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Food Science and Human Wellness 2024年第2期13卷 879-884页

作者： Xin Wang chengyi Hong Zhengzhong Lin Zhiyong huang college of Ocean Food and Biological Engineering Jimei UniversityXiamen 361021China

A ratiometric fluorescent probe for hypoxanthine(Hx)detection was established based on the mimic enzyme and fluorescence characteristics of cobalt-doped graphite-phase carbon nitride(co doped g-c_(3)N_(4)).In addition to emitting strong fluorescence,the peroxidase activity of co doped g-c_(3)N_(4)can catalyze the reaction of O-phenylenediamine and H_(2)O_(2)to produce diallyl phthalate which can emit yellow fluorescence at 570 *** the decomposition of Hx by xanthine oxidase,Hx can be indirectly detected by the generating hydrogen peroxide based on the measurement of fluorescent ratio I(F_(570)/F_(370)).The linear range was 1.7-272.2 mg/kg(R^(2)=0.997),and the detection limit was 1.52 mg/kg(3σ/K,n=9).The established method was applied to Hx detection in bass,grass carp,and shrimp,and the data were verified by *** result shows that the established probe is sensitive,accurate,and reliable,and can be used for Hx detection in aquatic products.

关键词： co doped g-c_(3)N_(4) Ratiometric fluorescent probe Hypoxanthine Freshness Aquatic products

Palladium complexes with N,O-Bidentate Ligands Based on N-Oxide Units from cyclic Secondary Amines:Synthesis and catalytic Application in Mizoroki-Heck Reaction

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chinese Journal of chemistry 2024年第3期42卷 294-300页

作者： Xuefeng Jia Yanyan Wen changhui He Xianqiang huang Key Laboratory of Magnetic Molecules and Magnetic Information Materials of Ministry of Education School of Chemistry and Materials ScienceShanxi Normal UniversityTaiyuanShanxi030032 China Shandong Provincial Key Laboratory of chemical Energy Storage and Novel cell Technology School of Chemistry & Chemical EngineeringLiaocheng UniversityLiaochengShandong252059 China

Palladium-catalyzed Mizoroki-Heck reaction is a powerful and efficient method for construction of csp2–csp2 ***,four palladium complexes(I—IV)with N,O-bidentate ligands(L1—L4)based on N-oxide units from cyclic secondary amines were easily synthesized and successfully applied in Mizoroki-Heck reaction of aryl bromides with electron-deficient olefins.X-ray diffraction analyses indicated the palladium(II)atom of II took the distorted square planar geometry and was four-coordinated by nitrogen and oxygen atoms from two ligands(L2).Two free chloride ions were presented as counter anions in complex *** the palladium(II)center of IV was coordinated by nitrogen and oxygen atoms from one ligand(L4)as well as two chlorine atoms,which exhibited the nearly square-planar *** study on catalytic properties of palladium complexes revealed that complex II exhibited high activity superior to the other *** coupling reactions of a series of aryl bromides and olefin derivatives proceeded in the presence of 2—5 mol%palladium complex II,giving the desired products in good to excellent *** advantages of this method such as good compatibility of functional groups,high yields,and short reaction times made it more attractive for constructing csp2–csp2 bonds in the synthesis of functional molecules and materials.

关键词： Palladium complexes N,O-Bidentate ligands N-Oxide units Mizoroki-Heck reaction Aryl bromide Electron-deficient olefins c—c coupling Homogeneous catalysis Substituent effects

Experimental study of face passive failure features of a shallow shield tunnel in coastal backfill sand

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Frontiers of Structural and civil Engineering 2024年第2期18卷 252-271页

作者： Weifeng QIAN Ming huang Bingnan WANG chaoshui XU Yanfeng HU School of civil Engineering Fuzhou UniversityFuzhou 350108China School of civil Environment and Mining EngineeringUniversity of AdelaideAdelaide 5005Australia china First Highway Xiamen Engineering co. Ltd.Xiamen 361000China

Face passive failure can severely damage existing structures and underground utilities during shallow shield tunneling,especially in coastal backfill *** this work,a series of laboratory model tests were developed and conducted to investigate such failure,for tunnels located at burial depth ratios for which c/D=0.5,0.8,1,and *** pressures,the evolution of failure processes,the failure modes,and the distribution of velocity fields were examined through model tests and numerical *** support pressure in the tests first rose rapidly to the elastic limit and then gradually increased to the maximum value in all *** maximum support pressure decreased slightly in cases where c/D=0.8,1,and 1.3,but the rebound was insignificant where c/D=*** addition,the configuration of the failure mode with c/D=0.5 showed a wedge-shaped arch,which was determined by the outcropping shear *** configuration of failure modes was composed of an arch and the inverted trapezoid when c/D=0.8,1,and 1.3,in which the mode was divided into lower and upper failure zones.

