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Tuning the reactivity of Al-Ni by fine coating of halogen-containing energetic composites

Defence Technology（防务技术） 2022年第10期18卷 1810-1821页

作者： su-lan yang Ke-juan Meng Wu-xi Xie Hong-qi Nie Qi-Long Yan Science and Technology on Combustion Internal Flow and Thermo-Structure LaboratoryNorthwestern Polytechnical UniversityXi'an710072China b Xi'an Modern Chemistry Research Institute Xi'an710065China

In this paper,various core-shell structured Al—Ni@ECs composites have been prepared by a spray-drying *** involved ECs refer to the energetic composites(ECs)of ammonium perchlorate/nitrocellulose(AP/NC,NA)and polyvinylidene fluoride/hexanitrohexaazaisowurtzitane(PVDF/CL-20,PC).Two Al—Ni mixtures were prepared at atomic ratios of 1:1 and 1:3 and named as Al/Ni and Al/3Ni,*** thermal reactivity and combustion behaviors of Al—Ni@ECs composites have been comprehensively *** showed that the reactivity and combustion performance of Al—Ni could be enhanced by introducing both NA and PC energetic *** which the Al/Ni@NA composite exhibited higher reactivity and improved combustion *** measured flame propagation rate(v=20.6 mm/s),average combustion wave temperature(T_(max)=1567.0°C)and maximum temperature rise rate(γ_(t)=1633.6°C/s)of Al/Ni@NA are higher than that of the Al/Ni(v=15.8 mm/s,T_(max)=858.0°C,andγ_(t)=143.5°C/s).The enhancement in combustion properties could be due to presence of the acidic gaseous products from ECs,which could etch the Al_(2)O_(3)shell on the surface of Al particles,and make the inner active Al to be easier transported,so that an intimate and faster intermetallic reaction between Al and Ni would be ***,the morphologies and chemical compositions of the condensed combustion products(CCPs)of Al—Ni@ECs composites were found to be different depending on the types of *** compositions of CCPs are dominated with the Al—Ni intermetallics,combining with a trace amount of Al_(5)O_(6)N and Al_(2)O_(3).

关键词： Arrested high energy ball milling Intermetallic alloy Combustion performance Energetic composites Reactivity control

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基于非参数核密度估计法的红枣市场价格波动与风险评估

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中国农业大学学报 2016年第10期21卷 172-179页

作者：李凤马惠兰苏洋新疆农业大学经济与贸易学院乌鲁木齐830052

利用非参数核密度方法,以5种红枣(灰枣、骏枣、金丝枣、青枣和冬枣)的批发市场价格为研究对象,比较分析不同红枣的短期价格波动形态及波动强度,并对其短期价格波动风险进行评估和比较。结果表明:从波动形态看,总体上红枣市场价格短期波... 详细信息

利用非参数核密度方法,以5种红枣(灰枣、骏枣、金丝枣、青枣和冬枣)的批发市场价格为研究对象,比较分析不同红枣的短期价格波动形态及波动强度,并对其短期价格波动风险进行评估和比较。结果表明:从波动形态看,总体上红枣市场价格短期波动有明显谷峰和谷底,呈"春冬高、夏秋低"季节性特征,其中骏枣和灰枣的价格呈"V"型波动,金丝枣和冬枣的价格呈"M"和"W"型波动,青枣价格呈"N"型波动;从波动强度看,整体上鲜食枣价格波动强度高于干制枣,大小排序依次为冬枣>青枣>金丝枣>骏枣>灰枣;红枣市场价格波动风险分布不对称,降价风险高于涨价风险,其中冬枣降价风险最高,其次是灰枣和骏枣,金丝枣降价风险略低,只有青枣价格下跌风险与上涨跌风险发生的概率接近一致;从强警风险概率(价格波动幅度在±15%以上)分布看,鲜食枣价格出现强警的概率高于干制枣。

