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Science China Technological Sciences 2025年第1期 6-53页

作者： Zhe sun Xuelong LI School of Artificial Intelligence Optics and Electronics (iOPEN)Northwestern Polytechnical University Key Laboratory of Intelligent Interaction and Applications (Northwestern Polytechnical University) Ministry of Industry and Information Technology The Institute of Artificial Intelligence (TeleAI) China Telecom

Water-related optical imaging constitutes a pivotal domain within the field of water-related optics and vision,furnishing essential tools for comprehending the water-related environment, harnessing water resources, and safeguarding water ecology. Its merits encompass facile target detection, elevated imaging resolution, and copious information ***, the formidable challenge of attaining clear images in water-related environments is challenging due to the water's absorption and scattering properties. Substantial strides have been achieved in recent years through advancements in software and hardware optical imaging and processing techniques. This review offers a comprehensive exploration of the present state of water-related optical imaging, spanning historical, theoretical, and methodological dimensions. A retrospective analysis of the historical evolution of water-related optical imaging is presented, accompanied by a detailed exposition of the operational principles and the latest noteworthy advancements in various categories of water-related optical imaging. Furthermore, a meticulous comparative analysis of these methodologies is undertaken. These approaches not only enhance water-related optical imaging efficacy but also furnish robust support for scientific inquiry and resource exploitation in water-related environments. This review enhances the comprehension of advancements in water-related optical imaging research, acting as a crucial touchpoint for future explorations and innovations. Water-related optical imaging is critical for comprehending marine ecosystems, supporting environmental conservation, and improving industry efficiency.

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Engineering nanoparticle structure at synergistic Ru-Na interface for integrated CO2 capture and hydrogenation

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Journal of Energy Chemistry 2025年第1期 779-791页

作者： Hanzi Liu Ling Cen Xinlin Xie Lei Liu Zhao sun Zhiqiang sun Hunan Engineering Research Center of Clean and Low-Carbon Energy Technology School of Energy Science and Engineering Central South University

The development of dual functional material for cyclic CO2capture and hydrogenation is of great significance for converting diluted CO2into valuable fuels,but suffers from kinetic limitation and deactivation of adsorbent and ***,we engineered a series of RuNa/γ-Al2O3materials,varying the size of ruthenium from single atoms to clusters/*** coordination environment and structure sensitivity of ruthenium were quantitatively investigated at atomic *** findings reveal that the reduced Ru nanoparticles,approximately 7.1 nm in diameter with a Ru-Ru coordination number of 5.9,exhibit high methane formation activity and selectivity at 340°*** Ru-Na interfacial sites facilitate CO2migration through a deoxygenation pathway,involving carbonate dissociation,carbonyl formation,and ***-situ experiments and theoretical calculations show that stable carbonyl intermediates on metallic Ru nanoparticles facilitate heterolytic C–O scission and C–H bonding,significantly lowering the energy barrier for activating stored CO2.

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In situ polymerization of poly(3,4-ethylenedioxythiophene)protective layer towards stable zinc anode

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Nano Research 2025年第1期18卷 382-394页

作者： Debin Luo Peng Zhou Xiaowei Lv Panpan sun Xiaohua sun Hewei Zhao College of Materials and Chemical Engineering Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion MaterialsChina Three Gorges UniversityYichang 443002China Hubei Three Gorges Laboratory Yichang 443007China School of Chemistry Beihang UniversityBeijing 100191China

Aqueous zinc-ion devices are considered promising candidates for energy storage due to their high safety,low cost and relatively high energy ***,the dendrite growth,hydrogen evolution reaction(HER)and corrosion of the zinc anode significantly limit the development of Zn-ion ***,an inexpensive poly(3,4-ethylenedioxythiophene)(PEDOT)protective layer was constructed in situ on the Zn surface using electropolymerization to suppress dendrite growth and side reactions,thereby enhancing the reversibility of *** and theoretical calculations revealed that this hydrophilic protective layer promotes the desolvation process of hydrated Zn^(2+)and facilitates the transport of zinc ions,thus improving the thermodynamic and kinetic properties of Zn^(2+)deposition and inhibiting interfacial side ***,the optimized PEDOT@Zn symmetric battery exhibited a cycling stability exceeding 1250 h at 0.5 mA·cm^(-2)and 0.25 mAh·cm^(-2),with a significantly reduced overpotential(from 91.8 to 35 mV).With the assistance of the PEDOT protective layer,the PEDOT@Zn//Cu battery maintained approximately 99.5%Coulombic efficiency after 450 ***-situ scanning electron microscopy(SEM)and in situ optical microscopy characterizations further confirmed that the PEDOT protective layer can effectively suppress the growth of zinc ***,the Zn-ion capacitors assembled by the PEDOT@Zn and activated carbon also demonstrated outstanding cycling stability.

