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Stable immobilization of lithium polysulfides using three-dimensional ordered mesoporous Mn_(2)O_(3) as the host material in lithium-sulfur batteries

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Carbon Energy 2024年第6期6卷 99-112页

作者： sung joon park Yun Jeong Choi Hyun-seung Kim Min Joo Hong Hongjun Chang Janghyuk Moon Young-Jun Kim Junyoung Mun Ki Jae Kim Department of Energy Science Sungkyunkwan UniversitySuwonGyeonggi-doRepublic of Korea Department of Energy Engineering Konkuk UniversitySeoulRepublic of Korea Advanced Batteries Research Center Korea Electronic Technology InstituteSeongnamRepublic of Korea Department of Future Energy Engineering Sungkyunkwan UniversitySuwonRepublic of Korea Department of Energy Systems Engineering Chung-Ang UniversitySeoulRepublic of Korea SKKU Advanced Institute of Nanotechnology Sungkyunkwan UniversitySuwonGyeonggi-doRepublic of Korea SKKU Institute of Energy Science and Technology(SIEST) Sungkyunkwan UniversitySuwonRepublic of Korea School of Advanced Materials Science and Engineering Sungkyunkwan UniversitySuwonRepublic of Korea

Lithium-sulfur batteries(LSBs)have drawn significant attention owing to their high theoretical discharge capacity and energy ***,the dissolution of long-chain polysulfides into the electrolyte during the charge and discharge process(“shuttle effect”)results in fast capacity fading and inferior electrochemical *** this study,Mn_(2)O_(3)with an ordered mesoporous structure(OM-Mn_(2)O_(3))was designed as a cathode host for LSBs via KIT-6 hard templating,to effectively inhibit the polysulfide shuttle ***-Mn_(2)O_(3)offers numerous pores to confine sulfur and tightly anchor the dissolved polysulfides through the combined effects of strong polar-polar interactions,polysulfides,and sulfur chain *** OM-Mn_(2)O_(3)/S composite electrode delivered a discharge capacity of 561 mAh g^(-1) after 250 cycles at 0.5 C owing to the excellent performance of OM-Mn_(2)O_(3).Furthermore,it retained a discharge capacity of 628mA h g^(-1) even at a rate of 2 C,which was significantly higher than that of a pristine sulfur electrode(206mA h g^(-1)).These findings provide a prospective strategy for designing cathode materials for high-performance LSBs.

关键词： host material lithium-sulfur battery ordered mesoporous structure shuttle effect transition-metal oxides

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Thermoresponsive Al^(3+)-crosslinked poly(N-isopropylacrylamide)/alginate composite for green recovery of lithium from Li-spiked seawater

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Green Energy & Environment 2022年第2期7卷 334-344页

作者： sung Ho park Sang joon Lee Department of Mechanical Engineering Pohang University of Science and Technology(POSTECH)Pohang790-784South Korea

With the rapid increase in the demand for lithium as an energy-critical element,the recovery of Li+ions from seawater is a worldwide challenging ***,we propose a new facile and fast selective recovery approach of Li+using an Al^(3+)-crosslinked poly(N-isopropylacrylamide)(PNIPAAm)/alginate(Alg)(PNP/Alg(Al)) *** in situ TEM images indicate that Alg-Al^(3+)coordination is reorganized via the rearrangement of PNIPAAm and Alg networks,as the temperature *** reorganization eventually leads to the formation of polycrystalline *** in situ FTIR results exhibit that PNP/Alg(Al) composite has peculiar phase transitions,which includes a retrogressive phase change from hydrophobic to *** synergetic effect of the strong repulsion force of Al^(3+) ions and the attractive force of negatively charged polymeric chains enables the efficient adsorption of Li+ions with a low affinity from Li-spiked seawater.7.3% of Li+ions are recovered from Li-spiked seawater although the concentration of Li-spiked seawater is very *** addition,Li+ions can be extracted from PNP/Alg(Al) composite with the use of a small thermal *** proposed thermoresponsive IPN gel provides a strong potential in practical applications for Li+recovery as an innovative energy-material strategy.

