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Solar chemical looping reforming of methane combined with isothermal H2O/CO2 splitting using ceria oxygen carrier for syngas production

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Journal of Energy Chemistry 2020年第2期29卷 60-72页

作者： Srirat Chuayboon stéphane Abanades Sylvain Rodat Processes Materials and Solar Energy LaboratoryPROMES-CNRSFont-Romeu 66120France Department of Mechanical Engineering King Mongkut's Institute of Technology LadkrabangPrince of Chumphon CampusChumphon 86160Thailand Universite Grenoble Alpes Le-Bourget-du-Lac F-73375France CEA-LJTEN Laboratoire des Systemes Solaires Haute Temperature(LSHT) Grenoble F-38054France

The chemical looping reforming of methane through the nonstoichiometric ceria redox cycle(CeO2/CeO2-δ) has been experimentally investigated in a directly irradiated solar reactor to convert both solar energy and methane to syngas in the temperature range 900–1050 °C. Experiments were carried out with different ceria shapes via two-step redox cycling composed of endothermic partial reduction of ceria with methane and complete exothermic re-oxidation of reduced ceria with H2 O/CO2 at the same operating temperature, thereby demonstrating the capability to operate the cycle isothermally. A parametric study considering different ceria macrostructure variants(ceria packed powder, ceria packed powder mixed with inert Al2 O3 particles, and ceria reticulated porous foam) and operating parameters(methane flow-rate, reduction temperature, or sintering temperature) was conducted in order to unravel their impact on the bed-averaged oxygen non-stoichiometry(δ), syngas yield, methane conversion, and solar reactor performance. The ceria cycling stability was also experimentally investigated to demonstrate repeatable syngas production by alternating the flow between CH4 and H2 O(or CO2). A decrease in sintering temperature of the ceria foam was beneficial for increasing syngas selectivity, methane conversion,and reactor performance. Increasing both CH4 concentration and reduction temperature enhanced δ with the maximum value up to 0.41 but concomitantly favored CH4 cracking reaction. The ceria reticulated porous foam showed better performance in terms of effective heat transfer, due to volumetric absorption of concentrated solar radiation and uniform heating with lower solar power consumption, thereby promoting the solar-to-fuel energy conversion efficiency that reached up to 5.60%. The energy upgrade factor achieved during cycle was up to 1.19. stable patterns in the δ and syngas yield for consecutive cycles with the ceria foam validated material performance stability.

关键词： Chemical looping Methane reforming Ceria structure Concentrated solar power Syngas production H2O/CO2 splitting

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Conversion of the refractory ammonia and acetic acid in catalytic wet air oxidation of animal byproducts

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Journal of Environmental Sciences 2011年第3期23卷 520-528页

作者： Virginie Fontanier Sofiane Zalouk stéphane Barbati Aix-Marseille Universite's-CNRS (UMR 6264)-Laboratoire de Chimie Provence:quipe Chimie de l'Environnement Continental-3 Place Victor Hugo (case 29)-13331 Marseille cedex 3France

Wet air oxidation （WAO） and catalytic wet air oxidation （CWAO） of slaughtered animal byproducts （ABPs） were investigated. Two step experiment was carried out consisting of a non-catalysed WAO run followed by a CWAO run at 170-275 ℃, 20 MPa, and reaction time 180 min. The WAO （lst step） of sample （5 g/L total organic carbon （TOC）） yielded （82.0 ±4）% TOC removal and （78.4 ± 13.2）% conversion of the initial organic-N into NH4＋-N. Four metal catalysts （Pd, Pt, Rh, Ru） supported over alumina have been tested in catalytic WAO （2nd step） at elevated pH to enhance ammonia conversion and organic matter removal, particularly acetic acid. It was found that the catalysts Ru, Pt, and Rh had significant effects on the TOC removal （95.1%, 99.5% and 96.7%, respectively） and on the abatement of ammonia （93.4%, 96.7% and 96.3%, respectively） with high nitrogen selectivity. The catalyst Pd was found to have the less activity while Pt had the best performance. The X-Ray diffraction analysis showed that the support of catalyst was not stable under the experimental conditions since it reacted with phosphate present in solution. Nitrite and nitrate ions were monitored during the oxidation reaction and it was concluded that CWAO of ammonia in real waste treatment framework was in good agreement with the results obtained from the literature for ideal solutions of ammonia.

