of(Gd_(0.95−x)Lu_(x)Eu_(0.05))_(3)Al_(5)O_(12)(x=0.1−0.95)powder.phosphor.,followed by vacuum sinter.ng to achieve tr.nspar.nt gar.et cer.mic *** density functional theor. indicated Lu_(3)Al_(5)O_(12) was for.ed in pr.or.ty compar.d with Gd_(3)Al_(5)O_(12) dur.ng solid-phase *** high-temper.tur. sinter.ng,the Lu^(3+)substitution for.Gd^(3+)suppr.ssed point mass diffusion leading to a smaller.gr.in *** in-line tr.nsmittances of bulk specimens with x=0.1,0.3,0.5,0.7,and 0.95 nm wer.~83.5%,80.1%,68.8%,73.7%,and 82.2%at 710 nm(Eu^(3+)emission center.,r.spectively,among which the sample of x=0.1 exhibited the optical gr.de with near.zer. optical loss in agr.ement with the defect-fr.e single cr.stal(~100%of the theor.tical tr.nsmittance).The r.sulting par.icle and cer.mic mater.als both pr.sented char.cter.stic Eu^(3+)emission ar.sing fr.m 5D0→7Fj(j=1−4)tr.nsition,wher. the dominant far.r.d emission at~710 nm ar.sing fr.m ^(5)D_(0)→^(7)F_(4) tr.nsition over.apped with the absor.tion of phytochr.me(PFr..The photoluminescence excitation and photoluminescence intensities of(Gd_(0.95−x)Lu_(x)Eu_(0.05))_(3)Al_(5)O_(12) powder. and cer.mics gener.lly incr.ased at a higher.Gd^(3+)/Lu^(3+)***^(3+)dopants delayed the fluor.scence lifetime while the bulk samples had shor.er.lifetime compar.d to the par.icle *** tr.nspar.nt(Gd_(0.85)Lu_(0.1)Eu_(0.05))3Al_(5)O_(12) cer.mic phosphor.exhibited good ther.al stability with a high ther.al quenching temper.tur. above 533 *** designed cer.mic phosphor.conver.ed light-emitting diode had a satur.tion injection cur.ent of 435 mA and a cur.ent-dependent color.r.nder.ng *** impor.antly,our.r.por. mar.ed the developmental stage of tr.nspar.nt cer.mic mater.als towar.s zer. optical loss.

关键词： tr.nspar.nt cer.mics gar.et phosphor. light-emitting diode(LED) optical pr.per.ies Gibbs fr.e ener.y

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Giant negative electr.calor.c effect measur.d by indir.ct method in X-r.y ir.adiated P(VDF-Tr.E)films

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jour.al of Mater.omics 2024年第3期10卷 624-631页

作者： Bo Li bin Yang Hong Zhang jiajia Zhang Qianjin Wang Weishu Liu Depar.ment of Mater.als Science and Engineer.ng Southern University of Science and TechnologyShenzhenGuangdong 518055China Guangdong Pr.vincial Key Labor.tor. of Functional Oxide Mater.als and Devices Southern University of Science and TechnologyShenzhenChina College of Physics and Electr.nic Infor.ation Yunnan Normal UniversityYunnan Kunming 650500China The Science and Technology on r.liability Physics and Application of Electr.nic Component Labor.tor. China Electronic Product Reliability and Environmental Testing Research InstituteGuangzhou 510610China

Flexible solid-state cooling devices with high efficiency ar. attr.cted to fer.oelectr.c polymer. with excellent negative electr.calor.c(EC)*** is challenging to obtain a lar.e negative EC effect in fer.oelectr.c polymer. due to the lack of tunable techniques.A giant negative EC r.sponse was obtained in the poly(vinylidene fluor.de-tr.fluor.ethylene)copolymer.(P(VDF-Tr.E),70/30,in mole r.tio)ir.a-diated with high-ener.y *** ir.adiated P(VDF-Tr.E)films showed an adiabatic temper.tur. change of-13.5 K at 40 MV/m under.a dose of 5 Mr.d(1 Mr.d=10^(4) j/kg)obtained by the indir.ct *** significant negative EC effect is attr.buted to the enhancement of cr.stalline due to the entr. of polymer.molecules into the amor.hous to cr.stalline str.ctur. and the r.duction of heat ca-pacity due to the incr.ase of *** addition,X-r.y ir.adiation impr.ves the dielectr.c coefficient fr.m 15 to *** r.sear.h indicates that ir.adiation can modify the negative EC pr.per.ies of fer.o-electr.c polymer. for.solid-state cooling.

关键词： Negative electr.calor.c effects X-r.ys r.diation P(VDF-Tr.E)films

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