关键词： structure seawater lithium

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Designing a Biomimetic Ornithopter Capable of Sustained and Controlled Flight

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Journal of Bionic Engineering 2008年第1期5卷 39-47页

作者： joon Hyuk park Kwang-joon Yoon Department of Aerospace Information System and Artificial Muscle Research Center Konkuk University Seoul 143-701 Korea

We describe the design of four ornithopters ranging in wing span from 10 cm to 40 cm, and in weight from 5 g to 45 g. The controllability and power supply are two major considerations, so we compare the efficiency and characteristics between different types of subsystems such as gearbox and tail shape. Our current omithopter is radio-controlled with inbuilt visual sensing and capable of takeoff and landing. We also concentrate on its wing efficiency based on design inspired by a real insect wing and consider that aspects of insect flight such as delayed stall and wake capture are essential at such small size. Most importantly, the advance ratio, controlled either by enlarging the wing beat amplitude or raising the wing beat frequency, is the most significant factor in an ornithopter which mimics an insect.

关键词： biomimetic ornithopter flapping wing unsteady state low Reynolds number

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DYNAMIC PROPERTIES OF AL-ALLOY FOAM BEAM DAMAGED BY COMPRESSIVE FATIGUE

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Acta Mechanica Solida Sinica 2008年第3期21卷 241-246页

作者： sung-Gaun Kim Ilhyun Kim Amkee Kim Seung-joon Kim Junhong park Division of Mechanical and Automotive Engineering Kongju National University 275 Budae-dongCheonan Chungnam 330-717 Korea Department of Mechanical Engineering Hanyang University Seongdong-Gu Seoul 133-791 Korea

The permanent residual strain in aluminum （Al） alloy foams induced by compressive fatigue gradually increases with the increasing number of loading cycles. Consequently, the progressive shortening of Al-alloy foam degrades the dynamic material performance by the failure and ratcheting of multi-cells in the foam. In this paper, the dynamic properties of Al-alloy foams damaged by compressive fatigue were studied. The beam specimens with various residual strains were made by cyclic compression-compression stress. The dynamic bending modulus and loss factor were evaluated by using a beam transfer function method. As a result, the dynamic bending stiffness of Al-alloy foam turned out to be decreased due to damage while the loss factor was improved because of the increasing energy dissipation of such factors as cracked cell walls formed during the shortening process of the foam. The loss factor shows a manifest dependence on the fatigue residual strain.

关键词： Aluminum foam fatigue dynamic stiffness loss factor

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Effect of BainiticTreatment on Microstructure and Mechanical Properties of TRIP Cold-Rolled Steel Sheets

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Journal of Iron and Steel Research International 2011年第S1期18卷 1004-1007页

作者： Kim sung-joon Korea Institute of Machinery Science Changwon 641010Korea

The effects of bainitic treatment on microstructure and mechanical properties of 0.10C-1.5Mn-l.5Al TRIP-aided cold-rolled steels have been *** samples were heated by intercritical annealing at 820℃for 2 min and quenched in banitic temperature with different hoding time for 5 to 300s,two salt bath were used for the heat *** results show that the yield strength and elongation increase with the increasing of bainitic holding time,while the tensile strength *** volume fraction of retained austenite rise at the beginning of bainitic holding and then reduce,the carbon content of retained austenite increase during the bainitic *** tensile strengthen multiply elongation reaches the highest value at *** mechanical stability of retained austenite fits well with strain hardening during deformation.

关键词： TRIP bainitic treatment microstructure mechanical properties retained austenite

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Graphene electrode with tunable charge transport in thin-film transistors

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Nano Research 2018年第1期11卷 274-286页

作者： Ick-joon park Tae In Kim In-Tak Cho Chang-Woo Song Ji-Woong Yang Hongkeun park Woo-Seok Cheong sung Gap Im Jong-Ho Lee sung-Yool Choi School of Electrical Engineering GrapheneY2D Materials Research Center Korea Advanced Institute of Science and Technology (KAIST) Daejeon 34141 Republic of Korea Department of Electrical Engineering Seoul National University Seou108826 Republic of Korea Electronics and Telecommunications Research Institute Daejeon 34129 Republic of Korea Department of Chemical and Biomolecular Engineering Graphene/2D Materials Research Center Korea Advanced Institute of Science and Technology (KAIST) Daejeon 34141 Republic of Korea

