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Photoluminescence and radioluminescence properties of (Gd8Ca2)(SiO4)6O2 crystals with different concentrations of Ce

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Journal of Rare Earths 2017年第11期35卷 1071-1076页

作者： Takuya Igashira Masaki Mori Go Okada Noriaki Kawaguchi takayuki yanagida Graduate School of Materials Science Nara Institute of Sdence and Technology (NAIST) 8916-5 Takayama Ikoma Nam Japan

(GdCa)(SiO)Oapatite crystals doped with different concentrations of Ce were synthesized by the Floating Zone(FZ) method, and we have evaluated the photoluminescence(PL) and radio luminescence(RL) properties. In PL, an emission band appeared around 400 nm under excitation at 300 nm due to the5 d-4 f transitions of Ce3+. The PL decay curves were approximated by a second-order exponential decay function, and the derived decay time constants ranged around 20-25 ns and 40-480 ns. Similar emission was observed in RL, but the decay time constants were much longer than those in PL. The RL afterglow was the lowest in the 1.0% Ce-doped sample. The 1.0% and 2.0% Ce-doped samples showed a full-energy peak in the pulse height spectrum measured underAm 5.5 MeV α-ray irradiation, and the absolute scintillation light yields were estimated to be around 55 and 36 ph/5.5 MeV-a, respectively.

关键词： Scintillator Apatite Ce^(3+) 5d-4f transition

Sm-doped CsBr crystal as a new radio-photoluminescence (RPL) material

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Journal of Rare Earths 2016年第8期34卷 769-773页

作者： Go Okada Yutaka Fujimoto Hironori Tanaka Safa Kasap takayuki yanagida Graduate School of Materials Science Nara Institute of Science and Technology (NAIST) 8916-5 Takayama Ikoma Nara 630-0192 Japan Department of Applied Chemistry Graduate School of Engineering Tohoku University 6-6-07 Aoba Aramaki Aoba-ku Sendai 980-8579 Japan Department of Electrical and Computer Engineering University of Saskatchewan 57 Campus Dr. Saskatoon SK S7N5A9 Canada

Radio-photoluminescence （RPL） is a phenomenon seen in luminescent materials in which the appearance of new photolu- minescence （PL） emission is induced by an incident ionizing radiation such as X-rays; and the signal is stable even after the irradia- tion and during the PL measurement. Since the induced PL intensity is proportional to the irradiation dose, the RPL can be used in ra- diation measurements. The distinct advantage of RPL over the conventional thermally- or photo-stimulated luminescence （abbrevi- ated as TSL or PSL） dosimeters is the stability of response signal. With an RPL detector, it allows us to readout the signal multiple time without signal fading. In this work, we discovered that CsBr：Sm showed an RPL phenomenon by X-ray irradiation, and we characterized this new material as an RPL detector. While the sample showed PL emissions mainly in the visible range, after an X-ray irradiation additional emissions could be observed in the red to near-infrared range around 650-850 nm and 900-1000 nm and longer. The RPL response was fairly stable overall, but very interestingly the 650-850 nm signal slightly increased while the 900-1000 nm decreased during PL readout. The dynamic range was confirmed over 1-104 mGy with linear response.

关键词： radio-photoluminescence RPL CsBr Sm dosimeter X-rays rare earths

Photoluminescence, scintillation and thermally-stimulated luminescence properties of Tb-doped 12CaO·7Al2O3 single crystals grown by FZ method

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Journal of Rare Earths 2017年第10期35卷 957-963页

作者： Narumi Kumamoto Daisuke Nakauchi Takumi Kato Go Okada Noriaki Kawaguchi takayuki yanagida Graduate School of Materials Science Nara Institute of Science and Technology (NAIST) 8916-5 Takayama-cho Ikoma-shi Nara 630-0192 Japan

