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A mild, configurable, flexible CoNi-LDH（v）/Zn battery based on H-vacancy-induced reversible Zn2+ intercalation

Journal of Energy Chemistry 2025年第1期100卷 498-508页

作者： Xinyue Cheng Dingsheng Wu Hao Gao Qingqing Wang Pengfei Lv sam s.Yoon Qufu Wei Key Laboratory of Eco-textiles Ministry of Education Jiangnan University school of Mechanical Engineering Korea University

Flexible Zn-based batteries have attracted increasing research interest as essential components of wearable energy storage ***,the advancement of flexible aqueous Zn-based batteries based on Co-Ni layered double hydroxide （CoNi-LDH） as the cathode material is hampered by their poor cycling stability and the corrosiveness of alkaline ***,CoNi-LDH nanosheets enriched with H vacancies (CoNi-LDH（v）) were constructed on a flexible carbon cloth （CC） substrate via electrochemical deposition and *** Zn-based battery comprising CoNi-LDH（v）@CC as the cathode exhibited highly reversible conversion reactions and stable operation in 3 M ZnsO4electrolyte （pH=4）.The battery delivered an excellent specific capacity (225 mA h g-1,0.26 mA h cm-2),acceptable cycling stability（53.9%,900 cycles）,and high discharging *** abundant H vacancies served as active sites for the reversible intercalation of Zn2+and the extravasation of NO3-generated channels and space for Zn2+transport and storage,together enabling an excellent Zn2+storage ***,a sandwich-structured solid-state CoNi-LDH（v）@CC//Zn@CC battery was fabricated and was found to exhibit a noteworthy electrochemical performance and mechanical *** a proof of concept,the unencapsulated battery powered a digital watch under various deformation conditions and operated stably for 80 ***,the flexible battery displayed outstanding customizability,maintaining an open-circuit voltage of 1.42 V even after being cut *** proposed engineering strategy contributes to the realization of textiles with truly wearable energy-storage devices.

关键词： CoNi/Zn battery H vacancies Mild aqueous electrolyte Tailorable battery Wearable energy storage device

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Determination of F,s(total),and Cl in the Calcite Rich Limestone and Marbles by WD-XRF spectrometry

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Journal of Geological Resource and Engineering 2020年第5期8卷 137-144页

作者： svetlana Ivanovna shtel’makh Institute of the Earth’s Crust SB RAS128 Lermontov St.Irkutsk 664033Russia

Determining the contents of F,s(total),and Cl in the studied samples of the limestone and marbles with high calcite contents was carried out by the nondestructive method of WDXRFs(Wavelength Dispersive X-ray Fluorescence spectrometry).All measurements were performed in a vacuum condition using a WDXRF spectrometer s8 TIGER(Bruker AXs,Germany).The studied samples have wide ranges of F,s(total),and Cl contents,and high concentration of calcite(89.5%-99%).Main objective of this research is to develop WDXRF(WD X-ray fluorescence)technique for the determination of F,s(total),and *** calculated values of the ILD(instrumental limit of the detection)were within the interval from 3 for s(total)to 37 for F mg/*** repeatability was found to be satisfactory with the relative standard deviations lower than 7%.

关键词： X-ray fluorescence analysis carbonate rocks with high calcite contents limestone marble analytical figures of merit

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Nearly singular Integrals in 3D stokes Flow

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Communications in Computational Physics 2013年第10期14卷 1207-1227页

作者： svetlana Tlupova J.Thomas Beale Department of Mathematics University of MichiganAnn ArborMI 48109-1043USA Department of Mathematics Duke UniversityDurhamNC 27708-0320USA

A straightforward method is presented for computing three-dimensional stokes flow,due to forces on a surface,with high accuracy at points near the *** flowquantities arewritten as boundary integrals using the free-spaceGreen’s *** evaluate the integrals near the boundary,the singular kernels are regularized and a simple quadrature is applied in coordinate *** order accuracy is obtained by adding special corrections for the regularization and discretization errors,derived here using local asymptotic *** tests demonstrate the uniform convergence rates of the method.