关键词：红枣市场价格波动风险评估非参数核密度

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悬臂中厚矩形板的非线性弯曲

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上海交通大学学报 2001年第10期35卷 1497-1502页

作者：苏文兰杨健赵涛上海交通大学建筑工程与力学学院上海200030

基于 Reissner- Mindlin一阶剪切变形板理论 ,选取满足位移的边界条件 ,并以级数形式表示挠度函数 .采用摄动法 ,把大挠度非线性方程组化为一系列线性方程组 ,然后用 Rayleigh- Ritz法确定位移函数中的待定系数 ,给出悬臂中厚矩形板非... 详细信息

基于 Reissner- Mindlin一阶剪切变形板理论 ,选取满足位移的边界条件 ,并以级数形式表示挠度函数 .采用摄动法 ,把大挠度非线性方程组化为一系列线性方程组 ,然后用 Rayleigh- Ritz法确定位移函数中的待定系数 ,给出悬臂中厚矩形板非线性弯曲问题的大挠度渐近解 .同时 ,给出了数值算例及参数分析 ,讨论了板长宽比、宽厚比以及载荷形式对板载荷 -挠度曲线及载荷 -弯矩曲线的影响 .

关键词：矩形悬臂板中厚板非线性弯曲摄动法 Rayleigh-Ritz法

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A surface engineering strategy for the stabilization of zinc metal anodes with montmorillonite layers toward long-life rechargeable aqueous zinc ion batteries

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Journal of Energy Chemistry 2025年第1期100卷 94-105页

作者： Wenbo Wang Ruifeng Xu Xu Zhang Peiyu Wang Bao yang Bingjun yang Juan yang Kailimai su Pengjun Ma Yanan Deng Xianfeng Fan Wanjun Chen Key Laboratory for Electronic Materials College of Electrical Engineering Northwest Minzu University Resource Chemistry and Energy Materials Research Center State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical Physics Chinese Academy of Sciences University of Chinese Academy of Sciences Institute for Materials and Processes School of Engineering University of Edinburgh

Rechargeable aqueous zinc-ion batteries （AZIBs） exhibit appreciable potential in the domain of electrochemical energy ***,there are serious challenges for AZIBs,for instance zinc dendrite growth,hydrogen evolution reaction （HER）,and corrosion side ***,we propose a surface engineering modification strategy for coating the montmorillonite （MMT） layer onto the surface of the Zn anode to tackle these issues,thereby achieving high cycling stability for rechargeable *** results reveal that the MMT layer on the surface of the Zn anode is able to provide ordered zincophilic channels for zinc ions migration,facilitating the reaction kinetics of zinc *** functional theory（DFT） calculations and water contact angle （CA） tests prove that MMT@Zn anode exhibits superior adsorption capacity for Zn2+and better hydrophobicity than the bare Zn anode,thereby achieving excellent cycling ***,the MMT@Zn||MMT@Zn symmetric cell holds the stable cycling over 5600 h at 0.5 mA cm-2and 0.125 m A h cm-2,even exceeding 1800 h long cycling under harsh conditions of 5 m A cm-2and 1.25 m A h *** MMT@Zn||V2O5full cell reaches over 3000 cycles at 2 A g-1with excellent rate ***,this surface engineering modification strategy for enhancing the electrochemical performance of AZIBs represents a promising application.

关键词： surface engineering strategy Montmorillonite layer Protection mechanism of Zn anode Cycling stability Aqueous zinc ion batteries

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Robust interface and excellent as-built mechanical properties of Ti–6Al–4V fabricated through laser-aided additive manufacturing with powder and wire

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 154-168页

作者： Fei Weng Guijun Bi Youxiang Chew Shang sui Chaolin Tan Zhenglin Du Jinlong su Fern lan Ng Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials Ministry of EducationShandong Engineering&Technology Research Center for Superhard MaterialSchool of Materials Science and EngineeringShandong UniversityJinan 250061China Institute of Intelligent Manufacturing Guangdong Academy of SciencesGuangzhou 510095China Singapore Institute of Manufacturing Technology 5 Cleantech Loop636732Singapore