关键词： zinc-ion devices zinc anode poly(3 4-ethylenedioxythiophene)(PEDOT) dendrite desolvation process

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Microstructure and Wear/corrosion Resistance of Stainless Steel Laser-alloyed with Mn+W2C, Mn+NiWC and Mn+SiC

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Journal of Wuhan University of Technology(Materials Science) 2025年第1期 283-294页

作者：周瑞 DIAO Xiaogang sun Yixin School of Metallurgical Engineering Jiangsu University of Science and Technology CITIC Heavy Cast Iron Industry Co. Ltd.

In-situ formed high Mn steel coating reinforced by carbides was formed by laser surface alloying （LSA）.Laser alloyed layers on 1Cr18Ni9Ti steel with Mn+W2C （specimen A）,Mn+NiWC （specimen B） and Mn+SiC （specimen C） powders were fabricated to improve the wear and corrosion behavior of 1Cr18Ni9Ti steel blades in high speed *** evolution,phases,element distribution,microhardness,wear and corrosion behavior of the laser alloyed layers were *** indicated that high Mn steel matrix composites with undissolved W2C,WC and other in-situ formed carbides were formed by LSA with Mn+W2C and Mn+NiWC while SiC totally dissolved into the high Mn matrix when adding Mn+*** as the binding phase in Ni-WC powder decreased the crack sensitivity of the alloyed layer as compared with the addition of W2C *** improvement in average microhardness was achieved in the matrix in specimen A,B and C,with the value of 615,602 and 277 HV0.5,while that of the substrate was 212 *** increase of microhardness,wear and corrosion resistance is highly corelated to microstructure,formed phases,type and content of carbides,micro-hardness and toughness of the alloyed layers.

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Activatable chemiluminescence probe based on four-arm PEGconjugated-pyropheophorbide-a for in vivo autofluorescence-free imaging of peroxynitrite

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Science China Chemistry 2025年

作者： Jianmei Ke Lei Ding Ronggui Lian Cheng Zheng Wenjun Li Aixian Zheng Yupeng sun Ming Wu Yongyi Zeng Xiaolong Liu Maochun Hong Xiaolong Zhang The United Innovation of Mengchao Hepatobiliary Technology Key Laboratory of Fujian Province Mengchao Hepatobiliary Hospital of Fujian Medical University Ganjiang Innovation Academy Chinese Academy of Sciences School of Rare Earths University of Science and Technology of China College of Chemistry Fuzhou University State Key Laboratory of Structure Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences

Peroxynitrite（ONOO-） is a highly reactive nitrogen species that plays pivotal roles in cell signal transduction and physiological or pathological progresses. However, commonly used ONOO-optical imaging probes are still hampered by high background/autofluorescence（fluorescence probe）, short emission wavelength, or poor selectivity in the case of chemiluminescence. Herein,we report a facile method to prepare an activatable chemiluminescence probe（PPA-PEG） with good biocompatibility and functionality for in vivo autofluorescence-free imaging of ONOO-. The PPA-PEG consists of pyropheophorbide-a（PPA）, a typical deep red photosensitizer that acts as both the recognition and signaling element, and 4-arm poly（ethylene glycol）(4-arm PEG), which improves the biosafety and water solubility of probe. These components can self-assemble into nanoparticles（namely PPA-PEG nanoprobe） in aqueous solution. The PPA-PEG nanoprobe showed an ultra-low chemiluminescence signal before interacting with ONOO-, but exhibited good selectivity, high sensitivity and a fast response toward ONOO-. The PPAPEG was successfully applied to image cellular ONOO-changes, as well as the endogenous ONOO-changes in inflammation models and subcutaneous or orthotopic hepatocellular carcinoma（HCC） tumors models in living mice. In vitro and in vivo studies verified the good detection and imaging capabilities of PPA-PEG for peroxynitrite, demonstrating suitable tissue penetration and a high signal-to-background ratio（SBR）. Thus, our nanoprobe can serve as a valuable activatable chemiluminescence imaging tool for studying important peroxynitrite-related chemical and biological applications.

