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recent progress on impact induced reaction mechanism of reactive alloys

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Defence technology（防务技术） 2024年第7期37卷 69-95页

作者： Yansong Yang Chuanting Wang Yuanpei Meng Yue Ma Lei Guo Yuan he Zhichao Sun Yong he School of Mechanical Engineering Nanjing University of Science and TechnologyNanjing 210094JiangsuChina

In recent years,in order to improve the destructive effectiveness of munitions,the use of new types of destructive elements is an important way to improve destructive *** a new type of reactive material,reactive alloy contains a large portion of reactive metal elements(Al,Mg,ti,Zr,etc.),which breaks up under high-velocity impact conditions,generating a large number of high-temperature combustible fragments,which undergo a violent combustion reaction with *** with traditional metal polymers(Al-PtFE)and other reactive composites,it has higher density and strength,excellent mechanical properties and broader application ***,researchers have mainly investigated the impact energy release mechanism of reactive alloys through impact tests,and found that there are several important stages in the process of the material from fragmentation to reaction,i.e.,impact fragmentation of the material,rapid heating and combustion *** paper focuses on three problems that need to be solved in the impact-induced energy release process of reactive alloys,namely:the fragmentation mechanism and size distribution law of the fragments produced by the impact of the material on the target,the relationship between the transient temperatures and the size of the fragments,and the reaction temperatures and size thresholds of the fragments to undergo the chemical *** current status of the research of the above problems is reviewed,some potential directions to reveal the impact induced reaction mechanism of reactive alloy is discussed.

关键词： reactive alloys Impact Fragmentation Mass and size distribution Shock temperature rise Adiabatic shear Combustion

Illuminating functions of evolutionarily conserved long non-coding rNAs

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Science China(Life Sciences) 2024年第9期67卷 2043-2044页

作者： ruiqiao he Fangqing Zhao Institute of Zoology Chinese Academy of SciencesBeijing 100101China Key Laboratory of Systems health Science of Zhejiang Province Hangzhou Institute for Advanced StudyUniversity of Chinese Academy of SciencesHangzhou 310024China

Long non-coding rNAs(lnc rNAs)serve as crucial regulators of gene expression,influencing various physiological processes and disease states(Cabili et al.,2011;Ulitsky and Bartel,2013;Yao et al.,2019).Dysregulation of certain notable lnc rNAs,such as HOtAIr and MALAt1,has been implicated in a wide range of pathological processes,including tumorigenesis in various human cancers(Gupta et al.,2010;Kim et al.,2018).However,the functions of the majority of lnc rNAs remain elusive.

关键词： MALAt1 HOtAIr

Waste to treasure:reutilization of fluid catalytic cracking coke block as photothermal conversion material for water evaporation

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Particuology 2024年第5期88卷 62-70页

作者： Zhuwei Gao Chengxin Li Jingjing he Zhuo Wang Xinyu Qi Lan he Shihao Wang Zhongxin Liu School of Chemical Engineering and technology Hainan UniversityHaikou 570228China tJ-YZ School of Network Science Haikou University of EconomicsHaikou 570203China School of Food Science and Engineering Hainan UniversityHaikou 570228China Key Laboratory of Advanced Materials of tropical Island resources of Ministry of Education Hainan UniversityHaikou 570228China Hainan Provincial Key Laboratory of Fine Chemicals Hainan UniversityHaikou 570228China

this study aims to analyze the coking process and propose an effective method for the reutilization of fluid catalytic cracking(FCC)coke ***,we analyzed the basic characteristics and chemical composition of FCC coke *** results showed that the main components were carbon,oxygen,and aluminum,accounting for 60.8%,26.6%,and 11.5%,*** the conventional catalytic cracking reaction temperature from 500℃ to 600℃,the formation of the first aromatic hydrocarbon was particularly important for the formation of *** condensation of oil-gas-entrained catalyst particles and their heavy components was the physical cause of coking,while the dehydrogenation condensation reaction of oil-gas heavy components was the chemical *** addition,the membrane prepared by powdered coke had excellent photothermal conversion ability,which could be heated to more than 110℃ within 360 s under two fixed light *** evaporation rate of photothermal water was 5.89 kg m^(2) h^(−1),which has great industrial application *** works provide a novel and effective method of separation membrane for the reutilization of FCC coke blocks.

