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AN IMPRINTED POLYMER FOR REMOVAL OF Cd^(2+) FROM WATER SAMPLES:OPTIMIZATION OF ADSORPTION AND RECOVERY STEPS BY EXPERIMENTAL DESIGN

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Chinese Journal of Polymer Science 2011年第6期29卷 658-669页

作者： taher alizadeh Department of Applied Chemistry Faculty of ScienceUniversity of Mohaghegh ArdabiliArdabilIran

A new ion-imprinted polymer （liP） was synthesized by copolymerization of 4-vinylpyridine （monomer）, ethyleneglycoldimethacrylate （cross-linker） and 2,2-azobis-isobutyronitrile （initiator） in the presence of Cd2＋ and quinaldic acid （complexing agent）. It was found that the adsorption capacity of IIP and blank polymer were 45.0 and 6.2 mg g-l, respectively. The relative selectivity coefficients of the imprinted polymer for different binary mixture were also calculated. Compared to non-imprinted polymer （NIP）, the IIP had higher selectivity for Cd（II）. The IIP was used as a sorbent for cadmium extraction from water samples by using a simple batch extraction procedure. The effect of different parameters on Cd2＋ extraction and its recovery from the IIP were evaluated and optimized by using experimental design methodology. The optimized adsorption/desorption procedure was applied for cadmium removal from the real water samples. The obtained recoveries proved that this IIP could be used for removal of trace cadmium ions from water samples.

关键词： Cd2+ removal Ion imprinted polymer Solid phase extraction Experimental design

Voltammetric determination of venlafaxine as an antidepressant drug employing Gd_2O_3 nanoparticles graphite screen printed electrode

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Journal of Rare Earths 2019年第3期37卷 322-328页

作者： Hadi Beitollahi Shohreh Jahani Somayeh Tajik Mohammad Reza Ganjali Farnoush Faridbod taher alizadeh Environment Department Institute of Science and High Technology and Environmental Sciences Graduate University of Advanced Technology NanoBioElectrochemistry Research Center Bam University of Medical Sciences Center of Excellence in Electrochemistry School of Chemistry College of Science University of Tehran Biosensor Research Center Endocrinology & Metabolism Molecular-Cellular Sciences Institute Tehran University of Medical Sciences Department of Analytical Chemistry Faculty of Chemistry College of Science University of Tehran

Graphite screen printed electrode modified with Gd_2 O_3 nanoparticles(Gd_2 O_3/SPE) was developed for the determination of venlafaxine(VF). The Gd_2 O_3 nanoparticles were thoroughly characterized by scanning electron microscopy(SEM), transmission electron microscopy(TEM) and X-ray diffraction(XRD) analyses. To study the electrochemical behaviour of venlafaxine cyclic voltammetry(CV), chronoamperometry(CHA)and differential pulse voltammetry(DPV) were employed. These studies reveal that the oxidation of venlafaxine is facilitated at Gd_2 O_3/SPE. After optimization of analytical conditions, analysis of venlafaxine using the modified electrode in 0.1 mol/L PBS(pH 7.0) demonstrates that the peak currents corresponding to venlafaxine vary linearly with its concentration in the range of 5.0 ×10^(-6)-9.0 × 10^(-4) mol/L. The detection limit(S/N = 3) of 2.1 × 10^(-7) mol/L is obtained for venlafaxine using DPV. The prepared modified electrode benefits from advantages such as simple preparation method, high sensitivity and low detection ***, the evaluation of practical applicability of this proposed method is successful in the identification of venlafaxine in pharmaceutical formulations, urine and water samples.

