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Maximizing biomass utilization: An integrated strategy for coproducing multiple chemicals

Journal of Energy Chemistry 2025年第1期100卷 180-191页

作者： Byeongchan Ahn Sua Jo Jonggeol Na J.Jay Liu Young-Ju kim Wangyun Won Department of Chemical and Biological Engineering Korea University Department of Chemical Engineering (Integrated process) Kyung Hee University Department of Chemical Engineering and Materials Science Ewha Womans University Department of Chemical Engineering Pukyong National University Resources Engineering Plant Research Department Korea Institute of Geoscience and Mineral Resources

Lignocellulosic biomass is one of the viable solutions to alleviate the global warming. However, the limited utilization of biomass majorly focused on cellulose and hemicellulose restricts the economic and environmental feasibilities. To cope with this issue, we proposed an integrated process of co-producing 1,6-hexanediol（1,6-HDO） with tetrahydrofuran and adipic acid from biomass, referred to as Strategy A. To compare the impacts of lignin upgrading and feedstock, Strategy B, which co-produces tetrahydrofuran alone, and Strategy C, which is the traditional route to produce 1,6-HDO from fossil fuels, were used. Heat networks are also designed to reduce operating costs and indirect carbon emissions due to energy consumption, saving 87% and 83% of the heat and cooling requirements, respectively, in Strategy A. The market competitiveness of Strategy A was evaluated by determining the minimum selling price through techno-economic analysis, and sustainability was thoroughly investigated by quantifying the environmental impacts through both midpoint and endpoint life-cycle assessments（LCAs）.Strategy A was found to be the most favorable both economically（USRDSCHARDOLLAR3,402/ton） and environmentally（-26.9 kg CO2eq.）. This indicates that lignin valorization is not only economically but also environmentally preferred. Finally, changes in economic and environmental feasibilities depending on economic, process, and environmental parameters were investigated using sensitivity and uncertainty analyses. The results of these analyses provide valuable insight into bio-based chemical production.

关键词： Biorefinery Carbon mitigation Climate change Global warming Lignin utilization Bioeconomy

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Refractory lipoatrophy treated with autologous whole blood injection:A case report

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World Journal of Clinical Cases 2025年第2期13卷 33-38页

作者： Wonnam kim Jun Su Park En Hyung kim Department of Pharmacology School of Korean MedicinePusan National UniversityYangsan 50612GyeongnamSouth Korea Department of Dermatology College of MedicineChungbuk National UniversityCheongju 28644ChungbukSouth Korea Department of Dermatology Chungbuk National University HospitalCheongju 28644ChungbukSouth Korea

BACKGROUND Intramuscular corticosteroid injection may cause adverse effects such as dermal and/or subcutaneous atrophy,alopecia,hypopigmentation,and *** cutaneous atrophy can spontaneously resolve,several treatment options have been suggested for this *** SUMMARY In this paper,we report a case of corticosteroid injection induced lipoatrophy treated with autologous whole blood(AWB)injection,as the condition had been unresponsive to fractional laser therapy.A 29-year-old female patient visited the dermatology clinic complaining of skin depression on her right buttock area,which had appeared six months *** had been only subtle improvement at the margins after fractional CO_(2) laser treatment;therefore,after obtaining informed consent from the patient,AWB treatment was *** month after the first AWB injection,the size and depth of the lesion had noticeably improved,and a slight improvement was also observed in *** Close observation is the initial treatment of choice for steroid induced skin atrophy;however,for patients in need of immediate cosmetic improvement,AWB injection may be a safe and cost-effective alternative.

关键词： Atrophy Corticosteroid Subcutaneous fat Autologous whole blood injection Laser therapy Case report

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Prominent cycling reversibility and kinetics enabled by CaTiO3 protective layer on Zn metal for aqueous Zn-ion batteries

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Journal of Energy Chemistry 2025年第1期100卷 245-258页

作者： Gaeun Lee Yong Nam Ahn Seongjoon So Chanwoo Park Jong-Seong Bae Taehyun Park Il Tae kim Jaehyun Hur School of Chemical Biological and Battery Engineering Gachon University Seongnam Busan Center Korea Basic Science Institute

