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Chinese Chemical Letters 2024年第8期35卷 314-318页

作者： min song Qian Zhang Tao shen Guanyu Luo Deli Wang Key Laboratory of Material Chemistry for Energy Conversion and Storage Ministry of EducationSchool of Chemistry and Chemical EngineeringHuazhong University of Science and Technology(HUST)Wuhan 430074China

Palladium-based alloy catalysts have been employed as one of the potential candidates for oxygen reduc-tion reaction(ORR),but the dissolution of transition metal hinders their ***,structure or-dered PdTe intermetallic with Pd shell(o-PdTe@Pd)are synthesized via an electrochemical etching driven surface reconstruction *** surface reconstruction could tune the electronic structure,weaken the adsorption energy of reaction intermediates on o-PdTe@Pd,resulting in enhanced electrocatalytic ac-tivity for *** mass activity of o-PdTe@Pd is about 3.3 and 2.7 times higher than that of Pd/C in acid and alkaline,***,the half-potentials for ORR decay only about 44 mV and 12 mV after 30 k cycles accelerated durability test in acid and alkaline media,*** enhanced dura-bility originates from the resistance of Te atoms dissolve in the ordered PdTe intermetallic core and the core-shell *** assembled in a Zn-air battery,o-PdTe@Pd electrode delivers a higher specific capacity(794 mAh/g)and better cycling stability than Pt/C.

关键词： Surface reconstruction Core-shell structure Intermetallic Oxygen reduction reaction Tellurium

考虑输入受限和自动驾驶仪延迟的自适应滑模制导律

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中国惯性技术学报 2015年第3期23卷 339-344页

作者：宋俊红宋申民哈尔滨工业大学控制理论与制导技术研究中心哈尔滨150001

在输入受限的情况下,为了满足导弹拦截机动目标时高精度制导的需求,首先建立了满足输入受限和考虑导弹自动驾驶仪一阶动态特性的制导模型,其把目标加速度视为未知有界的外界干扰,通过设计自适应控制估计干扰的上界来避免对干扰上界的先... 详细信息

在输入受限的情况下,为了满足导弹拦截机动目标时高精度制导的需求,首先建立了满足输入受限和考虑导弹自动驾驶仪一阶动态特性的制导模型,其把目标加速度视为未知有界的外界干扰,通过设计自适应控制估计干扰的上界来避免对干扰上界的先验要求,同时结合滑模控制,设计了一种考虑输入受限和自动驾驶仪延迟的自适应滑模制导律,并且基于Lyapunov稳定性理论证明了制导系统状态渐进收敛到零。最后,在所设计的制导律下,对目标余弦机动和阶跃机动两种情况进行了仿真,得到的脱靶量分别为0.040 m和0.036 m,拦截时间分别为6.460 s和7.833 s。仿真结果表明所设计的制导律不仅保证导弹有效击中目标,并且具有较高的制导精度。

关键词：制导律自动驾驶仪延迟输入受限自适应控制滑模控制

Advances of Synergistic Electrocatalysis Between Single Atoms and Nanoparticles/Clusters

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Nano-Micro Letters 2024年第11期16卷 377-412页

作者： Guanyu Luo min song Qian Zhang Lulu An Tao shen Shuang Wang Hanyu Hu Xiao Huang Deli Wang Key Laboratory of Material Chemistry for Energy Conversion and Storage(Huazhong University of Science and Technology)ministry of Education School of Chemistry and Chemical EngineeringHuazhong University of Science and TechnologyWuhan 430074People’s Republic of China

Combining single atoms with clusters or nanoparticles is an emerging tactic to design efficient *** synergy effect and high atomic utilization of active sites in the composite catalysts result in enhanced electrocatalytic performance,simultaneously provide a radical analysis of the interrelationship between structure and *** this review,the recent advances of single-atomic site catalysts coupled with clusters or nanoparticles are ***,the synthetic strategies,characterization,dynamics and types of single atoms coupled with clusters/nanoparticles are introduced,and then the key factors controlling the structure of the composite catalysts are ***,several clean energy catalytic reactions performed over the synergistic composite catalysts are ***,the encountering challenges and recommendations for the future advancement of synergistic structure in energy-transformation electrocatalysis are outlined.

