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Diamond-Like carbon Depositing on the Surface of Polylactide Membrane for Prevention of Adhesion Formation During Tendon Repair

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Nano-Micro Letters 2024年第9期16卷 478-499页

作者： Yao Xiao Zaijin Tao Yufeng Ju Xiaolu huang Xinshu Zhang Xiaonan Liu Pavel A.Volotovski chao huang Hongqi chen Yaozhong Zhang Shen Liu Department of Orthopaedics Shanghai Jiao Tong University School of Medicine Affiliated Sixth People’s Hospital600 Yishan RdShanghai 200233People’s Republic of China Shanghai Tongji Hospital 389 Xincun RdShanghai 200065People’s Republic of China Key Laboratory for Thin Film and Microfabrication of Ministry of Education Research Institute of Micro/Nano Science and TechnologyShanghai Jiao Tong UniversityShanghai 200240People’s Republic of China Orthopedic Trauma Department Belarus Republic Scientific and Practical Center for Traumatology and OrthopedicsKizhevatova str.60/4220024 MinskBelarus Shanghai Haohai Biological Technology Limited Liability company 1386 Hongqiao RdShanghai 200336People’s Republic of China Department of General Surgery Shanghai Jiao Tong University School of Medicine Affiliated Sixth People’s Hospital600 Yishan RdShanghai 200233People’s Republic of China Shanghai Key Laboratory for High Temperature Materials and Precision Forming School of Materials Science and EngineeringShanghai Jiao Tong UniversityShanghai 200240People’s Republic of China

Post-traumatic peritendinous adhesion presents a significant challenge in clinical *** study proposes the use of diamond-like carbon(DLc)deposited on polylactic acid(PLA)membranes as a biophysical mechanism for anti-adhesion barrier to encase ruptured tendons in tendon-injured *** results indicate that PLA/DLc composite membrane exhibits more efficient anti-adhesion effect than PLA membrane,with histological score decreasing from 3.12±0.27 to 2.20±0.22 and anti-adhesion effectiveness increasing from 21.61%to 44.72%.Mechanistically,the abundant c=O bond functional groups on the surface of DLc can reduce reactive oxygen species level effectively;thus,the phosphorylation of NF-κB and M1 polarization of macrophages are ***,excessive inflammatory response augmented by M1 macrophage-originated cytokines including interleukin-6(IL-6),interleukin-1β(IL-1β),and tumor necrosis factor-α(TNF-α)is largely *** biocompatibility evaluation,PLA/DLc membrane is slowly absorbed within tissue and displays prolonged barrier effects compared to traditional PLA *** studies show the DLc depositing decelerates the release of degradation product lactic acid and its induction of macrophage M2 polarization by interfering esterase and PLA ester bonds,which further delays the fibrosis *** was found that the PLA/DLc membrane possess an efficient biophysical mechanism for treatment of peritendinous adhesion.

关键词： Diamond-like carbon Reactive oxygen species scavenging Foreign body reaction Biodegradation Antioxidant Peritendinous adhesion

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copper catalyzed Enantioconvergent Nucleophilic Substitutions

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chinese Journal of chemistry 2024年第10期42卷 1161-1174页

作者： chunxi huang Zilong Wan Aoping Zhu caiyou chen college of chemistry and Molecular Sciences Wuhan UniversityWuhanHubei 430072China Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules and college of chemistry and chemical Engineering Hubei UniversityWuhanHubei 430062China

As a versatile earth-abundant transition metal,cu has long been widely applied in the c—c and c—X bond forming *** for now,low-valent cu(Ⅰ)is known to reduce the redox active electrophiles via an SET pathway to give the corresponding radical and cu(Ⅱ)*** resulting cu(Ⅱ)species can interact with the radical via the out-sphere pathway,affording the coupling ***,cu(Ⅱ)can trap the radical through the inner-sphere process to generate cu(Ⅲ)species and then realize challenging bond formations due to the facile reductive elimination of cu(Ⅲ)*** copper catalysis has been widely applied in arylations of various nucleophiles,copper-catalyzed enantioconvergent nucleophilic substitutions of racemic alkyl electrophiles have been less explored,likely due to the difficulties in overcoming the reduction potential of alkyl electrophiles,elimination of side reactions,and enantiomeric *** order to overcome the high reduction potential of alkyl electrophiles,the photo-induced strategy has been developed under mild *** alternative strategy with new anionic tridentate ligands has also been reported in this *** review summarizes recent developments in copper-catalyzed enantioconvergent nucleophilic substitutions of alkyl electrophiles by various nucleophiles to realize c—N,c—c,c—B,c—P and c—O bond formations and their brief mechanistic studies.