Aqueous Zn-ion batteries （AZIBs） have received considerable attention owing to their various advantages such as safety,low cost,simple battery assembly conditions,and high ionic ***,they still suffer from serious problems,including uncontrollable dendrite growth,corrosion,hydrogen evolution reaction （HER） from water decomposition,electrode passivation,and unexpected *** creation of a uniform artificial nanocrystal layer on the Zn anode surface is a promising strategy for resolving these ***,we propose the use of a perovskite CaTiO3（CTO） protective layer on Zn（CTO@Zn） as a promising approach for improving the performance of *** CTO artificial layer provides an efficient pathway for Zn ion diffusion towards the Zn metal because of the high dielectric constant （εr=180） and ferroelectric characteristics that enable the alignment of dipole moments and redistribute the Zn2+ions in the CTO *** avoiding the direct contact of the Zn anode with the electrolyte solution,the uneven dendrite growth,corrosion,parasitic side reactions,and HER are mitigated,while CTO retains its mechanical and chemical robustness during ***,CTO@Zn demonstrates an improved lifespan in a symmetric cell configuration compared with bare ***@Zn shows steady overpotential （～68 m V） for 1500 h at 1 mA cm-2/0.5 mA h cm-2,excelling bare ***,when paired with the V2O5-C cathode,the CTO@Zn//V2O5-C full battery delivers 148.4 mA h g-1（based on the mass of the cathode） after 300 *** study provides new insights into Zn metal anodes and the development of high-performance AZIBs.

关键词： Artificial layer Dielectric constant Zn metal anode Zinc aqueous battery

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Experimental and Modeling Studies on the Chemical Vapor Infiltration with Respect to the Effects of Thermal Gradient and Other Operating Parameters

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Journal of Wuhan University of Technology(Materials Science) 2018年第3期33卷 525-532页

作者： Kyung Do Joo Do Hoon kim Gui yung Chung Department of Chemical Engineering Hong Ik University

Effects of operating parameters in the thermal gradient chemical vapor infiltration of propane such as thermal gradient, diffusion, infiltrations time, and concentration of propane were studied by focusing on the visualizations of the intrinsic effects of these parameters. A uniform deposition in the preform was obtained with a gradually increasing temperature along the gas flow. The uniformity of deposition through the preform got improved with increasing deposition time. Results of numerical modeling estimated the experimental data very well when the pre-exponential factor of the overall rate of carbon deposition from propane reported by Vaidyaraman[1] was multiplied by 4. The average density of a preform increased by about 3 times from 0.38 to 1.15 g/cm3 after 60 hr deposition with a thermal gradient under the conditions of 3% propane in nitrogen and 840 to 900 ℃.

关键词： TG-CVI propane C/C composites uniform deposition mathematical modeling

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Regulation of sleep by astrocytes in the hypothalamic ventrolateral preoptic nucleus

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Neural Regeneration Research 2025年第4期20卷 1098-1100页

作者： Jae-Hong kim Ruqayya Afridi Il-Sung Jang Maan Gee Lee Kyoungho Suk Brain Korea 21 four KNU Convergence Educational Program of Biomedical Sciences for Creative Future Talents School of MedicineKyungpook National UniversityDaeguRepublic of Korea Department of Pharmacology School of MedicineKyungpook National UniversityDaeguRepublic of Korea Department of Pharmacology School of DentistryKyungpook National UniversityDaeguRepublic of Korea Brain Science&Engineering Institute Kyungpook National UniversityDaeguRepublic of Korea

Astrocytes are functionally dynamic cells that support neurons in multiple ways throughout an organism’s *** astrocytic regulation of neuronal activity has been increasingly recognized in recent *** are now recognized as playing a more complex role than mere bystanders in the central nervous ***,their role in regulating the sleep neurocircuitry is not well *** this perspective,we highlight the role of astrocytes in sleep modulation,with a particular focus on regulatory mechanisms related to the ventrolateral preoptic nucleus(VLPO)of the *** briefly discuss recent literature reporting the role of VLPO astrocytes in regulating sleep-associated behaviors.