The feasibility of manufacturing Ti-6Al-4V samples through a combination of laser-aided additive manufacturing with powder(LAAM_(p))and wire(LAAM_(w))was explored.A process study was first conducted to successfully circumvent defects in Ti-6Al-4V deposits for LAAM_(p) and LAAM_(w),*** the optimized process parameters,robust interfaces were achieved between powder/wire deposits and the forged substrate,as well as between powder and wire *** characterization results revealed the epitaxial prior β grains in the deposited Ti-6Al-4V,wherein the powder deposit was dominated by a finerα′microstructure and the wire deposit was characterized by lamellar α *** mechanisms of microstructure formation and correlation with mechanical behavior were analyzed and *** mechanical properties of the interfacial samples can meet the requirements of the relevant Aerospace Material Specifications(AMS 6932)even without post heat *** fracture occurred within the interfacial area,further suggesting the robust *** findings of this study highlighted the feasibility of combining LAAM_(p) and LAAM_(w) in the direct manufacturing of Ti-6Al-4V parts in accordance with the required dimensional resolution and deposition rate,together with sound strength and ductility balance in the as-built condition.

关键词： laser-aided additive manufacturing powder deposition wire deposition interfacial characteristic mechanical behavior

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Laparoscopic liver resection utilizing the ventral avascular area of the inferior vena cava:A retrospective cohort study

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World Journal of Gastroenterology 2025年第1期31卷 42-57页

作者： Kun Huang Zhu Chen Heng Xiao Hai-yang Hu Xing-Yu Chen Cheng-You Du Xiang lan Department of Hepatobiliary surgery The First Affiliated Hospital of Chongqing Medical UniversityChongqing 400000China Department of General surgery Mianyang Hospital of Traditional Chinese MedicineMianyang 621000Sichuan ProvinceChina

BACKGROUND Laparoscopic liver resection(LLR)can be challenging due to the difficulty of establishing a retrohepatic tunnel under *** the third hepatic hilum before parenchymal transection often leads to significant liver mobilization,tumor compression,and bleeding from the short hepatic veins(SHVs).This study introduces a novel technique utilizing the ventral avascular area of the inferior vena cava(IVC),allowing SHVs to be addressed after parenchymal transection,thereby reducing surgical complexity and improving outcomes in in situ *** To introduce and evaluate a novel LLR technique using the ventral avascular area of the IVC and compare its short-term outcomes with conventional *** The clinical cohort data of patients with pathologically confirmed hepatocellular carcinoma or intrahepatic cholangiocarcinoma who underwent conventional LLR and novel LLR between July 2021 and July 2023 at the First Affiliated Hospital of Chongqing Medical University were retrospectively *** novel LLR,we initially separated the caudate lobe from the IVC using dissecting forceps along the ventral avascular area of the ***,we transected the parenchyma of the left and right caudate lobes from the caudal side to the cephalic side using the avascular area as a ***,we addressed the SHVs and finally dissected the root of the right hepatic vein or left hepatic *** short-term postoperative outcomes and oncological results of the two approaches were evaluated and *** A total of 256 patients were included,with 150(58.59%)undergoing conventional LLR and 106(41.41%)undergoing novel *** novel technique resulted in significantly larger tumor resections(6.47±2.96 cm vs 4.01±2.33 cm,P<0.001),shorter operative times(199.57±60.37 minutes vs 262.33±83.90 minutes,P<0.001),less intraoperative blood loss(206.92±37.09 mL vs 363.34±131.27 mL,P<0.001),and greater resection volume(345.11±31.40 mL vs 264.38±31.98 mL,P<0.001)comp

关键词： Laparoscopic liver resection Inferior vena cava Retrohepatic tunnel Short hepatic veins Complex liver tumors Intraoperative bleeding control