关键词： stokes equations boundary integral equation method nearly singular integrals

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Impact of Zika virus non-structural protein mutations on hippocampal damage

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Neural Regeneration Research 2025年第8期20卷 2307-2308页

作者： Larissa M.G.Cassiano Roney s.Coimbra Neurogenômica/Imunopatologia Instituto RenéRachouFiocruzBelo HorizonteBrazil Departamento de Bioquímica e Imunologia Instituto de Ciências BiológicasUniversidade Federal de Minas GeraisBelo HorizonteBrazil

The Zika virus(ZIKV),a member of the Flaviviridae family,attracted worldwide attention for its connection to severe neurological effects,notably microcephaly in newborns,first reported during the 2015 epidemic in ***,its impact goes beyond fetal and neonatal abnormalities,also affecting the central nervous system(CNs)in both children and adults,leading to enduring cognitive and behavioral impairments.

关键词： damage fetal neonatal

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A Review on the Taxonomic,Evolutionary and Phytogeographic studies of the Lotus Plant(Nelumbonaceae:Nelumbo)

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Acta Geologica sinica(English Edition) 2014年第4期88卷 1252-1261页

作者： LI Ya Popova svetlana YAO Jianxin LI Chengsen Institute of Geology Chinese Academy of Geological Sciences Key Laboratory of stratigraphy and Paleontology Ministry of Land and Resources of the People's Republic of China state Key Laboratory of systematic and Evolutionary Botany Institute of BotanyChinese Academy of Sciences Laboratory of Palaeobotany Komarov Botanical InstituteRussian Academy of Sciences

Nelumbo Adans. （Nelumbonaceae） is an important member of the early-diverging eudicots. It contains two extant species： N. nucifera Gaertn. （the sacred lotus）, distributed in Asia and Australia and N. lutea Willd. （the American lotus）, occurring in North America. This paper reviews the taxonomic, evolutionary and phytogeographic studies of the genus Nelumbo, and also raises scientific questions about it in further paleobotanic research. There are about 30 fossil species of Nelumbo established since the Early Cretaceous. Based on fossil studies, the ancestors of the extant N. nucifera and N. lutea are respectively considered to be N. protospeciosa from the Eocene to Miocene of Eurasia, and N. protolutea from the Eocene of North American. However, molecular systematic studies indicate that N. nucifera and N. lutea are probably split from a common ancestor during the Late Miocene to Early Pliocene, or even the Pleistocene, rather than separate relicts from extinct species on different continents. The characters of lotus stomatal development, seedling morphology as well as its flowering, pollination and fertilization in air reveal that it evolves from the land plants. Fossil data of Nelumbo indicates that the genus first occurs in mid-latitude area of Laurasia in the Early Cretaceous, then becomes widespread in North America and Eurasia and expands into Africa and south America during the Late Cretaceous; the genus probably colonizes the Indian subcontinent from Asia during the Early Eocene after the collision of India and the Asian plates; the genus becomes extinct in Europe, but survives in Asia and North America during the Quaternary Ice Age, and later forms the present East Asia and North Australia-North America disjunctive distribution.

关键词： taxonomy evolution phytogeography Nelumbo Nelumbonaceae

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Peculiarities of Ethylene Polymerization Reactions with Bis(imino)pyridyl Complexes of CoCl_(2) and FeCl_(2)

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Chinese Journal of Polymer science 2024年第4期42卷 492-500页

作者： Laura A.Rishina Yury V.Kissin svetlana s.Lalayan Artem A.Antonov Vadim G.Krasheninnikov Alexander A.Gulin N.N.semenov Federal Research Center for Chemical Physics Russian Academy of Sciences4 Kosygin St.Moscow119991Russia Department of Chemistry and Chemical Biology RutgersThe State University of New Jersey123 Bevier Rd.PiscatawayNJ08854USA Boreskov Institute of Catalysis Russian Academy of Sciences5 Lavrentieva Prosp.Novosibirsk630090Russia