Tb-doped 12CaO·7Al_2O_3（Tb：C12A7） crystals were synthesized by the floating zone（FZ） method and the photoluminescence（PL）, scintillation and thermally-stimulated luminescence（TSL） properties were investigated. The photoluminescence（PL） emission spectra and PL decay time profiles were investigated by using Quantaurus-tau（Hamamatsu）. The scintillation spectra and decay time profiles were measured by using our laboratory-constructed set-up under X-ray irradiation. Finally, TSL glow curve was measured by using Nanogray TL-2000 with the heating rate of 1 °C/s. In PL and scintillation, emission peaks were observed at 493, 543, 587 and 620 nm due to the 4f-4f transitions of Tb3~＋. Decay time constants of the emission by PL and scintillation appeared to be different, and the measured values were approximately 2.4 and 1.9 ms, respectively. After X-ray irradiations, the 0.5%（all Tb contents in this paper are in mole fraction） and 1.0% Tb-doped samples showed a single intense and broad glow peak around 100 oC while 1.2%–1.5% Tb-doped samples showed notable additional peak around 250 oC.

关键词： C12A7 single crystal FZ terbium scintillation photoluminescence TSL rare earths

Scintillation and optical properties of Ce-doped YAGG transparent ceramics

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Journal of Rare Earths 2016年第8期34卷 763-768页

作者： Masaki Mori Jian Xu Go Okada takayuki yanagida Jumpei Ueda Setsuhisa Tanabe Graduate School of Materials' Science Nara Institute of Science and Technology (NAIST) 8916-5 Takayama-cho Ikoma-shi Nara 630-0192 Japan Graduate School of Human and Environmental Studies Kyoto University Yoshida-nihonmatsu-eho Sakyo-ku Kyoto 606-8501 Japan

We investigated photoluminescence （PL） and scintillation properties of Ce3＋-doped Y3A12Ga3OI2 （Ce：YAGG） trans- parent ceramics synthesized by vacuum sintering with different Ce3＋ concentrations （mol.%） from 0.3% to 1% （0.3%Ce：YAGG, 0.5%Ce：YAGG, 0.8%Ce：YAGG and I%Ce：YAGG）. The samples were synthesized by the vacuum sintering technique. The obtained samples showed a very strong and broad PL emission by the 5dl-4f transition of Ce3＋ in the wavelength range from 470 to 600 nm. The PL decay profiles were approximated by a single exponential decay function with the time constants of around 33-39 ns, Fur- thermore, the scintillation spectra induced by X-rays showed similar features with those observed in PL. The scintillation decay time profiles followed a second-order exponential decay function. The fast component group （ranged 3542 ns） were dominantly contrib- uted by the 5d1-4f transition of Ce3＋. The pulse height spectra utilizing the latter emissions showed a clear photoabsorption peak. Among those samples tested, 0.5%Ce：YAGG sample showed the highest scintillation light yield of 21,400 ph/MeV under 13VCs y-ray irradiation.

关键词： YAGG cerium transparent ceramic scintillation photoluminescence rare earths

Féeton(B-L gauge boson)dark matter for the 511-keV gamma-ray excess and the prediction of low-energy neutrino flux

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Chinese Physics C 2024年第8期48卷 76-82页

作者： Jie Sheng Yu Cheng Weikang Lin Tsutomu T.yanagida Tsung-Dao Lee Institute&School of Physics and Astronomy Shanghai Jiao Tong UniversityChina Key Laboratory for Particle Astrophysics and Cosmology(MOE)&Shanghai Key Laboratory for Particle Physics and Cosmology Shanghai Jiao Tong UniversityShanghai 200240China South-Western Institute For Astronomy Research Yunnan UniversityKunming 650500China Kavli IPMU(WPI) UTIASUniversity of TokyoKashiwa277-8583Japan

The féeton is the gauge boson of the U(1)_(B−L) gauge *** the gauge coupling constant is extremely small,the féeton becomes a candidate for dark *** show that its decay to a pair of an electron and a positron explains the observed Galactic 511-keV gamma-ray excess in a consistent *** féeton dark matter decays mainly into pairs neutrino and *** low-energy experiments with improved directional capability will enable capturing these neutrino *** seesaw-motivated parameter space predicts a relatively short féeton lifetime that is comparable to the current cosmological constraint.