关键词： Enantioconvergent Nucleophilic substitution copper Radical reactions Photocatalysis Asymmetric catalysis

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Estimation of unfrozen water content of saturated sandstones using nuclear magnetic resonance, mercury intrusion porosimetry, and ultrasonic tests

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Journal of Rock Mechanics and Geotechnical Engineering 2024年第9期16卷 3465-3484页

作者： Fei Liu Shibing huang Gang Liu Shilin Yu School of Resources and Environmental Engineering Wuhan University of Science and TechnologyWuhan430081China Hubei Key Laboratory for Efficient Utilization and Agglomeration of Metallurgic Mineral Resources Wuhan University of Science and TechnologyWuhan430081China

The unfrozenwater content(UWc)is a crucial parameter that affects the strength and thermal properties of rocks in relation to engineering construction and geological disasters in cold *** this study,three different methods were employed to test and estimate the UWc of saturated sandstones,including nuclear magnetic resonance(NMR),mercury intrusion porosimetry(MIP),and ultrasonic *** NMR method enabled the direct measurement of the UWc of sandstones using the free induction decay(FID).The MIP method was used to analyze the pore structures of sandstones,with the UWc subsequently calculated based on pore ice ***,the MIP test constituted an indirect measurement ***,a correlation was established between the P-wave velocity and the UWc of these sandstones based on the mixture theory,which could be employed to estimate the UWc as an empirical *** methods demonstrated that the UWc initially exhibited a rapid decrease from 0c to5c and then generally became constant beyond20***,these test methods had different *** NMR method was used to directly and accurately calculate the UWc in the ***,the cost and complexity of NMR equipment have precluded its use in the *** UWc can be effectively estimated by the MIP test,but the estimation accuracy is influenced by the ice crystallization process and the pore size *** P-wave velocity has been demonstrated to be a straightforward and practical empirical parameter and was utilized to estimate the UWc based on the mixture *** method may be more suitable in the *** methods confirmed the existence of a hysteresis phenomenon in the freezing-thawing *** average hysteresis coefficient was approximately 0.538,thus validating the GibbseThomson *** study not only presents alternative methodologies for estimating the UWc of saturated sandstones but also contribute to our understanding of the freezin

关键词： Unfrozen water content(UWc) Nuclear magnetic resonance(NMR) Mercury intrusion porosimetry(MIP) Pore structures P-wave velocity Sandstone

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“co-coordination force”assisted rigid-flexible coupling crystalline polymer for high-performance aqueous zinc-organic batteries

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chinese chemical Letters 2024年第9期35卷 501-506页

作者： Jun Guo Zhenbang Zhuang Wanqiang Liu Gang huang School of Materials Science and Engineering Changchun University of Science and TechnologyChangchun 130022China State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022China Key Laboratory of Automobile Materials Ministry of EducationDepartment of Materials Science and EngineeringJilin UniversityChangchun 130022China

Organic electrode materials(OEMs)have attracted substantial attention for aqueous zinc-ion batteries(AZIBs)due to their advantages in relieving resource and environmental ***,the potential of OEMs is plagued by their low achievable capacity and high ***,we have proposed a new concept of“co-coordination force”and designed a rigid-flexible coupling crystalline polymer that can overcome the abovementioned *** obtained crystalline polymer(BQSPNs)with multiredox centres makes the BQSPNs exist intermolecular hydrogen bonds(HB)among-c=O,-c=N,and-NH and consequently exhibits transverse two-dimensional arrays and longitudinalπ-πstacking ***,in-situ FTIR,Raman,variable temperature FTIR spectra,and 2D nuclear overhauser effect spectroscopy(NOESY)well capture the existence and evolution process of HB during the electrochemistry reaction process of BQSPNs,uncovering the effect of HB in stabilizing the structure and promoting the reaction *** a result,the BQSPNs with rationally designed“co-coordination force”deliver a high capacity of 459.6 m Ah/g and a stable cycling lifetime for more than 100,000 cycles at 10 A/g in *** results disclose the HB effect and provide a brand-new strategy for high-performance OEMs design.