The article describes ethylene polymerization reactions with transition metal catalysts based on complexes of CoCl_(2) and FeCl_(2) with an N,N,N-tridentate ligand 2,6-bis[1-(2,6-dimethylphenylimino)ethyl]pyridine. The complexes are converted into polymerization catalysts by reacting them either with polymethylalumoxane (MAO) or with a combination of Al(C2H5)2Cl and Mg(C4H9)2 at an [Al]:[Mg] ratio of ~3. Both MAO-activated complexes readily polymerize ethylene at 35 ℃ with the formation of linear, low molecular weight polymers with a narrow molecular weight distribution. The same complexes, when activated with the Al(C2H5)2Cl-Mg(C4H9)2 combination, form multi-center catalysts and generate polyethylenes with a broad molecular weight distribution.

关键词： Ethylene polymerization Bis(imino)pyridyl complexes of CoCl_(2)and FeCl_(2) Molecular-weight distribution Polymer chain structure

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Detection of CO2 and O2 by iron loaded LTL zeolite films

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Frontiers of Chemical science and Engineering 2018年第1期12卷 94-102页

作者： Veselina Georgieva Richard Retoux Valerie Ruaux Valentin Valtchev svetlana Mintova Laboratoire Catalyse et spectrochimie (LCs) ENSICAEN CNRS Normandy University 14000 Caen France Laboratoire de Cristallographie et sciences des Matériaux (CRIsMAT) ENSICAEN CNRS Normandy University 14000 Caen France

Detection of oxygen and carbon dioxide is important in the field of chemical and biosensors for atmosphere and biosystem monitoring and fermentation processes. The present study reports on the preparation of zeolite films doped with iron nanoparticles for detection of CO2 and O2 in gas phase. Pure nanosized LTL type zeolite with monomodal particle size distribution loaded with iron （Fe-LTL） was prepared under hydrothermal condition from colloidal precursor suspensions. The zeolite was loaded with iron to different levels by ion exchange. The Fe-LTL suspensions were used for preparation of thin films on silicon wafers via spin coating method. The reduction of the iron in the zeolite films was carried out under H2 flow （50% H2 in Ar） at 300 ℃. The presence of iron nanoparticles is proved by in situ ultra-violet-visible spectroscopy. The properties of the films including surface roughness, thickness, porosity, and mechanical stability were studied. In addition, the loading and distribution of iron in the zeolite films were investigated. The Fe-LTL zeolite films were used to detect O2 and CO2 in a concentration dependent mode, followed by IR spectroscopy. The changes in the IR bands at 855 and 642 cm^-1 （Fe O-H and Fe-O bending vibrations） and at 2363 and 2333 cm^-1 （CO2 asymmetric stretching） corresponding to the presence of O2 and CO2, respectively, were evaluated. The response to O2 and CO2 was instant, which was attributed to great accessibility of the iron in the nanosized zeolite crystals. The saturation of the Fe-LTL films with CO2 and O2 at each concentration was reached within less than a minute. The Fe-LTL films detected both oxygen and carbon dioxide in contrast, to the pure LTL zeolite film.

关键词： zeolite films detection of CO2 and O2 adsorption

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Microdevice for directional axodendritic connectivity between micro 3D neuronal cultures

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Microsystems & Nanoengineering 2021年第5期7卷 227-239页

作者： Yixuan Ming Md Joynal Abedin svetlana Tatic-Lucic Yevgeny Berdichevsky Department of Electrical&Computer Engineering Lehigh UniversityBethlehemPAUSA Department of Bioengineering Lehigh UniversityBethlehemPAUSA

Neuronal cultures are widely used in neuroscience ***,the randomness of circuits in conventional cultures prevents accurate in vitro modeling of cortical development and of the pathogenesis of neurological and psychiatric disorders.A basic feature of cortical circuits that is not captured in standard cultures of dissociated cortical cells is directional *** this work,a polydimethylsiloxane(PDMs)-based device that achieves directional connectivity between micro 3D cultures is *** device consists of through-holes for micro three-dimensional(n3D)clusters of cortical cells connected by microtrenches for axon and dendrite *** design of the trenches relies in part on the concept of axonal edge guidance,as well as on the novel concept of specific dendrite *** replicates dominant excitatory connectivity in the cortex,enables the guidance of the axon after it forms a synapse in passing(an"en passant"synapse),and ensures that directional selectivity is preserved over the lifetime of the *** directionality of connections was verified morphologically and *** were dependent on glutamatergic *** design of this device has the potential to serve as a building block for the reconstruction of more complex cortical circuits in vitro.