关键词： Venlafaxine Gd2O3 nanoparticles Electrochemical techniques Screen printed electrode Rare earths

Smart Energy Management System Using Machine Learning

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Computers, Materials & Continua 2024年第1期78卷 959-973页

作者： Ali Sheraz Akram Sagheer Abbas Muhammad Adnan Khan Atifa Athar taher M.Ghazal Hussam Al Hamadi School of Computer Science National College of Business Administration&EconomicsLahore54000Pakistan Riphah School of Computing&Innovation Faculty of ComputingRiphah International UniversityLahore CampusLahore54000Pakistan Pattern Recognition and Machine Learning Lab Department of SoftwareGachon UniversitySeongnamGyeonggido13120Korea Department of Computer Science COMSATS University IslamabadLahore CampusLahore54000Pakistan School of Information Technology Skyline University CollegeSharjah1797United Arab Emirates Network and Communication Technology Lab Center for Cyber SecurityFaculty of Information Science and TechnologyUniversiti Kebangsaan MalaysiaBangiSelangor43600Malaysia College of Engineering and IT University of DubaiDubaiUnited Arab Emirates

Energy management is an inspiring domain in developing of renewable energy ***,the growth of decentralized energy production is revealing an increased complexity for power grid managers,inferring more quality and reliability to regulate electricity flows and less imbalance between electricity production and *** major objective of an energy management system is to achieve optimum energy procurement and utilization throughout the organization,minimize energy costs without affecting production,and minimize environmental *** energy management is an essential and complex subject because of the excessive consumption in residential buildings,which necessitates energy optimization and increased user *** address the issue of energy management,many researchers have developed various frameworks;while the objective of each framework was to sustain a balance between user comfort and energy consumption,this problem hasn’t been fully solved because of how difficult it is to solve *** inclusive and Intelligent Energy Management System(IEMS)aims to provide overall energy efficiency regarding increased power generation,increase flexibility,increase renewable generation systems,improve energy consumption,reduce carbon dioxide emissions,improve stability,and reduce energy *** Learning(ML)is an emerging approach that may be beneficial to predict energy efficiency in a better way with the assistance of the Internet of Energy(IoE)*** IoE network is playing a vital role in the energy sector for collecting effective data and usage,resulting in smart resource *** this research work,an IEMS is proposed for Smart Cities(SC)using the ML technique to better resolve the energy management *** proposed system minimized the energy consumption with its intelligent nature and provided better outcomes than the previous approaches in terms of 92.11% accuracy,and 7.89% miss-rate.

关键词： Intelligent energy management system smart cities machine learning

A cross-sectional study on the nurses’attitude towards rapid response system activation for clinically deteriorated patients

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Nursing Communications 2024年第6期8卷 1-8页

作者： Salamah Ahmed taher Alnajei Jefferson Garcia Guerrero East Jeddah General Hospital/Jeddah First cluster Jeddah 22253Saudi Arabia Fakeeh College for Medical Sciences Jeddah 22253 Saudi Arabia

Background:Hospitals have reported that implementing rapid response system activation(RRS)activation has increased patient *** a result,there has been growing interest in identifying factors that lead to successful RRS *** introducing an automated RRS activation system has prompted nurses to be more vigilant about monitoring vital signs,it has not necessarily encouraged them to conduct thorough patient assessments to identify early signs of ***:The current study aimed to assess nurses’attitudes towards RRS activation for clinically deteriorated patients in the clinical units of King Abdul-Aziz ***:A descriptive cross-sectional research design was utilised in the study,and 144 nurses working in the medical and surgical units of King Abdul-Aziz Hospital were recruited to participate using a convenient non-probability sampling ***:The study’s findings reported that nurses have a positive attitude towards RRS benefits(Mean=3.70;SD=0.70).Their overall attitude towards RRS activation among clinically deteriorated patients is still low positive(Mean=2.71;SD=0.61).The nurses’attitudes towards RRS benefits significantly differ among nationalities and the clinical area/unit where they were assigned,with a P-value of 0.0194 and 0.000,*** towards RRS barriers significantly differ among nationality(P-value=0.0037),education level(P-value=0.0032),area of assignment(P-value=0.020),and whether they have a good understanding of abnormal observations(P-value=0.0122).Regarding the nurses’attitude towards management belief,the significant result is only with the clinical area/unit of assignment with a P-value of ***:The current study found a low positive attitude towards RRS activation among ward nurses,especially given that monitoring vital signs is critical to their *** may fear being perceived as clinically inept for redundant activations caused by poor quality,but their attitude t