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高速气流加速下雾粒的传质(英文)

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四川大学学报（工程科学版） 2003年第3期35卷 42-48页

作者：关国强朱家骅夏素兰杨雪峰四川大学化学工程学院四川成都610065

针对高分散气雾两相流动体系,提出了一种新的传质理论表达式,其传质系数用Kolmogoroff长度时间尺度进行关联,并开发出基于MonteCarlo和CFD的联合模拟方案。运用该传质表达式和模拟方案,成功地模拟了氢氧化钠与二氧化碳的气雾两相射流中... 详细信息

针对高分散气雾两相流动体系,提出了一种新的传质理论表达式,其传质系数用Kolmogoroff长度时间尺度进行关联,并开发出基于MonteCarlo和CFD的联合模拟方案。运用该传质表达式和模拟方案,成功地模拟了氢氧化钠与二氧化碳的气雾两相射流中和反应体系。结果表明:相间传质时间尺度(1.6×10-4s)远小于弛豫时间尺度(4.5×10-4s),进一步研究说明尽管气雾相间传质的速率很快,但相间传递量是主要通过速度滑移实现的,相间传质对雾粒相的运动行为影响甚小,因而在工程上对于雾粒相运动行为的描述可以忽略传质的影响。由激光多普勒测速仪得到的实验数据证实了模拟结果,表明模拟能正确预测此类输运现象。

关键词：传质气雾两相射流反应 Monte Carlo和CFD联合模拟

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Deep eutectic solvents for separation and purification applications in critical metal metallurgy:Recent advances and perspectives

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 1-19页

作者： Shuo Chen Shengpeng su Yanfang Huang Bingbing Liu Hu sun Shuzhen yang Guihong Han School of Chemical Engineering Zhengzhou UniversityZhengzhou 450001China Zhongyuan Critical Metals Laboratory Henan ProvinceZhengzhou 450001China

Solvent extraction,a separation and purification technology,is crucial in critical metal *** solvents commonly used in solvent extraction exhibit disadvantages,such as high volatility,high toxicity,and flammability,causing a spectrum of hazards to human health and environmental *** solvents have been recognized as potential alternatives to these harmful organic *** the past two decades,several neoteric solvents have been proposed,including ionic liquids(ILs)and deep eutectic solvents(DESs).DESs have gradually become the focus of green solvents owing to several advantages,namely,low toxicity,degradability,and low *** this critical review,their classification,formation mechanisms,preparation methods,characterization technologies,and special physicochemical properties based on the most recent advancements in research have been systematically ***,the major separation and purification applications of DESs in critical metal metallurgy were comprehensively ***,future opportunities and challenges of DESs were explored in the current research *** conclusion,this review provides valuable insights for improving our overall understanding of DESs,and it holds important potential for expanding separation and purification applications in critical metal metallurgy.

关键词： deep eutectic solvents preparations properties separation and purification critical metal metallurgy

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Gamma-glutamyl transferase 5 overexpression in cerebrovascular endothelial cells improves brain pathology,cognition,and behavior in APP/PS1 mice

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Neural Regeneration Research 2025年第2期20卷 533-547页

作者： Yanli Zhang Tian Li Jie Miao Zhina Zhang Mingxuan yang Zhuoran Wang Bo yang Jiawei Zhang Haiting Li Qiang su Junhong Guo Department of Neurology First Hospital of Shanxi Medical UniversityTaiyuanShanxi ProvinceChina Department of Neurology Sixth Hospital of Shanxi Medical University(General Hospital of Tisco)TaiyuanShanxi ProvinceChina Department of Physiology Key Laboratory of Cellular PhysiologyMinistry of EducationShanxi Medical UniversityTaiyuanShanxi ProvinceChina Department of Hernia and Abdominal Wall surgery Shanxi Bethune HospitalShanxi Academy of Medical SciencesTongji Shanxi HospitalThird Hospital of Shanxi Medical UniversityTaiyuanShanxi ProvinceChina Department of Laboratory Medicine of Fenyang College Shanxi Medical UniversityFenyangShanxi ProvinceChina