Graphene, a single atomic layer of sp2-hybridized carbon, has immense potential as a transparent conducting material in electronic applications owing to its superior properties, including optical transparency and high conductivity. Particularly, the tunable work function of graphene enables the integration of graphene electrodes with various electronic devices. To achieve high performance in graphene-based devices, effective charge transport between the graphene electrode and the semiconducting material needs to be optimized; this is closely related to the modulation of the Schottky barrier （SB）. In this study, we investigate the ~nable charge transport properties as a function of graphene doping in n-channel thin-film transistors （TFTs） in terms of the electrical characteristics and low-frequency noise （LFN） behaviors. Alkali metal carbonates tuned the work function of graphene, resulting in a dramatic decrease in the SB and an improvement of the carrier injection in n-channel TFTs. The electrical performance of the TFTs was evaluated by extraction of the field-effect mobilities and ratio of contact resistance to total resistance. Furthermore, the level of contact noise created by the barrier height fluctuation and relative contribution of channel noise and contact noise in the TFTs was investigated by LFN measurements to demonstrate the ~nable charge transport. Our findings therefore provide new insights into the tunable charge transport mechanism in graphene-based devices and reveal the immense potential of graphene as electrodes in high performance flexible and transparent displays.

关键词： charge transport graphene doping Schottky barrier work function contact property low-frequency noise

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Occult gastric cancer with distant metastasis proven by random gastric biopsy

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World Journal of Gastroenterology 2016年第16期22卷 4270-4274页

作者： Sang Hyuk Lee Kyu-Hyoung Lim Seo-Young Song Hui-Young Lee sung Chul park Chang Don Kang sung joon Lee Dong Wook Choi sung Bae park Young-joon Ryu Department of Internal Medicine Kangwon National University School of Medicine Department of General Surgery Kangwon National University School of Medicine Department of Pathology Kangwon National University School of Medicine

Krukenberg tumor, a rare metastatic ovarian tumor arising from gastrointestinal adenocarcinoma mainly, tends to occur in premenopausal females. Finding the origin of a Krukenberg tumor is crucial for determining prognosis. In Eastern countries, the most common origin of Krukenberg tumor is stomach cancer, which is generally diagnosed via endoscopic biopsy to investigate an abnormal mucosal lesion. Here, we describe a case of huge adnexal mass in a 33-year-old woman who presented with abdominal distension. Two independent endoscopic examinations performed by experts in two tertiary university hospitals revealed no abnormal mucosal lesion. The patient was diagnosed with a Krukenberg tumor according to findings from random endoscopic biopsies taken from normal-looking gastric mucosa in our hospital. It is very rare to be diagnosed via a random biopsy in cases where three well-trained endoscopists had not found any mucosal lesion previously. Thus, in this case, random biopsy was helpful in finding the origin of a Krukenberg tumor.

关键词： Gastric cancer Krukenberg tumor Biopsy Endoscopy Diagnosis

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Body-Shaping Membrane to Regenerate Breast Fat by Elastic Structural Holding

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Research 2024年第1期2023卷 165-180页

作者： Hye-Seon Kim Jeongeun park Hyun-Su Ha Sewoom Baek Chan Hee Lee Kyubae Lee Suji park Jueun Kim Se Won Yi Hak-joon sung Department of Medical Engineering Graduate School of Medical ScienceBrain Korea 21 ProjectYonsei University College of MedicineSeoul 03722Republic of Korea TMD LAB Co.Ltd. 6th Floor31Gwangnaru-ro 8-gilSeongdong-guSeoul 04799Republic of Korea

Tissue regeneration requires structural holding and movement support using tissue-type-specific aids such as bone casts,skin bandages,and joint ***,an unmet need exists in aiding breast fat regeneration as the breast moves following continuous body motion by exposing the breast fat to dynamic ***,the concept of elastic structural holding is applied to develop a shape-fitting moldable membrane for breast fat regeneration(“adipoconductive”)after surgical defects are *** membrane has the following key characteristics:(a)It contains a panel of honeycomb structures,thereby efficiently handling motion stress through the entire membrane;(b)a strut is added into each honeycomb in a direction perpendicular to gravity,thereby suppressing the deformation and stress concentration upon lying and standing;and(c)thermo-responsive moldable elastomers are used to support structural holding by suppressing large deviations of movement that occur *** elastomer became moldable upon a temperature shift above T_(m).The structure can then be fixed as the temperature *** a result,the membrane promotes adipogenesis by activating mechanotransduction in a fat miniature model with pre-adipocyte spheroids under continuous shaking in vitro and in a subcutaneous implant placed on the motion-prone back areas of rodents in vivo.