关键词： Coking process reutilization of FCC coke Carbonaceous deposition Membrane Photothermal conversion

the role of Adipose tissue-derived Exosomes in Chronic Metabolic Disorders

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Current Medical Science 2024年第3期44卷 463-474页

作者： rui he Yong CheN Division of Endocrinology Department of Internal MedicineTongji HospitalTongji Medical CollegeHuazhong University of Science and TechnologyWuhan430030China Laboratory of Endocrinology & Metabolism Key Laboratory of Vascular Aging of the Ministry of EducationTongji HospitalTongji Medical CollegeHuazhong University of Science and TechnologyWuhan430030China Branch of National Clinical research Center for Metabolic Diseases Wuhan430030China

Excessive fat deposition in obese subjects promotes the occurrence of metabolic diseases,such as type 2 diabetes mellitus(t2DM),cardiovascular diseases,and non-alcoholic fatty liver disease(NAFLD).Adipose tissue is not only the main form of energy storage but also an endocrine organ that not only secretes adipocytokines but also releases many extracellular vesicles(EVs)that play a role in the regulation of whole-body *** are a subtype of EVs,and accumulating evidence indicates that adipose tissue exosomes(At Exos)mediate crosstalk between adipose tissue and multiple organs by being transferred to targeted cells or tissues through paracrine or endocrine ***,the roles of At Exos in crosstalk with metabolic organs remain to be fully *** this review,we summarize the latest research progress on the role of At Exos in the regulation of metabolic ***,we discuss the potential role of At Exos as biomarkers in metabolic diseases and their clinical application.

关键词： exosome adipose tissue obesity diabetes chronic metabolic disorder mirNA

Nano-scale reinforcements and Properties of Al-Si-Cu Alloy Processed by High-Pressure torsion

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Journal of Wuhan University of technology(Materials Science) 2024年第5期39卷 1253-1259页

作者： DONG Ying WU Siyuan he Ziyang LIANG Chen CheNG Feng he Zuwei QIAN Chenhao School of Mechanical Engineering Jiangnan UniversityWuxi 214122China Jiangsu Key Laboratory of Advanced Food Manufacturing Equipment and technology Wuxi 214122China School of International Studies Renmin University of ChinaBeijing 100872China School of Engineering University of LiverpoolLiverpool L693GHUnited Kingdom

to improve the comprehensive mechanical properties of Al-Si-Cu alloy,it was treated by a high-pressure torsion process,and the effect of the deformation degree on the microstructure and properties of the Al-Si-Cu alloy was *** results show that the reinforcements(β-Si andθ-CuAl_(2)phases)of the Al-Si-Cu alloy are dispersed in theα-Al matrix phase with finer phase size after the *** processed samples exhibit grain sizes in the submicron or even nanometer range,which effectively improves the mechanical properties of the *** hardness and strength of the deformed alloy are both significantly raised to 268 HV and 390.04 MPa by 10 turns HPt process,and the fracture morphology shows that the material gradually transits from brittle to plastic before and after *** elements interdiffusion at the interface between the phases has also been effectively *** addition,it is found that the severe plastic deformation at room temperature induces a ternary eutectic reaction,resulting in the formation of ternary Al+Si+CuAl_(2)eutectic.

关键词： Al-Si-Cu alloy high-pressure torsion nano-scale reinforcements ternary eutectic

Ce-and La-doped polymetallic layered double hydroxides for enhanced oxygen evolution reaction performance at high current density

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Science China Chemistry 2024年第8期67卷 2586-2598页

作者： rinel r.Kimaka P. Ping Wang Miao he Senyao Meng Jiasai Yao Huawei Li Cheng Yang Zhenxing Li State Key Laboratory of heavy Oil Processing College of New Energy and MaterialsChina University of Petroleum(Beijing)Beijing 102249China

Polymetallic layered double hydroxides are promising cost-effective catalysts for the oxygen evolution reaction(OEr) due to their versatile anionic and cationic tunability. Nevertheless, several challenges persist, notably, issues related to low electrical conductivity, poor catalytic activity, and stability, especially at high current density. herein, we report the design of Ce-and Ladoped Co Ni Fe-layered double hydroxide(Ce La Co Ni Fe-LDH) nanosheets through a facile and scalable in situ self-assembly strategy that displays enhanced OEr activity. Experimental and theoretical investigations provide insights into the impact of Ceand La-doping by comparing Ce Co Ni Fe-LDH, La Co Ni Fe-LDH, and pristine Co Ni Fe-LDH, all synthesized using the same methodology. these results reveal that doping Ce^(3+)and La^(3+)into Co Ni Fe-LDH substantially improves its electronic structure,resulting in enhanced conductivity, more oxygen vacancies(Vo), electron interaction, and active site formation. Consequently,significantly reduced overpotentials of 175, 314, and 424 m V at 10, 100, and 500 m A cm^(-2), respectively, and a highly stable current density of 120 h in 1 M KOH were achieved. Notably, these performance metrics surpass those of unmodified LDHs and are competitive with many lanthanide-doped transition metal-based LDH electrocatalysts, as well as noble metal catalysts like ruthenium catalysts. this work represents a pioneering effort in doping Ce^(3+)and La^(3+)ions into a functional Co Ni Fe-based electrocatalyst, offering inspiring OEr performance and scalability potential.