In patients with Alzheimer’s disease,gamma-glutamyl transferase 5(GGT5)expression has been observed to be downregulated in cerebrovascular endothelial ***,the functional role of GGT5 in the development of Alzheimer’s disease remains *** study aimed to explore the effect of GGT5 on cognitive function and brain pathology in an APP/PS1 mouse model of Alzheimer’s disease,as well as the underlying *** observed a significant reduction in GGT5 expression in two in vitro models of Alzheimer’s disease(Aβ_(1-42)-treated hCMEC/D3 and bEnd.3 cells),as well as in the APP/PS1 mouse ***,injection of APP/PS1 mice with an adeno-associated virus encoding GGT5 enhanced hippocampal synaptic plasticity and mitigated cognitive ***,increasing GGT5 expression in cerebrovascular endothelial cells reduced levels of both soluble and insoluble amyloid-βin the brains of APP/PS1 *** effect may be attributable to inhibition of the expression ofβ-site APP cleaving enzyme 1,which is mediated by nuclear factor-kappa *** findings demonstrate that GGT5 expression in cerebrovascular endothelial cells is inversely associated with Alzheimer’s disease pathogenesis,and that GGT5 upregulation mitigates cognitive deficits in APP/PS1 *** findings suggest that GGT5 expression in cerebrovascular endothelial cells is a potential therapeutic target and biomarker for Alzheimer’s disease.

关键词： Alzheimer’s disease amyloid-β APP/PS1 mice cerebrovascular endothelial cells cognitive deficits gamma-glutamyl transferase 5 neurovascular unit nuclear factor‐kappa B synaptic plasticity β-site APP cleaving enzyme 1

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Reduced mesencephalic astrocyte-derived neurotrophic factor expression by mutant androgen receptor contributes to neurodegeneration in a model of spinal and bulbar muscular atrophy pathology

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Neural Regeneration Research 2025年第9期20卷 2655-2666页

作者： Yiyang Qin Wenzhen Zhu Tingting Guo Yiran Zhang Tingting Xing Peng Yin Shihua Li Xiao-Jiang Li su yang Guangdong Key Laboratory of Non-human Primate Research Key Laboratory of CNS Regeneration(Ministry of Education)Guangdong–HongKong–Macao Institute of CNS RegenerationJinan UniversityGuangzhouGuangdong ProvinceChina

Spinal and bulbar muscular atrophy is a neurodegenerative disease caused by extended CAG trinucleotide repeats in the androgen receptor gene,which encodes a ligand-dependent transcription facto *** mutant androgen receptor protein,characterized by polyglutamine expansion,is prone to misfolding and forms aggregates in both the nucleus and cytoplasm in the brain in spinal and bulbar muscular atrophy *** aggregates alter protein-protein interactions and compromise transcriptional *** this study,we reported that in both cultured N2a cells and mouse brain,mutant androgen receptor with polyglutamine expansion causes reduced expression of mesencephalic astrocyte-de rived neurotrophic *** n of mesencephalic astrocyte-derived neurotrophic factor amelio rated the neurotoxicity of mutant androgen receptor through the inhibition of mutant androgen receptor *** down endogenous mesencephalic astrocyte-derived neurotrophic factor in the mouse brain exacerbated neuronal damage and mutant androgen receptor *** findings suggest that inhibition of mesencephalic astrocyte-derived neurotrophic factor expression by mutant androgen receptor is a potential mechanism underlying neurodegeneration in spinal and bulbar muscular atrophy.

关键词： androgen receptor mesencephalic astrocyte-derived neurotrophic factor mouse model neurodegeneration neuronal loss neurotrophic factor polyglutamine disease protein misfolding spinal and bulbar muscular atrophy transcription factor

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