关键词： wet oxidation, heterogeneous catalysis animal byproducts acetic acid ammonia, nitrite nitrate

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Numerical study of Classical and Composite Solar Walls by TRNSYS

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Journal of Thermal Science 2007年第1期16卷 46-55页

作者： Jibao SHEN stéphane LASSUE Laurent ZALEWSKI Dezhong HUANG School of Engineering Shaoxing College of Arts and Sciences Shaoxing University Zhejiang 312000 China Laboratoire d＇Artois de MéThermique et Instrumentation （LAMTI） Faculté des Sciences Appliquées Univeristé d＇Artois 62400 Béthune France

The laboratory LAMTI has worked for several years on the study and the optimization of the thermal performances of passive solar walls like solar Trombe wall. These components of the buildings envelope have very complex behaviour because they are the seat of various coupled heat transfers modes and are subjected to the random variations of the meteorological parameters. Using the finite difference method （FDM） and starting from experimental results recorded during several years, a simulation model was developed and validated concerning the ＂composite＂ Trombe wall. In order to make this work more accessible to the community of the heat engineers, it appears interesting to build a simulation model which can be integrated into the library of elements of the TRNSYS software. A ＂Type＂ was thus carried out and the results obtained compared with those of the FDM model. In this work we compare the obtained results with these two numerical ways. The assumptions and the results of simulations are also confronted with those of an existing module in TRNSYS （Type 36） established for the ＂classical＂ Trombe wall. The study shows that the models that we developed are very precise and that certain assumptions must be used with a lot of precautions. The advantages of the composite Trombe solar wall compared to the Classical Trombe wall are highlighted for cold and/or cloudy climates.

关键词： Trombe wall solar wall classical wall composite wall finite difference method TRNSYS

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Natural gas pyrolysis in double-walled reactor tubes using thermal plasma or concentrated solar radiation as external heating source

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Journal of Natural Gas Chemistry 2009年第1期18卷 1-8页

作者： stphane Abanades stefania Tescari Sylvain Rodat Gilles Flamant Processes Materials and Solar Energy Laboratory (PROMES-CNRS) 7 Rue du Four Solaire 66120 Font-Romeu France

The thermal pyrolysis of natural gas as a clean hydrogen production route is examined. The concept of a double-walled reactor tube is proposed and implemented. Preliminary experiments using an external plasma heating source are carried out to validate this concept. The results point out the efficient CH4 dissociation above 1850 K （CH4 conversion over 90%） and the key influence of the gas residence time. Simulations are performed to predict the conversion rate of CH4 at the reactor outlet, and are consistent with experimental tendencies. A solar reactor prototype featuring four independent double-walled tubes is then developed. The heat in high temperature process required for the endothermic reaction of natural gas pyrolysis is supplied by concentrated solar energy. The tubes are heated uniformly by radiation using the blackbody effect of a cavity-receiver absorbing the concentrated solar irradiation through a quartz window. The gas composition at the reactor outlet, the chemical conversion of CH4, and the yield to H2 are determined with respect to reaction temperature, inlet gas flow-rates, and feed gas composition. The longer the gas residence time, the higher the CH4 conversion and H2 yield, whereas the lower the amount of acetylene. A CH4 conversion of 99% and H2 yield of about 85% are measured at 1880 K with 30% CH4 in the feed gas （6 L/min injected and residence time of 18 ms）, A temperature increase from 1870 K to 1970 K does not improve the H2 yield.