关键词： Single atoms Nanoparticles Clusters Synergistic composite catalysts Synergistic effect

基于旋转矩阵描述的航天器无角速度测量姿态跟踪无源控制

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控制与决策 2014年第9期29卷 1628-1632页

作者：郑重宋申民哈尔滨工业大学控制理论与制导技术研究中心哈尔滨150001

利用系统无源性和旋转矩阵性质研究无角速度测量下的姿态跟踪控制问题.为了避免姿态参数的奇异性和模糊性,提出基于三维特殊正交群(SO(3))的控制策略.首先利用旋转矩阵建立姿态跟踪误差方程,然后分析了系统的内在无源性,从而揭示了闭环... 详细信息

利用系统无源性和旋转矩阵性质研究无角速度测量下的姿态跟踪控制问题.为了避免姿态参数的奇异性和模糊性,提出基于三维特殊正交群(SO(3))的控制策略.首先利用旋转矩阵建立姿态跟踪误差方程,然后分析了系统的内在无源性,从而揭示了闭环系统的稳定性.当角速度无法获得时,利用新的无源滤波提出一种无角速度测量控制律,并给出了严格的Lyapunov稳定性分析.最后,通过数值仿真验证了所提出的控制方法的有效性.

关键词：姿态跟踪旋转矩阵无源控制无速度反馈 Barbalat引理

Study on thermal decomposition kinetics of azobenzene-4,4′-dicarboxylic acid by using compensation parameter method and nonlinear fitting evaluation

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Chinese Journal of Chemical Engineering 2024年第6期70卷 269-279页

作者： Shuyi shen song Guo Sining Chen Jinhua Zhao Nanjing University of Science&Technology Nanjing 210094China China Academy of Safety Science and Technology Beijing 100012China

Recently,azobenzene-4,4'-dicarboxylic acid(ADCA)has been produced gradually for use as an organic synthesis or pharmaceutical intermediate due to its eminent *** large quantities put into application in the future,the thermal stability of this substance during storage,transportation,and use will become quite ***,in this work,the thermal decomposition behavior,thermal decomposition kinetics,and thermal hazard of ADCA were *** were conducted by using a SENSYS evo DSC device.A combination of differential iso-conversion method,compensation parameter method,and nonlinear fitting evaluation were also used to analyze thermal kinetics and mechanism of ADCA *** results show that when conversion rate α increases,the activation energies of ADCA's first and main decomposition peaks *** amount of heat released during decomposition varies between 182.46 and 231.16 J·g^(-1).The proposed kinetic equation is based on the Avrami-Erofeev model,which is consistent with the decomposition *** the Frank-Kamenetskii model,a calculated self-accelerating decomposition temperature of 287.0℃is obtained.

关键词： Azobenzene-4,4′-dicarboxylic acid Thermal decomposition behavior Kinetic mechanism Thermal hazard evaluation Compensation parameter effect

拦截高超声速飞行器的三维有限时间制导律设计

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中国惯性技术学报 2017年第3期25卷 405-414页

作者：司玉洁宋申民哈尔滨工业大学控制理论与制导技术研究中心哈尔滨150001

由于高超声速飞行器具有飞行速度快、机动能力强等特点,因此,传统的制导方式难以保证拦截弹拦截高超声速飞行器时的制导精度。为了减小弹目相对速度,降低对拦截弹的过载能力要求,按照前向制导方式,设计了有限时间收敛的三维前向滑模制... 详细信息

由于高超声速飞行器具有飞行速度快、机动能力强等特点,因此,传统的制导方式难以保证拦截弹拦截高超声速飞行器时的制导精度。为了减小弹目相对速度,降低对拦截弹的过载能力要求,按照前向制导方式,设计了有限时间收敛的三维前向滑模制导律。该制导律采用了连续的快速双幂次趋近律,不仅保证收敛速度快,同时削弱了传统制导律中存在的抖振现象。在此基础上为了处理系统扰动的上界未知的问题,又设计了自适应滑模制导律,该制导律既可以处理未知上界的外部扰动又可以保证第一种制导律所具有的良好特性。运用李雅普诺夫稳定性理论对所设计的滑模制导律进行了理论证明,最后,通过数值仿真验证了所设计制导律的有效性及优越性。

