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Evaluation of the Oxidation Reactivity and Behavior of Exhaust Soot Particles from Diesel Engines with Different Emission Levels

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China Petroleum Processing & Petrochemical Technology 2024年第2期26卷 72-80页

作者： Wang Yajun Lin Lei Xing Jianqiang LüXu Yang He song haiqing SINOPEC Research Institute of Petroleum Processing Co. Ltd.Beijing 100083China State Key Laboratory of Engines Tianjin UniversityTianjin 300072China

The aim of this study was to investigate the oxidation reactivity and behavior of exhaust particulate matter(PM)from diesel *** samples from two diesel engines(1K,CY4102)with different emission levels were collected by a thermophoretic system and a quartz *** oxidation reactivity,oxidation behaviors,and physicochemical properties of the PM samples were analyzed using thermogravimetric analysis(TGA),high-resolution transmission electron microscopy(HRTEM),Fourier-transform infrared spectrometry(FTIR),and Raman *** results showed that there was a great difference in the oxidation reactivity of soot particles emitted by the two different diesel engines.A qualitative analysis of the factors influencing oxidation reactivity showed that the nanostructure,degree of graphitization,and relative concentration of aliphatic C—H functional groups were the most important factors,whereas no significant correlation was found between the primary particle size and activation energy of the diesel *** on the oxidation behavior analysis,the diesel soot particles exhibited both internal and surface oxidation modes during the oxidation *** oxidation was dominant during the initial stage,and as oxidation progressed,the mode gradually changed to internal *** oxidation mode of soot particles from the 1K engine was significantly higher than that of CY4102.

关键词： diesel engine soot particles oxidation reactivity oxidation behavior

Disruption of cyclin D1 degradation leads to the development of mantle cell lymphoma

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Acta Pharmaceutica Sinica B 2024年第7期14卷 2977-2991页

作者： Ke Lu Ming Zhang Hongyu Qin Siyu Shen haiqing song Hua Jiang Chunxiang Zhang Guozhi Xiao Liping Tong Qing Jiang Di Chen Research Center for Computer-aided Drug Discovery Shenzhen Institute of Advanced TechnologyChinese Academy of SciencesShenzhen 518055China Faculty of Pharmaceutical Sciences Shenzhen Institute of Advanced TechnologyShenzhen 518055China Oncology Department Johns Hopkins University School of MedicineBaltimoreMD 21205USA Division of Spine Surgery the First Affiliated Hospital of Guangxi Medical UniversityNanning 530021China Division of Sports Medicine and Adult Reconstructive Surgery Department of Orthopedic SurgeryNanjing Drum Tower HospitalAffiliated Hospital of Medical SchoolState Key Laboratory of Pharmaceutical BiotechnologyNanjing UniversityNanjing 210008China Wenzhou Institute University of Chinese Academy of SciencesWenzhou 325000China Department of Cardiology Basic Medicine Innovation Center for Cardiometabolic Diseases of Ministry of EducationInstitute of Cardiovascular Researchthe Affiliated HospitalSouthwest Medical UniversityLuzhou 646000China School of Medicine Southern University of Science and TechnologyShenzhen 518055China

Cyclin D1 has been recognized as an oncogene due to its abnormal upregulation in different types of ***,we demonstrated that cyclin D1 is SUMOylated,and we identified Itch as a specific E3 ligase recognizing SUMOylated cyclin D1 and mediating SUMO-induced ubiquitination and proteasome degradation of cyclin *** generated cyclin D1 mutant mice with mutations in the SUMOylation site,phosphorylation site,or both sites of cyclin D1,and found that double mutant mice developed a Mantle cell lymphoma(MCL)-like *** showed that arsenic trioxide(ATO)enhances cyclin D1 SUMOylation-mediated degradation through inhibition of cyclin D1 deSUMOylation enzymes,leading to MCL cell *** of severe combined immunodeficiency(SCID)mice grafted with MCL cells with ATO resulted in a significant reduction in tumor *** this study,we provide novel insights into the mechanisms of MCL tumor development and cyclin D1 regulation and discover a new strategy for MCL treatment.

关键词： Cyclin D1 SUMOylation Mantle cell lymphoma Arsenic trioxide SENP2 Proteasome degradation

公路隧道喷射型ECC物理力学性能及其喷层稳定性

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工程科学与技术 2024年第3期56卷 109-121页

作者：胡时李晓芳蔡海兵韩辰悦宋海清安徽理工大学土木建筑学院安徽淮南232001 清华大学山西清洁能源研究院山西太原030032 同济大学土木工程学院上海200092 安徽文达信息工程学院城市建设学院安徽合肥231201

传统纤维增强水泥基复合材料(ECC)存在成本高、收缩大和应用场景局限等问题,且关于开挖扰动下公路隧道喷射型ECC层稳定性的研究尚不完善,此外缺乏对其工程应用后的监测评估。基于此,本文研究了公路隧道喷射型ECC的物理力学性能,分析了... 详细信息