关键词： methane hydrogen thermal cracking plasma concentrated solar energy tubular reactor

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Numerical Investigation of Flutter stability in Subsonic Space Turbine Blisk with Emphasis on Cut-on/Cut-off Modes and Interblade Phase Angles

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Journal of Thermal Science 2012年第6期21卷 492-499页

作者： Hakim Ferria Pascal Ferrand Franois Pacull stéphane Aubert Laboratoire de Mécanique des Fluides et d'Acoustique CNRS UMR 5509 Université de LyonUniversité Claude Bernard Lyon 1INSA Lyon 36avenue Guy de Collongue69134 EcullyFrance Fluorem 64 chemin des Mouilles69134 EcullyFrance

The so-called blisks,*** bladed disks,are characterized by very low viscous material damping and make the flutter prediction much more *** that framework,a two-dimensional numerical study of a space turbine blisk featuring complex deformation of blades and high eigenfrequency(>40kHz)is *** simulations are based on unsteady Reynolds Averaged Navier stokes computations linearized in the frequency domain and consist in the superposition of an unsteady linear(in time)pressure field,generated by a harmonic perturbation,upon a steady nonlinear(in space)*** aerodynamic damping coefficient is calculated over a range of nodal diameters,and the blades are predicted aeroelastically ***,violent changes occur and are rather critical since sudden and large deviations in stability *** that context,the nature of the waves propagating from the cascade are *** an approach provides fundamental knowledge about the perturbations which can either propagate to the far-field(cut-on mode)or decay(cut-off mode).It is expected that the ability of the flow to damp or to amplify the blade motion is strongly affected by the way unsteady perturbations are transferred from the cascade to the *** nature of the waves are first assessed from the aforementioned linearized results,then they are evaluated analytically and finally compared.A good agreement is found despite the strong assumptions of the analytical *** results show a clear correlation between the cut-on/cut-off conditions and *** least stable configuration corresponds to cut-off mode at the inlet and no wave at the *** outgoing waves from the cascade,the blade is prone to be less stable:the energy from the blades vibration is necessarily dissipated or sent out by the cascade.

关键词： subsonic flutter LRANS blisk cut-on/cut-off mode interblade phase angle nodal diameter.

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Polygeneration study of Low-to-Medium Enthalpy Geothermal Reservoirs in Mexico

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Journal of Thermal Science 2021年第3期30卷 1077-1087页

作者： CHÁVEZ Oscar godÍNEZ Francisco Tecnológico Nacional de México/I.T.Chihuahua.Av.Tecnológico 2909 C.P.31310ChihuahuaChihuahuaMéxico Instituto de Ingeniería Universidad Nacional Autónoma de MéxicoUNAMC.U.Ciudad de MéxicoC.P.04510México Polo Universitario de Tecnología Avanzada Universidad Nacional Autónoma de MéxicoVía de la Innovación No.410Autopista Monterrey-Aeropuertokm.10 PIITC.P.66629Apodaca Nuevo LeónMéxico

This study combines the thermodynamic analysis of a polygeneration system along with the numerical modelling of the thermal behavior of geothermal reservoirs in Mexico to exploit their *** reservoir was modeled as a porous medium assuming a five-spot well configuration and local thermal *** heat conduction-convection along with the Laplace equations were solved to compute temperature distributions,the useful life and the optimum distance between injection-extraction *** predicted temperature and pressure of the geothermal fluid at the outlet of the reservoir were exploited in the polygeneration system consisting of:(1)a Rankine cycle,(2)an absorption refrigeration cycle,and(3)a heat *** developed approach allows calculating both the optimal distance between injection-extraction wells and the global(utilization)efficiency of six arrangements(each composed by a reservoir connected to a polygeneration system)by assuming that reservoirs have a lifespan of 30 *** also show that:(a)due to the low efficiency of the Rankine cycle,very little thermal energy is converted into electrical one;(b)not only the temperature and the size are important when evaluating the power production performance of reservoirs,but also the permeability plays a fundamental role;(c)the first law efficiency of the polygeneration system ranges from 41.9%to 43.7%;(d)the utilization efficiency of the six arrangements lies in the range between 25.8%and 31%.

