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Concurrently Boosting Activity and Stability of Oxygen Reduction Reaction Catalysts via Judiciously Crafting Fe-Mn Dual Atoms for Fuel Cells

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Nano-Micro Letters 2025年第4期17卷 275-289页

作者： Lei Zhang Yuchen Dong Lubing Li Yuchuan Shi Yan Zhang Liting Wei Chung-Li Dong Zhiqun Lin jinzhan su International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi’an Jiaotong UniversityXi’an 710049People’s Republic of China Department of Physics Tamkang UniversityNew Taipei CityTaiwan 25137People’s Republic of China Department of Chemical and Biomolecular Engineering National University of SingaporeEngineering Drive 4Singapore 117585Singapore

The ability to unlock the interplay between the activity and stability of oxygen reduction reaction(ORR)represents an important endeavor toward creating robust ORR catalysts for efficient fuel ***,we report an effective strategy to concurrent enhance the activity and stability of ORR catalysts via constructing atomically dispersed Fe-Mn dualmetal sites on N-doped carbon(denoted(FeMn-DA)-N-C)for both anion-exchange membrane fuel cells(AEMFC)and proton exchange membrane fuel cells(PEMFC).The(FeMn-DA)-N-C catalysts possess ample dual-metal atoms consisting of adjacent Fe-N_(4)and Mn-N_(4)sites on the carbon surface,yielded via a facile doping-adsorption-pyrolysis *** introduction of Mn carries several advantageous attributes:increasing the number of active sites,effectively anchoring Fe due to effective electron transfer to Mn(revealed by X-ray absorption spectroscopy and density-functional theory(DFT),thus preventing the aggregation of Fe),and effectively circumventing the occurrence of Fenton reaction,thus reducing the consumption of ***(FeMn-DA)-N-C catalysts showcase half-wave potentials of 0.92 and 0.82 V in 0.1 M KOH and 0.1 M HClO_(4),respectively,as well as outstanding *** manifested by DFT calculations,the introduction of Mn affects the electronic structure of Fe,down-shifts the d-band Fe active center,accelerates the desorption of OH groups,and creates higher limiting *** AEMFC and PEMFC with(FeMn-DA)-N-C as the cathode catalyst display high power densities of 1060 and 746 mW cm^(-2),respectively,underscoring their promising potential for practical *** study highlights the robustness of designing Fe-containing dual-atom ORR catalysts to promote both activity and stability for energy conversion and storage materials and devices.

关键词： Doping-adsorption-pyrolysis Dual-atom catalysts Oxygen reduction reaction Fuel cells

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Enhancing the performance of proton-exchange membrane fuel cell by optimizing the hydrophobicity and porosity of cathode catalyst layer

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Science China Technological Sciences 2025年第3期68卷 76-85页

作者： Yan ZHANG Puping JIA suyi YANG jinzhan su Liejin GUO International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringSchool of Energy & Power Engineering Xi'an Jiaotong University

Appropriate hydrophobicity and porosity of the proton-exchange membrane fuel cell（PEMFC） cathode catalyst layer（CCL） are essential for efficient charge and mass transport. In this study, the effects of the CCL hydrophobicity and porosity on PEMFC performance were comprehensively investigated. Compared to a normal CCL, a cathode hydrophobic duallayer catalyst structure(with a 2:1 Pt loading ratio between the inner and outer layers and 9.3% polytetrafluoroethylene（PTFE）in the outer layer) exhibited a 29.8% increase in power density. Among the tested pore-forming agents, ammonium bicarbonate（NH4HCO3） was the most suitable because of its low pyrolysis temperature. The maximum power density of the CCL with a porous structure（prepared with a Pt/C:NH4HCO3mass ratio of 1:3） was 38.3% higher than that of the normal CCL. By simultaneously optimizing the pore structure and hydrophobicity of the CCL, the maximum power density of the cathode hydrophobic dual-layer CCL（DCL） with pores showed a 44.7% increase compared to that of the normal CCL. This study demonstrates for the first time that simultaneously optimizing cathode porosity and hydrophobicity can enhance PEMFC performance.