传统纤维增强水泥基复合材料(ECC)存在成本高、收缩大和应用场景局限等问题,且关于开挖扰动下公路隧道喷射型ECC层稳定性的研究尚不完善,此外缺乏对其工程应用后的监测评估。基于此,本文研究了公路隧道喷射型ECC的物理力学性能,分析了开挖扰动下围岩及喷射型ECC层的稳定性,并通过现场监测分析了其应用效果。结果表明:将脱硫石膏、混杂纤维、机制砂、膨胀剂和减缩剂引入ECC中,所研发的喷射型ECC物理力学性能满足公路隧道喷射混凝土的要求。基于数值模拟,当支护12 m后,喷射型ECC层的拉伸和压缩最大主应力较C25喷射混凝土(C25SC)层分别提高了36.8%、28.4%,并且其内侧拱顶的最大竖向位移较C25SC可降低3.15%,仅为1.23 mm。基于现场实测,在近似相同的围岩地质条件下,使用喷射型ECC较C25SC,能够降低10.26%的竖直沉降变形,此外其喷层表面未发现开裂、线状渗水等情况。因此,喷射型ECC在公路隧道支护领域具有广阔的应用前景。

关键词：喷射型ECC 公路隧道物理力学性能数值模拟稳定性

2000-2020年内蒙古NDVI时空动态及其对水热条件的响应

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水土保持研究 2024年第4期31卷 197-204,213页

作者：皇彦宋海清胡琦吴昊卢佳玥李碧云乌兰察布市气象局内蒙古乌兰察布012000 内蒙古自治区生态与农业气象中心呼和浩特010051 中国农业大学资源与环境学院北京100193

[目的]了解植被生态现状,剖析植被变化影响因素,为区域生态环境治理和规划提供科学依据。[方法]基于MOD13A3 NDVI数据和气象数据,采用Sen趋势分析、M-K检验、Hurst指数、相关系数等方法研究了内蒙古地区NDVI时空变化及其对水热条件的响... 详细信息

[目的]了解植被生态现状,剖析植被变化影响因素,为区域生态环境治理和规划提供科学依据。[方法]基于MOD13A3 NDVI数据和气象数据,采用Sen趋势分析、M-K检验、Hurst指数、相关系数等方法研究了内蒙古地区NDVI时空变化及其对水热条件的响应。[结果]内蒙古NDVI显著增长(p<0.01),空间分布呈东高西低的特征,大部分地区NDVI以增加趋势为主,耕地增长率最大且呈增加趋势面积占比最大。研究期内NDVI变化相对稳定,林地的稳定性最好。未来内蒙古NDVI变化以反持续性为主,反持续性和持续性面积占比分别为76.51%,23.49%。NDVI与气温呈负相关的区域占78.25%,其中极显著和显著负相关的区域占19.92%;与降水、土壤湿度呈正相关的区域占93.16%,93.53%,其中极显著和显著正相关的区域分别占51.37%,55.85%。[结论]内蒙古地区植被生态整体趋于改善,未来植被生态可能退化,土壤湿度是影响内蒙古植被生长的主导因子。

关键词： NDVI 时空变化水热条件内蒙古

工业广场保护煤柱开采井筒破损致因及防治技术

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煤炭工程 2024年第5期56卷 42-50页

作者：程桦喻宏宋海清成浪荣传新姚直书彭世龙安徽理工大学土木建筑学院安徽淮南商232001 安徽大学资源与环境工程学院安徽合肥230022 冀中能源峰峰集团有限公司大社矿河北邯郸β056008 安徽建筑大学建筑结构与地下工程安徽省重点实验室安徽合肥230022

针对工业广场保护煤柱开采导致井筒破损的问题,以大社煤矿为工程背景,分析工广煤柱开采井筒围岩移动变形特征,揭示井筒破损致因;提出工广内后续工作面开采防治井筒破坏方案,形成相应的施工技术,并成功应用工程实践。研究表明:该矿工广内... 详细信息

针对工业广场保护煤柱开采导致井筒破损的问题,以大社煤矿为工程背景,分析工广煤柱开采井筒围岩移动变形特征,揭示井筒破损致因;提出工广内后续工作面开采防治井筒破坏方案,形成相应的施工技术,并成功应用工程实践。研究表明:该矿工广内92606工作面邻近副井,开采引发的井筒竖向附加力是井筒破坏的致因;如不提前采取防治措施,后续92606外工作面开采,将导致副井井筒发生二次破坏;研究提出的不停产单卸压槽防治方案,具有不影响矿井生产、卸压率高、施工简单、成本低等优点。采用壁后注浆、开切卸压槽、架设密集井圈等技术,顺利完成了该矿不停产防治副井井筒破损工程。监测表明,该井筒竖向和环向应力,均小于井壁极限.承载力,处于安全状态,运行良好,达到了预期效果。