关键词： polygeneration system geothermal reservoir local thermal equilibrium low-to-medium enthalpy

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Reconstruction of hollow areas in density profiles from frequency swept reflectometry

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Plasma Science and Technology 2020年第6期22卷 32-40页

作者： Rennan B MORALES stéphane HEURAUX Roland SABOT Sébastien HACQUIN Frédéric CLAIRET the Tore Supra Team United Kingdom Atomic Energy Authority Culham Centre for Fusion EnergyCulham Science CentreAbingdonOxonOX143DBUnited Kingdom IJL UMR CNRSUniversity of LorraineBP50840NancyF-54011France Institute of Physics University of Sao PauloSao Paulo 05315-970Brazil IRFM CEACadaracheF-13108 Saint-Paul-lez-DuranceFrance EUROfusion Programme Management Unit Culham Science CentreCulham OX143DBUnited Kingdom

The standard density profile reconstruction techniques are based on the WKB approximation of the probing wave’s phase,making them unable to properly reconstruct blind areas in the cut-off frequency *** reconstruction suffers a significant immediate error that is not rapidly *** is demonstrated that even though no reflections occur inside the hollow region causing the blind area,the higher probing frequencies that propagate through it carry information that can be used to estimate its *** usually ignored full-wave effects were investigated with the use of full-wave simulations in 1 D,with special attention paid to the frequency band where they are dominant.A database of perturbation signals was simulated onfive-dimensions of parameters and an application of the database inversion was demonstrated for a magnetic island in a Tore Supra *** new adapted reconstruction scheme improved the description of the density profile inside the hollow region and also along 10 cm after it.

关键词： FM-CW reflectometry profile reconstruction reflectometry density profile hollow profile blind area

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Behavior of ductile steel X-braced RC frames in seismic zones

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Earthquake Engineering and Engineering Vibration 2019年第4期18卷 845-869页

作者： Eber Alberto godínez-Domínguez Arturo Tena-Colunga Facultad de Ingeniería Universidad Autónoma de Chiapas Tuxtla Gutiérrez 29050 Mexico Departamento de Materiales Universidad Autónoma Metropolitana México City 02200 Mexico

A satisfactory ductile performance of moment-resisting reinforced concrete concentric braced frame structures (RC-MRCBFs) is not warranted by only following the provisions proposed in Mexico’s Federal District Code (MFDC-04). The nonlinear behavior of low to medium rise ductile RC-MRCBFs using steel X-bracing susceptible to buckling is evaluated in this study. The height of the studied structures ranges from 4 to 20 stories and they were located for design in the lakebed zone of Mexico City. The design of RC-MRCBFs was carried out considering variable contribution of the two main lines of defense of the dual system (RC columns and steel braces). In order to observe the principal elements responsible for dissipating the earthquake input energy, yielding mappings for diff erent load-steps were obtained using both nonlinear static and dynamic analyses. Some design parameters currently proposed in MFDC-04 as global ductility capacities, overstrength reduction factors and story drifts corresponding to diff erent limit states were assessed as a function of both the considered shear strength and slenderness ratios for the studied RC-MRCBFs using pushover analyses. Additionally, envelopes of response maxima of dynamic parameters were obtained from the story and global hysteresis curves. Finally, a brief discussion regarding residual drifts, residual drift ratios, mappings of residual deformations in steel braces and residual rotations in RC beams and columns is presented. From the analysis of the obtained results, it is concluded that when a suitable design criterion is considered, good structural behavior of RC-MRCBFs with steel-X bracing can be obtained. It is also observed that the shear strength balance has an impact in the height-wise distribution of residual drifts, and an important “shake-down” eff ect is obtained for all cases. There is a need to improve design parameters currently proposed in MFDC to promote an adequate seismic performance of RC-MRCBFs.