关键词： rapid response team rapid response system clinically deteriorated patients cardiopulmonary arrest medical-surgical nurses

Correlations between serum kidney injury molecule-1,cystatin C and immunosuppressants:A cross-sectional study of renal transplant patients in Bahrain

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Journal of Biomedical Research 2024年第3期38卷 269-277页

作者： Kannan Sridharan Shamik Shah Mona Al Hammad Fatima Ali Mohammed Sindhan Veeramuthu Mona Abdulla taher Mustafa Mohamed Hammad Lamees Jawad Eman Farid Department of Pharmacology and Therapeutics College of Medicine and Medical SciencesArabian Gulf UniversityManamaKingdom of Bahrain Department of Nephrology Salmaniya Medical ComplexManamaKingdom of Bahrain Department of Internal Medicine College of Medicine and Medical SciencesArabian Gulf UniversityManamaKingdom of Bahrain Salmaniya Medical Complex ManamaKingdom of Bahrain Department of Laboratory Medicine Salmaniya Medical ComplexManamaKingdom of Bahrain Department of Microbiology Immunologyand Infectious DiseasesCollege of Medicine and Medical SciencesArabian Gulf UniversityManamaKingdom of Bahrain

Renal transplant patients receive several immunosuppressive drug regimens that are potentially nephrotoxic for *** creatinine is the standard for monitoring kidney function;however,cystatin C(Cys C)and kidney injury molecule-1(KIM-1)have been found to indicate kidney injury earlier than serum creatinine and provide a better reflection of kidney ***,we assessed Cys C and KIM-1 serum levels in renal transplant patients receiving mycophenolate mofetil,tacrolimus,sirolimus,everolimus,or cyclosporine to evaluate kidney *** used both the Chronic Kidney Disease Epidemiology Collaboration(CKD-EPI)2021 equation,which is based on creatinine and combined creatinine with Cys C,and the CKD-EPI 2012 equation,which is based on Cys C alone,to estimate glomerular filtration rate(GFR).Then,we assessed the association between serum KIM-1 and GFR<90 mL per minute per 1.73 *** observed significantly higher serum Cys C levels in patients with the elevated serum creatinine,compared with those with normal serum *** estimated GFRs based on creatinine were significantly higher than those based on the other equations,while a significant positive correlation was observed among all *** KIM-1 levels were negatively correlated with the estimated GFRs by the CKD-EPI Cys C and the combined creatinine with Cys C equations.A serum KIM-1 level above 0.71 ng/mL is likely to indicate GFR<90 mL per minute per 1.73 *** observed a significant correlation between serum creatinine and Cys C in our renal transplant ***,serum KIM-1 may be used to monitor renal function when using potentially nephrotoxic drugs in renal transplants.

关键词： KIM-1 cystatin C mycophenolate mofetil tacrolimus everolimus sirolimus cyclosporine

Integrated adsorption and photocatalytic removal of methylene blue dye from aqueous solution by hierarchical Nb_(2)O_(5)@PAN/PVDF/ANO composite nanofibers

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Nano Materials Science 2024年第1期6卷 96-105页