关键词：高超声速飞行器前向制导滑模制导律输入受限三维导引律自适应方法

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具有乘性噪声和随机量测时滞的目标跟踪算法

中国惯性技术学报 2017年第1期25卷 128-135页

作者：吴骁航宋申民哈尔滨工业大学控制理论与制导技术研究中心哈尔滨150001

针对在机动目标跟踪过程中产生的乘性量测噪声与随机量测时滞问题,提出了一种改进的高斯滤波(GF)算法,并给出了该算法的一种具体实现形式——随机时滞和乘性噪声容积卡尔曼滤波器(CKF-RDMN)。首先,利用一组满足伯努利分布的随机序列描... 详细信息

针对在机动目标跟踪过程中产生的乘性量测噪声与随机量测时滞问题,提出了一种改进的高斯滤波(GF)算法,并给出了该算法的一种具体实现形式——随机时滞和乘性噪声容积卡尔曼滤波器(CKF-RDMN)。首先,利用一组满足伯努利分布的随机序列描述随机出现的量测时滞现象。其次,利用乘性噪声满足高斯条件分布的特性,改进量测更新过程。最后依据三阶球径容积法则,对高斯积分进行求解。由于该算法是对经典GF算法的改进,因此,也可作为通用的滤波框架解决上述问题。通过与推广无迹卡尔曼滤波和推广扩展卡尔曼滤波对比,仿真结果表明,CKF-RDMN在解决乘性量测噪声与随机量测时滞问题时,具有更高的估计精度。

关键词：高斯滤波容积卡尔曼滤波乘性噪声随机时滞

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基于容积卡尔曼滤波的卫星姿态估计

宇航学报 2013年第2期34卷 193-200页

作者：魏喜庆宋申民哈尔滨工业大学控制理论与制导技术研究中心哈尔滨150001

为了获得更好的估计精度和滤波稳定性,提出了一种基于容积卡尔曼滤波(Cubature Kalman Filter,CKF)的容积四元数估计器(Cubature Quaternion Estimator,CQE)估计卫星姿态。新方法利用四元数进行姿态更新,同时采用广义罗德里格参数表示... 详细信息

为了获得更好的估计精度和滤波稳定性,提出了一种基于容积卡尔曼滤波(Cubature Kalman Filter,CKF)的容积四元数估计器(Cubature Quaternion Estimator,CQE)估计卫星姿态。新方法利用四元数进行姿态更新,同时采用广义罗德里格参数表示误差角,有效地避免了滤波过程中的奇异。为克服多传感器融合时运算效率低的问题,通过容积四元数估计器与信息滤波相结合,提出了一种容积信息四元数估计器(Cubature Information Quaternion Estimator,CIQE)。仿真表明角度和陀螺漂移初始估计误差较大时,新方法仍能取得良好的估计性能。

关键词：姿态估计容积卡尔曼滤波容积四元数估计器容积信息四元数估计器

Regulation and application of supramolecular gel with circularly polarized luminescence

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Science China Chemistry 2024年第6期67卷 1865-1880页

作者： shen song Yulong Shi Liangliang Zhu Bingbing Yue School of Materials and Chemistry&Institute of Bismuth and Rhenium University of Shanghai for Science and TechnologyShanghai200093China State Key Laboratory of Molecular Engineering of Polymers Fudan UniversityShanghai200438China

Supermolecular gel is a three-dimensional network structure assembled by small molecules or polymers in solvents through noncovalent *** emergence of system complexity occurs spontaneously during the molecular self-assembly process.A multitude of chiral molecular self-assembly systems have been engineered,facilitating the achievement of circularly polarized luminescence(CPL)through the amalgamation of chiral entities with *** bonding,π-πstacking,and noncovalent forces,such as host-guest interactions and Van der Waals'forces,confer upon supramolecular gels the capacity to react to diverse *** to the flexibility of supramolecular assembly,the CPL properties of supramolecular gels have rich controllability and can be used in various *** this review,we summarized the examples of CPL-active supramolecular gel assembly,and further summarized the assembly environment factors and external ***,the versatility of CPL applications in supramolecular gels is demonstrated,ranging from optical devices,information encryption,biosensing and chemical sensing,and other practical *** conclusion,the study provides insights into the multicultural factors influencing CPL in supramolecular gels,describes their applications in various domains,and presents future perspectives in the field.

关键词： supramolecular gels circularly polarized luminescence self-assembly chirality stimuli-response