关键词： RC braced-frames seismic design nonlinear dynamic analyses steel-X bracing overstrength collapse mechanism story drifts residual drifts

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The evolution of a geoscience standard:An instructive tale of science keyword development and adoption

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Geoscience Frontiers 2023年第5期14卷 396-401页

作者： Mark A.Parsons Ruth Duerr Øystein godøy University of Alabama in Huntsville AlabamaUSA Ronin Institute BroomfieldCOUSA Norwegian Meteorological Institute OsloNorway

In 1987,NASA sponsored an international workshop that inspired the Directory Interchange Format or DIF–a metadata format to enable“catalog interoperability”.The DIF formed the basis of the International Directory Network(IDN)and the Global Change Master Directory(GCMD)and included a set of science *** primary intent was to catalog NASA Earth science and related data,but the keywords have been implemented in many different systems and adopted in varying ways by many different organizations around the *** review provides an ethnographic examination of how the keywords have evolved and been managed and how they have been adopted over the last 35 *** illustrates how semantic approaches have evolved over time and provides insights on how standards and associated processes can be sustained and *** institutional commitment is essential,but so is transparency and technical *** and empowering the different roles involved in standards creation,maintenance,and use of standards as well as the services that standards enable is also *** is apparent that semantic representations need to be mindful of different contexts and carefully define verbs as well as nouns and *** and representing relationships is central to interdisciplinary interoperability.

关键词： Data management standards Digital earth Semantic web Information science

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Diesel engine exhaust exposures in two underground mines

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International Journal of Mining Science and Technology 2017年第4期27卷 641-645页

作者： Debia Maximilien Couture Caroline Njanga Pierre-Eric Neesham-Grenon Eve Lachapelle Guillaume Coulombe Hugo Hallé stéphane Aubin Simon Department of Environmental and Occupational Health School of Public Health Universite de Montreal 2375 chemin de la Cote Ste-Catherine Montreal H3T IA8 Canada Department of Mechanical Engineering F.cole de Technologie Superieure 1100 rue Notre-Dame Ouest Montreal H3C 1K3 Canada Health and Safety Agnico Eagie Mines 145 King Street East Suite 400 Toronto MSC 2Y7 Canada Health and Safety Westwood Mine (IAMGOLD) Chemin Arthur Doyon PreissacJOY 2EO Canada Institut de recherche Robert-Sauve en sante et en securite du travail (IRSst) 505 Boul. de Maisonneuve Ouest Montreal H3A 3C2 Canada

Exposure to diesel engine exhaust(DE) is a major concern in underground mines. It has been linked to cardiopulmonary diseases and is classified as a human carcinogen. The goal of this study is to assess DE exposures in workers at two underground gold mines, to compare exposure levels within and between the mines, and to compare different methods of measuring DE exposures, namely respirable combustible dust(RCD), elemental carbon(EC) and total carbon(TC). Ambient and personal breathing zone(PBZ) measurements were taken. Side-by-side monitoring of RCD and of the respirable fraction of EC and TC(EC_Rand TC_R) was carried out in the workers' breathing zone during full-shift *** ambient measurements, in addition to EC_R, TC_Rand RCD, a submicron aerosol fraction(less than 1 mm) of EC and TC was also sampled(EC_1and TC_1). Average ambient results of 240 mg/m^3 in RCD, 150 mg/m^3 in EC_Rand 210 mg/m^3 in TC_Rare obtained. Average PBZ results of 190 mg/m^3 in RCD,84 mg/m^3 in EC3Rand 150 mg/min TC_Rare obtained. Very good correlation is found between EC_Rand EC_1 with a Pearson correlation coefficient of 0.99(p st exposures are reported for loadhaul-dump(LHD) and jumbo drill operators and conventional miners. Significant exposure differences are reported between mines for truck and LHD operators(p < 0.01). The average TC_R/EC_Rratio is 1.6 for PBZ results, and 1.3 for ambient results. The variability observed in the TC_R/EC_Rratio shows that interferences from non-diesel related organic carbon can skew the interpretation of results when relying only on TC data.

关键词： Diesel exposure Underground mine Respirable combustible dust Elemental carbon Total carbon Diesel particulate matter Similar exposure groups

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