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Enhanced dielectric and electrocaloric properties in lead-free rod-like BCZT ceramics

Journal of Advanced Ceramics 2020年第2期9卷 210-219页

作者： Zouhair HANANI soukaina merselmiz Abdelaadim DANINE Nicolas STEIN Daoud MEZZANE M’barek AMJOUD Mohammed LAHCINI Yaovi GAGOU Matjaz SPREITZER Damjan VENGUST Zdravko KUTNJAK Mimoun El MARSSI Igor ALUK'YANCHUK Mohamed GOUNE IMED-Lab Cadi Ayyad UniversityMarrakesh 40000Morocco ICMCB University of 1.BordeauxPessac 33600France IJL University of LorraineNancy 54000France UM6P Ben Guerir 43150Morocco LPMC University of Picardy Jules VerneAmiens 80039France Jozef Stefan Institute Ljubljana 1000Slovenia Physics Faculty Southern Federal UniversityRostov-on-Don 344090Russia

Ba0.85Ca0.15Zr0.10Ti0.90O3(BCZT)lead-free ceramics demonstrated excellent dielectric,ferroelectric,and piezoelectric properties at the morphotropic phase boundary(MPB).So far,to study the effect of morphological changes on dielectric and ferroelectric properties in lead-free BCZT ceramics,researchers have mostly focused on the influence of spherical grain shape *** this study,BCZT ceramics with rod-like grains and aspect ratio of about 10 were synthesized by surfactant-assisted solvothermal route.X-ray diffraction(XRD)and selected area electron diffraction(SAED)performed at room temperature confirm the crystallization of pure perovskite with tetragonal *** electron microscopy(SEM)image showed that BCZT ceramics have kept the 1D rod-like grains with an average aspect ratio of about ***-like BCZT ceramics exhibit enhanced dielectric ferroelectric(εr=11,906,tanδ=0.014,Pr=6.01μC/cm^2,and Ec=2.46 kV/cm),and electrocaloric properties(ΔT=0.492 K andz=0.289(K×mm)/kV at 17 kV/cm)with respect to spherical BCZT ***,rod-like BCZT lead-free ceramics have good potential to be used in solid-state refrigeration technology.

关键词： lead-free Ba0.85Ca0.15Zr0.10Ti0.90O3(BCZT) rod-like Ba0.85Ca0.15Zr0.10Ti0.90O3(BCZT) dielectric ferroelectric electrocaloric effect

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Novel lead-free BCZT-based ceramic with thermally-stable recovered energy density and increased energy storage efficiency

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Journal of Materiomics 2022年第4期8卷 873-881页

作者： Zouhair Hanani soukaina merselmiz M'barek Amjoud Daoud Mezzane Mohammed Lahcini Jaafar Ghanbaja Matjaz Spreitzer Damjan Vengust Mimoun El Marssi Igor A.Luk'yanchuk Zdravko Kutnjak Brigita Rozic Mohamed Goune IMED-Lab Cadi Ayyad UniversityAvenue Abdelkrim El KhattabiP.B.549Marrakesh40000Morocco ICMCB University of Bordeaux87 Avenue Du Dr Albert SchweitzerPessac33600France Jozef Stefan Institute Jamova Cesta 39Ljubljana1000Slovenia LPMC University of Picardy Jules Verne33 Rue Saint LeuAmiens80039France Mohammed VI Polytechnic University Lot 660-Hay Moulay RachidBen Guerir43150Morocco IJL University of Lorraine54000NancyFrance Department of Building Materials Kyiv National University of Construction and ArchitectureKyiv03680Ukraine

The eco-responsible lead-free piezoelectric ceramics have been intensively searched for more than adecade, however, the final goal to replace toxic ceramics like lead zirconate titanate (PZT) with lead-freecompounds, having comparable or even better performance has not yet been reached. In this road, thelead-free ceramics Ba_(0.85)Ca_(0.15)Zr_(0.1)Ti_(0.9)O_(3) (BCZT), possessing excellent dielectric, ferroelectric, andpiezoelectric properties are regarded as serious candidates for the PZT replacement. Besides, nano-structuring BCZT is of paramount importance to enhance these functionalities even more. Here, BCZTmultipodes are designed by template-growth hydrothermal synthesis using hydrogen zirconate titanatenanowires. We demonstrate that the fabricated BCZT multipodes exhibit high dielectric permittivity of5300 with a temperature stability coefficient of ±5.9% between 20 and 140℃. A significant recoveredenergy density of 315.0 mJ/cm^(3) with high thermal stability and high energy storage efficiency of 87.4%,and enhanced large-signal piezoelectric coefficient d^(*)_(33) (310 pm/V) are found. Compared to the tradi-tional BCZT ceramics reported in the literature, relying on high-temperature processing, our sampleexhibits boosted energy storage parameters at a much lower temperature. These outcomes may offer anew strategy to tailor eco-responsible relaxor ferroelectrics toward superior energy storage performancefor ceramic capacitor applications.

关键词： Lead-free ceramics Low temperature Piezoelectric Thermal stability Energy storage Nanostructuration

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