关键词： tunnel face stability passive failure model test support pressure failure mode

Pairing nitroxyl radical and phenazine with electron-withdrawing/-donating substituents in “water-in-ionic liquid” for high-voltage aqueous redox flow batteries

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Green Energy & Environment 2024年第4期9卷 713-722页

作者： Zhifeng huang Rolf Hempelmann Yiqiong Zhang Li Tao Ruiyong chen Transfercenter Sustainable Electrochemistry Saarland University and KIST Europe66125SaarbruckenGermany State Key Laboratory of chem/Bio-Sensing and chemometrics college of chemistry and chemical Engineering Hunan University Changsha410082HunanChina college of Materials Science and Engineering changsha University of Science and Technology Changsha410114HunanChina Materials Innovation Factory Department of ChemistryUniversity of LiverpoolLiverpoolL697ZDUnited Kingdom

Aqueous redox-active organic materials-base electrolytes are sustainable alternatives to vanadium-based electrolyte for redoxﬂow batteries(RFBs)due to the advantages of high ionic conductivity,environmentally benign,safety and low ***,the underexplored redox properties of organic materials and the narrow thermodynamic electrolysis window of water(1.23 V)hinder their wide ***,seeking suitable organic redox couples and aqueous electrolytes with a high output voltage is highly suggested for advancing the aqueous organic *** this work,the functionalized phenazine and nitroxyl radical with electron-donating and electron-withdrawing group exhibit redox potential of-0.88 V and 0.78 V ***,respectively,in“water-in-ionic liquid”supporting *** spectra reveal that the activity of water is largely suppressed in“water-in-ionic liquid”due to the enhanced hydrogen bond interactions between ionic liquid and water,enabling an electrochemical stability window above 3 V.“Water-in-ionic liquid”supporting electrolytes help to shift redox potential of nitroxyl radical and enable the redox activity of functionalized *** assembled aqueous RFB allows a theoretical cell voltage of 1.66 V and shows a practical discharge voltage of 1.5 V in the“water-in-ionic liquid”***,capacity retention of 99.91%per cycle is achieved over 500 charge/discharge cycles.A power density of 112 mW cm^(-2) is obtained at a current density of 30 mA cm^(-2).This work highlights the importance of rationally combining supporting electrolytes and organic molecules to achieve high-voltage aqueous RFBs.

关键词： Aqueous redoxﬂow batteries Water-in-ionic liquid electrolytes High-voltage aqueous batteries Organic redox-active materials

Making small molecules in plants:A chassis for synthetic biology-based production of plant natural products

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Journal of Integrative Plant Biology 2023年第2期65卷 417-443页

作者： Xinyu Liu Peijun Zhang Qiao Zhao Ancheng c.huang Key Laboratory of Molecular Design for Plant cell Factory of Guangdong Higher Education Institutes Department of BiologySchool of Life SciencesSUSTech-PKU Institute of Plant and Food ScienceSouthern University of Science and TechnologyShenzhen 518055China Shenzhen Institutes of Advanced Technology(SIAT) the Chinese Academy of SciencesShenzhen 518055China

Plant natural products have been extensively exploited in food,medicine,flavor,cosmetic,renewable fuel,and other industrial *** biology has recently emerged as a promising means for the cost-effective and sustainable production of natural *** with engineering microbes for the production of plant natural products,the potential of plants as chassis for producing these compounds is underestimated,largely due to challenges encountered in engineering *** in plant engineering is instrumental for enabling the effective and efficient production of valuable phytochemicals in plants,and also paves the way for a more sustainable future *** this manuscript,we briefly recap the biosynthesis of plant natural products,focusing primarily on industrially important terpenoids,alkaloids,and *** further summarize the plant hosts and strategies that have been used to engineer the production of natural *** challenges and opportunities of using plant synthetic biology to achieve rapid and scalable production of high-value plant natural products are also discussed.

关键词： biosynthesis natural products plant engineering synthetic biology

In situ anchoring in carbon matrix of Bi_(2)O_(2)cO_(3) as a high-performance anode material for Li-ion batteries

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Rare Metals 2024年第8期43卷 3634-3646页

作者： Pu-Qiang He Jun Guo Hui huang Zhong-cheng Guo Faculty of Metallurgy and Energy Engineering Kunming University of Science and TechnologyKunming 650093China Research center of Metallurgical Electrode Materials Engineering Technology Kunming 650106China Kunming Hendera Science and Technology co. Ltd.Kunming 650106China