关键词： feeton 511-keV gamma-ray excess low-energy neutrino

Abnormal uterine bleeding successfully treated via ultrasoundguided microwave ablation of uterine myoma lesions: Three case reports

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World Journal of Clinical Cases 2024年第5期12卷 980-987页

作者： Toshiyuki Kakinuma Kaoru Kakinuma Rora Okamoto Kaoru yanagida Michitaka Ohwada NobuhiroTakeshima Takeshima Department of Obstetrics and GynecologyInternational University of Health and Welfare HospitalTochigi 329-2763Japan

BACKGROUND Microwave endometrial ablation(MEA)is a minimally invasive treatment method for heavy menstrual ***,additional treatment is often required after recurrence of uterine myomas treated with ***,because this treatment ablates the endometrium,it is not indicated for patients planning to become *** overcome these issues,we devised a method for ultrasound-guided microwave ablation of uterine myoma feeder *** report three patients successfully treated for heavy menstrual bleeding,secondary to uterine myoma,using our novel *** SUMMARY All patients had a favorable postoperative course,were discharged within 4 h,and experienced no ***,no postoperative recurrence of heavy menstrual bleeding was *** method also reduced the myoma’s maximum *** This method does not ablate the endometrium,suggesting its potential appli-cation in patients planning to become pregnant.

关键词： Uterine myoma Microwave Heavy menstrual bleeding Dysmenorrhea Fertility preservation Case report

Uterine artery pseudoaneurysm caused by hysteroscopic surgery: A case report

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World Journal of Clinical Cases 2024年第26期12卷 5968-5973页

作者： Kaoru Kakinuma Toshiyuki Kakinuma Kyouhei Ueyama Rora Okamoto Kaoru yanagida Nobuhiro Takeshima Michitaka Ohwada Department of Obstetrics and Gynecology International University of Health and Welfare Hospital537-3 IguchiNasushiobaraTochigi 329-2763Japan

BACKGROUND We report a case of uterine artery pseudoaneurysm(UAP)occurrence during hysteroscopic endometrial polypectomy and its treatment via uterine artery embolization(UAE).CASE SUMMARY A 48-year-old primigravid,primiparous patient was incidentally found to have an endometrial polyp during a health checkup,and underwent a hysteroscopic polypectomy at another *** cervix was dilated with a Laminken-R®*** the Laminken-R®was withdrawn,a large amount of genital bleeding was *** bleeding persisted after the hysteroscopic polypectomy,and,as hemostasis became impossible,the patient was transferred to our hospital by *** arrival,transvaginal ultrasonography revealed a 3-cm hypoechoic mass with a swirling internal pulse on the right side of the uterus,and color Doppler ultrasonography showed feeder vessels penetrating the *** contrast-enhanced computed tomography(CT)confirmed the presence of a mass at this site,and vascular proliferation was observed within the uterine ***,UAP was diagnosed,and UAE was *** patient’s postoperative course was uneventful,and 6 mo post-UAE,no recurrence of blood flow to the UAP was *** When abnormal genital bleeding occurs during hysteroscopic surgery,ultrasonography and contrast-enhanced CT can assist in the detection of early UAPs.