关键词：工业广场保护煤柱地层沉降井壁破损卸压槽围岩控制

Effects of Gasoline with Ester Additives on the Swelling Behavior of Rubbers

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China Petroleum Processing & Petrochemical Technology 2018年第1期20卷 44-51页

作者： Wang Pengfei Yang He song haiqing Zhang Jianrong SINOPEC Research Institute of Petroleum Processing Beijing 100083

In this study, gasoline was blended with dimethyl carbonate, ethyl acetate or methyl acetate respectively with four different volume fraction, i.e. 1%, 3%, 5% and 10%. The nitrile-butadiene rubber (NBR), fluorocarbon rubber (FKM), and Silastic were prepared for the immersion tests. To assess the performance of the three ester additives, the changes in the weight and volume of these three elastomers during the immersion tests with different gasoline samples were studied. The results showed that gasoline blended with the ester additives could lead to serious swelling problem for the elastomer materials which were widely used in the vehicle manufacture industry. The seal ability of elastomer materials would also be impaired by being exposed in the ester additives-gasoline blending for a long time.

关键词： gasoline ester additives swelling problem

Constant Volume Spray Auto-ignition Study of Alkanes

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China Petroleum Processing & Petrochemical Technology 2019年第1期21卷 71-79页

作者： Wang Jun Yang He song haiqing Tian Huayu Wang Pengfei SINOPEC Research Institute of Petroleum Processing

Spray auto-ignition experiments were carried out in a constant volume combustion chamber for some pure alkanes(n-paraffins with different chain length, cyclohexane, n-butyl cyclohexane, and isooctane) and blends of n-decane with Standard Blended Fuel(isooctane/n-heptane) and product gasoline. Test results showed that the reaction activity of n-paraffins was relatively high. Meanwhile, the auto-ignition characteristics differed significantly with the molecular structures of alkanes. Adding different volume fractions of n-decane to Standard Blended Fuel and product gasoline could improve the fuel reaction activity at varying degree. Finally, functional groups effects were used to simulate the relationship between the molecular topology and the auto-ignition quality.

关键词： spray auto-ignition reaction activity functional group alkane

Study on Tribology Performance of Different Lubricant Additives under Atmospheric Pressure and High Vacuum Conditions

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China Petroleum Processing & Petrochemical Technology 2016年第4期18卷 81-91页

作者： Peng Qian Huang Zhiyang Yang He song haiqing Zhang Jianrong Research Institute of Petroleum Processing SINOPEC

By using PAO-10 as the base oil, the tribological behavior of 11 additives under high vacuum condition was evaluated. By adopting some surface analytical instruments, such as scanning electron microscopy(SEM), energy dispersive spectroscopy(EDS) and X-ray photoelectron spectroscopy(XPS), the tribological mechanisms of these additives were studied. In air, O_2 can react with metal to form metal oxide that can protect the surfaces of rubbing pair during the tribological tests. According to the theory of the competitive adsorption, the function of some active elements is weakened. In a vacuum environment, the additives contributed more to the lubrication performance. The sulfur-containing additives could react with Fe to produce Fe Sx and "M—C" bonds("M" represents metal). They both had contributions to the lubrication. As for the phosphorus-containing additives, they only generated the phosphates during the tests. When the sulfur and phosphorus-containing additives were applied, the generated phosphates and Fe Sx had the primary contribution to the lubrication performance during the tests.

关键词： anti-wear additive high vacuum lubrication mechanism anti-wear properties friction reducing properties

Influence of Ethanol Addition on the Spray Auto-ignition Properties of Gasoline and Its Relationship with Octane Number

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China Petroleum Processing & Petrochemical Technology 2022年第2期24卷 68-75页

作者： Wang Jun Yang He Hu Xiaoming song haiqing Zhang Ran Tian Huayu SINOPEC Research Institute of Petroleum Processing Beijing 100083

In this study,the spray auto-ignition properties of binary primary reference fuels(PRFs)of 2,2,4-trimethylpentane and n-heptane with different research octane numbers(RONs)were measured according to the industry standard NB/SH/T 6035 to determine their ignition delay times at various initial ***,the auto-ignition properties were investigated after blending the PRFs with various amounts of *** results revealed a very good correlation between the derived cetane number and the RON for the PRFs in both the presence and absence of *** addition,a concept of ignition delay sensitivity was developed for ethanol-containing fuels that exhibited a close relationship with the octane sensitivity,which is defined as the RON minus the motor octane number(MON).Finally,the developed method was applied to conveniently estimate the RON and MON values of several ethanol-containing fuels by simply measuring their auto-ignition properties.

关键词： ethanol spray auto-ignition ignition delay octane number sensitivity