作者： Aditya Rianjanu Kurniawan Deny Pratama Marpaung Elisabeth Kartini Arum Melati Rizky Aflaha Yudha Gusti Wibowo I Putu Mahendra Nursidik Yulianto Januar Widakdo Kuwat Triyana Hutomo Suryo Wasisto Tarmizi taher Department of Materials Engineering Institut Teknologi SumateraTerusan RyacuduWay HuiJati AgungLampung Selatan35365Indonesia Center for Green and Sustainable Materials Institut Teknologi SumateraTerusan RyacuduWay HuiJati AgungLampung Selatan35365Indonesia Department of Environmental Engineering Institut Teknologi SumateraTerusan RyacuduWay HuiJati AgungLampung Selatan35365Indonesia Department of Physics Faculty of Mathematics and Natural SciencesUniversitas Gadjah MadaSekip Utara PO Box BLS 21Yogyakarta55281Indonesia Department of Mining Engineering Institut Teknologi SumateraTerusan RyacuduWay HuiJati AgungLampung Selatan35365Indonesia Department of Chemistry Institut Teknologi SumateraTerusan RyacuduWay HuiJati AgungLampung Selatan35365Indonesia Research Center for Photonics National Research and Innovation Agency(BRIN)Kawasan Puspitek SerpongTangerang Selatan15314Indonesia Department of Physics Faculty of Mathematics and Natural SciencesUniversitas IndonesiaDepok16424Indonesia PT Nanosense Instrument Indonesia UmbulharjoYogyakarta55167Indonesia Department of Chemical Engineering Faculty of EngineeringUniversitas Gadjah MadaJl Grafika No.2Yogyakarta55281Indonesia

This work presents the development of hierarchical niobium pentoxide(Nb_(2)O_(5))-based composite nanofiber membranes for integrated adsorption and photocatalytic degradation of methylene blue(MB)pollutants from aqueous *** Nb_(2)O_(5) nanorods were vertically grown using a hydrothermal process on a base electrospun nanofibrous membrane made of polyacrylonitrile/polyvinylidene fluoride/ammonium niobate(V)oxalate hydrate(Nb_(2)O_(5)@PAN/PVDF/ANO).They were characterized using field-emission scanning electron microscopy(FE-SEM),X-ray diffraction(XRD)analysis,and Fourier transform infrared(FTIR)*** composite nanofibers possessed a narrow optical bandgap energy of 3.31 eV and demonstrated an MB degradation efficiency of 96%after 480 min contact *** pseudo-first-order kinetic study was also conducted,in which Nb_(2)O_(5)@PAN/PVDF/ANO nanofibers have kinetic constant values of 1.29×10^(-2) min^(-1) and 0.30×10^(-2) min^(-1) for adsorption and photocatalytic degradation of MB aqueous solutions,*** values are 17.7 and 7.8 times greater than those of PAN/PVDF/ANO nanofibers without Nb_(2)O_(5) *** their outstanding photocatalytic performance,the developed membrane materials exhibit advantageous characteristics in recycling,which subsequently widen their practical use in environmental remediation applications.

关键词： Hierarchical nanostructure Composite nanofiber Niobium pentoxide Dye degradation Synergetic adsorption and photocatalysis

Constructing a small organic molecule by using the derivative of oxadiazole for photovoltaic applications

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Optoelectronics Letters 2024年

作者： HUSSEIN K.MEJBEL ABDIULRSOOL H.AL-taher FAYEZ A.NAMAH LAFY F.AL-BADRY Department of Physics College of Education for Pure Science University of Thi-Qar Directorate-General for Education Dhi Qar Department of Physics College of Science University of Thi-Qar

Because of their elasticity， light weight， little cost， and wide-area applications， besides that a notable increase in power conversion efficiency （PCE）， organic solar cells have recently caught the concern of numerous researchers. In the current project， we created a variety of organic small compounds as donor materials by using Gaussian 09. Our design approach entails swapping the core part， which is benzothiadiazole （BT）， based on a derivative of oxadiazole， as the terminals on both sides of the prototype compound （RM） with a variety of fragments to improve the electronic and optic characterization and performance for PCE in organic solar cells. Careful theoretical consideration under density-functional theory DFT and time-dependent density functional theory TD-DET at the B3LYP/6-31G（d，p） basis set was made to find the maximum absorption wavelengthλmax， the efficiency of light harvesting （LHE）， excitation energy (EX)， HOMO and LOMO levels， energy band gap (Eg)， dipole moment （ρ）， the DOS， ionization potential （LP）， electron affinity （EA）， fill factor （EF）， and open circuit voltage (Voc) of molecules RM and TSstudied in a methodical manner. Calculated values revealed that proposed compounds T1-T4 can be encouraging materials for manufacturing organic solar cells as a donor tiny compound with acceptor PC61BM to predict a rise in power conversion efficiency （PCE） owing to their possession of proper values for some optical and electronic features， like the lowest HOMO level， narrower band gaps， and a greater absorption wavelength compared with the reference model RM.