关键词： Cervical dilation Hysteroscopic surgery Uterine artery pseudoaneurysm Uterine artery embolization Case report

Managing Vogt–Koyanagi–Harada disease during pregnancy with steroid pulse therapy:A case report

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World Journal of Clinical Cases 2024年第31期12卷 6493-6499页

作者： Kyouhei Ueyama Toshiyuki Kakinuma Keisuke Mori Ayumi Hayashi Kaoru Kakinuma Rora Okamoto Ayaka Kaneko Kaoru yanagida Nobuhiro Takeshima Michitaka Ohwada Department of Obstetrics and Gynecology International University of Health and Welfare HospitalTochigi 329-2763NasushiobaraJapan Department of Ophthalmology International University of Health and Welfare HospitalTochigi 327-2763Japan

BACKGROUND High-dose steroid administration is a common initial therapeutic approach for Vogt–Koyanagi–Harada disease(VKH).Nonetheless,administering substantial doses of steroids to pregnant women necessitates meticulous consideration due to the potential impacts on the mother and *** present a case wherein steroid pulse therapy was administered to a patient who developed VKH during the late stages of *** SUMMARY The patient was a 26-year-old nulliparous *** 33 weeks and 1 day of her pregnancy,she experienced a decline in visual acuity and noticed metamorphopsia in her left *** revealed bilateral serous retinal detachment,leading to VKH diagnosis.A collaborative effort involving the departments of ophthalmology,internal medicine,and neonatology was *** pulse therapy was administered at 34 weeks and 1 day of pregnancy under hospital ***,such as threatened preterm labor and gestational diabetes,emerged,necessitating the initiation of oral ritodrine hydrochloride and insulin ***,serous retinal detachment was resolved,and visual acuity was *** pains initiated 32 days post-initiation of steroid pulse therapy(at 38 weeks and 4 days of gestation),culminating in a normal *** and newborn experienced an uneventful puerperal course and were discharged from the hospital on the 5th day following *** VKH management in pregnancy requires multidisciplinary coordination,emphasizing collaboration with ophthalmologists and specialists in internal medicine and neonatology.

关键词： Vogt-Koyanagi-Harada disease Gestational diabetes mellitus pregnancy Steroid pulse therapy Threatened preterm labor Case report

Removal of hexavalent chromium from water by Z-scheme photocatalysis using TiO_(2)(rutile)nanorods loaded with Au core-Cu_(2)0 shell particles

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Journal of Environmental Sciences 2022年第5期34卷 173-189页

作者： Sayaka yanagida Takumi Yajima Takahiro Takei Nobuhiro Kumada Center for Crystal Science and Technology University of YamanashiKofu 400-8511Japan Advanced Materials Development Sector Tokyo Metropolitan Industrial Technology Research Institute2-4-10AomiKoto-kuTokyo 135-0064Japan

All-solid-state Z-scheme photocatalysts,containing Cu_(2)O,TiO_(2)(rutile),and Au as the elec-tron mediator,were prepared and applied to the reduction of Cr(Ⅵ)in aqueous *** Cu_(2)O-Au-TiO_(2) composites were prepared by loading Au core-Cu_(2)O shell hemisphere particles on TiO_(2)(rutile)nanorods using a two-step photocatalytic deposition ***-der ultraviolet-visible(UV-vis)light illumination,the Cu_(2)O-Au-TiO_(2) composites exhibited higher photocatalytic Cr(Ⅵ)reduction activities than those exhibited by single TiO_(2)(rutile)and Cu_(2)*** this reaction,a precipitate containing Cr,which was considered to be Cr(OH)_(3),was deposited site-selectively on the Au core-Cu_(2)O shell particles of the composites,indi-cating that the reduction site of the composite was Cu_(2)O,and the reaction proceeded accord-ing to the *** Cu_(2)O-Au-TiO_(2) composites also exhibited photocatalytic activity under visible light *** oxidation state of Cu in the Cu_(2)O-Au-TiO_(2) composite gradually changed from Cu(Ⅰ)to Cu(Ⅱ)during the photocatalytic Cr(Ⅵ)*** the composite maintained its high photocatalytic performance even after *** role of Au in the Cu_(2)O-Au-TiO_(2) composite was examined by comparing the properties of the Cu_(2)O-Au-TiO_(2) composite with those of the Cu_(2)O-TiO_(2) composite prepared via direct Cu_(2)O deposition on TiO_(2).

关键词： Cu_(2)O TiO_(2)(rutile) Z-scheme Photocatalyst Chromium