关键词： proton-exchange membrane fuel cell cathode catalyst layer membrane electrode assemblies polytetrafluoroethylene pore-forming agent

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Design and analysis of spiral bevel gears with seventh-order function of transmission error

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Chinese Journal of Aeronautics 2013年第5期26卷 1310-1316页

作者： su jinzhan Fang Zongde Cai Xiangwei Key Laboratory of Road Construction Technology and Equipment Ministry of EducationChang’an University School of Mechanical Engineering Northwestern Polytechnical University

This paper proposes a new approach to mial function of transmission error （TE） for spiral design and implement a seventh-order polyno- bevel gears with an aim to reduce the running vibration and noise of gear drive and improve the loaded distribution of the tooth. Based on the constraint conditions of predesigned seventh-order polynomial function curve and the theory of linear algebra, the polynomial coefficients of the seventh-order polynomial function of transmission error can be obtained. By applying a method named reverse tooth contact analysis, the modified roll coefficients as well as parts of machine-tool settings for the face-milling of spiral bevel gears can be individually determined. Therefore, a predesigned seventh-order polynomial function of transmission error for spiral bevel gears can be obtained by the modified roll with high-order coef- ficients, and comparisons of the seventh-order polynomial and parabolic functions of transmission error are also performed. The achievement of spiral bevel gears with the seventh-order function of transmission error can be accomplished on a universal Cartesian-type hypoid gear generator or a numerically controlled cradle-style hypoid gear generator due to its simple generating motion of axes of the cradle and the work piece. The results of a numerical example show that the bending stresses of the tooth of seventh-order are less than those of a parabolic one, while the contact stresses remain almost eouivalent.

关键词： Loaded tooth Modified roll Spiral bevel gear Tooth contact analysis Transmissions

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Hierarchical growth of a novel Mn-Bi coupled BiVO4 arrays for enhanced photoelectrochemical water splitting

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Nano Research 2019年第3期12卷 575-580页

作者： Lu Wang jinzhan su Liejin Guo International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power Engineering School cf Energy & Power Engineering Xian Jiaotong University Xian 710049 China

Oxygen evolving catalyst (OEC) is a critical determinant for the efficiency of photoelectrochemical (PEC) water splitting. Here we report an approach to depositing a novel manganese borate (Mn-Bi) OER catalyst on BiVO4 nanocone photoanode by photodeposition in sodium borate buffer solution containing Mn(Ⅱ) ions. Due to the spontaneous photo-electric-field-enhancement effect at the vertically oriented BiVO4 nanocone structure, spherical Mn-Bi nanoparticle was selectively photodeposited at the apex of BiVO4 nanocone. Significant improvement of photocurrent was observed for the obtained hierarchical Mn-Bi/BiVO4 photoanode which could be ascribed to enhanced hole injection efficiency, especially in low bias region. It was observed that the injection efficiency of Mn-Bi/BiVO4 is 98% which gave a photocurrent of 0.94 mA/cm^2 at 1.5 V vs. RHE.

关键词： bismuth vanadate photoelectrochemistry solar water splitting oxygen evolution

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Room-temperature photodeposition of conformal transition metal based cocatalysts on BiVO4 for enhanced photoelectrochemical water splitting

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Nano Research 2020年第1期13卷 231-237页

作者： Lu Wang Tao Zhang jinzhan su Liejin Guo International Research Center for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringSchool of Energy&Power EngineeringXi’an Jiaotong UniversityXi’an710049China