关键词： thereby shaking Elastic

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Uncertainty analysis of flow rate measurement for multiphase flow using CFD

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Acta Mechanica Sinica 2015年第5期31卷 698-707页

作者： joon-Hyung Kim Uk-Hee Jung sung Kim joon-Yong Yoon Young-Seok Choi Department of Mechanical Design Engineering Hanyang University Thermal & Fluid System R&BD Group Korea Institute of Industrial Technology Energy System Engineering University of Science and Technology

The venturi meter has an advantage in its use,because it can measure flow without being much affected by the type of the measured fluid or flow ***,it has excellent versatility and is being widely applied in many *** flow of a liquid containing air is a representative example of a multiphase flow and exhibits complex flow *** particular,the greater the gas volume fraction（GVF）,the more inhomogeneous the flow *** a result,using a venturi meter to measure the rate of a flow that has a high GVF generates an *** this study,the cause of the error occurred in measuring the flow rate for the multiphase flow when using the venturi meter for analysis by *** ensure the reliability of this study,the accuracy of the multiphase flow models for numerical analysis was verified through comparison between the calculated results of numerical analysis and the experimental *** a result,the Grace model,which is a multiphase flow model established by an experiment with water and air,was confirmed to have the highest ***,the characteristics of the internal flow Held about the multiphase flow analysis result generated by applying the Grace model were analyzed to find the cause of the uncertainty occurring when measuring the flow rate of the multiphase flow using the venturi meter.A phase separation phenomenon occurred due to a density difference of water and air inside the venturi,and flow inhomogeneity happened according to the flow velocity difference of each *** was confirmed that this flow inhomogeneity increased as the GVF increased due to the uncertainty of the flow measurement.

关键词： Multiphase flow Measurement Numerical analysis Venturi meter Gas volume fraction(GVF) Uncertainty Multiphase flow model Grace model

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Empathic Responses of Behavioral-Synchronization in Human-Agent Interaction

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Computers, Materials & Continua 2022年第5期71卷 3761-3784页

作者： sung park Seongeon park Mincheol Whang Savannah College of Art and Design SavannahGA31401USA Sangmyung University Seoul03016Korea

Artificial entities,such as virtual agents,have become more *** long-term presence among humans requires the virtual agent’s ability to express appropriate emotions to elicit the necessary empathy from the *** empathy involves behavioral mimicry,a synchronized co-movement between dyadic ***,the characteristics of such synchrony between humans and virtual agents remain unclear in empathic *** study evaluates the participant’s behavioral synchronization when a virtual agent exhibits an emotional expression congruent with the emotional context through facial expressions,behavioral gestures,and *** viewed an emotion-eliciting video stimulus(negative or positive)with a virtual *** participants then conversed with the virtual agent about the video,such as how the participant felt about the *** virtual agent expressed emotions congruent with the video or neutral emotion during the *** participants’facial expressions,such as the facial expressive intensity and facial muscle movement,were measured during the dialog using a *** results showed the participants’significant behavioral synchronization(i.e.,cosine similarity≥.05)in both the negative and positive emotion conditions,evident in the participant’s facial mimicry with the virtual ***,the participants’facial expressions,both movement and intensity,were significantly stronger in the emotional virtual agent than in the neutral virtual *** particular,we found that the facial muscle intensity of AU45(Blink)is an effective index to assess the participant’s synchronization that differs by the individual’s empathic capability(low,mid,high).Based on the results,we suggest an appraisal criterion to provide empirical conditions to validate empathic interaction based on the facial expression measures.

关键词： Facial emotion recognition facial expression virtual agent virtual human embodied conversational agent empathy human-computer interaction

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