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Polybenzimidazolium-reinforced polyimide separators to inhibit dendrites for high-security lithium-ion batteries

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Science China Chemistry 2025年

作者： Guohua sun Jiaqi Cui Qingsong Zhang Yisong Zhou Xinluo Li Yingying Zhang Zhanao Zhang Xin Zhang Jiantao Fan Pengpeng Li Lianlong Hou Nanjun Chen Hebei Key Laboratory of Flexible Functional Materials School of Materials Science and Engineering Hebei University of Science and Technology State Key Laboratory of Organic-Inorganic Composites Beijing University of Chemical Technology Academy for Advanced Interdisciplinary Studies Southern University of Science and Technology State Key Laboratory of Physical Chemistry of Solid Surfaces College of Chemistry and Chemical Engineering Xiamen University

Lithium dendrite formation poses a significant safety hazard in lithium-ion batteries（LIBs）, severely impeding their widespread adoption and further technological advancements. Here, we present a novel quaternized polybenzimidazolium（q-PBI） to armor polyimide（PI） nanofiber separator（q-PBI@PI）, in which the q-PBI containing lithiophilicity and anionphilicity sites serves as the multifunctional nano-layers to suppress the Li dendrite and reinforce the mechanical properties of PI nanofiber ***, the q-PBI@PI separator displays an unprecedented mechanical strength of 82.8 MPa, significantly outperforming previously reported PI nanofiber membranes（typically below 50.0 MPa）. Besides, we demonstrate that the q-PBI@PI separator simultaneously possesses low nucleation overpotential（59 mV） and exceptional average coulombic efficiency due to the suppression of Li dendrite. Importantly, q-PBI@PI-based Li||Li battery enables a stable Li plating-stripping at 1.0 m A cm-2for600 h. Attributing to these exceptional merits, the armored PI separator-based LIBs display remarkable specific capability and capacity retention. The density function theory calculations reveal that q-PBI is conducive to the desolvation of Li+and can immobilize Li+and PF6-ions near affinity sites of PI nanofibers for inhibiting the formation of Li dendrites. Our work paves a new avenue for the design of next-generation high-performing separators in LIBs.

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MOFs和COFs在选择性富集及色谱分离中药活性成分中的应用进展

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分析测试学报 2025年第1期44卷 82-90页

作者：司甜甜赵薇孙启慧容蓉孙敏山东中医药大学药学院山东济南250355 济南大学化学与化工学院山东济南250022

金属有机框架材料(MOFs)和共价有机框架材料(COFs)具有超大比表面积和可调节的孔径等结构特点,可以实现目标化合物的选择性富集和分离,在中药活性成分领域表现出广泛的应用前景。该文综述了MOFs、COFs的常用制备方法,阐述了MOFs、COFs... 详细信息

金属有机框架材料(MOFs)和共价有机框架材料(COFs)具有超大比表面积和可调节的孔径等结构特点,可以实现目标化合物的选择性富集和分离,在中药活性成分领域表现出广泛的应用前景。该文综述了MOFs、COFs的常用制备方法,阐述了MOFs、COFs及其复合材料在选择性富集、色谱分离不同中药基质活性成分方面的应用,并结合网络药理学探讨了其在靶向中药活性成分方面的发展前景,为新型有机框架材料在中药有效成分领域的研究提供了思路。

关键词：金属有机框架共价有机框架中药活性成分选择性富集色谱分离

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圣女果串采收末端执行器的设计与实验

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农机化研究 2025年第3期47卷 103-110页

作者：李小平孙丙宇重庆三峡学院机械工程学院重庆万州404000 中国科学院合肥物质科学研究院合肥230031

为提高圣女果采摘效率和降低果实损伤,设计了圣女果串采收末端执行器。其末端结构采用平面四连杆驱动夹持剪切机构,夹持机构采用自补偿设计,使夹持与剪切动作一体化完成。同时,基于螺旋理论,建立接触模型,验证分析了夹持结构的力封闭性... 详细信息