关键词： sleep ventrolateral astrocytes

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Curcumin attenuates the release of pro-inflammatory cytokines in lipopolysaccharide-stimulated BV2 microglia

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Acta Pharmacologica Sinica 2007年第10期28卷 1645-1651页

作者： Jae-dong LEE Cheol PARK yung hyun CHOI Gi-young kim Department of Microbiology College of Natural Sciences Pusan National UniversityBusan 609-735 Department of Biochemistry Dongeui University College of Oriental MedicineBusan 614-054Korea Faculty of Applied Marine Science Cheju National UniversityJeju-siJeju Special Self-Governing Province 690-756Korea

Aim:Pro-inflammatory mediators,such as prostaglandin E2（PGE2） and nitric oxide（NO）,and pro-inflammatory cytokines such as interleukin （IL）-1β,IL-6,and TNF-α,play pivotal roles in brain *** anti-inflammatory properties are knownto be associated with significant reductions in pro-inflammatory mediators in *** the present study we investigate whether the effects of curcumin onthe production of pro-inflammatory mediators in lipopolysaccharide （LPS）-stimu-lated BV2 ***:Curcumin were administered and their effects onLPS-induced pro-inflammatory mediators were monitored by Western blottingand ***:Curcumin significantly inhibited the release of NO,PGE2,and pro-inflammatory cytokines in a dose-dependent *** alsoattenuated the expressions of inducible NO synthase and cyclooxygenase-2 mRNAand protein ***,curcumin suppressed NF-kB activation via thetranslocation of p65 into the *** data also indicate that curcumin exertsanti-inflammatory properties by suppressing the transcription of proinflammatorycytokine genes through the NF-kB signaling ***:Anti-inflam-matory properties of curcumin may be useful for treating the inflammatory anddeleterious effects of microglial activation in response to LPS stimulation.

关键词： curcumin inducible nitric oxide synthase cyclooxygenase-2 pro-inflammatory cytokines NF-kB

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Anti-melanogenic properties of FBCC-EP850 derived from Carex pumila Thunb

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Asian Pacific Journal of Tropical Biomedicine 2024年第11期14卷 477-485页

作者： Mirissa Hewage Dumindu Kavinda Jinkuk Park Nayeong kim yung Hyun Choi Gi-Young kim Department of Marine Life Science Jeju National UniversityJeju 63243Republic of Korea Department of Biochemistry College of Korean MedicineDong-Eui UniversityBusan 47227Republic of Korea

Objective:To elucidate the anti-melanogenic potential of Carex pumila ***(FBCC-EP850).Methods:A collection of 180 plant extracts was tested for inhibition of mushroom tyrosinase activity using an in vitro *** them,FBCC-EP850 exhibited the most promising inhibitory *** analysis was conducted to investigate its mechanisms and therapeutic potential in reducing melanogenesis in B16F10 melanoma cells and zebrafish ***:FBCC-EP850 inhibited mushroom tyrosinase activity in a dose-dependent manner,with a half-maximal inhibitory concentration of 45.83μg/***-EP850 at concentrations up to 50μg/mL demonstrated minimal cytotoxicity against B16F10 melanoma cells and no adverse effects on zebrafish *** with 50μg/mL of FBCC-EP850 significantly reducedα-melanocyte stimulating hormone-induced melanin production and suppressed cellular tyrosinase activity in B16F10 melanoma ***,FBCC-EP850 at 25 and 50μg/mL effectively diminished hyperpigmentation inα-melanocyte stimulating hormone-stimulated zebrafish *** anti-melanogenic action could be attributed to modulation of the cAMP-CREB-MITF signaling ***:Carex pumila extract can inhibit melanogenesis by modulating the cAMP-CREB-MITF signaling pathway,which can be used as a promising candidate for treating hyperpigmentation disorders.

关键词： Carex pumila Thunb. Melanogenesis Tyrosinase cAMP-CREB-MITF signaling

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Spindle-like FeySs/N-doped carbon nanohybrids for high-performance sodium ion battery anodes

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Nano Research 2019年第3期12卷 695-700页

作者： Aihua Jin Mi-Ju kim Kug-Seung Lee Seung-Ho Yu yung-Eun Sung Center for Nanoparticle Research Institute for Basic Science (IBS) Seoul 08826 Republic of Korea School cf Chemical and Biological Engineering Seoul National University Seoul 08826 Republic cf Korea Beamline Department Pohang Accelerator Laboratory (PAL) Pohang 790-784 Republic of Korea Department of Chemistry and Chemical Biology Cornell University Ithaca New York 14853 USA