Photoelectrochemical(PEC)water splitting using semiconductors offers a promising way to convert renewable solar energy to clean hydrogen ***,due to the sluggish reaction kinetics of water oxidation,significant charge recombination occurred at the photoanode/electrolyte interface and cause decrease of its PEC *** reduce the surface recombination,we deposit different transition metal complexes on BiVO4 nanocone arrays by a versatile light driven in-situ two electrode photodeposition approach without applied *** cobalt phosphate“Co-Pi”,nickel borate“Ni-Bi”and manganese phosphate“Mn-Pi”complexes were deposited on BiVO4 nanocone arrays to form core-shell structure photoanode,all of which lead to enhanced photoelectrochemical *** photocurrent of the Co-Pi/BiVO4 photoanode under front-side illumination for 5 min is increased by 4 folds comparing to that of bare BiVO4 photoanode at 0.6 V ***,reaching a hole transfer efficiency as high as 94.5%at 1.23 V *** proposed photodeposition strategy is simple and efficient,and can be extended to deposite cocatalyst on other semiconductors with a valence band edge located at a potential more positive than the oxidation potential of transition metal ion in the cocatalyst.

关键词： bismuth vanadate photoelectrochemcial water splitting conformal photodeposition cocatalyst

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Synthesis and application of transition metal phosphides as electrocatalyst for water splitting

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Science Bulletin 2017年第9期62卷 633-644页

作者： jinzhan su Jinglan Zhou Lu Wang Cong Liu Yubin Chen International Research Center for Renewable Energy (IRCRE) State Key Laboratory for Multiphase Flow in Power Engineering Xi'an Jiaotong University Xi'an 710049 China

With continuous research on photocatalytic water splitting, searching for efficient catalyst for hydrogen evolution reaction(HER) becomes popular topic in addition to main catalyst research. Transition metal phosphides are receiving intense attention due to its abundance in the Earth's crust and comparable catalytic properties to noble metals. In this review, the synthesis approaches, HER reaction mechanism,photocatalytic activity, approaches to improve the activity of transition metal phosphides were reviewed and discussed. It was showed that the transition metal phosphides have great potential to reduce the cost of photocatalyst and promising application on water splitting. The stability problem and participation of poisonous reactant and product in its synthesis reaction limit its application and developing in a certain extent, but with the continuous efforts on the development and improvement of the synthesis methods,transition metal phosphides will find wide application in water splitting.

关键词： Transition metal phosphide Electrocatalyst HER Photocatalytic water splitting

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Spontaneous photoelectric field-enhancement effect prompts the low cost hierarchical growth of highly ordered heteronanostructures for solar water splitting

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Nano Research 2016年第6期9卷 1561-1569页

作者： Yankuan Wei jinzhan su XiaokangWan Liejin Guo Lionel Vayssieres International Research Center for Renewable Energy State Key Laboratory for Multiphase Flow in Power Engineering School of Energy &Power Engineering Xi'an Jiaotong University Xi'an 710049 China

In this study, a potentially universal new strategy is reported for the large-scale, low-cost fabrication of visible-light-active highly ordered heteronanostructures based on the spontaneous photoelectric-field-enhancement effect inherent in pyramidal morphology. The hierarchical vertically oriented arrayed structures comprise an active molecular co-catalyst at the apex of a visible-light-active large band gap semiconductor for low-cost solar water splitting in a neutral aqueous medium without the use of a sacrificial agent.

关键词： bismuth vanadate co-catalysts photocatalysis solar water splitting oxygen evolution

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Precise modeling of arc tooth face-gear with transition curve

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Chinese Journal of Aeronautics 2013年第5期26卷 1346-1351页

作者： Cui Yanmei Fang Zongde su jinzhan Feng Xianzhang Peng Xianlong School of Mechanical Engineering Northwestern Polytechnical University School of Construction Machinery Chang’an University School of Mechatronics Engineering Zhengzhou Institute of Aeronautical Industry Management

A fabrication method is adopted for which an imaginary gear simultaneously realizes conjugated meshing with an arc tooth cylindrical gear and an arc tooth face-gear. The cutter fillet and tooth crest edge form the tooth root fillet of the gear, and the linear tooth surface equation of the imaginary gear and the position vector of the curvature center of the cutter fillet arc constructed with certain cutter inclination to deduce a working arc tooth surface equation. The tooth root fillet equation of the arc tooth face-gear is derived from the meshing geometry and kinematics. A numer- ically controlled machining model of the arc tooth face-gear is established through the transforma- tion of adjustment parameters from the cutter-tilt milling machine to a common multi-axis NC machine. Motion parameters of each movement axis of the NC machine are acquired. A processing example is presented to verify the precision of the fabrication method in processing the arc tooth face-gear. The method provides a theoretical and tentative basis for the analysis of tooth surface contact stress, tooth root bending stress and dynamics. A hobbing test is conducted to demonstrate the good meshing condition of the arc tooth face-gear pair.