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Role of molecular imaging in prognosis,diagnosis,and treatment of gastrointestinal cancers:An update on new therapeutic methods

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World Journal of Methodology 2024年第4期14卷 43-60页

作者： Mobina Fathi Hayder Jasim taher Sabah Jassim Al-Rubiae Shirin Yaghoobpoor Ashkan Bahrami Reza Eshraghi Hossein Sadri Mahsa Asadi Anar Ali Gholamrezanezhad Student Research Committee School of MedicineShahid Beheshti University of Medical SciencesTehran ***Iran Department of Radiology Hilla University CollegeBabylon 00964Iraq Faculty of Medicine Kashan University of Medical SciencesKashan ***Iran Department of Radiology Keck School of MedicineUniversity of Southern CaliforniaLos AngelesCA 90033United States

One of the leading causes of cancer-related death is gastrointestinal cancer,which has a significant morbidity and mortality *** preoperative risk assessment is essential for directing patient care,its biological behavior cannot be accurately predicted by conventional imaging *** pathophysiological information in anatomical imaging that cannot be visually identified can now be converted into high-dimensional quantitative image features thanks to the developing discipline of molecular *** order to enable molecular tissue profile in vivo,molecular imaging has most recently been utilized to phenotype the expression of single receptors and targets of biological *** is expected that molecular imaging will become increasingly important in the near future,driven by the expanding range of biological therapies for *** this live molecular fingerprinting,molecular imaging can be utilized to drive expression-tailored customized *** technical aspects of molecular imaging are first briefly discussed in this review,followed by an examination of the most recent research on the diagnosis,prognosis,and potential future clinical methods of molecular imaging for GI tract malignancies.

关键词： Molecular imaging Personalized medicine Gastrointestinal cancers Positron emission tomography-computed tomography

Swarm-Based Extreme Learning Machine Models for Global Optimization

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Computers, Materials & Continua 2022年第3期70卷 6339-6363页

作者： Mustafa Abdul Salam Ahmad taher Azar Rana Hussien Artificial Intelligence Department Faculty of Computers and Artificial IntelligenceBenha UniversityBenha13518Egypt Scientific Computing Department Faculty of Computers and Artificial IntelligenceBenha UniversityBenha13518Egypt

Extreme Learning Machine(ELM)is popular in batch learning,sequential learning,and progressive learning,due to its speed,easy integration,and generalization ***,Traditional ELM cannot train massive data rapidly and efficiently due to its memory residence,high time and space *** ELM,the hidden layer typically necessitates a huge number of ***,there is no certainty that the arrangement of weights and biases within the hidden layer is *** solve this problem,the traditional ELM has been hybridized with swarm intelligence optimization *** paper displays five proposed hybrid Algorithms“Salp Swarm Algorithm(SSA-ELM),Grasshopper Algorithm(GOA-ELM),Grey Wolf Algorithm(GWO-ELM),Whale optimizationAlgorithm(WOA-ELM)andMoth Flame Optimization(MFO-ELM)”.These five optimizers are hybridized with standard ELM methodology for resolving the tumor type classification using gene expression *** proposed models applied to the predication of electricity loading data,that describes the energy use of a single residence over a fouryear *** the hidden layer,Swarm algorithms are used to pick a smaller number of nodes to speed up the execution of *** best weights and preferences were calculated by these algorithms for the hidden *** results demonstrated that the proposed MFO-ELM achieved 98.13%accuracy and this is the highest model in accuracy in tumor type classification gene expression *** in predication,the proposed GOA-ELM achieved 0.397which is least RMSE compared to the other models.

关键词： Extreme learning machine salp swarm optimization algorithm grasshopper optimization algorithm grey wolf optimization algorithm moth flame optimization algorithm bio-inspired optimization classification model and whale optimization algorithm