Bismuth-based anode materials have been regarded as promising Li-ion batteries due to their high theoretical ***,their low conductivity and associated volume expansion inhabited their *** this work,Bi_(2)O_(2)cO_(3)@c composites were successfully synthesized by in situ anchoring of flower-like Bi_(2)O_(2)cO_(3) nanosheets on a carbon-based substrate via *** unique composited structure of Bi_2O_(2)-cO_(3)@c leads to a stable specific capacity of 547 mAh·g^(-1)after 100 cycles at a current density of 0.1 A·g^(-1).Notably,it demonstrates excellent rate capability with a specific capacity of 210 mAh·g^(-1)at 5 A·g^(-1).After 550 cycles at a current density of 0.5 A·g^(-1),a high reversible capacity of nearly 400 mAh·g^(-1)was ***,in situ X-ray diffraction measurements clearly demonstrate the conversion between Bi and Li_(3)Bi during alloying/dealloying,confirming the good electrochemical reversibility of the materials for Li *** reaction kinetics of Bi_(2)O_(2)cO_(3)@c were further investigated using galvanostatic intermittent titration ***,Bi_2O_(2)-cO_(3)@c exhibited excellent long-term stability,maintaining its high reversible capacity for over 200 cycles at a current density of 0.5 A·g^(-1)in a full cell configuration using Li_(1.20)Mn_(0.54)Ni_(0.13)co_(0.13)O_(2) as the cathode *** result further underscores its promising potential for lithium-ion *** work may provide inspiration for the design of alloy-type negative electrode materials for high-performance rechargeable batteries.

关键词： Bi_(2)O_(2)cO_(3) composite materials Anode materials Full batteries

Arbuscular mycorrhizal fungi regulate plant mineral nutrient uptake and partitioning in iron ore tailings undergoing eco-engineered pedogenesis

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Pedosphere 2024年第2期34卷 385-398页

作者： Zhen LI Songlin WU Yunjia LIU Qing YI Merinda HALL Narottam SAHA Junjian WANG Yuanfang huang Longbin huang college of Land Science and Technology China Agricultural UniversityBeijing 100193China centre for Mined Land Rehabilitation Sustainable Minerals InstituteThe University of QueenslandBrisbaneQLD 4072Australia Guangdong Provincial Key Laboratory of Soil and Groundwater Pollution control School of Environmental Science and EngineeringSouthern University of Science and TechnologyShenzhen 518055China

Excess available K and Fe in Fe ore tailings with organic matter amendment and water-deficiencies may restrain plant colonization and growth,which hinders the formation of eco-engineered soil from these tailings for sustainable and cost-effective mine site *** mycorrhizal(AM)fungi are widely demonstrated to assist plant growth under various unfavorable ***,it is still unclear whether AM symbiosis in tailings amended with different types of plant biomass and under different water conditions could overcome the surplus K and Fe stress for plants in Fe ore tailings,and if so,by what ***,host plants(Sorghum *** ***),either colonized or noncolonized by the AM fungi(Glomus spp.),were cultivated in lucerne hay(LH,c:N ratio of 18)-or sugarcane mulch(SM,c:N ratio of 78)-amended Fe ore tailings under well-watered(55%water-holding capacity(WHc)of tailings)or water-deficient(30%WHc of tailings)*** mycorrhizal colonization,plant growth,and mineral elemental uptake and partitioning were *** indicated that AM fungal colonization improved plant growth in tailings amended with plant biomass under water-deficient *** mycorrhizal fungal colonization enhanced plant mineral element uptake,especially P,both in the LH-and SM-amended tailings regardless of water ***,AM symbiosis development restrained the translocation of excess elements(i.e.,K and Fe)from plant roots to shoots,thereby relieving their *** AM fungal roles in P uptake and excess elemental partitioning were greater in LH-amended tailings than in SM-amended *** deficiency weakened AM fungal colonization and functions in terms of mineral element uptake and *** findings highlighted the vital role AM fungi played in regulating plant growth and nutrition status in Fe ore tailings technosol,providing an important basis for involvement of AM fungi in the eco-engineered pedo

关键词： Fe stress fungal symbiosis K stress mine site rehabilitation mycorrhizal colonization plant biomass amendment plant nutrition water deficiency

Weakly Polarized Organic cation-Modified Hydrated Vanadium Oxides for High-Energy Efficiency Aqueous Zinc-Ion Batteries

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Nano-Micro Letters 2024年第7期16卷 169-186页

作者： Xiaoxiao Jia chaofeng Liu Zhi Wang Di huang Guozhong cao Department of Materials Science and Engineering University of WashingtonSeattleWA 98195USA School of Materials Science and Engineering Tongji UniversityShanghai 201804People’s Republic of China