关键词： connectivity directional lifetime

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Amur tiger conservation education program:A pilot study on program effectiveness

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Integrative Zoology 2015年第4期10卷 403-407页

作者： Anna s.MUKHACHEVA Vasilissa V.DERUGINA Galina D.MAKsIMOVA svetlana V.sOUTYRINA sikhote-Alin Biosphere Zapovednik Primorskii KraiTerneiRussia Wildlife Conservation society BronxNew YorkUSA Youth Creative Arts Center of Ternei Uragus Ecological ClubTerneiPrimorskii KraiRussia

Anthropogenic impacts are the primary threats to Amur tigers(Panthera tigris altaica)and their *** living in proximity to tigers tend to view them negatively and,often,as a source of revenue on black *** aim to reduce human–tiger conflict by working with young students of Ternei County in the heart of tiger habitat in Primorskii Krai(Province).To inform and influence Ternei County’s future decision-makers,we developed“safe Conduct”,a year-long education program held in 6 villages,culminating in a multi-school *** tested the efficacy of safe Conduct as a potential model for tiger conservation educational *** measured levels of student knowledge about tiger ecology,their attitude towards tigers,and their willingness to engage in tiger conservation activites prior to,immediately after and 6 months following the completion of our *** supported the fundamental premise of safe Conduct that knowledge and attitude towards tigers are *** of tiger ecology and attitude towards tigers increased by the project’s completion;both remained high after 6 ***,commitment to participation in conservation efforts rose temporarily post-program and then *** varied by *** recommend that the reasons for the high performance measures of students in 2 villages be investigated,and that lessons learned be applied to villages that *** Conduct represents a potential model for environmental education programs in Ternei County and elsewhere to educate future generations,to eventually develop a strong commitment to Amur tiger conservation at the community level.

关键词： Amur tiger behavior change conservation children education programs

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Lanthanide NIR luminescence for telecommunications, bioanalyses and solar energy conversion

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Journal of Rare Earths 2010年第6期28卷 824-842页

作者： Jean-Claude G. Bünzli svetlana V. Eliseeva cole Polytechnique Fédérale de Lausanne Institute of Chemical Sciences and Engineering WCU Professor Korea University Center for Next Generation Photovoltaic Systems Katholieke Universiteit Leuven Department of Chemistry Laboratory of Coordination Chemistry

Present-day advanced technologies heavily rely on the exciting magnetic and spectroscopic properties of lanthanide ions. In particular, their ability to generate well-characterized and intense near-infrared (NIR) luminescence is exploited in any modern fiber-optic telecommunication network. In this feature article, we first summarize the whereabouts underlying the design of highly luminescent NIR molecular edifices and materials. We then focus on describing the main trends in three applications related to this spectral range: telecommunications, biosciences, and solar energy conversion. In telecommunications, efforts concentrate presently on getting easily processable polymer-based waveguide amplifiers. Upconversion nanophosphors emitting in the visible after NIR excitation are now ubiquitous in many bioanalyses while their application to bio-imaging is still in its early stages; however, highly sensitive NIR-NIR systems start to be at hand for both in vitro and in vivo imaging, as well as dual probes combining magnetic resonance and optical imaging. Finally, both silicon-based and dye-sensitized solar cells benefit from the downconversion and upconversion capabilities of lanthanide ions to harvest UV and NIR solar light and to boost the overall quantum efficiency of these next-generation devices.

关键词： lanthanide luminescence near-infrared luminescence telecommunications bioanalysis solar energy conversion solar cell upconversion downconversion

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