关键词： co-coordination force crystalline polymer Hydrogen bonds Organic electrode materials Aqueous zinc-ion batteries

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Dynamic Multi-Physics Behaviors and Performance Loss of cylindrical Batteries Upon Low-Velocity Impact Loading

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ENERGY & ENVIRONMENTAL MATERIALS 2024年第6期7卷 184-192页

作者： huang, Qingdan Bai, Yang Luo, Han Jia, Yikai Zhang, chao Northwestern Polytech Univ Sch Civil Aviat Xian 710072 Peoples R China Key Lab Impact Protect & Safety Assessment civil A Taicang 215400 Peoples R China Northwestern Polytech Univ Sch Aeronaut Xian 710072 Peoples R China EVE Energy co Ltd Huizhou 516006 Peoples R China

In challenging operational environments, Lithium-ion batteries (LIBs) inevitably experience mechanical stresses, including impacts and extrusion, which can lead to battery damage, failure, and even the occurrence of fire and explosion incidents. consequently, it is imperative to investigate the safety performance of LIBs under mechanical loads. This study is grounded in a more realistic coupling scenario consisting of electrochemical cycling and low-velocity impact. We systematically and experimentally uncovered the mechanical, electrochemical, and thermal responses, damage behavior, and corresponding mechanisms under various conditions. Our study demonstrates that higher impact energy results in increased structural stiffness, maximum temperature, and maximum voltage drop. Furthermore, heightened impact energy significantly influences the electrical resistance parameters within the internal resistance. We also examined the effects of State of charge (SOc) and c-rates. The methodology and experimental findings will offer insights for enhancing the safety design, conducting risk assessments, and enabling the cascading utilization of energy storage systems based on LIBs. In this study, the impact of low-velocity impacts on the performance and safety of LIBs is explored. Various conditions, such as impact energy, State of charge (SOc), and c-rates, systematically reveal mechanical, electrochemical, and thermal responses, as well as damage behaviors. The study demonstrates that higher energy leads to increased structural stiffness, maximum temperature, and maximum voltage drop. Additionally, heightened impact energy and SOc significantly influence electrochemical parameters, including charging capacity and internal resistance. image

关键词： cycling performance damaged battery lithium-ion battery low-velocity impact mechanical safety LITHIUM-ION BATTERY SHORT-cIRcUIT MEcHANIcAL-BEHAVIOR POUcH cELLS cOMPUTATIONAL MODEL ELEcTRIc VEHIcLES THERMAL-BEHAVIOR STRAIN-RATE DEFORMATION OVERcHARGE

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Fe-Induced Electronic Transfer and Structural Evolution of Lotus Pod-Like coNiFePx@P,N-c Heterostructure for Sustainable Oxygen Evolution

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Energy & Environmental Materials 2024年第3期7卷 186-193页

作者： Xiaojun Zeng Qingqing Zhang chulong Jin Hui huang Yanfeng Gao Advanced ceramic Materials Research Institute School of Materials Science and EngineeringJingdezhen Ceramic University Singapore Institute of Technology School of Materials Science and Engineering Shanghai University

Transition metal phosphides with metallic properties are a promising candidate for electrocatalytic water oxidation,and developing highly active and stable metal phosphide-based oxygen evolution reaction catalysts is still ***,we present a facile ion exchange and phosphating processes to transform intestine-like coNiPx@P,N-c into lotus pod-like coNiFePx@P,N-c heterostructure in which numerous P,N-codoped carboncoated coNiFePxnanoparticles tightly anchors on the 2D carbon ***,the as-prepared coNiFePx@P,N-c enables a core-shell structure,high specific surface area,and hierarchical pore structure,which present abundant heterointerfaces and fully exposed active ***,the incorporation of Fe can also induce electron transfer in coNiPx@P,IM-c,thereby promoting the oxygen evolution ***,coNiFePx@P,IM-c delivers a low overpotential of 278 mV （vs RHE） at a current density of10 mA cm-1and inherits excellent long-term stability with no observable current density decay after 30 h of chronoamperometry *** work not only highlights heteroatom induction to tune the electronic structure but also provides a facile approach for developing advanced and stable oxygen evolution reaction electrocatalysts with abundant heterointerfaces.