Vanadium oxides,par-ticularly hydrated forms like V_(2)O_(5)·nH_(2)O(VOH),stand out as promising cathode candidates for aqueous zinc ion batteries due to their adjustable layered structure,unique electronic characteristics,and high theoretical ***,challenges such as vanadium dissolution,sluggish Zn^(2+)diffusion kinetics,and low operating voltage still hinder their direct *** this study,we present a novel vanadium oxide([c_(6)H_(6)N(cH_(3))_(3)]_(1.08)V_(8)O_(20)·0.06H_(2)O,TMPA-VOH),developed by pre-inserting trimethylphenylammonium(TMPA+)cations into *** incorporation of weakly polarized organic cations capitalizes on both ionic pre-intercalation and molecular pre-intercalation effects,resulting in a phase and morphology transition,an expansion of the interlayer distance,extrusion of weakly bonded interlayer water,and a substantial increase in V^(4+)*** modifications synergistically reduce the electrostatic interactions between Zn^(2+)and the V-O lattice,enhancing structural stability and reaction kinetics during *** a result,TMPA-VOH achieves an elevated open circuit voltage and operation voltage,exhibits a large specific capacity(451 mAh g^(-1)at 0.1 A g^(-1))coupled with high energy efficiency(89%),the significantly-reduced battery polarization,and outstanding rate capability and cycling *** concept introduced in this study holds great promise for the development of high-performance oxide-based energy storage materials.

关键词： Zinc-ion battery Vanadium oxide V_(2)O_(5)·nH_(2)O Pre-intercalation Interlayer engineering

conversion of Lignin into Porous carbons for High-Performance Supercapacitors via Spray Drying and KOH Activation: Structure-Properties Relationship and Reaction Mechanism

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Journal of Renewable Materials 2024年第7期12卷 1207-1218页

作者： Shihao Feng Qin Ouyang Jing huang Xilin Zhang Zhongjun Ma Kun Liang Qing huang Zhejiang Key Laboratory of Data-Driven High-Safety Energy Materials and Applications Ningbo Key Laboratory of Special Energy Materials and ChemistryNingbo Institute of Materials Technology and EngineeringChinese Academy of SciencesNingbo315201China Engineering Laboratory of Advanced Energy Materials Qianwan Institute of CNITECHNingbo315336China School of Physics Henan Normal UniversityXinxiang453007China School of Environment Henan Normal UniversityXinxiang453007China

Lignin-derived porous carbons have emerged as promising electrode materials for ***,the challenge remains in designing and controlling their structure to achieve ideal electrochemical performance due to the complex molecular structure of lignin and its intricate chemical reactions during the activation *** this study,three porous carbons were synthesized from lignin by spray drying and chemical activation with vary-ing KOH *** speciﬁc surface area and structural order of the prepared porous carbon continued to increase with the increase of the KOH ***-mass spectrometry(TG-MS)was employed to track the molecular fragments generated during the pyrolysis of KOH-activated lignin,and the mechanism of the thermochemical conversion was *** the thermochemical conversion of lignin,KOH facili-tated the removal of H2 and cO,leading to the formation of not only more micropores and mesopores,but also more ordered carbon *** pore structure exhibited a greater impact than the carbon structure on the electrochemical performance of porous *** optimized porous carbon exhibited a capacitance of 256 F g-1 at a current density of 0.2 A g-1,making it an ideal electrode material for high-performance supercapacitors.

关键词： Lignin porous carbon KOH activation mechanism supercapacitor

Realization of nonreciprocal acoustic energy transfer using an asymmetric strong nonlinear vibroacoustic system

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International Journal of Mechanical System Dynamics 2024年第1期4卷 99-114页

作者： Jiangming Jin Jingxiao huang Yuepeng Xiao Sound and Vibration Laboratory College of Mechanical EngineeringZhejiang University of TechnologyHangzhouChina

In this paper,an asymmetric vibroacoustic system that can passively realize nonreciprocal transmission of acoustic energy is *** experimental system consists of a waveguide,a strongly nonlinear membrane,and three acoustic cavities with different *** theoretical modeling of the system is verified by experiments,and parametric analysis is also carried *** intensive studies reveal the nonreciprocal transmission of acoustic energy in this prototype *** forward excitation,internal resonance between the two nonlinear normal modes of the vibroacoustic system occurs,and acoustic energy is irreversibly transferred from the waveguide to the nonlinear ***,under backward excitation,there is no internal resonance in the *** spectra and wavelet analysis are used to highlight the mechanism of nonreciprocal transfer of acoustic ***,nearly unidirectional(preferential)transmission of acoustic energy transfer is shown by this *** nonreciprocal acoustic energy transfer method illustrated in this paper provides a new way to design the odd acoustic element.

关键词： vibroacoustic system acoustic nonreciprocity nonlinear normal mode transient resonance capture