关键词： Face-gear Geometry Kinematics Mechanical drive NC machine Transmissions

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Modulating redox transition kinetics by anion regulation in Ni-Fe-X(X=O,S,Se,N,and P)electrocatalyst for efficient water oxidation

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Nano Research 2024年第6期17卷 4720-4728页

作者： Liting Wei Kaini Zhang Rui Zhao Lei Zhang Yan Zhang suyi Yang jinzhan su International Research Center for Renewable Energy&State Key Laboratory of Multiphase Flow in Power Engineering Xi’an Jiaotong UniversityXi’an 710049China Department of Applied Chemistry Yuncheng UniversityYuncheng 044000China

NiFe-based electrocatalysts will experience dynamical surface reconstruction during oxygen evolution reaction(OER)process,and the derived metal(oxy)hydroxide hybrids on the surface have been considered as the actual active species for *** efforts have been dedicated to understanding the surface reconstruction,but there is rare research on recognizing the origin of improved performance derived from anion species of ***,the OER electrocatalytic characteristics were tuned with different anions in NiFe-based catalyst,using NiFe-based oxides/nitride/sulfide/selenides/phosphides(NiFeX,X=O,N,S,Se,and P)as the model *** combination of X-ray photoelectronic spectroscopy,electrochemical tests,operando spectroscopic characterizations,and density functional theory(DFT)calculations,reveals that anion with lower electronegativity in NiFe-based catalyst leads to higher conductivity and delayed valence transition of Ni sites,as well as optimized adsorption behavior towards oxygen intermediates,contributing to enhanced OER ***,NiFeP electrocatalyst demonstrates an ultralow overpotential of 265 mV at 20 mA·cm−2 for OER,as well as long-term *** work not only offers further insights into the effect of anionic electronegativity on the intrinsic OER electrocatalytic properties of NiFe-based electrocatalyst but also provides guide to design efficient non-noble metal-based electrocatalysts for water oxidation.

关键词： oxygen evolution reaction(OER) anion species electronegativity valence transition

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Recent advances in all-in-one flexible supercapacitors

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Science China Materials 2021年第1期64卷 27-45页

作者： Tiezhu Guo Di Zhou Wenfeng Liu jinzhan su Electronic Materials Research Laboratory Key Laboratory of the Ministry of Education&International Center for Dielectric ResearchSchool of Electronic Science and EngineeringXi’an Jiaotong UniversityXi’an710049China State Key Laboratory of Electrical Insulation and Power Equipment Xi’an Jiaotong UniversityXi’an710049China International Research Centre for Renewable Energy State Key Laboratory of Multiphase Flow in Power EngineeringXi’an Jiaotong UniversityXi’an710049China

The rise of personalized flexible electronics has promoted the rapid development of flexible supercapacitors due to their long service life,fast charging-discharging rates and safe *** from the traditional flexible supercapacitors,the all-in-one integrated flexible supercapacitors are more resistant to deformation and lower interface resistance,which have a broader application prospect in the field of flexible *** review briefly summarizes the preparation methods and electrochemical properties of some typical all-in-one supercapacitors,represented by planar and fibrous structures in recent ***,the basic understanding of traditional flexible supercapacitors and all-in-one integrated flexible supercapacitors,and the key parameters of the performance of flexible supercapacitors are ***,the hydrogel matrix all-in-one supercapacitors with different functional characteristics(stretchable,self-healing and compressible)and the nonhydrogel matrix(separator,flexible membrane)all-in-one supercapacitors are ***,the challenges and future development of flexible supercapacitors are considered.

关键词： flexible supercapacitors all-in-one hydrogel

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