关键词： electronic transfer Fe exchange multi-metal phosphides OER electrocatalysts structural evolution

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A universal multifunctional dual cation doping strategy towards stabilized ultra-high nickel cobalt-free lithium layered oxide cathode

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Journal of Energy chemistry 2024年第8期95卷 296-305,I0007页

作者： Yabin Shen Dongming Yin Limin Wang Gang huang Yong cheng Henan Institute of Advanced Technology Zhengzhou UniversityZhengzhou 450002HenanChina State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022JilinChina

Ultra-high nickel cobalt-free lithium layered oxides are promising cathode material for lithium-ion batteries(LIBs)because of their relatively high capacity and low ***,the high nickel content would induce bulk structure degradation and interfacial environment deterioration,and the absence of co element reduces the lithium diffusion kinetics,severely limiting the performance liberation of this kind of ***,a multifunctional Ti/Zr dual cation co-doping strategy has been employed to improve the lithium storage performance of LiNi_(0.9)Mn_(0.1)O_(2)(NM91)*** the one hand,the Ti/Zr co-doping weakens the Li^(+)/Ni^(2+)mixing through magnetic interactions due to the inexistence of unpaired electrons for Ti^(4+)and Zr^(4+),increasing the lithium diffusion rate and suppressing the harmful coexistence of H1 and H2 *** the other hand,they enhance the lattice oxygen stability because of the strong Ti-O and Zr-O bonds,inhibiting the undesired H3 phase transition and lattice oxygen loss,improving the bulk structure and cathode-electrolyte interface *** a result,the Ti/Zr co-doped NM91(NMTZ)exhibits a 91.2%capacity retention rate after 100 cycles,while that of NM91 is only82.9%.Also,the NMTZ displays better rate performance than NM91 with output capacities of 115 and93 mA h g^(-1)at a high current density of 5 c,***,the designed NMTZ could enable the full battery to deliver an energy density up to 263 W h kg^(-1),making the ultra-high nickel cobaltfree lithium layered oxide cathode closer to practical applications.

关键词： Lithium-ion battery Ultra-high nickel cobalt-free cathode Ti/Zr co-doping Li^(+)/Ni^(2+)mixing Lattice oxygen stability

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Global Zero-relaxation Limit Problem of the Electro-diffusion Model Arising in Electro-Hydrodynamics

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Acta Mathematicae Applicatae Sinica 2024年第1期40卷 241-268页

作者： Ming-hua Yang Si-ming huang Jin-yi Sun Department of Mathematics Jiangxi University of Finance and EconomicsNanchang330032China School of Public Administration Guangdong University of Foreign StudiesGuangzhou510006China college of Mathematics and Statistics Northwest Normal UniversityLanzhou730070China

In this paper,we study a global zero-relaxation limit problem of the electro-diffusion model arising in electro-hydrodynamics which is the coupled Planck-Nernst-Poisson and Navier-Stokes *** is,the paper deals with a singular limit problem of{u^(∈)_(t)+u^(∈)·▽u^(∈)-Δu^(∈)+▽P^(∈)=Δφ^(∈)▽φ^(∈),in R^(3)×(0,∞),▽·u^(∈)=0,in R^(3)×(0,∞),n^(∈)_(t)+u^(∈)·▽n^(∈)-Δn^(∈)=-▽·(n^(∈)▽φ^(∈)),in R^(3)×(0,∞),ct+u^(∈)·▽c^(∈)-Δc^(∈)=▽·(c^(∈)▽φ^(∈)),in R^(3)×(0,∞),∈^(-1)φ^(∈)_(t)=Δφ^(∈)-n^(∈)+c^(∈),in R^(3)×(0,∞),(u^(∈),n^(∈),c^(∈),φ^(∈))|t=0=(u0,n0,c0,φ0),in R^(3) involving with a positive,large parameter^(∈).The present work show a case that(u^(∈),n^(∈),c^(∈))stabilizes to(u^(∞),n∞,c∞):=(u,n,c)uniformly with respect to the time variable as^(∈)→+∞with respect to the strong topology in a certain Fourier-Herz space.

