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Property-performance relationship of core-shell structured black TiO_(2) photocatalyst for environmental remediation

引用

Frontiers of Environmental Science & Engineering 2023年第9期17卷 177-195页

作者： Sajjad Haider Rab Nawaz Muzammil Anjum tahir haneef Vipin Kumar Oad Salah Uddinkhan Rawaiz Khan Muhammad Aqif Chemical Engineering Department College of EngineeringKing Saud UniversityRiyadh 11421Saudi Arabia Department of Environmental Sciences Institute of Soil and Environmental SciencesPir Mehr Ali Shah Arid Agriculture University ShamsabadRawalpindi 46300Pakistan Centre of Innovative Nanostructures and Nanodevices(COINN) Institute of Autonomous SystemUniversiti Teknologi PETRONASBandar Seri Iskandar 32610Malaysia Civil and Environmental Engineering Department The University of Alabama in HuntsvilleHuntsvilleAL 35899USA Faculty of Civil and Environmental Engineering Gdansk University of TechnologyGdansk 80-233Poland College of Engineering King Saud UniversityRiyadh 11421Saudi Arabia Restorative Dental Sciences Department College of DentistryKing Saud UniversityRiyadh 11545Saudi Arabia Faculty of Materials and Chemical Engineering Department of Chemical EngineeringGhulam Ishaq Khan InstituteKhyber Pakhtunkhwa Topi 23460Pakistan

Understanding the relationship between the properties and performance of black titanium dioxide with core-shell structure(CSBT)for environmental remediation is crucial for improving its prospects in practical *** this study,CSBT was synthesized using a glycerol-assisted sol-gel *** effect of different water-to-glycerol ratios(W:G=1:0,9:1,2:1,and 1:1)on the semiconducting and physicochemical properties of CSBT was *** effectiveness of CSBT in removing phenolic compounds(PHCs)from real agro-industrial wastewater was *** CSBT synthesized with a W:G ratio of 9:1 has optimized properties for enhanced removal of *** has a distinct coreshell structure and an appropriate amount of Ti3+cations(11.18%),which play a crucial role in enhancing the performance of *** exposed to visible light,the CSBT performed better:48.30%of PHCs were removed after 180 min,compared to only 21.95%for TiO_(2) without core-shell *** CSBT consumed only 45.5235 kWh/m^(3) of electrical energy per order of magnitude and cost$2.4127 per unit volume of treated agro-industrial *** the conditions tested,the CSBT demonstrated exceptional stability and *** CSBT showed promising results in the treatment of phenols-containing agro-industrial wastewater.

关键词： Black TiO_(2) Core-shell structure Property-performance relationship Agro-industrial effluent Environmental remediation

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