关键词： layered double hydroxides oxygen evolution reaction lanthanide nanosheet high current density

Large eddy simulation study of 3D wind field in a complex mountainous area under different boundary conditions

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2024年第7期25卷 541-556页

作者： Yan LI Lei YAN Xuhui he School of Civil Engineering Central South UniversityChangsha410075China National Engineering research Center for High-speed railway Construction Changsha410075China Hunan Provincial Key Laboratory for Disaster Prevention and Mitigation of rail transit Engineering Structures Changsha410075China

Large eddy simulations generally are used to predict 3D wind field characteristics in complex mountainous *** simulation boundary conditions,such as the height and length of the computational domain or the characteristics of inflow turbulence,can significantly impact the quality of *** this study,we examined these boundary conditions within the context of the mountainous terrain around a long-span cable-stayed bridge using a wind tunnel *** sizes of computational domains and turbulent incoming wind velocities were used in large eddy *** results show that when the height of the computational domain is five times greater than the height of the terrain model,there is minimal influence from the top wall on the wind field characteristics in this complex mountainous *** the length of the wake region of the computational domain has negligible effects on the wind *** in the inlet boundary reduces the length of the wake region on a leeward hill with a low slope,but has less impact on the mean wind velocity of steep hills.

关键词： Large eddy simulation(LES) Spectral representation method recycling method High mountainous canyon Wind characteristics Atmospheric boundary layer Computational domain

Lifetime-tunable circularly polarized luminescent system based on triplet-to-singlet Förster resonance energy transfer

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Science China Chemistry 2024年第9期67卷 2918-2922页

作者： Zhenyi he Zizhao Huang Xiang Ma Key Laboratory for Advanced Materials and Feringa Nobel Prize Scientist Joint research Center Institute of Fine ChemicalsSchool of Chemistry and Molecular EngineeringEast China University of Science and TechnologyShanghai 200237China

Circularly polarized luminescence(CPL)materials have received widespread attention due to their remarkable performance and broad ***,current CPL material research primarily focuses on tunable color,intensity,and *** CPL with adjustable lifetime remains a significant ***,a series of CPL polymeric materials with tunable lifetime were obtained by employing phosphorescent terephthalic acid and chiral organic small molecule r/S-BNAF(a luminescent binaphthol derivative)to copolymerize with acrylamide in different *** was verified that this performance results from the different energy transfer efficiency between luminophores with varying ratios of the monomers for *** strategy to realize CPL with tunable lifetime by modulating the energy transfer efficiency will provide a new perspective to broaden the applications of CPL materials.

关键词： circularly polarized luminescence tunable lifetime Förster resonance energy transfer room temperature phosphorescence

An efficient physics-guided Bayesian framework for predicting ground settlement profile during excavations in clay

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Journal of rock Mechanics and Geotechnical Engineering 2024年第4期16卷 1411-1424页

作者： Cong tang Shuyu he Wanhuan Zhou State Key Laboratory of Internet of things for Smart City and Department of Civil and Environmental Engineering University of MacaoChina

recently,the application of Bayesian updating to predict excavation-induced deformation has proven successful and improved prediction accuracy ***,updating the ground settlement profile,which is crucial for determining potential damage to nearby infrastructures,has received limited *** address this,this paper proposes a physics-guided simplified model combined with a Bayesian updating framework to accurately predict the ground settlement *** advantage of this model is that it eliminates the need for complex finite element modeling and makes the updating framework ***,the model is physically interpretable,which can provide valuable references for construction *** effectiveness of the proposed method is demonstrated through two field case studies,showing that it can yield satisfactory predictions for the settlement profile.

关键词： Bayesian updating Excavations Ground settlement profile Simplified model Uncertainty