关键词： fourier-Herz space littlewood-Paley decomposition stability limit dissipative system

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Effect of Tanshinone IIA on High Glucose-induced Apoptosis and Oxidative Stress Damage in Vascular Endothelial cells

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chinese Journal of Biomedical Engineering 2024年第2期33卷 62-68页

作者： QIU Shui-lin huang Rong huang Jian-qing QIU Rong-shui Longyan First Affiliated Hospital of Fujian Medical University Xiamen Medical college Affiliated Haicang Hospital

Objective: The primary cause of microvascular disease in diabetic complications is long-term hyperglycemia, wherein the damage and apoptosis of vascular endothelial cells play a significant role. Sodium tanshinone IIA sulfonate(STS) has been found to have beneficial effects on cardiovascular health. This study aimed to investigate the impact of STS on high glucose-induced apoptosis and oxidative stress damage in vascular endothelial cells, as well as its potential protective mechanisms. Methods:Human umbilical vein endothelial cells(HUVEcs) were divided into five groups:low-glucose group, high-glucose group, and three STS groups(STS-a, STS-b, and STS-c). The low-glucose group was incubated with DMEM low-sugar medium containing 5.5 mmol·L-1glucose, while the high-glucose group was treated with 33.3mmol·L-1glucose. The STS groups were exposed to 10, 30, and 50 μg·m L-1of STS,respectively. Each group was cultured for 72 h, and the MTT method was utilized to assess cell proliferation. Additionally, flow cytometry was employed to monitor changes in cell apoptosis and cellular oxidative stress indicators at 24, 48, and 72 h of cell culture in each group. Results: As time went on, the cell proliferation ability and apoptosis rate of each group gradually increased. The high-glucose group exhibited lower proliferation ability compared to the other groups. The STS-c group demonstrated the highest OD value for proliferation ability(24 h: 1.19±0.12; 48 h: 1.20±0.13; 72 h:1.25 ±0.12), but it was still lower than that of the low-sugar group. Notably, the high-glucose group had the highest cell apoptosis rate, while the low-glucose group had the lowest. The apoptosis rate of the STS-c group(24 h: 8.02±0.13; 48 h: 10.10±0.12;72 h: 13.18 ±0.11)% was between that of the low-glucose group and the high-glucose group, and lower than the STS-a and STS-b groups. Furthermore, the high-glucose group exhibited the highest malondialdehyde and nitric oxide synthase activities, as well as super

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Flexible, Transparent and conductive Metal Mesh Films with Ultra‑High FoM for Stretchable Heating and Electromagnetic Interference Shielding

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Nano-Micro Letters 2024年第5期16卷 201-213页

作者： Zibo chen Shaodian Yang Junhua huang Yifan Gu Weibo huang Shaoyong Liu Zhiqiang Lin Zhiping Zeng Yougen Hu Zimin chen Boru Yang Xuchun Gui State Key Laboratory of Optoelectronic Materials and Technologies School of Electronics and Information TechnologySun Yat-Sen UniversityGuangzhou 510275People’s Republic of China Guangdong Provincial Key Laboratory of Materials for High Density Electronic Packing Shenzhen Institutes of Advanced TechnologyChinese Academy of SciencesShenzhen 518055GuangdongPeople’s Republic of China School of Materials Science and Engineering Sun Yat-Sen UniversityGuangzhou 510275People’s Republic of China

Despite the growing demand for transparent conductive films in smart and wearable electronics for electromagnetic interference(EMI)shielding,achieving a flexible EMI shielding film,while maintaining a high transmittance remains a significant ***,a flexible,transparent,and conductive copper(cu)metal mesh film for EMI shielding is fabricated by self-forming crackle template method and electroplating *** cu mesh film shows an ultra-low sheet resistance(0.18Ω□^(-1)),high transmittance(85.8%@550 nm),and ultra-high figure of merit(>13,000).It also has satisfactory stretchability and mechanical stability,with a resistance increases of only 1.3%after 1,000 bending *** a stretchable heater(ε>30%),the saturation temperature of the film can reach over 110°c within 60 s at 1.00 V applied ***,the metal mesh film exhibits outstanding average EMI shielding effectiveness of 40.4 dB in the X-band at the thickness of 2.5μ*** a demonstration,it is used as a transparent window for shielding the wireless communication electromagnetic ***,the flexible and transparent conductive cu mesh film proposed in this work provides a promising candidate for the next-generation EMI shielding applications.

关键词： Metal mesh Transparent conductive film Stretchable heater Electromagnetic interference shielding

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