Iron sulfides have bee n con sidered as one of the most promising can didates for sodium ion battery anode materials due to their high theoretical capacity and low cost. I n this work, spin dle-like Fe7S8 with n itroge rvdoped carb on (FeiS/N-C) nano hybrids are successfully syn thesized via a solvothermal method by sulfidation iron-based metal organic framework (FeMOF). As sodium ion battery an odes, FeySs/N-C nano hybrids exhibit high reversible capacity of 450.8 mAh g-1 at 200 mA·g^-1, and 406.7 mAh·g^-1 at 500 mA·g^-1 even after 500 cycles. They also show excellent rate properties and delivering the capacity of 327.8 mAh·g^-1 at a very high current density of 3.2 A·g^-1. These outstanding electrochemical performa nces can be attributed to the unique structure of Fe7S8/ N-C nan ohybrids. The nano scale dime nsion in their size can be ben eficial for facile ion and electro n tran sports. Furthermore, the stable n itroge n doped carb on frameworks can also improve electrical conductivity and relieve the problems related to volume expansion. X-ray absorption spectroscopy and X-ray photoelectron spectroscopy analyses have been performed to study reactions occurred in spindle-like FeySs/N-C nanohybrid electrode at both bulk and surface.

关键词： sodium ion batteries iron sulfides metal organic frameworks X-ray absorption spectroscopy X-ray photoelectron spectroscopy

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Fuzzy entropy design for non convex fuzzy set and application to mutual information

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Journal of Central South University 2011年第1期18卷 184-189页

作者： LEE Sang-Hyuk LEE Sang-Min SOHN Gyo-Yong kim Jaeh-yung Department of Electronics Engineering Inha UniversityIncheon 402-751Korea School of Electrical Engineering and Computer Science Kyungpook National UniversityDaegu 702-701Korea School of Mechatronics Changwon National University

Fuzzy entropy was designed for non convex fuzzy membership function using well known Hamming distance *** proposed fuzzy entropy had the same structure as that of convex fuzzy membership *** procedure of fuzzy entropy was proposed by considering fuzzy membership through distance measure,and the obtained results contained more flexibility than the general fuzzy membership ***,characteristic analyses for non convex function were also *** on the mutual information were carried out through the proposed fuzzy entropy and similarity measure,which was also dual structure of fuzzy *** the illustrative example,mutual information was discussed.

关键词： fuzzy entropy non convex fuzzy membership function distance measure similarity measure mutual information

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A Rapid Adaptation Approach for Dynamic Air‑Writing Recognition Using Wearable Wristbands with Self‑Supervised Contrastive Learning

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Nano-Micro Letters 2025年第2期17卷 417-431页

作者： Yunjian Guo Kunpeng Li Wei Yue Nam‑Young kim Yang Li Guozhen Shen Jong‑Chul Lee Department of Electronic Convergence Engineering Kwangwoon UniversitySeoul 01897South Korea Radio Frequency Integrated Circuit(RFIC)Bio Centre Kwangwoon UniversitySeoul 01897South Korea Department of Electronic Engineering Kwangwoon UniversitySeoul 01897South Korea School of Microelectronics Shandong UniversityJinan 250101People’s Republic of China State Key Laboratory of Integrated Chips and Systems Fudan UniversityShanghai 200433People’s Republic of China School of Integrated Circuits and Electronics Beijing Institute of TechnologyBeijing 100081People’s Republic of China

Wearable wristband systems leverage deep learning to revolutionize hand gesture recognition in daily *** existing approaches that often focus on static gestures and require extensive labeled data,the proposed wearable wristband with selfsupervised contrastive learning excels at dynamic motion tracking and adapts rapidly across multiple *** features a four-channel sensing array composed of an ionic hydrogel with hierarchical microcone structures and ultrathin flexible electrodes,resulting in high-sensitivity capacitance *** wireless transmission from a Wi-Fi module,the proposed algorithm learns latent features from the unlabeled signals of random wrist ***,only few-shot labeled data are sufficient for fine-tuning the model,enabling rapid adaptation to various *** system achieves a high accuracy of 94.9%in different scenarios,including the prediction of eight-direction commands,and air-writing of all numbers and *** proposed method facilitates smooth transitions between multiple tasks without the need for modifying the structure or undergoing extensive task-specific *** utility has been further extended to enhance human–machine interaction over digital platforms,such as game controls,calculators,and three-language login systems,offering users a natural and intuitive way of communication.

关键词： Wearable wristband Self-supervised contrastive learning Dynamic gesture Air-writing Human-machine interaction

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