为提高圣女果采摘效率和降低果实损伤,设计了圣女果串采收末端执行器。其末端结构采用平面四连杆驱动夹持剪切机构,夹持机构采用自补偿设计,使夹持与剪切动作一体化完成。同时,基于螺旋理论,建立接触模型,验证分析了夹持结构的力封闭性,并对整体装置进行了动力学和运动学分析与仿真。室内实验结果表明:整串采摘的夹持成功率为100%,剪切成功率为86.7%。

关键词：圣女果串采收末端执行器夹持剪切一体化运动学仿真

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Potassium ions and cyano group modified g-C3N4 for effective generation of H2O2 through two-electron oxygen reduction

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Science China Chemistry 2025年第1期 192-200页

作者： Dongying Wang Shulan Pu Yongmin Chen Ke Lei Yujie Duan Linjiao Mao Xuhui Zeng Xi Luo Yuntao Zhang Yuqin Dong Jin Zhong Zhang Yan sun School of Mechanical Engineering Chengdu University Department of Chemistry and Biochemistry University of California

Potassium ions （K+） doped graphitic carbon nitride （g-C3N4） was prepared by a thermal etching method using potassium hydroxide （KOH） as an ion *** transform infrared spectroscopy （FTIR） and X-ray photoelectron spectroscopy （XPS）results showed that the generation of the cyano group was detected while introducing K+.Under simulated sunlight irradiation,the sample with a K+doping amount of 10%showed the highest hydrogen peroxide （H2O2） generation rate of2,140.2μmol *** apparent quantum yield （AQY） at 400 nm and the solar-to-chemical conversion （SCC） are 4.35%and1.23%,respectively.K+acted as a bridge between g-C3N4layers,which enhanced charge transfer ***,the cyano group enhanced the adsorption capacity of protons （H+） and promoted the yield of *** catalyst exhibited excellent photocatalytic stability based on four-cycle *** addition,a mechanism study showed that superoxide radicals （·O2-）were the most important active species in the reaction *** production of H2O2was achieved through consecutive single-electron *** study deepens the understanding of the oxygen reduction reaction process and opens up a new venue for improving H2O2generation.

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大兴安岭森林可燃物燃烧危险性评估

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东北林业大学学报 2025年第1期53卷 73-78页

作者：蔡志勇孙龙孙家宝东北林业大学哈尔滨150040 黑龙江省森林保护研究所

评估森林可燃物燃烧危险性,有助于客观认识森林火灾风险水平,从而制定相应防火和灭火措施,为开展森林火灾防治和应急管理工作提供决策依据。以黑龙江省大兴安岭林区为研究区,利用“森林火灾风险普查”3 300块标准样地调查数据,通过森林... 详细信息

评估森林可燃物燃烧危险性,有助于客观认识森林火灾风险水平,从而制定相应防火和灭火措施,为开展森林火灾防治和应急管理工作提供决策依据。以黑龙江省大兴安岭林区为研究区,利用“森林火灾风险普查”3 300块标准样地调查数据,通过森林可燃物燃烧试验,对潜在初始火强度、灌木层连续性和易燃树种密度等指标进行等级划分,量化森林可燃物的燃烧性和空间分布的连续性,判断潜在林火强度大小和易发林火种类,评估森林可燃物燃烧危险性等级。结果表明:(1)黑龙江省大兴安岭林区森林可燃物燃烧危险性等级分为4个等级,即高危险性等级、中高危险性等级、中低危险性等级、低危险性等级;(2)大兴安岭林区从北纬50°~53°30′,从低纬度到高纬度标准地森林火灾高危险性等级比例依次为0.02、0.02、0.02、0.05、0.07、0.10、0.08,低危险性等级比例依次为0.50、0.48、0.41、0.36、0.34、0.30、0.29。

关键词：森林火灾风险评估林火强度林火蔓延速度林火种类

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